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Chapter Fourteen
Some Compounds with
Oxygen, Sulfur, or a Halogen
James E. Mayhugh
Oklahoma City University
2007 Prentice Hall, Inc.
Outline
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14.6 Phenols
Phenol is the name both of a specific compound,
hydroxybenzene, and of a family of compounds.
Phenols are usually named with the ending -phenol
rather than -benzene even though their structures
include a benzene ring.
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14.8 Ethers
Ethers, compounds with two organic groups bonded
to the same O atom, are named by identifying the
two organic groups and adding the word ether.
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14.10 Halogen-Containing
Compounds
Alkyl halides, R-X, have an alkyl group, R, bonded
to a halogen, X. Their common names consist of the
name of the alkyl group followed by the halogen
name with an -ide ending. Systematic names
consider the halogen atom as a substituent on a
parent alkane.
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Chapter Summary
An alcohol has an OH group bonded to a saturated,
alkane-like carbon atom; a phenol has an OH group
bonded directly to an aromatic ring; and an ether has an
oxygen atom bonded to two organic groups.
Phenols are notable for their use as disinfectants and
antiseptics; ethers are used primarily as solvents.
Thiols are sulfur analogs of alcohols, with unpleasant
odors. Thiols are found in proteins.
Alkyl halides contain a halogen atom bonded to an alkyl
group. Halogenated compounds are widely used in
industry as solvents and in agriculture as herbicides,
fungicides, and insecticides.
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End of Chapter 14
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