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Announcements

Discovery has started! Dont forget to


go!
The tutorial center is open (MEYR 145).
Exam 1 is 2 weeks from Friday.

For most solids, solubility increases as


temperature increases.
A. True
B. False

For which of the following does pressure


influence solubility?
A. Solid dissolving in a liquid
B. Gas dissolving in a liquid
C. Liquid dissolving in a liquid
D. All of the above.
E. None of the above.

Which of the following interactions are


important in forming a solution?
A. Solute-solvent
B. Solvent-solvent
C. Solute-solute
D. All of the above.
E. None of the above.

What is the most important factor in


determining the formation of a solution?
A. Intramolecular forces
B. Intermolecular forces
C. Water

When/why does a solution form?

Cg = k P g
6

Predict whether C7H16 is more likely to


dissolve in carbon tetrachloride or in water.
A. H2O
B. CCl4

Predict whether Na2SO4


is more likely to dissolve in carbon
tetrachloride or in water.
A. H2O
B. CCl4

Indicate the type of solute-solvent


interaction that should be most important
in a solution of hexane (C6H14) in benzene
(C6H6).
A. LDF
B. H-bonding
C. Dipole-dipole
D. Ion-dipole

Indicate the type of solute-solvent


interaction that should be most important
in a solution of propanol (CH3CH2CH2OH)
in water.
A. H-bonding
B. Ion-dipole
C. Dipole-dipole
D. LDF

10

Calculate the concentration of CO2 in a soft


drink that is bottled with a partial pressure of
4.0 atm over the liquid at 25C. For CO2 in
water at this temp., k = 3.1 x 10-2 mol/L-atm.
A.
B.
C.
D.

2.6 M
1.7 M
0.59 M
0.12 M

11

The concentration of CO2 in a soft drink under a


pressure of 2.3 atm is 0.071 M. Calculate the
concentration of CO2 in a soft drink after the
bottle is opened and equilibrates at the same
temperature under a CO2 partial pressure of 3.0
x 10-4 atm.
A.
B.
C.
D.

6.1 x 10-5 M
2.7 x 10-6 M
8.4 x 10-5 M
9.3 x 10-6 M

12

The partial pressure of O2 in air at sea level is 0.21


atm. Use Henrys Law (k = 1.38x10-3 M/atm) to calculate
the molar concentration of O2 in the surface water of a
mountain lake saturated with air at 20C and
atmospheric pressure of 665 torr.

A.
B.
C.
D.

2.5 x 10-4 M
1.2 x 10-3 M
2.9 x 10-4 M
7.3 x 10-3 M

13

14

Announcements
Discovery has started! Dont forget to
go!
The tutorial center is open (MEYR 145).
Exam 1 is 2 weeks from Friday.

15

For most solids, solubility decreases as


temperature increases.
A. True
B. False

16

For which of the following does pressure


influence solubility?
A. Solid dissolving in a liquid
B. Gas dissolving in a liquid
C. Liquid dissolving in a liquid
D. All of the above.
E. None of the above.

17

Which of the following interactions are


important in forming a solution?
A. Solute-solvent
B. Solvent-solvent
C. Solute-solute
D. All of the above.
E. None of the above.

18

What is the most important factor in


determining the formation of a solution?
A. Intramolecular forces
B. Intermolecular forces
C. Water

19

When/why does a solution form?

Cg = k P g
20

Predict whether methanol (CH3OH)


is more likely to dissolve in carbon
tetrachloride or in water.
A. H2O
B. CCl4

21

Predict whether I2
is more likely to dissolve in carbon
tetrachloride or in water.
A. H2O
B. CCl4

22

Indicate the type of solute-solvent


interaction that should be most important
in a solution of CaCl2 in water.
A. LDF
B. H-bonding
C. Dipole-dipole
D. Ion-dipole

23

Calculate the concentration of CO2 in a soft


drink that is bottled with a partial pressure of
4.0 atm over the liquid at 25C. For CO2 in
water at this temp., k = 3.1 x 10-2 mol/L-atm.
A.
B.
C.
D.

2.6 M
1.7 M
0.59 M
0.12 M

24

The concentration of CO2 in a soft drink under a


pressure of 2.3 atm is 0.071 M. Calculate the
concentration of CO2 in a soft drink after the
bottle is opened and equilibrates at the same
temperature under a CO2 partial pressure of 3.0
x 10-4 atm.
A.
B.
C.
D.

6.1 x 10-5 M
2.7 x 10-6 M
8.4 x 10-5 M
9.3 x 10-6 M

25

The partial pressure of O2 in air at sea level is 0.21


atm. Use Henrys Law (k = 1.38x10-3 M/atm) to calculate
the molar concentration of O2 in the surface water of a
mountain lake saturated with air at 20C and
atmospheric pressure of 665 torr.

A.
B.
C.
D.

2.5 x 10-4 M
1.2 x 10-3 M
2.9 x 10-4 M
7.3 x 10-3 M

26

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