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PERIODIC TABLE
Lecturer:
Nor Fadilah Chayed
CLASSIFICATION OF ELEMENTS
in
increasing
atomic
Categories of Electrons
Inner (core) electrons are those an atom has in common
with the previous noble gas and any completed transition
series.
Outer electrons are those in the highest energy level
(highest n value).
Valence electrons are those involved in forming
compounds.
- For main group elements, the valence electrons are the outer
electrons.
- For transition elements, the valence electrons include the outer
electrons and any (n -1)d electrons.
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metallic properties
B, Si, Ge, As, Sb, Te, Po and At
9
11
12
(b) Period
Horizontal bars,
Each period consists of elements that have the same
13
15
ns2np6
ns2np5
ns2np4
ns2np3
ns2np2
ns2np1
d10
d5
d1
ns2
ns1
4f
5f
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Na : [Ne]
+
Al3+: [Ne]
Atoms lose
electrons so that
cation has a
noble-gas outer
electron
configuration.
-1
-2
-3
+3
+2
+1
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Fe:
[Ar]4s23d6
Mn:
[Ar]4s23d5
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Problem 1
Determine the period, block and group for each element with the following
configuration:
A: 1s2 2s2 2p3
B: 1s2 2s2 2p6 3s2 3p6
C: 1s2 2s2 2p6 3s2
D: 1s2 2s2 2p6 3s2 3p6 4s2 3d3
Answer:
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Metallic Behavior
Metallic character decreases across a period (increase non
metallic character) and increase down a group.
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Periodic Physical
Properties
The periodic law: When elements are arranged in the
periodic table in order of increasing atomic number, a regular
change in the outer electronic configuration and a periodic
variation of properties is observed.
The following physical properties show a periodic trend:
1. Atomic size
2. Ionization energy
3. Electron affinity
4. Electronegativity
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1. Atomic size
The atomic radius
= of the distance between 2 nuclei of two adjacent atoms
=d
Screening effect
The atomic radius increase downwards in a group.
Electrons fill up a new shell downwards. Outer electrons are
shielded from the nucleus by electrons in inner shells
(mutual repulsions between electrons in different shell) and
are less tightly held.
Nucleus charge
The atomic radius decrease towards the right across a
period.
Electrons fill up the same shell, cause the effective nuclear
charge (Zeff) of the atom increases which pulls all electrons
closer to nucleus, thus the electrons are held more tightly.
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Core
Zeff
Radius
Na
11
10
186
Mg
12
10
160
Al
13
10
143
Si
14
10
132
As the distance
from nucleus
increases,
increases and
Zeff decreases
8.3
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increasing Zeff
increasing Zeff
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8.3
28
Reason:
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Size of cations
Ionic Radius
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31
32
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Isoelectronic ions
Isoelectronic: a series of ions or atoms which have the same
Ne : 1s22s22p6
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(b) K, Ga, Ca
Answer:
35
Answer:
36
2. Ionization energy
Ionization energy is the minimum energy (kJ/mol)
required to remove an electron from a gaseous atom in its
ground state.
I1 + X (g)
X+(g) + e-
I2 + X (g)
X2+(g) + e-
I3 + X (g)
X3+(g) + e-
I1 < I2 < I3
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H1 = +X kJ mol-1
H2 = +Y kJ mol-1
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41
42
Answer:
43
3. Electron affinity
F (g) + e-
F-(g)
HEA = -A kJ mol-1
H = -328 kJ/mol
EA = +328 kJ/mol
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General trend:
46
47
48
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4. Electronegativity
The higher the electronegativity of an atom, the greater its attraction for
bonding electrons.
General trend:
In a group (downwards) the electronegativity
decrease.
Reason: Increased distance between the valence
electrons and the nucleus weakens the pull of the
nucleus on the electrons.
The a period (towards the right), the electronegativity
increase.
Reason: Decreased distance between the valence
electrons and the nucleus, thus stronger pull of the
nucleus on the electrons.
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TOP TO BOTTOM
(Down the group)
Atomic Radius
Decreases
Increases
Ionization energy
Increases
Decreases
Electron affinity
Increases
(more ve)
Decreases
(less ve)
Electronegativity
Increases
Decreases
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