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(DMC)
Why arent You using it?
Kowa American Corp.
www.chemical.kowa.com
212-303-7800
July 2013
DMC Structure
Dimethyl Carbonate CAS # 616-38-6
DMC Introduction
DMC is an inexpensive oxygenated solvent
with excellent solubility properties, that can
solve almost all coating resins.
DMC is now cheaper than MEK, Ethyl
Acetate, MIBK, Butyl Acetate and most
other Ketones and Glycol Ethers.
DMC is price competitive with acetone,
toluene, ethanol and mineral spirits
DMC Supply
Drums and bulk isotanks readily available
from multiple factories in China.
DMC is used in very large volumes in
China for coatings primarily because of its
low cost.
Totes can be filled from isotanks.
Long term a bulk tank in USA is possible
PCBTF Replacement
PCBTF is twice to 3 times the price of
DMC, PCBTF has an objectionable odor
DMC - Flammability
DMC has a flashpoint of 63F (17C)
Flammability will limit use in consumer
coatings, cleaning or indoor applications
Flammability risk still much lower than
acetone (-4 F), ethyl acetate (26F) or
MEK (26F), which DMC can readily
replace
Partially water soluble (up to 13 % in
water), which allows water to be more
effective in fighting DMC based fires.
DMC SCAQMD
South Coast AQMD (Los Angeles area) has
issued a proposed metal coatings rule 1107
allowing for no permit for volumes under
180,000 lbs per year, permits required for
above this threshold. There will be reporting
requirements for all users in SCAQMD.
After this rule has been approved, we will
request DMC to be exempted for all uses here,
since proposed rule treats DMC as safer to use
than TBAC (560 lb permit threshold)
Canada
Canada has a proposed rule under
development that updates their VOC
exempt list to be harmonized with the USA
VOC exempt list.
Proposed rule covers all of Canada, there
will no separate approval process needed
for each province.
Rule is expected to be out for public
comment in July
DMC Toxicity
DMC (like all methyl esters) rapidly deesterifies in the body to methanol & CO2
DMC has low acute oral toxicity (LD50 rat
12,900 mg/Kg, LD50 mouse 6,000 mg/Kg)
DMC was found to be negative in mutagenic
tests (in vitro Ames & comet assay)
Readily biodegradable and has low potential to
bio-accumulate or be persistent in environment
Not expected to be toxic to fish or bacteria
(possibly toxic to algae)
BENZOTRIFLUORIDE - BTF
Proposed VOC exempt solvent, EPA tabled
petition due to BTFs revised MIR values
(2.8) in 2009 being higher than ethane (2.7).
BTF is now allowed for aerosol coatings on
federal level (June 2012), and is still allowed
in Aerosol coatings in Calif. with a MIR
value or reactivity factor of .26 (2004 table).
BTFs similar solvency and evaporation rate
(BTF = 2.8 vs toluene = 2.0) to toluene
makes BTF a great replacement for toluene.
Boiling
point C
DMC
3.22
63
90
PCBTF
.9
109*
139
Acetone
5.6
-4
56.5
<.005
269.6
240
Prop Carb
tBAc
2.8
40
98
BTF
2.8
54
102
0.055
4.95
Ethane
0.26
7.8
Acetone
0.35
20.3
Methyl Acetate
0.067
5.2
Prop Carbonate
0.27
27.56
Benzotrifluoride
0.28
40.91