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Chemical Engineering
Thermodynamics II
Credit Hours
30
By
Dr. Qazi Nasir
Lecture # 1
In
nineteenth
century,
the
science
of
thermodynamic was born which describe the
operation of steam engines
The name was given as power developed from
heat is the main application of steam engine
The principle which
generalized as first
thermodynamics
valid
and
Pressure-volume-temperature
relationships
(PVT)
quantities
potential
are
called
useful
thermodynamic
in
the
chemical
experimentally
or
(1)
dQ = TdS
dU = TdS PdV
U = f(S, V)
(2)
(3)
(4)
Eq (3) and Eq (4) completely describe the
system once S and P are specified. It is
therefore, also a fundamental equation