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H O H O
2 R N H + Cl C CH 3 R N C CH3 + HCl
1o amine 2o amide
R O R O
2 R N H + Cl C CH3 R N C CH3 + HCl
2o amine 3o amide
R O O R O
R N H + R N C CH3 + CH3COO H
CH 3 C O C CH 3
2o amine acid anhydride 3o amide
Hinsberg’s test
19.5 2° amines
Reaction with : Benzenesulphonyl chloride reacts with a
2° amines to form a white precipitate
Acyl chloride (N,N-disubstituted sulphonamide)
R' O R' O
Acid anhydride -
OH
Benzenesulphonyl R-N-H
+
Cl-S- R-N -S-
chloride (-HCl)
o O
2 amine O
N,N-disubstituted
Nitrous acid
benzenesulphonamides
Bromine water (precipitate)
N,N-disubstituted sulphonamides do not
No reaction
have an acidic hydrogen, N-H.NaOH
Formation of dye Therefore, it dissolve in aqueous NaOH.
3° amines
Observation : C=C +
ROH +
RX
Formation of gas bubbles
(N2)
1° amines (Aromatic)
NH2 N2+Cl−
NaNO2, HCl
+ NaCl + H2O
cold
arenediazonium salt
1° aliphatic amines and 2° aliphatic amines
Identification
Aniline reacts with aqueous bromine to test
yield white precipitates
3Br2(aq) Br Br
Br
(2,4,6-tribromoaniline)
(orange)
+
-
N N: X CH3
CH3
(yellow)