Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Covalent Compounds
6.5
Electronegativity and
Bond Polarity
6.6
Polarity of Molecules
Electronegativity
Electronegativity values:
Indicate the attraction of an atom for shared
electrons
Increase from left to right going across a period on
the periodic table
Is high for the nonmetals with fluorine as the
highest
Is low for the metals
Low
values
Copyright 2005 by Pearson Education, Inc.
Publishing as Benjamin Cummings
Type of Bond
Nonpolar covalent
Nonpolar covalent
Nonpolar covalent
Type of Bond
Polar covalent
Polar covalent
Polar covalent
5
Ionic Bonds
An ionic bond,
Occurs between metal and nonmetals ions
Is a results of electron transfer
Has a large electronegativity difference (1.8 or more)
Examples:
Atoms
Electronegativity
Difference
Cl-K
3.0 0.8
= 2.2
N-Na
3.0 0.9
= 2.1
S-Cs
2.5 0.7
= 1.8
Type of Bond
Ionic
Ionic
Ionic
Learning Check
Use the electronegativity difference to identify the
type of bond between the following as:
nonpolar covalent (NP), polar covalent (P), or
ionic (I).
A.
B.
C.
D.
K-N
N-O
Cl-Cl
H-Cl
10
Solution
Use the electronegativity difference to identify the
type of bond between the following as:
nonpolar covalent (NP), polar covalent (P), or
ionic (I).
A.
B.
C.
D.
K-N
N-O
Cl-Cl
H-Cl
2.2
0.5
0.0
0.9
ionic (I)
polar covalent (P)
nonpolar covalent (NP)
polar covalent (P)
11
Polar Molecules
A polar molecule,
Contains polar bonds
Cl
dipoles do not cancel
12
Nonpolar Molecules
A nonpolar molecule,
Contains nonpolar bonds
ClCl
HH
Cl
ClCCl
Cl
dipoles cancel
13
..
HO:
H2O is polar
H
dipoles do not cancel
14
Learning Check
Identify each of the following molecules as:
1) polar or 2) nonpolar. Explain.
A.
PBr3
B.
HBr
C.
Br2
D.
SiBr4
15
Solution
Identify each of the following molecules as:
1) polar or 2) nonpolar. Explain.
A.
PBr3
B.
C.
HBr
Br2
D.
SiBr4
16