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Acids:
acids are sour tasting
Arrhenius acid: Any substance that, when dissolved
in water, increases the concentration of hydronium
ion (H3O+)
Bronsted-Lowry acid: A proton donor
Lewis acid: An electron acceptor
Bases:
bases are bitter tasting and slippery
Arrhenius base: Any substance that, when dissolved
in water, increases the concentration of hydroxide
ion (OH-)
Bronsted-Lowery base: A proton acceptor
Lewis acid: An electron donor
General Equation
Reversible reaction
ELECTROLYTES
Electrolytes are species which conducts electricity when
dissolved in water. Acids, Bases, and Salts are all
electrolytes.
Salts and strong Acids or Bases form Strong
Electrolytes. Salt and strong acids (and bases) are fully
dissociated therefore all of the ions present are
available to conduct electricity.
HCl(s) + H2O H3O+ + ClWeak Acids and Weak Bases for Weak Electrolytes.
Weaks electrolytes are partially dissociated therefore
not all species in solution are ions, some of the
molecular form is present. Weak electrolytes have
less ions avalible to conduct electricity.
NH3 + H2O NH4+ + OH-
_ strong electrolyte
_ ionic/very polar bonds
bonds
Strong Acids:
HClO4
H2SO4
HI
HBr
HCl
HNO3
vs
WEAK
_ partially ionized
_ weak electrolyte
_ some covalent
Strong Bases:
LiOH
NaOH
KOH
Ca(OH)2
Sr(OH)2
Ba(OH)2
2H
2
4
4
+
2HSO4 H + SO4
Three ionizable protons:
H3PO4 H+ + H2PO4
Combined:
H2PO4- H+ + HPO42H3PO4 3H+ + PO43HPO42- H+ + PO4-3
a. Al(OH)3 + HCl
Weak base
Strong acid
b. Ba(OH)2 +
Strong base
HC2H3O2
Weak acid
c. KOH + H2SO4
Strong base Strong acid
d. NH3 + H2O
Weak base Weak acid
CA
CB
CA
CA
TITRATION
Titration of a strong acid with a strong base
nacid = nbase
Since M=n/V
MAVA = MBVB
TITRATION
MAVA = MBVB
1. Suppose 75.00 mL of hydrochloric acid was required to
neutralize 22.50 mLof 0.52 M NaOH. What is the molarity of
the acid?
HCl + NaOH H2O + NaCl
Ma Va = Mb Vb rearranges to Ma = Mb Vb / Va
so Ma = (0.52 M) (22.50 mL) / (75.00 mL)
= 0.16 M
TITRATION
Titration of a strong acid with a strong base
nacid = nbase
TITRATION
1. If 37.12 mL of 0.543 M LiOH neutralized 40.50 mL
of H2SO4, what is the molarity of the acid?
2 LiOH + H2SO4 Li2SO4 + 2 H2O
First calculate the moles of base:
0.03712 L LiOH (0.543 mol/1 L) = 0.0202 mol LiOH
Next calculate the moles of acid:
0.0202 mol LiOH (1 mol H2SO4 / 2 mol LiOH)= 0.0101 mol
H2SO4
Last calculate the Molarity:
Ma = n/V = 0.010 mol H2SO4 / 0.4050 L = 0.248 M
Water Equilibrium
Water Equilibrium
Kw = [H+] [OH-] = 1.0 x 10-14
Equilibrium constant for water
Water or water solutions in which [H+] = [OH-] = 10-7 M
are neutral solutions.
A solution in which [H+] > [OH-] is acidic
pH
A measure of the hydronium ion
The scale for measuring the hydronium ion concentration
[H3O+] in any solution must be able to cover a large range. A
logarithmic scale covers factors of 10. The p in pH stands for
log.
pH = - log [H3O+]
The pH scale
The pH scale ranges from 1 to 10-14 mol/L or from 1
to 14.
pH = - log [H3O+]
1 2 3 4 5 6 7 8 9 10 11 12 13 14
acid
neutral
base
Manipulating pH
Algebraic manipulation of:
pH = - log [H3O+]
allows for:
[H3O+] = 10-pH
If pH is a measure of the hydronium ion
concentration then the same equations could be
used to describe the hydroxide (base)
concentration.
[OH-] = 10-pOH
thus:
10.8 mL
0.0101 g
29.6 mL
5.623 x 10 M
pH = 4.0