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This document summarizes metallization techniques for crystalline silicon solar cells. It discusses the process of solar cell fabrication and different methods for pre-metallization patterning the anti-reflection coating. It then focuses on nickel and copper plating techniques, including electroless plating of a nickel seed layer and light-induced copper electroplating. Diagrams illustrate the chemical reactions and setup for these plating methods.
Descrizione originale:
this is an review of the Ni-Cu based front side metallization fabrication in C-Si Solar cells.
Titolo originale
Review of Ni-Cu Based Front Side Metallization for C-Si Solar Cells
This document summarizes metallization techniques for crystalline silicon solar cells. It discusses the process of solar cell fabrication and different methods for pre-metallization patterning the anti-reflection coating. It then focuses on nickel and copper plating techniques, including electroless plating of a nickel seed layer and light-induced copper electroplating. Diagrams illustrate the chemical reactions and setup for these plating methods.
This document summarizes metallization techniques for crystalline silicon solar cells. It discusses the process of solar cell fabrication and different methods for pre-metallization patterning the anti-reflection coating. It then focuses on nickel and copper plating techniques, including electroless plating of a nickel seed layer and light-induced copper electroplating. Diagrams illustrate the chemical reactions and setup for these plating methods.
Metallization for Crystallize Silicon Solar Cells Name: Vo Ngoc Phuong Anh Student ID number: 14110206 Contents Process of c-Si Solar Cell Fabrication Methods for Pre-metallization Ni and Cu Plating techniques References Process of c-Si Solar Cell Fabrication Solar Cell Manufacturing Process Flow Chart [1] Solar Cell Manufacturing Process [5] Process of c-Si Solar Cell Fabrication Solar cell structures composed of metallization scheme based on Ni/Cu/Ag plating [2], [4] Methods for Pre-metallization There are a number of method for Patterning the ARC [3]:
Etch Resist and Wet Etching Based Methods.
Direct Etching Based Methods.
Laser-Assisted Methods.
Mechanical Method for Patterning. Schematic mask and etch sequence. Mask patterning is done initially to open ARC followed by a process of photoresist removal [2] Ni and Cu Plating techniques The metallization technique involves two main steps [2]:
1. Ni Seed layer Formation.
2. Cu Electroplating technique.
Steps involved in formation of the metallization scheme based on Ni/Cu/Sn or Ag metallization scheme [2] Ni Seed layer formation Electroless plating [2]: The chemical reaction: Step 1: (anodic reactrion)
Step 2: (cathodic reaction)
Sum: Schematic of electroless plating setup [3] Ni Seed layer formation Light Induced Plating (LIP):
Schematic image of LIP system [6] Ni Seed layer formation Laser Assisted Ni Deposition:
Schematic image of LIP system [6] Cu Electroplating technique Cu electroplating is usually done by the LIP technique.
Reactions taking place at anode (Cu), electrolyte solution (H 2 SO 4 /CuSO 4 ) and cathode (substrate) Cu Electroplating technique Schematic diagram of the light induced plating (LIP) based Cu electroplating process References [1]. Annual Report on Form 10-K of Amtech Systems, Inc. (2007) [2]. Atteq ur Rehman and Soo Hong Lee, Review of the Potential of the Ni/Cu Plating Technique for Crystalline Silicon Solar Cells, Materials (2014), 7, 1318-1341. [3]. Mehul C. Raval and Chetan S. Solanki, Review of Ni-Cu Based Front Side Metallization for c-Si Solar Cells, Journal of Solar Energy (2013), Article ID 183812, 20 pages. [4]. Hariklia (Lili) Deligianni, Shafaat Ahmed, and Lubomyr T. Romankiw, The Next Frontier: Electrodeposition for Solar Cell Fabrication, The Electrochemical Society Interface (2011), 47-53. [5]. http://www.think-solar-power.com/Photovoltaic-Solar-Power.html [6]. J. Bartsch, A. Mondon, B.-J. Godejohann, M. Horteis, S.W. Glunz, Advanced Front Side Metallization for Crystalline Silicon Solar Cells Based on a Fully Planted Contact, Presentated at the 25th European PV Solar Energy Conference and Exhibition (2010).