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Carnot Refrigerator
Vapor-Compression Cycle
Absorption Refrigeration
Heat Pump
Liquefaction Processes
Refrigerator
9.1 The Carnot Refrigerator
In continuous refrigeration process, heat transfer is
continuous: the heat absorbed at low temperature is
continuously rejected to the surroundings at a higher
temperature
Refrigerator is a reversed heat engine, work is consumed
to transfer heat from a low temperature level to a high
temperature level
The ideal refrigerator, like the ideal heat engine, operates
on a Carnot cycle
TS Diagram of a Carnot Refrigerator
1 2
3
4
T
S
Coefficient of Carnot Refrigerator Performance
Calculated in Eq(9.3) is the maximum value of for the given T
H
and
T
C
conditions.
1. T
C
high, large
2. (T
H
T
C
) small, large
9.2 The Vapor-Compression Cycle
Const T/P
Const T/P
Const H
Coefficient of Performance of a Vapor
Compression Process
the small changes in kinetic energy and potential energy are negligible:
Heat adsorbed at low temperature and rejected at high temperature.
Q
H
= H
4
H
3
and Q
C
= H
2
H
1
The work of compression is:
W =H
3
H
2
coefficient of performance:
|Q
C
|
W
The Rate of Circulation of Refrigerant
The rate of circulation of refrigerant determines the
sizing of the evaporator, compressor, condenser, and
auxiliary equipment.
The rate of circulation of refrigerant can be determined
by the following equation:
PH Diagram for a Refrigeration Process
The vapor-compression
cycle is more commonly
shown on a PH diagram
because they show directly
the required enthalpies.
Although the evaporation
and condensation
processes are show by
constant-pressure paths,
small drops do occur
because of fluid friction.
PH Diagram
Examples (9.12)
The Choice of Refrigerant
Vapor pressure ~ temperature relationship
The vapor pressure at the evaporator temperature
should be larger than atmospheric pressure
The vapor pressure in the condenser should be
reasonably low to reduce the cost of high pressure
equipment
Toxicity
Flammability (non-flammable)
Cost
Corrosion
Environment-friendly
The coefficient of performance of a Carnot
refrigerator is independent of working fluid.
Common Refrigerants
Ammonia, methyl chloride, carbon dioxide, propane and other
hydrocarbons can serve as refrigerants
Halogenated hydrocarbons are commonly used as refrigerants:
Fully halogenated hydrocarbons: CCl
3
F (trichlorofluoromethane or CFC-
11) and CCl
2
F
2
(dichlorodifluoromethane or CFC-12). Damaging to
ozone layer in the atmosphere
Hydrochlorofluorocarbons less than fully halogenated, e.g., CHCl
2
CF
3
(dichlorotrifluoroethane or HCFC-123), which cause relatively little
damage to ozone layer
Hydrofluorocarbons, contains no chloride and causes no ozone
depletion, e.g., CF
3
CH
2
F (tetrafluoroethane or HFC-134a , see Table
9.1 & Fig. G2) and CHF
2
CF
3
(pentafluoroethane or HFC-123)
Difficulties with Large Temperature Difference
When the temperature difference is too large between the
working environment and the required temperature, using one
simple refrigerator may not be able to fulfill the requirement
because:
The refrigerant has to be vapor at atmospheric pressure at the
temperature of required low temperature (e.g. water cannot be
used under 100
o
C), otherwise, the evaporator would have to
operate at vacuum condition, which is infeasible.
The saturation pressure at the temperature of surroundings (T
H
)
shouldnt be too high, otherwise, the compression pressure would
too high to be cost-effective.
A two-stage cascade refrigeration system may be used to serve
this situation.
Two-Stage Cascade Refrigeration System
9.4 Absorption Refrigeration
Advantage: direct use of heat as energy for refrigeration:
higher efficiency due to less irreversible steps
Thermodynamic Calculations
Work requirement of a Carnot refrigerator
Minimal heat required
The pumping work is not included in the above
calculations.
C S
C C
T T
T
W
Q
| |