LARAI B RAFI QUE PP-038 FARKHUNDA YOUNUS PP-043 MAHA TARI Q PP-046
VI NYL CHLORI DE MONOMER Chlorinated hydrocarbons (CHCs)
More resilient to biodegradation, unlike simple hydrocarbons Man-made CHCs are beginning to accumulate in the environment. BASI C I DEA BEHI ND THE PRODUCTI ON OF VCM PRODUCTI ON OF VCM I S ESSENTI AL TO THE PRODUCTI ON OF POLYVI NYL CHLORI DE Many CHCs are created during the production of PVC this is a growing concern.
VCM needs to be produced in a way that will minimize or totally eliminate the release of CHCs into the environment.
First bullet point here Second bullet point here Third bullet point here Group A Group B Class 1 2 85 Class 2 76 88 Class 3 84 90 Two Content Layout with Table
Direct chlorination of ethylene to form EDC. Oxychlorination of ethylene to form from recycled HCl and oxygen. Purification of EDC. Thermal cracking of EDC to form VCM and HCl. The purification of VCM. Process Outline DIRECT CHLORINATION OXY- CHLORINATION HYRDRO- GENATION CATALYTIC OXIDATION VCM STORAGE Ethylene HCL H LIGHTS & HEAVIES HCL RECYCLE EDC EDC PROLYSIS HEAVY ENDS (TO CATALYTIC OXIDATION) VCM DISTILLATION EDC LIGHTS ENDS (TO CATALYTIC OXIDATION) Cl Vent gas O Vent gas EDC EDC DISTILLATION VCM VCM O CO HO PROCESS FLOW DI AGRAM DI RECT CHLORI NATI ON Ethylene Cl Ferric chloride (catalyst) FeCl3 + Cl2 FeCl4-Cl+ FeCl4-Cl+ + CH2CH2 FeCl3 + ClCH2CH2Cl
REACTOR EFFLUENT (lb-mol/hr)
EDC 2682 Trichloroethane 5 HCL 0.5 Ethylene 18 Chlorine 8 Direct Chlorination Reactor Effluent Flow Rates (lb-mol/hr) PARAMETERS VALUES Reactor temperature 120 C Reactor pressure 15 psig Reactor volume 90 ft3 Tube diameter 2 inch Tube length 115 ft Residence time 0.018 hr Direct Chlorination Reactor Parameters Trichloro ethane HCL Ethylene HCL Oxygen Cupric chloride (catalyst) OXYCHLORI NATI ON REACTI ON REACTORS PARAMETER VALUES Reactor temperature 305 C Reactor pressure 58 psig Reactor volume 461 ft3 Tube diameter 2 inch Tube length 1320 ft Residence time 0.05 hr Oxychlorination Reactor Parameters Air based oxychlorination process have been converted to the oxygen. Ethylene Dichloride Purification EDC Cracking and Quenching Vinyl Chloride Purification
Medical application Packaging application Industrial & construction Application
APPLICATION with PROPERTIES *FLAME RETARDANT pvc fire-retardant insulating tape DUE TO THE FOLLOWING MAJOR REASONS:
flameretardant underground pipe wrapping tap *CHEMICAL RESISTANT: PVC Powder chemical resistance Disposable Medical Glove PVC Chemical-Resistant Kneeboots
Modified Polymers, Their Preparation and Properties: Main Lectures Presented at the Fourth Bratislava Conference on Polymers, Bratislava, Czechoslovakia, 1-4 July 1975