So far, you have been taught on how to determine the energy target and design the heat exchanger network that will attain it respectively Temp. Enthalpy (H) QC QH DTmin COLD UTILITIES HOT UTILITIES PINCH POINT Composite Curve Problem Table Algorithm and Heat Cascade Diagram alternatives HOT 1 HOT 2 COLD 1 COLD 2 180 C 80 C 130 C 40 C 30 C 120 C 60 C 100 C Cp Q 20 40 36 80 2000 3600 3240 3200 800 2400 1080 70 C 43 C 60 C 2000 160 120 90 C 115.56 C PINCH Energy Targeting Maximum Energy Recovery Design CBB 4313 HEAT INTEGRATION CBB 4313 HEAT INTEGRATION Now we will learn on how to use a software that can perform the PINCH Analysis .. The software is called STAR and was developed by University of Manchester CBB 4313 HEAT INTEGRATION Let us suppose we do the data extraction for the process below . R1 S1 S2 CW FEED T = 30 C T = 200 C
T = 350 C BOILER FEED WATER MP STEAM T = 220 C T = 90 C MP STEAM T = 220 C T = 100 C T = 250 C T = 150 C T = 60 C T = 130 C T = 150 C T = 180 C T = 120 C MP STEAM T = 220 C T = 150 C CW T = 40 C PROD 1 T = 60 C PROD 2 T = 40 C PROD 3 T = 40 C CW CW LP STEAM T = 120 C CBB 4313 HEAT INTEGRATION So where are the streams ? R1 S1 S2 CW FEED T = 30 C T = 200 C
T = 350 C BOILER FEED WATER MP STEAM T = 220 C T = 90 C MP STEAM T = 220 C T = 100 C T = 250 C T = 150 C T = 60 C T = 130 C T = 150 C T = 180 C T = 120 C MP STEAM T = 220 C T = 150 C CW T = 40 C PROD 1 T = 60 C PROD 2 T = 40 C PROD 3 T = 40 C CW CW LP STEAM T = 120 C CBB 4313 HEAT INTEGRATION FEED 30 C 200 C S1 REB 130.1 C 130 C 130 C 150 C S1 EFF 180.1 C 180 C S2 REB 350 C 100 C REACTOR EFF. S1 COND 60.1 C 60 C 180 C 40 C PROD 3 S2 COND 120.1 C 120 C 120 C PROD 2 40 C UTILITIES : COOLING WATER, MP STEAM AND LP STEAM These are the set of streams extracted from the process flowsheet. H (Enthalpy change) 2,500 kW 3,000 kW 1,200 kW 2,000 kW 600 kW 2,500 kW 3,500 kW 150 kW 2,300 kW CBB 4313 HEAT INTEGRATION To start with, go to the file option and click new. CBB 4313 HEAT INTEGRATION You will be asked to put some description here Then click finish CBB 4313 HEAT INTEGRATION Go to the edit menu . Click at stream data CBB 4313 HEAT INTEGRATION You will be required to fill up all the streams data CBB 4313 HEAT INTEGRATION After filling up the stream data click ok CBB 4313 HEAT INTEGRATION Go to the target menu . Set your DT min . CBB 4313 HEAT INTEGRATION As you change your DT min , the energy target for hot and cold utility will also vary The energy target for the two utilities. CBB 4313 HEAT INTEGRATION You can also go back to the target menu, and select to see the problem table, composite curve, grand composite curve and design grid . CBB 4313 HEAT INTEGRATION Composite Curve CBB 4313 HEAT INTEGRATION Problem Table actually heat cascade CBB 4313 HEAT INTEGRATION Grand Composite Curve CBB 4313 HEAT INTEGRATION Design Grid representing stream data. CBB 4313 HEAT INTEGRATION Another software that can be used is called SPRINT and was also developed by the University of Manchester. CBB 4313 HEAT INTEGRATION In order to input the stream data, similar steps as applied in STAR is used. CBB 4313 HEAT INTEGRATION You can basically obtain the same information for the MER target - Problem table, Composite Curve, Grand Composite Curve, Design Grid etc. You will also need to set the DT min . CBB 4313 HEAT INTEGRATION Consider the flowsheet for the Phthalic Anhydride Production Process below, Perform the stream extraction exercise CBB 4313 HEAT INTEGRATION Process Description The phthalic anhydride is manufactured using controlled oxidation of o-xylene. The reaction uses a fixed bed vanadium pentoxide titanium dioxide catalyst. The reaction is carried out in vapour phase at a temperature range of 380 400 C. Reaction is exothermic. Reactor cooling is by means of a molten salt loop.
Air and o-xylene are heated and mixed in a venturi where the o-xylene vapourises. The gaseous reactor product is cooled first by boiler feedwater before entering a cooling water condenser. The phthalic anhydride forms a solid on the condenser tube walls and is cooled to 70 C. Periodically the condenser is taken off line and the phthalic anhydride melted off the surface by recirculation of high pressure hot water. Two condensers are used in parallel. The noncondensible gases contain small quantities of byproducts and traces of phthalic anhydride are scrubbed prior to venting it to atmosphere.
The crude phthalic anhydride is heated and held at 260 C to allow some byproduct reactions to go to completion.
Purification is by continuous distillation in two columns. In the first column, maleic anhydride, benzoic and toluic acids are removed as the overhead. Pure phthalic anhydride is removed as the overhead in the 2 nd column while the high boiling residues are removed as the bottoms. CBB 4313 HEAT INTEGRATION The hot stream locations Perform the stream extraction exercise 1 2 3 4 5 CBB 4313 HEAT INTEGRATION The hot streams on grid diagram . Reactor Cooling 377 C 375 C 376 C 180 C 180 C 70 C 280 C 279 C 197 C 196 C Reactor Product Cooling Product Sublimation Column 1 Condenser Column 2 Condenser DH -7000 -3600 -2400 -400 -800 CBB 4313 HEAT INTEGRATION Perform the stream extraction exercise 1 2 6 3 4 5 Next, lets work out the cold stream . CBB 4313 HEAT INTEGRATION Air Feed O-xylene Feed Product Melting Holding Tank Feed Column 1 Reboiler DH 200 1600 900 200 400 Column 2 Reboiler 700 160 C 60 C 130 C 20 C 180 C 70 C 260 C 160 C 291 C 290 C 236 C 235 C The cold streams on grid diagram . CBB 4313 HEAT INTEGRATION Overall Reactor Cooling 377 C 375 C 376 C 180 C 180 C 70 C 280 C 279 C 197 C 196 C Reactor Product Cooling Product Sublimation Column 1 Condenser Column 2 Condenser DH -7000 -3600 -2400 -400 -800 Air Feed O-xylene Feed Product Melting Holding Tank Feed Column 1 Reboiler 200 1600 900 200 400 Column 2 Reboiler 700 160 C 60 C 130 C 20 C 180 C 70 C 260 C 160 C 291 C 290 C 236 C 235 C CBB 4313 HEAT INTEGRATION Now attempt the simulation study using the software Obtain the following from the software; i. Composite curve ii. Problem Table (Heat Cascade) iii. Grand Composite Curve iv. Grid Diagram
CBB 4313 HEAT INTEGRATION Stream Data Entry CBB 4313 HEAT INTEGRATION i. The Composite Curve CBB 4313 HEAT INTEGRATION ii. Problem Table (Heat Cascade) CBB 4313 HEAT INTEGRATION iii. Grand Composite Curve CBB 4313 HEAT INTEGRATION iv. Grid Diagram