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Chapter 13
12.1 Designations and Classification
of Steels
12.2 Simple Heat Treatments
12.3 Isothermal Heat Treatments
12.4 Quench and Temper Heat
Treatments
12.5 Effect of Alloying Elements
12.6 Application of Hardenability
2
12.7 Specialty Steels
12.8 Surface Treatments
12.9 Weldability of Steel
12.10 Stainless Steels
12.11 Cast Irons
Chapter Outline (Continued)
3
Figure 12.1 (a) In a blast furnace,
iron ore is reduced using coke
(carbon) and air to produce liquid
pig iron. The high-carbon content
in the pig iron is reduce by
introducing oxygen into the basic
oxygen furnace to produce liquid
steel. An electric arc furnace can
be used to produce liquid steel by
melting scrap. (b) Schematic of a
blast furnace operation. (Source:
www.steel.org. Used with
permission of the American Iron
and Steel Institute.)
4
Designations - The AISI (American Iron and Steel
Institute) and SAE (Society of Automotive Engineers)
provide designation systems for steels that use a four- or
five-digit number.
Classifications - Steels can be classified based on their
composition or the way they have been processed.
Section 12.1
Designations and Classification
of Steels
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Figure 12.2 (a) The
eutectoid portion of
the Fe-Fe
3
C phase
diagram. (b) An
expanded version of
the Fe-C diagram,
adapted from
several sources.
6
Figure 12.3 Electron micrographs of (a) pearlite, (b)
bainite, and (c) tempered martensite, illustrating the
differences in cementite size and shape among these
three microconstituents ( 7500). (From The Making,
Shaping, and Treating of Steel, 10th Ed. Courtesy of
the Association of Iron and Steel Engineers.)
7
8
An unalloyed steel tool used for machining aluminum
automobile wheels has been found to work well, but the
purchase records have been lost and you do not know the
steels composition. The microstructure of the steel is
tempered martensite, and assume that you cannot estimate
the composition of the steel from the structure. Design a
treatment that may help determine the steels carbon
content.
Example 12.1
Design of a Method to Determine
AISI Number
9
Example 12.1 SOLUTION
The first way is to heat the steel to a temperature just below
the A
1
temperature and hold for a long time. The steel
overtempers and large Fe
3
C spheres form in a ferrite matrix.
We then estimate the amount of ferrite and cementite and
calculate the carbon content using the lever law. If we measure
16% Fe
3
C using this method, the carbon content is:
% 086 . 1 or 16 100
) 0218 . 0 67 . 6 (
) 0218 . 0 (
C Fe % 3 = =
(
= x
x
A better approach, however, is to heat the steel above
the A
cm
to produce all austenite. If the steel then cools slowly,
it transforms to pearlite and a primary microconstituent. If,
when we do this, we estimate that the structure contains 95%
pearlite and 5% primary Fe
3
C, then:
% 065 . 1 or 95 100
77 . 0 67 . 6
- 6.67
Pearlite % = =
(
= x
x
10
Process Annealing Eliminating Cold Work: A low-
temperature heat treatment used to eliminate all or part
of the effect of cold working in steels.
Annealing and Normalizing Dispersion Strengthening:
Annealing - A heat treatment used to produce a soft,
coarse pearlite in steel by austenitizing, then furnace
cooling. Normalizing - A simple heat treatment obtained
by austenitizing and air cooling to produce a fine pearlitic
structure.
Spheroidizing Improving Machinability: Spheroidite - A
microconstituent containing coarse spheroidal cementite
particles in a matrix of ferrite, permitting excellent
machining characteristics in high-carbon steels.
Section 12.2
Simple Heat Treatments
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Figure 12.5 The effect of
carbon and heat
treatment on the
properties of plain-carbon
steels.
13
Figure 12.6 The microstructure
of spheroidite, with Fe
3
C
particles dispersed in a ferrite
matrix ( 850). (From ASM
Handbook, Vol. 7, (1972), ASM
International, Materials Park,
OH 44073.)
14
Recommend temperatures for the process annealing,
annealing, normalizing, and spheroidizing of 1020,
1077, and 10120 steels.
Example 12.2
Determination of Heat Treating
Temperatures
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Figure 12.2 (a) The
eutectoid portion of
the Fe-Fe
3
C phase
diagram. (b) An
expanded version of
the Fe-C diagram,
adapted from
several sources.
16
Example 12.2 SOLUTION
From Figure 12.2, we find the critical A1, A
3
, or A
cm
,
temperatures for each steel. We can then specify the heat
treatment based on these temperatures.
17
Austempering - The isothermal heat treatment by which
austenite transforms to bainite.
Isothermal annealing - Heat treatment of a steel by
austenitizing, cooling rapidly to a temperature between
the A
1
and the nose of the TTT curve, and holding until
the austenite transforms to pearlite.
Section 12.3
Isothermal Heat Treatments
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Figure 12.8 The TTT
diagrams for (a) a 1050 and
(b) a 10110 steel.
20
A heat treatment is needed to produce a uniform
microstructure and hardness of HRC 23 in a 1050 steel axle.
Example 12.3
Design of a Heat Treatment for an Axle
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Figure 12.8 The TTT
diagrams for (a) a 1050
and (b) a 10110 steel.
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Figure 12.2 (a) The
eutectoid portion of
the Fe-Fe
3
C phase
diagram. (b) An
expanded version of
the Fe-C diagram,
adapted from
several sources.
22
Example 12.3 SOLUTION
1. Austenitize the steel at 770 + (30 to 55) = 805
o
C to
825
o
C, holding for 1 h and obtaining 100% .
2. Quench the steel to 600
o
C and hold for a minimum of 10 s.
Primary ferrite begins to precipitate from the unstable
austenite after about 1.0 s. After 1.5 s, pearlite begins to
grow, and the austenite is completely transformed to
ferrite and pearlite after about 10 s. After this treatment,
the microconstituents present are:
% 64 100
) 0218 . 0 77 . 0 (
0.0218) (0.5
Pearlite
% 36 100
) 0218 . 0 77 . 0 (
0.5) (0.77
Primary
=
(
=
=
(
=
3. Cool in air-to-room temperature, preserving the
equilibrium amounts of primary ferrite and pearlite. The
microstructure and hardness are uniform because of the
isothermal anneal.
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Figure 12.9 Producing
complicated structures
by interrupting the
isothermal heat
treatment of a 1050
steel.
24
Figure 12.10 Dark feathers of
bainite surrounded by light
martensite, obtained by
interrupting the isothermal
transformation process ( 1500).
(ASM Handbook, Vol. 9
Metallography and Microstructure
(1985), ASM International,
Materials Park, OH 44073.)
25
Retained austenite - Austenite that is unable to
transform into martensite during quenching because of
the volume expansion associated with the reaction.
Tempered martensite - The microconstituent of ferrite
and cementite formed when martensite is tempered.
Quench cracks - Cracks that form at the surface of a
steel during quenching due to tensile residual stresses
that are produced because of the volume change that
accompanies the austenite-to-martensite transformation.
Marquenching - Quenching austenite to a temperature
just above the M
S
and holding until the temperature is
equalized throughout the steel before further cooling to
produce martensite.
Section 12.4
Quench and Temper Heat Treatments
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Figure 12.13
Increasing carbon
reduces the M
s
and
M
f
temperatures in
plain-carbon steels.
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Figure 12.18 (a) TTT and (b)
CCT curves for a 4340 steel.
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Figure 12.19 The
effect of 6%
manganese on the
stability ranges of
the phases in the
eutectoid portion of
the Fe-Fe
3
C phase
diagram.
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Figure 12.23 The
hardenability curves
for several steels.
37
38
A gear made from 9310 steel, which has an as-quenched
hardness at a critical location of HRC 40, wears at an excessive
rate. Tests have shown that an as-quenched hardness of at
least HRC 50 is required at that critical location. Design a steel
that would be appropriate.
Example 12.5
Design of a Wear-Resistant Gear
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Figure 12.23 The
hardenability curves for
several steels.
39
40
Example 12.5 SOLUTION
From Figure 12.23, a hardness of HRC 40 in a 9310 steel
corresponds to a Jominy distance of 10/16 in. (10
o
C/s). If we
assume the same Jominy distance, the other steels shown in
Figure 12.23 have the following hardnesses at the critical
location:
1050 HRC 28 1080 HRC 36 4320 HRC 31
8640 HRC 52 4340 HRC 60
In Table 12-1, we find that the 86xx steels contain less alloying
elements than the 43xx steels; thus the 8640 steel is probably
less expensive than the 4340 steel and might be our best
choice. We must also consider other factors such as durability.
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Figure 12.23 The
hardenability curves
for several steels.
45
Example 12.6 SOLUTION
Several quenching media are listed in Table 12-2. We can find
an approximate H coefficient for each of the quenching media,
then use Figure 12.24 to estimate the Jominy distance in a 1.5-
in. diameter bar for each media. Finally, we can use the
hardenability curve (Figure 12.23) to find the hardness in the
4320 steel. The results are listed below.
The last three methods, based on brine or agitated water, are
satisfactory. Using an unagitated brine quenchant might be least
expensive, since no extra equipment is needed to agitate the
quenching bath. However, H
2
O is less corrosive than the brine
quenchant.
46
Tool steels - High-carbon steels with high hardness,
toughness, or resistance to high temperatures.
Secondary hardening peak Unusually high hardness
in a steel tempered at a high temperature caused by
the precipitation of alloy carbides.
HSLA Low-carbon steels containing the least amount of
alloying element.
Dual-phase steels - Special steels treated to produce
martensite dispersed in a ferrite matrix.
Maraging steels - A special class of alloy steels that
obtain high strengths by a combination of the
martensitic and age-hardening reactions.
Section 12.7
Specialty Steels
47
Selectively Heating the Surface - Rapidly heat the
surface of a medium-carbon steel above the certain (A
3
)
temperature and then quench the steel.
Carburizing - A group of surface-hardening techniques
by which carbon diffuses into steel.
Cyaniding - Hardening the surface of steel with carbon
and nitrogen obtained from a bath of liquid cyanide
solution.
Carbonitriding - Hardening the surface of steel with
carbon and nitrogen obtained from a special gas
atmosphere.
Section 12.8
Surface Treatments
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The development of
the heat-affected
zone in a weld: (a)
the structure at the
maximum
temperature, (b)
the structure after
cooling in a steel of
LOW HARDENABILITY,
and (c) the
structure after
cooling in a steel of
HIGH
HARDENABILITY.
53
Compare the structures in the heat-affected zones of
welds in 1080 and 4340 steels if the cooling rate in the
heat-affected zone is 5
o
C/s.
Example 12.8 SOLUTION
The cooling rate in the weld produces the following
structures:
1080: 100% pearlite
4340: Bainite and martensite
The high hardenability of the alloy steel reduces
the weldability, permitting martensite to form and
embrittle the weld.
Example 12.8
Structures of Heat-Affected Zones
54
Stainless steels - A group of ferrous alloys that contain
at least 11% Cr, providing extraordinary corrosion
resistance.
Categories of stainless steels:
Ferritic Stainless Steels
Martensitic Stainless Steels
Austenitic Stainless Steels
Precipitation-Hardening (PH) Stainless Steels
Duplex Stainless Steels
Section 12.10
Stainless Steels
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Figure 12.30 (a) The
effect of 17% chromium
on the iron-carbon
phase diagram. At low-
carbon contents, ferrite
is stable at all
temperatures. (b) A
section of the iron-
chromium-nickel-carbon
phase diagram at a
constant 18% Cr-8% Ni.
At low-carbon contents,
austenite is stable at
room temperatures.
56
57
Figure 12.31 (a) Martensitic stainless steel containing
large primary carbides and small carbides formed
during tempering ( 350). (b) Austenitic stainless
steel ( 500). (From ASM Handbook, Vols. 7 and 8,
(1972, 1973), ASM International, Materials Park, OH
44073.)
58
In order to efficiently recycle stainless steel scrap, we wish to
separate the high-nickel stainless steel from the low-nickel
stainless steel. Design a method for doing this.
Example 12.9 SOLUTION
Performing a chemical analysis on each piece of scrap is tedious
and expensive. Sorting based on hardness might be less
expensive; however, because of the different types of
treatmentssuch as annealing, cold working, or quench and
temperingthe hardness may not be related to the steel
composition.
The high-nickel stainless steels are ordinarily austenitic,
whereas the low-nickel alloys are ferritic or martensitic. An
ordinary magnet will be attracted to the low-nickel ferritic and
martensitic steels, but will not be attracted to the high-nickel
austenitic steel. We might specify this simple and inexpensive
magnetic test for our separation process.
Example 12.9
Design of a Test to Separate
Stainless Steels
59
Cast iron - Ferrous alloys containing sufficient carbon so
that the eutectic reaction occurs during solidification.
Eutectic and Eutectoid reaction in Cast Irons
Types of cast irons:
Gray cast iron
White cast iron
Malleable cast iron
Ductile or nodular, cast iron
Compacted graphite cast iron
Section 12.11
Cast Irons
60
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning
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Figure 12.36 The
effect of the cooling
rate or casting size
on the tensile
properties of two
gray cast irons.
65
Figure 12.37 The heat treatments for ferritic and
pearlitic malleable irons.
66
Figure 12.38 (a) White cast iron prior to heat treatment ( 100). (b) Ferritic malleable
iron with graphite nodules and small MnS inclusions in a ferrite matrix ( 200). (c)
Pearlitic malleable iron drawn to produce a tempered martensite matrix ( 500).
(Images (b) and (c) are from Metals Handbook, Vols. 7 and 8, (1972, 1973), ASM
International, Materials Park, OH 44073.) (d) Annealed ductile iron with a ferrite matrix
( 250). (e) As-cast ductile iron with a matrix of ferrite (white) and pearlite ( 250). (f)
Normalized ductile iron with a pearlite matrix ( 250).
67
68
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Figure 12.23
(Repeated for
Problem 12.54)
The hardenability
curves for several
steels.
70
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Figure 12.30b
(Repeated for Problem
12.48) (b) A section of
the iron-chromium-
nickel-carbon phase
diagram at a constant
18% Cr-8% Ni. At
low-carbon contents,
austenite is stable at
room temperature.