Mixtures 2013 Marshall Cavendish International (Singapore) Private Limited 4.1 Elements
4.2 Compounds
4.3 Mixtures Elements, Compounds and Mixtures Chapter 4 2 Learning Outcomes define an element;
state the chemical symbols for a number of elements.
At the end of this section, you should be able to: 4.1 Elements 3 It is a pure substance that cannot be broken down into two or more simpler substances by chemical processes. 4.1 Elements What is an Element? Sugar is not an element.
When heated, it breaks down into carbon and water vapour. Examples: Carbon, copper, oxygen 4 Is Water an Element? Water is not an element.
It can be broken down into hydrogen and oxygen.
Hydrogen and oxygen are elements. 4.1 Elements URL 5 Chemical Symbols of Elements Chemists use chemical symbols to represent elements. Each symbol is unique, consisting of one or two letters. 4.1 Elements The names and symbols of all known elements are found in Periodic Table. Element Symbol
calcium Ca carbon C hydrogen H iron Fe Element Symbol
mercury Hg neon Ne silicon Si sodium Na 6 Element Symbol
Aluminium Magnesium Lead Copper Nitrogen Neon Bromine Sulfur Using the Periodic Table, find the symbols of the following elements. 4.1 Elements Al Mg Pb Cu N Ne Br S 7 Classification of Elements Based on their properties, elements are classified into: 4.1 Elements metals; e.g. sodium, magnesium, calcium non-metals; e.g. hydrogen, carbon, chlorine metalloids. e.g. boron, silicon, germanium, arsenic (Metalloids have properties of metals and non-metals.) 8 Differences Between Metals and Non-Metals 4.1 Elements Properties Metals Metalloids Non-metals
Appearance Shiny (lustrous) Shiny (lustrous) Dull (non- lustrous) Physical state at r.t.p. Mostly solids (except mercury) Solids Gases, volatile liquids or solids Melting and boiling points High (except for sodium, potassium and mercury) High Low (except for carbon and silicon) Heat and Electrical Conductivity Good Moderate Poor (except carbon in the form of graphite and diamond) 9 Differences Between Metals and Non-Metals 4.1 Elements Properties Metals Metalloids Non-metals
Ductility and Malleability Ductile (can be drawn into wires) Malleable (can be hammered into different shapes without breaking Sonorous (makes a ringing sound when struck) Brittle (easily broken when hammered) Brittle if solid 10 neon atom Atoms and Molecules An element is made up of tiny particles called atoms.
Atoms are the smallest particles of an element that have the chemical properties of that element.
The atoms of an element are different from that of another element. 4.1 Elements gold atom 11 A molecule is a group of two or more atoms that are chemically combined (joined together). 4.1 Elements Diatomic molecules are those that are formed by the combination of two atoms. E.g. hydrogen, oxygen, nitrogen. Elements like hydrogen, oxygen, ozone and sulfur exist as molecules. Atoms and Molecules 12 Polyatomic molecules consists of three or more atoms that are chemically combined together. 4.1 Elements Polyatomic Molecules ozone (O 3 ) phosphorus (P 4 ) sulfur (S 8 ) 13 4.1 Elements
4.2 Compounds
4.3 Mixtures Elements, Compounds and Mixtures Chapter 4 14 Learning Outcomes define a compound;
describe the difference between elements and compounds;
deduce the formula of a compound from the ratio of elements present. At the end of this section, you should be able to: 4.2 Compounds 15 What is a Compound? A compound is a pure substance that contains two or more elements that are chemically combined in a fixed ratio. 4.2 Compounds What are compounds made of? molecules ions water molecule sodium ion chloride ion 16 Properties of Compounds Example: When magnesium is burned, it combines with oxygen in the air to form a compound called magnesium oxide. A compound has different properties from the elements that form it. 4.2 Compounds
magnesium + oxygen magnesium oxide shiny grey solid colourless gas white solid URL 17 Names of Compounds 4.2 Compounds Each compound has a chemical name indicating the elements it contains. Compound Elements present
sodium chloride sodium, chlorine carbon dioxide carbon, oxygen zinc oxide zinc, oxygen calcium carbonate (marble) calcium, carbon, oxygen copper(II) sulfate copper, sulfur, oxygen hydrogen chloride hydrogen, chlorine 18 4.2 Compounds Chemical Formula A compound can be represented by a chemical formula. The chemical formula shows:
the types of elements present;
the ratio of the different atoms present. Chemical formula for lead(II) nitrate Pb(NO 3 ) 2 Pb
1 lead atom (N) 2 1 2 = 2 nitrogen atoms (O 3 ) 2 3 2 = 6 oxygen atoms 19 Composition of Compounds Every compound has fixed compositions of the different elements it contains. 4.2 Compounds Chemical formula can be deduced by the ratio of atoms present in a compound. Compound Chemical formula
Ratio of atoms
hydrogen chloride HCl H : Cl = 1 : 1 carbon dioxide CO 2 C : O = 1 : 2 carbon monoxide CO C : O = 1 : 1 sulfuric acid H 2 SO 4 H : S : O = 2 : 1 : 4 sulfurous acid H 2 SO 3 H : S : O = 2 : 1 : 3 ethanol C 2 H 5 OH C : H : O = 2 : 6 : 1 20 Decomposition of Compounds In thermal decomposition, heat is used to break down compounds into elements or simpler compounds. A chemical reaction is necessary to separate the elements in a compound. 4.2 Compounds Compounds can also be broken down by using electricity. This process is known as electrolysis. mercury(II) oxide mercury oxygen gas 21 4.1 Elements
4.2 Compounds
4.3 Mixtures Elements, Compounds and Mixtures Chapter 4 22 Learning Outcomes define a mixture;
differentiate between compounds and mixtures. At the end of this section, you should be able to: 4.3 Mixtures 23 What are Mixtures? 4.3 Mixtures Examples of mixtures: petrol air muddy water alloys such as brass, bronze and steel Mixtures are made up of two or more substances that are not chemically combined. 24 4.3 Mixtures Types of Mixtures A mixture can exist as a combination of two elements; two compounds; one element and one compound. 25 Example: Neon and Hydrogen 4.3 Mixtures Mixture of Two Elements Neon is monatomic.
Hydrogen is diatomic. hydrogen (H 2 ) neon (Ne) 26 Example: Water and Carbon dioxide 4.3 Mixtures Mixture of Two Compounds A water molecule is made up of two hydrogen atoms and one oxygen atom.
A carbon dioxide molecule is made up of two oxygen atoms and one carbon atom. water (H 2 O) carbon dioxide (CO 2 ) 27 Example: Hydrogen and Ammonia 4.3 Mixtures Mixture of an Element and a Compound Hydrogen is an element.
Ammonia is a compound. Each ammonia molecule consists of three hydrogen atoms and one nitrogen atom. hydrogen (H 2 ) ammonia (NH 3 ) 28 Differences between Mixture and Compound 4.3 Mixtures Mixture Compound Separation
The components of a mixture can be separated by physical processes such as magnetic separation, filtration or distillation. A compound can only be broken down into its elements or into simpler compounds by chemical processes (e.g. thermal decomposition or electrolysis). Properties The chemical properties of a mixture are the same as those of its components. The physical and chemical properties of a compound are different from those of its constituent elements. 29 Differences between Mixture and Compound 4.3 Mixtures Mixture Compound Energy changes No chemical reaction takes place when a mixture is formed usually there is little or no energy change. A chemical reaction takes place when a compound is formed usually there is an energy change, e.g. the reactants get hot or cold. Composition The components of a mixture can be mixed in any proportion. The elements in a compound are always combined in a fixed proportion. 30 4.3 Mixtures Separation Example: Comparing a mixture of iron filings and sulfur with a compound iron(II) sulfide Mixture Compound
Can be separated by physical methods
E.g. In a mixture of iron filings and sulfur, iron filings can be separated with the use of a magnet. Can only be separated by chemical methods or by using electricity E.g. Iron in iron(II) sulfide cannot be simply separated with a magnet. 31 4.3 Mixtures Physical and Chemical Properties Example: Comparing a mixture of iron filings and sulfur with a compound iron(II) sulfide Mixture Compound
Has the same chemical properties as its components
E.g. In a mixture of iron filings and sulfur, each component retains their colour, texture and magnetic property (iron). Has different physical and chemical properties from those of its components
E.g. Iron(II) sulfide has a different appearance from iron filings or sulfur; has no magnetic property. 32 4.3 Mixtures Energy Change Example: Comparing a mixture of iron filings and sulfur with a compound iron(II) sulfide Mixture Compound
No chemical reaction takes place. Little or no energy change.
E.g. Mixture of iron filings and sulfur no chemical change takes place without heating. Chemical reaction takes place. Heat and light usually given off.
E.g. When a mixture of iron filings and sulfur is heated, it glows red hot to form iron(II) sulfide. 33 4.3 Mixtures Example: Comparing a mixture of iron filings and sulfur with a compound iron(II) sulfide Composition Mixture Compound
No fixed composition.
E.g. A mixture of iron filings and sulfur can have more or less of each component. Fixed composition.
E.g. The compound iron(II) sulfide is formed in the ratio of iron to sulfur (by mass) of 7:4. 34 Concept Map Elements, Compounds and Mixtures Chapter 4 35 Elements, Compounds and Mixtures Chapter 4 Acknowledgements (slide 1) Image DJ2 CD (slide 4) Marshall Cavendish International (Singapore) (slide 11) goldkey logo removed Swiss Banker | Wikimedia Commons | Public Domain (slide 11) neon sign Steve Estvanik | 123RF 36 The URLs are valid as at 15 October 2013.