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  • UV-visible Spectrum of A Transition Metal Complex (d3 - d8) From Internet - Assign The Peaks and Using The Appropriate Tanabe - Sugano Diagram Calculate Do For The Complex.

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    Exercises on page 489 19. To 19. 3. Find a UV-visible spectrum of a transition metal complex (d3 d8) from Internet. Assign the peaks and using the appropriate Tanabe -sugano diagram calculate [?]o for the complex.

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    UV-visible spectrum of a transition metal complex (d3 - d8) from internet . Assign the peaks and using the appropriate Tanabe –Sugano diagram calculate Do for the complex.

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    Exercises on page 489 19. To 19. 3. Find a UV-visible spectrum of a transition metal complex (d3 d8) from Internet. Assign the peaks and using the appropriate Tanabe -sugano diagram calculate [?]o for the complex.

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    2K visualizzazioni5 pagine

    UV-visible Spectrum of A Transition Metal Complex (d3 - d8) From Internet - Assign The Peaks and Using The Appropriate Tanabe - Sugano Diagram Calculate Do For The Complex.

    Caricato da

    peptidesynthesizer
    Exercises on page 489 19. To 19. 3. Find a UV-visible spectrum of a transition metal complex (d3 d8) from Internet. Assign the peaks and using the appropriate Tanabe -sugano diagram calculate [?]o for the complex.

    Copyright:

    Attribution Non-Commercial (BY-NC)
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    di 5

    ASSIGNMENT.

    Inorganic Chemistry
    Fourth Edition
    Peter Atkins, Tina Overton, Jonathan Rourke, Mark Weller, and Fraser
    Armstrong
    848 pages | 1500 colour line drawings | 276x219mm
    978-0-19-926463-6 | Paperback | 26 January 2006
    Price: £39.99

    1. Exercises on page 489

    •19.15 to 19.23

    2. Find a UV-visible spectrum of a transition metal complex (d3 -


    d8) from internet . Assign the peaks and using the appropriate
    Tanabe –Sugano diagram calculate ∆ο for the complex.
    Cr(NH3)63+
    Assigning transitions
    (blue arrow reproduces observed transitions)

    21550cm-1

    28500cm-1

    Two allowed, one forbidden transition


    Analysis of Tanabe Sugano
    -Using Ruler to find ratio

    Get the Ratio of


    v2/v1=28500/215500=1.32

    Now,using a ruler.Find a y value by moving the ruler


    along the x axis and find the ratio approximately at 1.32

    4
    T2g
    Approximately 1.30 at 33.0
    4
    T1g
    4
    T2g ← 4A2g

    4
    T1g ← 4A2g
    From the Tanabe –Sugano diagram ∆ο/Β
    =33.0

    It’s mean that

    32.8B=21550cm-1

    So B=657cm-1

    ∆ο=21700 cm-1

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