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Dr. M. RAMESH KUMAR, Dept. of Garment and Fashion Technology, Sona College of Technology, Salem 636 005.
IEI Salem Chapter on 26-01-2013
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SOURCES OF WATER
The worlds water is found in oceans and seas, lakes and reservoirs, rivers and streams, glaciers and snowcaps in the polar regions in addition to ground water.
Distribution of water
Oceans and Seas Glaciers and Polar icecaps Fresh water
Reservoir
% of Total
Oceans Ice Caps/Glaciers Deep Groundwater Shallow Groundwater Lakes Soil Moisture Atmosphere Rivers Biosphere
0.125
0.065 0.013 0.0017 0.0006
0.01
0.005 0.001 0.0001 0.00004
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For domestic use 43 km3/year For industrial use 37 km3/year For agricultural use 550 km3/year India receives annual precipitation of about 4000 km3 Only 35% of surface water is utilizable.
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Water Pollution
Discharge of partially or untreated industrial effluent. Discharge of untreated domestic sewage. Mismanagement practice of solid wastes. Unscientific use of synthetic fertilizers.
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Effluent
Water is referred as wastewater (effluent) when it is impaired by anthropogenic contaminants Domestic Effluent Industrial Effluent
Ammoniacal Wastes Coloured Effluents Hazardous Effluents Malodourous Effluents Recalcitrant Effluents
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Polluting Industries
Pulp and Paper Industries Dairy Industries Slaughter Houses Ceramics Industry Fruits and Vegetables Processing Fish Processing and Canning Metal Plating Industries Paint Industries Pharmaceutical Industries Refineries Petrochemical Complexes
Textile Industries
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Textile Industries
Complicated Industry among other manufacturing Industries. Second largest Employment Generator. Textile account for - 17 % of Export Earnings - 14% of Indias industrial production - 4% to GDP Third largest polluter in the world. Erode, Tirupur and Karur are hub of textile sector.
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Textile Industries.
More than 1 lakh commercial dyes are available. Dye annual production approximately 10,00,000 tons. Azo dyes account for 60 to 80% of the dyes consumed in textile processing About 5200 organized bleaching and dyeing industries are in India & more unorganized industries are also available. 50% industries at Tirupur, Karur and Erode Districts
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Wastewater Issues
Wastewater Issues
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Printing industry
Rotary Printing
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CHEMICAL
PHYSICAL
BIOLOGICAL
Chemical Oxidation/
Precipitation/Coagulation air flotation/Flocculation Hydrolysis/Neutralization
Adsorption, Filtration
Stripping/ Sedimentation
Membrane technologies
Anaerobic processes
Rotating biological contactors SBR and trickling filters
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Solvent Extraction
Ion Exchange
CHEMICAL
PHYSICAL
BIOLOGICAL
Chemical Oxidation/
Precipitation/Coagulation
air flotation/Flocculation Hydrolysis/Neutralization Solvent Extraction
Adsorption, Filtration
Stripping/ Sedimentation
Skimming Membrane technologies
Physical/Chemical processes if chemical Bioaugmentation agents as coagulating agentssludge are added. Activated Extended aeration Anaerobic processes Rotating biological contactors SBR and trickling filters
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Ion Exchange
Membrane Technology
Micro filtration Ultrafiltration Nanofiltration Reverse Osmosis Membrane
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Reverse Osmosis
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RO Membrane Technology
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KOCH MEMBRANE
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MEMBRANE SPECIFICATIONS
PARTICULARS KOCH MEMBRANE ROSA MEMBRANE
Membrane Materials of Construction Software Pore size Range of operating pressure Temperature pH
Filmtech Polyamide
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Advantages of RO Membrane
Highly efficient High recovery% Lower rejection% Lower maintenance cost Lower power consumption Lower pressure Cost effectiveness Easy to operate & Maintain Wastewater can be reused in Large proportion
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PRELIMINARY TREATMENT
PRIMARY TREATMENT
Conventional Treatment
SECONDARY TREATMENT
ADVANCED TREATMENT
High-quality Treatment
To discharge or reuse/recycling
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PRELIMINARY TREATMENT
PRIMARY TREATMENT
SECONDARY TREATMENT
Feed wastewater stream PRELIMINARY TREATMENT PRIMARY TREATMENT The reached removal is up to 85-95% of BOD and SS & 65% of COD.
SECONDARY TREATMENT
ADVANCED TREATMENT
To discharge or reuse/recycling
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SECONDARY TREATMENT
Removal of : Additional organic and suspended solids. Nitrogenous Oxygen Demand (NOD) Nutrients Toxic materials
ADVANCED TREATMENT
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TREATMENT METHOD
WASH WATER PLANT TREATMENT SCHEME
PRIMARY TREATMENT (PHYSICO-CHEMICAL) SECONDARY TREATMENT (BIOLOGICAL) TERTIARY TREATMENT (PHYSICO-CHEMICAL) UF/RO RECYCLING PLANT
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RECEIVING SUMP
SLUDGE SUMP
FILTER PRESS
THICKENER
CENTRIFUGE
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PRIMARY TREATMENT
RECEIVING SUMP Wash water effluent received and screened. EQUALISATION TANK The effluent is homogenized with high speed floating aerators. FLASH MIXING TANK Coagulant and flocculent addition, Such as Lime , FeCl2 and Poly electrolyte.
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AIR SUPPLY
SECONDARY CLARIFIER
TO TERTIARY TREATMENT
EXCESS TO THICKENER
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SECONDARY CLARIFIER The mixed liquor from the biological rector is sent to secondary clarifier for settling the bio mass and a portion is pumped to biological rector for reactivation.
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TERTIARY TREATMENT
To improve the quality of secondary treated effluent
By reducing the suspended solids. By reducing the colloidal particles. By destroying the micro organism. By reducing the alkalinity. By reducing the color and metal ions.
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TERTIARY CLARIFIER
SLUDGE SUMP
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It will remove the colloidal particles, silica, suspended solids, biological matters (bacteria, Algae, Fungi) and also to reduce the total organic compounds.
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PG
AV
PG PG PT PT
AV AV
PT PG
AV
AV FT
AV
ULTRAFILTRATION SYSTEM
PG PT
UF RECIRCULATION PUMP FT
UF FEED TANK
UF PERMEATE TANK
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Stage I
14 kg/cm2 2500 3000 mg/l
Stage II
40 kg/cm2 > 3000 mg/l
Recovery
75%
REVERSE OSMOSIS - I
PRESSURE VESSEL 1 ANTI SCALANT MICRON FILTER 5
PG
PG
AV
AV
ORP
PT PG
SDI PT
HCl
SMBS
PG
PG
FROM RO CIP
PT
MICRON FILTER 10
FT
60
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MCF
HPP HPP
HPP
RO Feed
Tank
Feed Pump
MCF
RO I, 1st Array RO II, 2nd Array RO Reject
3m3/h (10%)
RO Array Classification RO Stage I 5 X 6: 3 X 6 RO Stage II 2 X 5: 1 X 5 RO 1, 5 vessels and 3 vessels (48 elements) Stage I, Feed 5 membranes Stage II, Feed 3 membranes RO II, 2 vessels and 1 vessel (15 membranes) Stage I, Feed 2 membranes Stage II, Reject 1 membrane
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Parameters
RO Feed (ppm)
NH4+
HCO3 SO42NO3 SiO2
8.00
700.00 338.00 7.80 20.50
0.60
300.00 350.00 5.00 15.00
0.03
7.27 1.08 0.42 0.26
0.33
9.61 5.27 2.02 0.42 68
6000
RO Permeate Values in ppm
5000
RO Permeate - KOCH
4000
3000
2000
1000
0 TDS COD BOD Cl Ca2+ Mg2+ Na+ K+ NH4+ HCO3 SO42- NO3 SiO2 Parameters
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CONCLUSION
The overall performance of Reverse Osmosis Membranes is better in Textile industry. The Reverse Osmosis Membrane treatment is very effective in Textile industry. RO membrane was found to be more efficient and economical.
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CONCLUSION 90% - 93% of RO Permeate water can be used for recycling. Remaining 7% - 10% RO Reject water can be sent to Solar evaporation/Multiple evaporation for salt recovery.
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