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Climate has changed a lot over the last 50-100 million years! Large-scale cooling at the poles and lower latitudes.
Most oxygen occurs as the very abundant or as the much less abundant 18O isotope.
16O
isotope
8 P+ 10 N
Oxygen-16
16O
Oxygen-18
18O
When water evaporates, the lighter isotope molecule is preferentially evaporated. When precipitation occurs, the heavier isotope preferentially condenses.
Snow and ice is mostly H216O with very little H218O (which is left behind in the ocean).
However, gateway changes definitely redistribute heat and salt at high latitude sites.
Also impossible to study enough rivers to reach an accurate measure of global weathering.
In Summary
The cause of global cooling over the last 50 Myr remains uncertain.