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y a
Seven different combinations of edge lengths and inter axial angles Distinct Crystal System
1 2
3 4 5
6
7
3
1. Cubic Crystals
z
a=b=c = = = 90o
2. Hexagonal Crystals
z
Calcite
x b
3. Tetragonal Crystals
z
c Ruby Hematite x b
a=bc = = = 90o
c Quartz
x b
a=bc = = 90o
5. Orthorhombic Crystals
z
Topaz
Barite
x
a bc = = = 90o
6. Monoclinic Crystals
z
c Gypsum Muscovite x
a bc = = 90o
7. Triclinic Crystals
z
a bc
P (q,r,s) c
sc qa rb
Crystallographic Points
z
c a
1b
P (, 1, ) c y a
Y 0.5b
Z 0.5c
Projections
0.5 nm
Y 0.3 nm 0.4 nm
0a
Y 0.5b 0.5 1
Z 0.5c 0.5 1
Projections
0.5 nm
Y 0.3 nm 0.4 nm
0a 0 0
Reduction Reduction
Y 0.5b 0.5 1
Z 0.5c 0.5 1
Projections
0.5 nm
Y 0.3 nm 0.4 nm
0a 0 0
Reduction Reduction
[011]
Y 0.5b 0.5 1
Z 0.5c 0.5 1
Projections
0.5 nm
Y 0.3 nm 0.4 nm
0a 0 0
Reduction Reduction
[011]
Y 0.5b 0.5 1
Z 0.5c 0.5 1
Projections
0.5 nm
Y 0.3 nm 0.4 nm
0a 0 0
Reduction Reduction
[011]
[ 1 0] or [1 2 0] ?
y a
Crystallographic Planes
In all crystal structures other than hexagonal, crystallographic planes are specified by three Miller Indices (hkl) Any two planes parallel to each other are equivalent and have identical indices The unit cell system is the basis
a y
Crystallographic Planes
23
Determining h,k,l
1. If the plane passes through selected origin, select another origin 2. Read off intercepts of plane with axes in terms of a, b, c 3. Take the reciprocals of these numbers
A plane that parallels an axis has infinite intercept hence zero index
c a
x b
c/2
c y x b a x
c/2
y
y
inf a
-b
c/2
c a x x b
c/2
inf
-1
1/2
y
y
-1
c a x x b
c/2
y
y
Step 5:
(012)
O O
c/2 y
-b x x
is , index is 0 2. Intercept along Y-axis is b/2, intercept is 1/2, index is 2 3. Plane parallel to Z-axis is c, intercept is , index is 0
c
y
-b b x
1 indicates that the intercept along X-axis is a 1 indicates that the intercept along Y axis is b 0 indicates that the plane is parallel to the Z-axis