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Properties of Fluids
Viscosity
Kinematic viscosity
SI system sq.m/s
Metric system sq.cm/s (Stokes)
1sq.m/s = 10000stokes
Dynamic viscosity of both liquids and gases can be
considered to be independent of pressure over the
ranges of pressure normally encountered; however it
is affected by high pressures
u =
Properties of Fluids
Viscosity
Dynamic viscosity of both liquids and gases vary with
temperature
In gases, dynamic viscosity increases with increase in
temperature whereas in liquids it decreases with
increase in temperature
Kinematic viscosity of liquids and gases is a function
of temperature at a given pressure
( )
000221 . 0 , 03368 . 0 , 0179 . 0
,
1
1 1 0
0
2
1 1
0
= = =
+ +
=
B A poise Water
C in T
T B T A
T
Properties of Fluids
Vapour Pressure
All liquids possess a tendency to evaporate or vapourise
by continuous escape of molecules through the free
surface
If the liquid is confined in a closed vessel, the
accumulated vapour molecules (in the space above the
free surface) exerts a partial pressure on the liquid
surface vapour pressure of the liquid
Vapour pressure of a liquid increases with increase in
temperature
If the external absolute pressure on the liquid is reduced
such that it equals or becomes less than the vapour
pressure of the liquid, the liquid will boil at that
temperature
Properties of Fluids
Compressibility and Elasticity
Fluids possess elastic characteristics like elastic solids
can be compressed by application of an external
force and expand back to the original volume once
the external force is removed
Volumetric strain = Change in volume =
Original volume
Compressibility of a fluid is the reciprocal of bulk
modulus of elasticity
Bulk modulus of elasticity
( )
|
.
|
\
|
= =
o
o
dp
V
V
dp
K
V
V o
Properties of Fluids
Compressibility and Elasticity
SI system Unit of is N/m
Water 2.06 x 10 N/m
Air 1.03 x 10 N/m
(at normal temperature and pressure)
Bulk modulus of elasticity of a fluid is not a constant; it
increases with increase in pressure
In liquids, decreases with increase in temperature; in
gases, as temperature increases, pressure also increases
and hence increases
K
2
9
2
5
2
K
K
Properties of Fluids
Compressibility and Elasticity
In normal problems involving flow of liquids, the
effect of compressibility of the liquid is neglected
and the liquid is considered to be incompressible
In the case of gases, the effect of compressibility
cannot be ignored
Properties of Fluids
Surface Tension and Capillarity
A molecule within the body of a liquid is attracted equally
in all directions by other molecules surrounding it; but at
the surface between the liquid and the air above
(interface), the upward and downward attractive forces are
unbalanced
The liquid surface hence behaves as if it were an elastic
membrane under tension
Surface tension is measured as the force acting across the
unit length of a line drawn on the surface and acts in the
plane of the surface, normal to any line in the surface
It is the same at all points
o
Properties of Fluids
Surface Tension and Capillarity
Surface tension is constant at any given temperature at the
surface of separation of any two given substances
It decreases with increase in temperature
Cohesion enables a liquid to resist tensile stresses,
whereas adhesion enables it to stick to another body
Surface tension is due to cohesion between liquid particles
at the surface, whereas capillarity is due to both adhesion
and cohesion
The effect of surface tension is to reduce the surface area
of a free body of liquid to a minimum (drops of a liquid
tend to take a spherical shape)
Properties of Fluids
Surface Tension and Capillarity
Forces acting on a diametral plane through a spherical
drop of radius
Force due to internal pressure =
Force due to surface tension around the perimeter =
For equilibrium, these two forces must be equal
Hence,
r
2
r x p t
r x t o 2
r
p
o 2
=
In many problems, surface tension forces are
very small compared to other forces acting on
the fluid and is hence neglected
Properties of Fluids
Surface Tension and Capillarity
In the case of a spherical soap bubble, two surfaces are in
contact with air, one inside and the other outside the
bubble and each of these contributes the same tensile
force due to surface tension
The pressure force acting on the hemispherical section of
the soap bubble remains the same
Forces acting on a diametral plane through a spherical
drop of a soap bubble of radius
Force due to internal pressure =
Force due to surface tension around the perimeter =
For equilibrium, these two forces must be equal
Hence,
r
2
r x p t
r x t o 2 2
r
p
o 4
=
Properties of Fluids
Surface Tension and Capillarity
If the molecules of a liquid exhibit greater adhesion than
cohesion, it will wet a solid surface with which it is in
contact and viceversa
If a fine tube, open at both ends, is lowered vertically into
a liquid which wets the tube, the level of the liquid inside
the tube will rise at the point of contact above the level of
the free surface outside (the liquid surface inside will be
concave upwards and the angle of contact will be less than
90 degrees); if the liquid does not wet the tube, the level
of the liquid inside the tube will be lower than that of the
free surface outside (the liquid surface inside will be
concave downwards and the angle of contact will be
greater than 90 degrees)
Properties of Fluids
If the angle of contact
between the liquid
and the solid is and
the diameter of the
tube is , then,
Upward pull due to
surface tension =
component of surface
tension acting up x
perimeter of the tube
=
u
r d 2 =
r x t u o 2 cos
The only force opposing this upward pull is the weight of the vertical
column of water of height =
Equating these forces, we get,
h h x r x g
2
t
r r g
h
u o
u o cos 2 cos 2
= =
Properties of Fluids
Surface Tension and Capillarity
The angle of contact between glass and water is zero
The phenomenon of rise or fall of the liquid surface relative
to the surrounding general level of the liquid is called
capillarity
Capillary rise or capillary depression m or mm of the liquid
Smaller the radius of the tube, larger the capillary rise or
depression
Assumption meniscus of the curved liquid surface is a
section of a sphere (valid only for small tube diameters
radius < 2.5mm); liquids and the tube surfaces are clean
For tubes of diameter >6mm, capillary rise/depression is
insignificant
Equation of State Perfect Gas
The density of a gas is related to its absolute pressure and
absolute temperature by the equation of state, which for a
perfect gas can be written as
The absolute pressure is the pressure measured above absolute
zero (complete vacuum) = gauge pressure + atmospheric pressure
Absolute temperature in K (kelvin) = 273.15 + t in deg C
Units of - SI system N.m/kg/K = J/kg K = m /s K
The value of the gas constant depends on the gas
p
T
t cons gas the is R
T R m V p or T R p
tan
= =
R
2
2
Universal Gas Constant
The quantity is a constant at a given pressure and
temperature
By Avogadros hypothesis, all pure gases have the same
number of molecules per unit volume at the same
temperature and pressure
Hence is proportional to the molar mass (kg/kmol)
The quantity will be a constant for all perfect gases and is
called the Universal Gas Constant (8.314kJ/kmolK or 8314J/kg
K)
R
M
MR