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Atom
The smallest particle of an element that can enter into a chemical combination
Electrons
Negatively charged subatomic particles
Quantum
A discrete amount
Quantum Mechanics
The branch of physics that replaced the classical-mechanical view (that everything moved according to exact laws of nature) with the concept of probability
Photoelectric effect
The emission of electrons that occurs when certain metals are exposed to light
Photon
A particle of electromagnetic energy
Ground state
The lowest energy level of an atom
Excited states
The energy levels above the ground state in an atom
Fluorescence
The property of a substance, such as the mineral fluorite, of producing visible light while it is being acted upon by ultraviolet light
Phosphorescence
A glow of light that persists after the removal of the source of photons needed for excitation of the materials electrons
X-rays
High-frequency, high-energy, electromagnetic radiation formed when high-speed electrons strike a metallic target
Laser
An acronym for Light Amplification by Stimulated Emission of Radiation It is coherent, monochromatic light
Stimulated emission
Process in which an excited atom is caused to emit a photon
Chapter 10
Nucleus
The central core of an atom Composed of protons and neutrons
Protons
Positively charged particles in the nuclei of atoms
Neutrons
Neutral particles found in the nuclei of atoms
Nucleons
A collective term for neutrons and protons (particles in the nucleus)
Atomic number
Symbolized Z, it is equal to the number of protons in the nucleus of an atom of that element
Element
A substance in which all the atoms have the same number of protons - the same atomic number
Neutron number
The number of neutrons in the nucleus of an atom
Mass number
The number of protons plus the number of neutrons in a nucleus The total number of necleons
Isotopes
Forms of atoms of an element that have the same numbers of protons but differ in their numbers of neutrons
Atomic mass
The average mass of an atom of the element in naturally occurring samples
Radioactive isotope
An isotope that undergoes spontaneous decay
Radioactivity
The spontaneous process of a sample of a radionuclide undergoing a change by the emission of particles or rays
Alpha decay
The disintegration of a nucleus into a nucleus of another element, with the emission of an alpha particle
Beta decay
The disintegration of a nucleus into a nucleus of another element, with the emission of a beta particle
Gamma decay
An event in which a nucleus emits a gamma ray and becomes a less energetic form of the same nucleus
Half-life
The time it takes for half the nuclei in a sample of a given radionuclide to decay
Carbon-14 dating
A procedure used to establish the age of ancient organic remains by measuring the concentration of 14C and comparing it to that of present-day organic remains
Fission
A process in which a large nucleus is split into two intermediate-size nuclei, with the emission of neutrons and the conversion of mass into energy
Chain reaction
Occurs when each fission event causes at least one more fission event
Critical mass
The minimum amount of fissionable material necessary to sustain a chain reaction
Fusion
A process in which a smaller nuclei are fused to form larger ones, with the release of energy
Plasma
A high-temperature gas of electrons and protons or other nuclei
Mass defect
Any decrease in mass during a nuclear reaction
Chapter 11
Chemistry
The division of physical science that studies the composition and structure of matter and the reactions by which substances are changed into other substances
Compound
A substance composed of two or more elements chemically combined in a definite, fixed proportion by mass
Mixture
A type of matter composed of varying proportions of two or more substances that are just physically mixed, not chemically combined
Solution
A mixture that is uniform throughout A homogeneous mixture
Unsaturated solution
A solution in which more solute can be dissolved at the same temperature
Saturated solution
A solution that has the maximum amount of solute dissolved in the solvent at a given temperature
Solubility
The amount of solute that will dissolve in a specified volume or mass of solvent (at a given temperature) to produce a saturated solution
Supersaturated solution
A solution that contains more than the normal maximum amount of dissolved solute at a given temperature and hence is unstable
Molecule
An electrically neutral particle composed of two or more atoms chemically combined
Allotropes
Two or more forms of the same element that have different bonding structures in the same physical phase
Period
In physics, the time for a complete cycle of motion. In chemistry, one of the seven horizontal rows of the periodic table
Periodic law
The properties of elements are periodic functions of their atomic numbers
Groups
The vertical columns in the periodic table
Representative elements
The A group elements in the periodic table
Transition elements
The B group of elements in the periodic table
Metal
An element whose atoms tend to lose valence electrons during chemical reactions
Nonmetal
An element whose atoms tend to gain (or share) valence electrons during chemical reactions
Electron configuration
The order of electrons in the energy levels of an atom
Valence shell
An atoms outer shell, which contains the valence electrons
Valence Electrons
The electrons that are involved in bond formation, usually those in an atoms outer shell
Ionization energy
The amount of energy it takes to remove an electron from an atom
Ion
An atom, or chemical combination of atoms, that has a net electric charge
Noble gases
The element of Group 8A of the periodic table He, Ne, Ar, Kr, Xe, Rn
Alkali metals
The elements in Group 1A of the periodic table Li, Na, K, Rb, Cs, Fr
Halogens
The elements in Group 7A of the periodic table F, Cl, Br, I, At
Chapter 12
Formula Mass
The sum of the atomic masses of the atoms showing in the chemical formula of the compound or element
Limiting reactant
A starting material that is used up completely in a chemical reaction
Excess reactant
A starting material that is only partially used up in a chemical reaction
Octet rule
In forming compounds, atoms tend to gain, lose, or share electrons to achieve electron configurations of the noble gases
Ionic compounds
Compounds formed by an electron transfer process in which one or more atoms lose electrons and one or more other atoms gain them to form ions
Lewis symbol
The elements symbol represents the nucleus and inner electrons of an atom, and the valence electrons are shown as dots arranged around the symbol
Lewis Structures
electron dot symbols used to show valence electrons in molecules and ions of combounds
Cations
Positive ions; so called because they move toward the cathode (the negative electrode) of an electrochemical cell
Anions
Negative ions; so called because they move toward the anode (the positive electrode) of an electrochemical cell
Ionic bonds
Electrical forces that hold the ions together in the crystal lattice of an ionic compound
Stock system
A system of nomenclature for compounds of metals that form more than one ion A roman numeral placed in parentheses directly after the name of the metal denotes its ionic charge in the compound being named
Covalent compounds
Those in which the atoms share pairs of electrons to form molecules
Covalent bond
The force of attraction caused by a pair of electrons to form molecules
Electronegativity
A measure of the ability of an atom to attract shared electrons to itself
Polar molecule
A molecule that has a positive end and a negative end that is, one that has a dipole
Hydrogen bond
The dipole-dipole forces between a hydrogen atom in one molecule and a nearby oxygen, nitrogen, or fluorine atom in the same or a neighboring molecule
Chapter 13
Chemical properties
Characteristics that describe the chemical reactivity of a substance that is, its ability to transform into another substance
Chemical reaction
A change that alters the chemical composition of a substance
Reactants
The original substances in a chemical reaction
Products
The substances formed during a chemical reaction
Combination reaction
One in which at least two reactants combine to form just one product A+B > AB
Decomposition reactions
One in which only one reactant is present and breaks into two (or more) products: AB > A + B
Exothermic reactions
A reaction that has a net release of energy to the surroundings
Endothermic reactions
A reaction that absorbs energy from the surroundings
Activation energy
The energy necessary to start a chemical reaction A measure of the minimum kinetic energy that colliding molecules must possess in order to react
Acid-carbonate reaction
An acid and a carbonate (or hydrogen carbonate) react to give carbon dioxide, water, and a salt
Combustion reaction
The reaction of a substance with oxygen to form an oxide, along with heat and light in the form of fire
Catalyst
A substance that increases the rate of reaction but is not itself consumed in the reaction
Acid
A substance that gives hydrogen ions (or hydronium ions) in water
Equilibrium
In chemistry, a dynamic process in which the reactants are combining to form the products at the same rate at which the products are combining to form the reactants
Base
A substance that produces hydroxide ions in water
pH
A measure (on a logarithmic scale) of the hydrogen ion (or hydronium ion) concentration in a solution
Acid-base reaction
The H+ of the acid unites with the OH- of the base to form water, while the cation of the base combines with the anion of the acid to form a salt
Salt
An ionic compound that contains any cation except H+ combined with any anion except OH-
Double-replacement reactions
Reactions that take the form of AB + CD > AD + CB The positive and negative components of the two compounds change partners
Precipitate
An insoluble solid that appears when two clear liquids (usually aqueous solutions) are mixed
Oxidation
Occurs when oxygen combines with another substance (or when an atom or ion loses electrons)
Reduction
Occurs when oxygen is removed from a compound (or when an atom or ion gains electrons)
Activity series
A list of elements in order of relative ability to of their atoms to be oxidized in solution
Single-replacement reaction
Reactions in which one element replaces another that is in a compound A + BC > B + AC
Mole (mol)
The quantity of a substance that contains 6.02 x 1023 formula units (the number of atoms in exactly 12 g of carbon-12)
Avogadros number
6.02 x 1023, symbolized NA; the number of entities in a mole.
Molarity (M)
A measure of solution concentration in terms of moles of solute per liter of solution