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Materials
Latex
2 mol dm-3 of ethanoic acid.
2 mol dm-3 of ammonium solution.
Litmus paper.
Observation.
Ethanoic acid solution
Beaker A
Stirred
Latex
Ammonium solution
Beaker B
After a day, no
coagulation
occur.
Beaker C
Discussion:
1.How the natural coagulation of
latex can occur?
Positive charge from
bacteria’s action
H+ H H H+
+ +
H+ H+
H+ - - - H +
H+
- Negative charge H + - - -
- H+ -
H +
- - H+
- Rubber polymer H+ -
- H
+ -
- H
+
H -
+
- H+ H+ -
- H+
H+ - - + -
H+ Protein membraneH -
- - H+
H H - -
- -H+
+ +
- H+ H+
- - -
H +
H+ H+ H+ H
+
Neutralized particle
rubber
H+ H H H+
+ +
H+ H+
- - H +
H+
H+ - - H + - - -
- H+ -
H+ - - H+
H+ -
- -
- H
+
- H
+
H+ - H+ -
- H+ - H+
H -
+
- H+ - -
H+
- - - - H+
H+ - - - + H
+
H+ - H+
H - -
H+ H+ H+ H+ H
+
2. How acidic solution can quicken
the coagulation process of latex?
ETHANOIC ACID
Positive charge from acid
H+ H H H+
+ +
H+ H+
- - H +
H+
H+ - - H + - - -
- H+ -
H+ - - H+
H+ -
- -
- H
+
- H
+
H+ - H+ -
- H+ - H+
H -
+
- H+ - -
H+
- - - - H+
H+ - - - + H
+
H+ - H+
H - -
H+ H+ H+ H+ H
+
Neutralized particle
rubber
H+ H H H+
+ +
H+ H+
- - H +
H+
H+ - - H + - - -
- H+ -
H+ - - H+
H+ -
- -
- H
+
- H
+
H+ - H+ -
- H+ - H+
H -
+
- H+ - -
H+
- - - - H+
H+ - - - + H
+
H+ - H+
H - -
H+ H+ H+ H+ H
+
3. Why alkaline solution able to
prevent coagulation to occur?
Ammonium solution / alkaline solution
Rubber particles still
remain it negative charges
- - and coagulation can not
OH- OH OH - -
- OH OH
OH - occur. OH -
- H +
H + OH
OH H+ H+ OH- H+ H H
+ +
- - H+
H + - - - H+ - - -
- H + OH - + OH
-
-
OH H+ - - - H
OH H + -
- + OH
-
- -
- H - H+ OH
-H+ -
OH OH- H -
+
- H+ OH- - H+OH-
H+ - - H+ - -
OH -
- - H +
OH -
- H+OH-
OH - -
H+ - - - H+ H+ - - H+
-
OH- H+ H+ H+ OH- OH- H+ H+ H+ OH-
OH- OH- OH- OH- OH- OH-