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1. Introduction The key to improve the material property is to change its structure at atomic level. This can be achieved through (i) alloying and controlled heat and cooling basically heat treatment
The basic steps of heat treatment are: Heat -> Soaking -> Cooling
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Full annealing Normalizing Process Anneal - Recrystallization anneal - Recovery Anneal Stress-relief annealing
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Martensite, M
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Eutectic
Eutectoid Fe3C
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Heat treatment
6. Precipitation hardening
A necessary condition for metals that can be heat treated to be hard is - Martensite formulation, which includes the following points: (a) The composition of metal, in the range 0.1-0.8 % C;
(b) The Ms should be above the room temperature;
(c) The TTT curve should allow the possibility that the cooling trajectory passes on the left of the nose.
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- Necessary condition may not be met in practice for all compositions of steel
- Further, heat treatment for non-ferrous metals, e.g., aluminum, copper, magnesium, do not follow the martensite formation. This calls for a new process.
(1) Composition of the metal has two phases at the room temperature, see Figure 1a (next slide).
(2) When the temperature arises, one phase should be be dissolved, i.e., sloping solvus line
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6. Precipitation hardening
Figure 1a, b
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6. Precipitation hardening
3 steps of precipitation/age hardening: (1) Solution treatment - alloy heated above Ts into alpha-phase and held to dissolve the beta phase (2) Quenching - to the room temperature to create a supersaturated solid solution - It is noted that the structure of martensite is of highly distorted BCC plus excessive carbon dissolved; Figure 2. Supersaturated structure that same feature. 18 Handoutshas 2
- Reheat the material to the temperature a little bit above the room temperature, Tp, but below Ts, to cause precipitation of fine particles of the beta phase.
- high strength and hardness achieved in this step - Temp. and time for the step are variables. Higher temp. hardness peaks quickly lower temp more time to harden, but hardness is more
Figure 2
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Nitriding
Carburizing -> HRC 60, Thickness: 0.025 4 mm Nitriding -> HRC 70, Thickness: 0.025 0.05 mm
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2. Surface hardening methods - flame hardening - induction heating - Laser beam heating
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