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QUIZ
What
is the molarity of a KSCN solution if 23.15ml was used to backtitrate a solution containing pure 1.1956 g of Barium Chloride (BaCl2; MW=208.23g/mol) dissolved in 52 ml of 0.4489 M Silver Nitrate?
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Complexometric Titration
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HISTORY
Justus Metal Ag
and Hg Ions
Ligands
are Cl and CN ions Monodentate only silver and Hg form stable complex with these Ligands.
However
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HISTORY
Schwarzenbach
Aminocarboxylic
ligands
Forming
ions
Analytical
Purposes was establish when metallochromic dyes were introduced. dyes visual indicators for complexation reactions
Metallochromic
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binding sites
Metal-ligand
stable
All
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= 0.0 pKa2 = 1.5 pKa3 = 2.0 pKa4 = 2.68 pKa5 = 6.11 pKa6 = 10.17 carboxylate ions must be ionized ammonium ions should be non ionized only if pH > 10.17
Achieved
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We
However
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form
Standardized Procedure:
Weigh
Dissolve Transfer
flask
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Standardization
0.1
M EDTA solution was standardized using Metallic Magnesium. 0.2414 g of Mg Metal was weighed and prepared for standardization. The EDTA solution consumed is 25 ml. What is the exact Concentration of EDTA solution?
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Calcium Determination
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Erichrome
At
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Murexide
Endpoint
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Erichrome
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Nickel Containing
pH
Murexide
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Aluminum Picky
pH
Too
Sulfate as Backtitrant
Indicator
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of amount of Mg and Ca in
water
High
procedure
Transfer Acidify Bring
exactly 50 mL of water to 250 mL Erlenmayer flask. the solution with hydrochloric acid. with ammonia. to boil, cool down.
Alkalize
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1 5 8 12
2 6 9 13
4 7 11 15
10 EDTA Back
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EXAMPLES
You
are using EDTA with a molarity of . 0080 for the titration. You titrate 50.00 mL of water sample using 10.68 mL of EDTA. is the CONCENTRATION of Ca2+ion?
What
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EXAMPLES
What
is the %w/w Ca ion content of a milf formula if 0.453 g of the powder was titrated with 23.17 ml of 0.1337 M EDTA Solution to a murexide endpoint?
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EXAMPLES
A
200 mg Aluminum Hydroxide tablet was dissolved in acetate buffer. What is the actual concentration of Aluminum Ions in the solution if 50 ml of 0.1 M EDTA solution is used as an excess titrant and is backtitrated with 30ml of 0.0983 M Zinc Sulfate to a pink endpoint?
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Standardization example
A
0.0352 g sample of pure calcium carbonate (100.09 g/mol) was dissolved in acid and titrated to its endpoint with newly made EDTA titrant (~0.010 M) according to the procedure given below. The starting burette volume was 0.10 mL. The ending burette volume was 35.52 mL. Calculate the exact concentration of the EDTA titrant. Show all work.
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SAMPLE PROBLEM
A
0.0456 g sample of an unknown sample was titrated using the EDTA titrant from question 1 and the procedure below. The starting burette volume was 0.05 mL. The ending burette volume was 42.35 mL. Calculate the % calcium oxide (CaO; 56.0774 g/mol) by mass in the sample.
What What
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WATER HARDNESS
100.0
mL of an unknown water sample was titrated using the EDTA from question 1 and the procedure below. The starting volume was 0.25 mL and the ending volume was 20.53 mL. Calculate the concentration of Ca2+in the tap water. Show all work.