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Chapter 1: Structure and Physical Properties of Organic Compounds Chapter 2: Reactions of Organic Compounds
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Section 1.1
Modern Definitions
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Section 1.1
Carbon can bond to four different atoms, producing a molecule with a tetrahedron shape.
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Section 1.1
Isomers
Most organic molecules consist of more than one carbon atom bonded together in a chain or ring structure. Molecules with the same molecular formula but atoms in different arrangements are known as isomers. Constitutional or structural isomers: molecules with the same molecular formula, but the atoms are bonded in a different sequence.
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Section 1.1
Isomers
Stereoisomers: molecules with the same molecular formula and sequence of atoms, but they differ in the three-dimensional orientation of their atoms diastereomer: stereoisomers based on the presence of a double bond enantiomer: stereoisomers that are mirror-images of each other.
These molecules are diastereomers.
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Section 1.1
LEARNING CHECK
Are the following molecules isomers? If so, what type of isomers are they?
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Section 1.1
LEARNING CHECK
Yes they are isomers.
They are stereoisomers, not constitutional isomers.
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Section 1.1
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Section 1.2
1.2 Hydrocarbons
Hydrocarbons are composed of only carbon and hydrogen. The different classes are:
cyclic hydrocarbons
alkanes
alkenes
aromatic hydrocarbons
alkynes
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Section 1.2
Drawing Hydrocarbons
Five ways to represent hydrocarbon molecules are:
structural formula
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Section 1.2
Alkanes
Contain only single covalent bonds. The general formula for straight and branched-chain alkanes: CnH2n+2. When naming and drawing alkanes: identify the root, suffix, and prefix.
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Section 1.2
Alkenes
Contain one or more double bonds. The general formula for straight and branched-chain alkenes: CnH2n. When naming and drawing alkenes: identify the root, suffix and prefix.
For main chains with more than four carbons, the position of the double bond must be indicated.
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Section 1.2
LEARNING CHECK
Name the following hydrocarbon and draw its condensed structural formula.
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Section 1.2
LEARNING CHECK
The name is: pent-2-ene The condensed structural formula is:
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Section 1.2
Alkynes
Contain one or more triple bonds. The general formula for straight and branched-chain alkynes: CnH2n-2. When naming and drawing alkynes: identify the root, suffix, and prefix.
For main chains with more than four carbons, the position of the double bond must be indicated.
4-ethylhex-2-yne.
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Section 1.2
Cyclic Hydrocarbons
Contain carbon-based ring structures. Most are alkanes or alkenes. The general formula for cyclic alkanes: CnH2n. When naming and drawing cyclic hydrocarbons: identify the root, suffix, and prefix.
Carbon atoms of a multiple bond are numbered 1 and 2, and side groups are the lowest possible numbers.
3,4-dimethylcyclopentene
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Section 1.2
Aromatic Hydrocarbons
Hydrocarbons that are derived from benzene, C6H6. When naming and drawing aromatic hydrocarbons identify the root and prefix. If a benzene ring is bonded to a hydrocarbon chain that is more than six carbons long, the benzene ring is a phenyl side group.
Benzene is best represented by the resonance hybrid structure. This aromatic hydrocarbon is 1-methyl-4-propylbenzene.
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Section 1.2
LEARNING CHECK
A student has named a hydrocarbon as 1-ethyl-5-propylbenzene. Use a drawing of the structure to show why that name is incorrect. What is the correct name?
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Section 1.2
LEARNING CHECK
The structure is shown below. Since the side groups should be identified using the lowest possible numbering, the correct name is 1-ethyl-3-propylbenzene
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Section 1.2
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Section 1.2
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Section 1.3
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Section 1.3
Hydrocarbon Derivatives
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Section 1.3
Alcohols
Contain a hydroxyl functional group, -OH When naming and drawing alcohols, identify the
root (longest chain with the OH group) suffix (add ol to the end of the parent alkane name) prefix (name and number the alkyl side groups)
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Section 1.3
Haloalkanes
Contain one or more halogen atoms (F, Cl, Br, I). When naming and drawing haloalkanes, identify the
root (longest chain with the halogen) suffix (use the alkane name) prefix (name and number the alkyl side groups and halogens)
1,3-dichloro-3-fluoro-2methylbutane
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Section 1.3
LEARNING CHECK
Draw the structural formula for fluoroethane.
Explain why numbers are not required in the prefix of the name.
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Section 1.3
LEARNING CHECK
Because there are only two carbon atoms, the number 1 is not used in the prefix to designate the position of the halogen.
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Section 1.3
Aldehydes
Contain a formyl group. When naming and drawing aldehydes, identify the
root (longest chain with the formyl group) suffix (ends in al) prefix (name and number the alkyl side groups)
3,4-dimethylpentanal
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Section 1.3
Ketones
Contain a carbonyl group bonded to two carbons. When naming and drawing ketones, identify the
root (longest chain with the carbonyl group) suffix (position of the carbonyl carbon is indicated and ends in -one)
Butanone
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Section 1.3
Carboxylic Acids
Contain a carboxyl group.
root (longest chain with the carboxyl group) suffix (ends in oic acid ) prefix (name and number the alkyl side groups)
2-ethylhexanoic acid
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Section 1.3
LEARNING CHECK
What functional group do aldehydes, ketones, and carboxylic acids have in common?
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Section 1.3
LEARNING CHECK
The carbonyl group
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Section 1.3
Esters
Contain a carbonyl group with another oxygen singly bonded to the carbon. When naming and drawing esters, identify the
root (the acid part) suffix (ends in oate )
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Section 1.3
Ethers
Contain an oxygen atom singly bonded to two carbon atoms (R-O-R)
When naming and drawing ethers, identify the
root (longest chain, or R group) suffix (ends according to the main chain) prefix (indicate the alkoxy group then side groups)
An ether is composed of an alkoxy group and parent alkane chain that are connected by an oxygen.
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Section 1.3
Amines
Primary (R-NH2), secondary (R2-NH), or tertiary (R3-N) When naming and drawing amines, identify the
root (longest chain bonded to the nitrogen) suffix (ends in amine and indicate position of the N) prefix (indicate alkyl groups on N)
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Section 1.3
Amides
Contain a carbonyl group bonded to a nitrogen
root (longest chain with the carbonyl) suffix (ends in -amide ) prefix (alkyl groups on N, then on main chain)
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Section 1.3
LEARNING CHECK
Draw the condensed structural formula for each of the following:
a. Methylethanoate b. 1-ethoxypropane c. N-ethylpentamide
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Section 1.3
LEARNING CHECK
a.
b.
c.
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Section 1.3
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