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Overview of Section 2
Content:
Describe the atom in terms of protons and neutrons in the nucleus Explain and describe the electrons in terms of energy levels, ionisation energy, atomic orbitals and extranuclear structure
The Greek philosopher Democritus (460 B.C. 370 B.C.) was among the first to suggest the existence of atoms (from the Greek word atomos)
He
believed that atoms were indivisible and indestructible His ideas did agree with later scientific theory, but did not explain chemical behavior, and was not based on the scientific method but just philosophy
3) Atoms of different elements combine in simple whole-number ratios to form chemical compounds 4) In chemical reactions, atoms are combined, separated, or rearranged but never changed into atoms of another element.
of subatomic
particles.
J. J. Thomson
Thomson believed that the electrons were like plums embedded in a positively charged pudding, thus it was called the plum pudding model.
Alpha particles are helium nuclei The alpha particles were fired at a thin sheet of gold foil Particle that hit on the detecting screen (film) are recorded
Rutherfords Findings
Most of the particles passed right through A few particles were deflected VERY FEW were greatly deflected
Conclusions:
a) The nucleus is small b) The nucleus is dense c) The nucleus is positively
charged
Based on his experimental evidence: The atom is mostly empty space All the positive charge, and almost all the mass is concentrated in a small area in the center. He called this a nucleus The nucleus is composed of protons and neutrons The electrons distributed around the nucleus, and occupy most of the volume His model was called a nuclear model
change to Daltons atomic theory is that atoms are divisible into subatomic particles:
Electrons,
protons, and neutrons are examples of these fundamental particles There are many other types of particles, but we will study these three
Atomic particles Section 2(a),(b),(c) Identify and describe protons,neutrons and electrons in terms of their relative charges and relative masses. Deduce the behavior of beams of protons, neutrons and electrons in electric fields. Describe the distribution of mass and charges within an atom
1916 Robert Millikan determines the mass of the electron: 1/1840 the mass of a hydrogen atom; has one unit of negative charge
Summary Table
Therefore Modern picture of an atom, then, consist of three types of particles-electrons, protons and neutron.
Electric Charge Particle SI (C ) Atomic Electron -1.602x10-19 -1 Proton +1.602x10-19 +1 Neutron 0 0 Mass SI (g) 9.109x10-28 1.673x10-24 1.675x10-24
Subatomic Particles
Particle
Electron (e-) Proton (p+)
Rel Charge
-1
Rel Mass
Location
1/1840
Electron cloud
+1 0
1 1
Nucleus Nucleus
Neutron (no)
Interaction of charged particles in electric field Non-interaction of Non-charged particles in electric field Direction of deflection depends on the charge of the particle Magnitude of deflection depends on the mass of the atomic particles when the magnitude of charge is the same
Question 1.Beams of particles traveling at the same speed from different sources are subjected to an electric field as shown in the diagram below. A beam of neutrons has already been drawn.
Sketch on the diagram above how beams of each of the following particles are affected by the electric field: (i) protons; (ii) electrons; (iii)
2 1H
Label each of the beams. Explain briefly the position and shape of each beam: (i) protons;(ii) electrons and (iii) 21H
Section 2(d)
Learning Outcomes
Deduce the numbers of protons, neutrons and electrons present in both atoms and ions given proton and nucleon numbers( and charge)
Proton Number
Atoms are composed of protons, neutrons, and electrons How then are atoms of one element different from another element? Elements are different because they contain different numbers of PROTONS The proton number of an element is the number of protons(#) in the nucleus
Proton Number
Proton number (Z) of an element is the number of protons in the nucleus of each atom of that element.
Element
Carbon
# of protons
6
Z
6
Phosphorus
Gold
15
79
15
79
Nucleon Number(A)
Nucleon number is the number of protons and neutrons in the nucleus of an isotope: A = p+ + n0 Nuclide
Oxygen - 18
Arsenic - 75 Phosphorus - 31
p+
8 33
15
n0
10 42
16
e8
33
15
A
18 75 31
Complete Symbols
Contain the symbol of the element, the nucleon number and the proton number. Nucleon Superscript Number(A)
Subscript
Proton Number(Z)
Symbols
Find each of these: a) number of protons b) number of neutrons c) number of electrons d) Proton number e) Nucleon Number
80 35
Br
Symbols
If an element has an proton number of 34 and a nucleon number of 78, what is the: a) number of protons b) number of neutrons c) number of electrons d) complete symbol
Symbols If an element has 91 protons and 140 neutrons what is the a) Proton number b) Nucleon number c) number of electrons d) complete symbol
Symbols If an element has 78 electrons and 117 neutrons what is the a) Proton number b) Nucleon number c) number of protons d) complete symbol
Note
In a neutral atom , the number of electrons is equal to the number of protons. In a negative ion (anion), the number of electrons is greater than the number of protons since a negative ion is obtained by adding electron(s) to a neutral atom. In a positive ion(cation), the number of electrons is less than the number of protons since a positive ion is obtained by removing electron(s) from a neutral atom.
Ions
is an electrically charged particle obtained from an atom or chemically bonded group of atoms lose or gain electrons. The charge on an ion is equal to the # of protons minus the # of electrons. An atom that gains extra electrons becomes a negatively charged ion, called an anion. An atom that loses electrons becomes positively charged ion, called a cation. number p + number n number p - number e A +?
number p
E Z
E.g. Determine numbers of electrons in Mg2+ cation and the S2anion? Mg2+ 12-number e = +2 S216-number e = -2 number e =10 number e =18
32 15
32 15
P 3
May/June 2008
32 15
Skin cancer can be treated using a radioactive isotope of phosphorus,3215P . A compound containing the phosphide ion 3215P3- , is wrapped in a plastic sheet, is strapped to the affected area. What is the composition of the phosphide ion, 3215P3 ?
Protons A B C D 15 15 17 32
Neutrons 17 17 15 17
electrons 18 32 17 15
Outcome:
Distinguish
Isotopes
Dalton was wrong about all elements of the same type being identical Atoms of the same element can have different numbers of neutrons.( see next slide) Thus, different nucleon numbers. These are called isotopes. Isotopes have the same chemical properties but different properties(e.g denstiy, mass)
Isotopes
Elements occur in nature as mixtures of isotopes.
Naming Isotopes
We
can also put the nucleon number after the name of the element:
carbon-12 carbon-14 uranium-235
Isotopes are atoms of the same element having different masses, due to varying numbers of neutrons.
Isotope Protons Electrons Neutrons Nucleus
1 1 1
1 1 1
0 1 2
i)
[2] ii) Br has 2 main isotopes. Complete the table below show the atomic structure of these isotopes. [2]
-
Isotope
79Br
81Br
Protons
Neutrons
Electrons
iii)
The percentage composition by mass of the isotopes in part (b) is 50.5% 79Br and 49.5% 81Br. Use this data to calculate the relative atomic mass of bromine to three significant figures.
[2]
Our understanding of atom is still in growing. The unknowns are yet to be discovered.
Outcomes
Describe
the number and relative energies of the s,p, and d orbitals for the principal quantum numbers 1, 2, and 3 and also the 4s and 4p Describe the shapes of s and p orbitals
What is an orbital?
An atomic orbital is a region of space(3 dimensional) round the nucleus in which the probability of finding a particular electron( in a free atom) is the greatest. Electrons can occupy four types of orbital, which differ from each other in shape and in their orientation in space. These are called s,p, d and f orbitals.
s orbitals are spherical p orbitals are dumb-bell-shaped and can be arranged in different directions.
Question
Sketch the shapes of and spatial distributions of all the occupied orbitals in nitrogen
Answers
1s
2s
2pz
2px
2py
Analogy
What is a shell?
A shell is a group of orbitals that are about the same distance out from the nucleus.
Shells are numbered starting with the shell nearest to the nucleus and working outwards Each successive shell has a different number of orbitals in it. In the nth shell, there are n sub-shells, n2 orbitals and a maximum of 2n2 electrons.
1 3 5 7 32
What is a sub-shell?
A sub-shell is a group of orbitals with the same energy level, but differ in their orientation in space, e.g. the second shell (n=2) contains two sub-shells:
a sub-shell containing one s orbital, and a sub-shell containing three p orbitals: 2px,2py,2pz
Section 2(h)
Learning Outcome
State the electronic configuration of atoms and ions given the proton number( and charge)
The electronic configuration of an element describes how the element of its atoms are arranged in their shells, sub-shells and orbitals.
Filling of orbitals
In an atom, the orbitals are filled in order of increasing energy(starting from 1s) according to the following rules.
N=3
n=2
Electronic Configurations
The Electron Configuration A short hand method for notating the electronic structure of atoms. Write the electron configuration for sodium. Sodium has 11 electrons. We know this because it has an atomic number of 11 which means it has 11 protons and thus must have 11 electrons. 1s22s2p63s1 or [Ne]3s1
1s22s22p63s1
Question
Construct a schematic diagram representing the number and relative energies of the orbitals of the first three principal quantum numbers.
Answers
3d
3p
3s Energy 2p 2s
1s
Question
Show the electronic configuration of nitrogen using the diagram in the previous answer
Answer
Energy
2p 2s
1s
Isoelectronic
Atoms that have the same number of electrons are known as isoelectronic.
Oct/Nov 2007
Use the Data Booklet is relevant to this question. In forming ionic compounds, elements generally form an ion with the electronic structure of a noble gas. Which ion does not have a noble gas electronic structure?
A. IB Rb+ C Sn 2+ D Sr 2+
By using electrons-in-boxes Using a noble gas core Using the s, p, d and f notation
Learning Outcomes
(i) explain and use of the term ionisation energy (ii) explain the factors influencing the ionisation energies of elements (iii) explain the trends in ionisation energies across a period and down a group of the Periodic Table.
Definition of IE
The energy to remove an electron from each atom/ion in a mole of atoms/ions of an element in the gaseous state Refer to data booklet for successive IE energies
Generally increase of IE is due to the consecutive electron removed because it is harder to remove electrons from the more positive ion. Large rise of IE implies that electron are removed from a different principal shell. Small increase of IE represent change in subshell.
Explanation of IE
Explain large rise in IE. When all valence shell electrons are removed, only the inner shell remains. The inner shell experience much less shielding , resulting in a higher nuclear attraction and therefore lead to a much higher IE big jump Explain small increase in IE. Electrons in higher level subshell removed first; after which electrons from lower energy subshell removed. For example, 3p electrons are removed before 3s. Lower subshell electron experience slightly higher nuclear attraction and therefore slightly higher IE small jump
Factors influencing IE
The size of the positive nuclear charge The distance of the electron from the nucleus The shielding effect by electrons in filled inner shells
Across the period, nuclear attraction on the valence electron increases. This is due to the increase in proton number,Z but a fairly constant shielding
Down the group, nuclear attraction on the valence electron decreases. This is due to great increase in Screening Effect,SE with atom having more inner shells.
IE depends on the effect of the nuclear attraction on the valence electron. Across the period, IE increases since the proton number increases but the shielding effect remains fairly constant. IE do not increase uniformly. Small kink may be produced, where the IE is lower than normal. 2 possible reasons(i) electron is removed from the higher energy subshell. Less energy is required to remove p-electron (ii) paired vs unpaired electron is removed. Paired electron experiences repulsion makes a removal easier( use only in p orbital) Always write out the electronic configuration to figure out the reason for non-uniformity.
IE down the group will decrease dramatically, since the effect of the nuclear attraction on the valence electron decreases significantly due to increase in number of principal quantum electron shells(inner shells) . Outer shell experiences much higher shielding effect which outweighs(greater weight attached to the effect) increase of nuclear charge. SE > Z
Importance of IE
To predict or confirm the simple electronic configurations of elements An example. the first four IE of an element are, in kJ per mol: 590,1150,4940,6480. Suggest the Group in the Periodic table to which this element belongs
Oct/Nov 2007
The graph show the first thirteen IE ionisation energies for element X What can be deduced about element X from the graph? A It is in the second period (Li-Ne) of the Periodic Table B It is a d-block element C It is in the Group II of the Periodic Table D It is in Group III of the Periodic Table
i)
Define the term first ionisation energy and write an equation to represent the first ionisation energy of chlorine. Definition
[3] Equation ii) Write an equation to show the fourth ionisation energy of nitrogen. Equation iii) State and explain the trend in first ionisation energies down group 2 in the Periodic Table. [2]
[2]
[4]
Ionisation number
i)
1st
2nd
3rd
4th
5th
6th
7th
Ionisation energy / kJmol1 1402 2856 4578 7475 9445 53268 64362
Explain why the successive ionisation energies show a general increase.
[2]
ii)
What can be deduced about the electronic structure of the nitrogen atom? Explain your deductions carefully.
[4]
i) ii) iii)
Define the term isotope. Br has 2 main isotopes. Complete the table below show the atomic structure of these isotopes. The percentage composition by mass of the isotopes in part (b) is 50.5% 79Br and 49.5% 81Br. Use this data to calculate the relative atomic mass of bromine to three significant figures.
Mark scheme i) Substances consisting of atoms with same atomic number / same number of protons / of the same element 1 but with different mass number / different numbers of nucleons / different neutron numbers 1 ii)
Isotope
iii)
Protons
Neutrons
Electrons
35 35
1
79 all 2 marks Br correct 35 1 mark 1 row or 2 columns correct 79 35 = 44 A r =81 x 0.505) + (81 x 0.495) (79 Br 35 81 35 = 46 = 79.99% 80.0% to 3 sig. figs.
i)
ii) iii)
Define the term first ionisation energy and write an equation to represent the first ionisation energy of chlorine. [5] Write an equation to show the fourth ionisation energy of nitrogen. [2] State and explain the trend in first ionisation energies down group 2 in the Periodic Table. [3]
ii) iii)
Energy required to remove first electron from each atom 1 in one mole of 1 gaseous atoms (to form one mole of gaseous +1 ions) 1 Equation: Cl (g) Cl + (g) + e 1 for species, 1 for state symbols N +3 (g) +4 (g) + e 1 for species, 1 for state symbols First ionisation energies decrease as group 2 is descended 1 Number of shells and hence atomic radii increase down the group 1 Greater number of shells means shielding increases 1 Overall, the outer shell electrons are further from the nucleus and less strongly attracted to it 1 These factors are more important than the increase in nuclear charge 1 Maximum 4 marks
The successive ionisation energies for nitrogen are show below. Ionisation number 1st 2nd 3rd 4th 5th 6th 7th i) Explain why the successive ionisation energies show a general increase. [2] Ionisation energy / kJmol1 1402 2856 4578 7475 9445 53268 64362 ii) What can be deduced about the electronic structure of the nitrogen atom? Explain your deductions carefully. [4]
Mark scheme i) Negative electrons are being removed from an increasingly positive ion / there is a greater proton to electron ratio. 1 The attraction between the nucleus and the remaining electrons increases. 1 Also, the repulsion amongst the remaining electrons decreased 1 Maximum 2 marks ii) There is a large increase in ionisation energy when the 6th electron is removed. 1 The 6th electron is removed from a new shell 1 that is closer to the nucleus with less shielding. 1 Within a shell, the increase in ionisation energy is much smaller. 1 So nitrogen has 5 electrons in outer shell and 2 in shell closer to the nucleus. 1 Maximum 4 marks