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CHEMISTRY EDUCATION STUDY PROGRAMMED DEPARTMENT OF MATHEMATICS AND NATURAL SCIENCE EDUCATION FACULTY OF TEACHER TRAINING AND EDUCATION SEBELAS MARET UNIVERSITY SURAKARTA 2012
: SMA : Chemical : X.RSBI :1 : Redox Reaction : 1. Describe the characteristic of solutions, method of
measurement and its application Basic Competence : 1.1. reaction Determine development of oxidation reduction concept and relation with compound
I. Indicators: a. Cognitive
1. Product
2. Process
b. Affective
Observation about oxidation Observation reduction reaction Observation the oxidation number of compound Observation the oxidation agent and the reduction agent
1. Character
a. Curiosity b. Honest c. Hard work d. Tolerance e. Communicative f. Rewarding achievement g. Responsibility h. Discipline i. Creative
2. Social Skills
2. Process
Students can explain reduction reaction if given a reaction correctly Students can explain oxidation reaction if given a reaction correctly Students can explain oxidation number if given a reaction
Students can distinguish about oxidation and reduction reaction if given a reaction correctly Students can determine the oxidation number if given a reaction correctly Students can determine the oxidation agent and the reduction agent if given a reaction correctly
b. Affective
1. Character
a. Curiosity b. Honest
2. Social Skills
III. Core Material : Definition Early chemists saw oxidation reactions only as the combination of a material with oxygen to produce an oxide. For example, when methane burns in air, it oxidizes and forms oxides of carbon and hydrogen. But, not all oxidation processes that use oxygen involve burning: Elemental iron slowly oxidizes to compounds such as iron (III) oxide, commonly called rust Bleaching stains in fabrics Hydrogen peroxide also releases oxygen when it decomposes
A process called reduction is the opposite of oxidation, and originally meant the loss of oxygen from a compound. Oxidation and reduction always occur simultaneously. The substance gaining oxygen (or losing electrons) is oxidized, while the substance losing oxygen (or gaining electrons) is reduced. Today, many of these reactions may not even involve oxygen. Redox currently says that electrons are transferred between reactants. Mg + S Mg2+ + S2 The magnesium atom (which has zero charge) changes to a magnesium ion by losing 2 electrons, and is oxidized to Mg2+
2 Na Cl 2 2 Na Cl
Each sodium atom loses one electron:
0 1
Na Na e
Each chlorine atom gains one electron:
Cl e Cl
In water, we learned that oxygen is highly electronegative, so: the oxygen gains electrons (is reduced and is the oxidizing agent), and the hydrogen loses electrons (is oxidized and is the reducing agent) Oxidation Numbers Define oxidation and reduction in terms of a change in oxidation number, and identify atoms being oxidized or reduced in redox reactions. o An oxidation number is a positive or negative number assigned to an atom to indicate its degree of oxidation or reduction. o Generally, a bonded atoms oxidation number is the charge it would have if the electrons in the bond were assigned to the atom of the more electronegative element.
Rules For Assignment Of Valences 1. The valence of all pure elements is zero. 2. The valence of H is +1, except in hydrides, where it is -1. 3. The valence of O is -2, except in peroxides, where it is -1. 4. The algebraic sum of valences must equal zero for a neutral molecule or the charge on a complex ion.
1 2
2 1
H2O
2(+1) + (-2) = 0 H O
Ca (O H ) 2
(+2) + 2(-2) + 2(+1) = 0 Ca O H
IV. Learning Method: Learning Method : expository learning V. Learning Scenario No. A. Activity Beginning Activity a. Apperception Ask to student Why an apple can be change the color after its cut? b. Orientation Tell about Learning purposes today. c. Motivation Motivate the students about the materials and tell them about the advantages of this materials. B. 1. Core Activity Teacher give a simple lesson (explanation) about reduction and oxidation definition. Curious Creative, Confidence, and hard work 2. Teacher divide student into 2 group (one group consist of two students). Appreciate achievement, cooperation, creative 3. 4.
Teacher give a task for each group. Student discuss the task.
Time
Character
Curious
5 Minutes
Discipline
20 minutes
5.
6.
Curiosity
Activity
Time
Character
guidance
teacher
make
conclusion of learning results today. b. Teacher giving homework to doing exercise 5 Minutes
VI.
A. Sources Justiana, Sandri and Muchtaridi. 2009. Chemistry for Senior High School. Jakarta: Yudistira Purba, Michael. 2004. Kimia Jilid IB untuk Kelas X SMA. Jakarta : Erlanggga Susilowati, Endang. 2009. Theory and Application of Chemistry. Solo: Tiga Serangkai B. Tools and Materials Redox reaction power point Laptop LCD Whiteboard Markers
VII.
ATTACHMENT
One sheet of questions One sheet of questions One sheet of affective Surakarta, March 20th 2012 Teacher
ASSESSMENT SHEET
Score 40
1. Determine the agent of oxidation and reduction from this reaction below : Ag2O (s) + C (s) Answer: The agent of reduction is oxidator : 2 Ag+ 2 Ag C2+ (score : 40) 2. Determine the oxidation number of this compound: 1. 2. 3. S in HSO4Mn in KMnO4 Cr in Cr2O722 Ag (s) + CO (g)
Answer: 3. S in HSO4BO H + BO S + 4 . BO O = -1 1 + BO S + 4 . ( -2 ) = -1
BO S 7 = -1 BO S = +6 (score : 20)
4.
Mn in KMnO4 BO K + BO Mn + 4 . BO O = 0 1 + BO Mn + 4 . ( -2 ) = 0 BO Mn 7 = 0
BO Mn = +7
(score :20)
5.
: Chemistry : X : :
Aspects that be rated Presence Cooperative in group Creative Hard work y Curiosity Responsibilit Confidence N o Name Total assessment
1 2 3 4
5
Scale of assessment :
Assessment =
maximum score
= 24