CHEMISTRY

D-1

CET - 2012
KEY ANSWERS
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Boscoss, Gopal Nivas Compound, Vriddashram Road, Near Sharada Vidyalaya, Mangalore-3, Ph: 0824-4272728, 9972458537/CET-2012

CHEMISTRY
CET - 2012

1. Ans(3)
80% petrol + 20% ethanol + small quantity of benzene
2. Ans(4)
A = Cumene B= Cumene hydroperoxide C= acetone
3. Ans (1)
CH4 +
2O2
CO2 +2H2O
t=0
20
50
0
0
t= t 20-20
50-40
20
volume
0
10 + 20 = 30
1 mol CH4 reacts with 2 mole of O2 to give one mole of CO2

The left out gas contains 30 ml

4.

Ans (2)
No of gram equivalents of acetic acid =

100 0.1
= 0.01
1000

1 mole of CH3COONa gives 22400 cm3 of ethane at S.T.P

0.5 102 mol CH3COONa gives

=

0.5 10 2 22400
= 112 cm3
1

5. Ans (3)
Toluene

D-1

6. Ans (1)
order of reactivity 30>20>10
7. Ans (2)
Oil of winter green is an ester
8. Ans (3)
Acetophenone
9. Ans (2)
Rate = k [A]x x [B]y

Exptl no 2
Exptl no1

x
y
4 k [0.2] [0.4]
=
2 k [0.2] x [0.2] y

2 = 2y y =1

Exptl no 3
Exptl no 2

36 k [0.6] x [0.4] y
=
4 k [0.2] x [0.4] y

9 = 3x x =2
Rate = k [A] x [B]1
2

10. Ans (1)

KK< 2s2 < *2s2 < 2p2z< [ 2p2x = 2p2y] < [ *2p2x = *2p2y]
11. Ans (4)
Na3[Co(N02)4Cl2] x= 3
EAN =Z-X+Y = 27-3+12 =36
12. Ans (1)
Ni[Ar] 3d84s2
Ni +2[Ar] 3d84s0 n =2
Magnetic moment = n( n + 2) = 8
13. Ans (3)
For a given value of n=3 the possible l values are 0,1,2 3f impossible
14. Ans (4)
1mol of water contains 6.022 x 1023 x10 electrons
15. Ans (2)
Linseed oil
16. Ans (4)
Amalgamating sodium
17. Ans (3)
low osmotic pressure
18. Ans (4)
Has crystal structure similar to dry ice (solid CO2 )
19. Ans (2)
Go = -2.303 RT log Kp
-2.303 x 8.314 x 298 x log 0.008
=
= 11.96 KJ
20. Ans (3)
water repellent
21. Ans (4)
F>O>N>P
22. Ans (1)
Buna-S (sodium)
23. Ans (3)
No definite geometry
24. Ans (4)
0.2 x V = 20 x 0.025 x 5
V = 12.5 ml
25. Ans (1)
Lewis base

26. Ans (2)

27. Ans (1)
The total energy of the universe remains constant
28. Ans (3)
Since no of gram equivalents are same resulting solution having pH =7 (neutral)
29. Ans (1)
Both have same strength
30. Ans (3)
E=E0-

0.0591
pH
n

= 0.0177V

31. Ans (1)

+

32.
33.
34.
35.
36.

20/H
CH3MgI + HCHO CH3-CH2-O-MgI H

CH3-CH2-OH
Ans (3)
Ans (1)
O-toluic acid > benzoic acid > p-toluic acid o- toluic acid stronger than benzoic acid due to ortho effect.
Ans (2)
CH3-CH3
sp3-s and sp3-sp3
Ans (2)
4-Hydroxy -2-pentanone
Ans (4)

2.303
100 2.303
100
=
log
log
t
40
t
16
2.303
2.303
log 2.5 =
log 6.25
20
t

t= 40 mins

37. Ans (1)

log

K2
T T1
Ea
=
x 2
K1 2.303 R
T1T2

Log 10=

Ea
300 270
x
Ea =2.303 x R x 2.7
2.303 R 300 270

38. Ans (1)

180-100=80
39. Ans (4)
40. Ans (2)
41. Ans (1)
Coordination number predict secondary valency
42. Ans (2)
Ti[Ar] 3d24s2
Ti 3+[Ar] 3d14s0 n=1
Magnetic moment = n( n + 2) = 1.73
43. Ans (4)
C<O<N<F
44. Ans (1)
Na(11) 1s2 2s2 2p6 3s1 when n =3 , l=0 for s orbital
45. Ans (2)
CuFeS2
46. Ans (3)
20 x2 +71 =111

47. Ans (3)

N2O4 2NO2
T=O
2
0
T=T
2-0.4
0.8
TOTAL NO.OF MOLES = 1.6+ 0.8 =2.4
Initial no .of moles
2
No. of moles at equilibrium
2.4

when pressure 1 atm

when pressure is p

2 .4
=1.2
2
48. Ans (3)
49. Ans (1) NaNC
50. Ans (4)
Glucose and protein
51. Ans (4)

100
=33.3 x2 (two p orbitals)=67
3
100
Diamond sp3 =
=25
4

graphite sp2 =

52. Ans (3)

-w = p(V)
= 105 (2-1)
= 105 N/m2 m3
= 102 kJ
53. Ans (2)

P0 P
=
P0

x
40
0.2 =
x + 40
40

n2
n1
x =10

54. Ans (4)

55. Ans (2)

20 --------96500
30 ----------- ?
Q = 144750
Q =I .t
144750 = 5 x t x 60 x 60 t = 8
56. Ans (4)
[H+]=

100 10 3 + 400 10 4
500

=0.00028

pH = 4 log 2.8
57. Ans (2)
log Kp =

nFE 0
2.303 R T

log Kp =

2 0.0295
0.059

log Kp =1 Kp =10

58. Ans (4)

E.F = C2H60 and n=1
M.F = C2H5OH Ethanol and diethyl ether are functional isomers.

59. Ans (2)

60. Ans (4)

Boscoss, Gopal Nivas Compound, Vriddashram Road, Near Sharada Vidyalaya, Mangalore-3, Ph: 0824-4272728, 9972458537/CET-2012