Standard Lesson Plan

University of Cebu Maritime Education Programs

Document Code: SLP-BSMARE-01-00 Date Date Filed: 02/26/2010 Reviewed : Prepared by Approved by : 3/E Marconi T. Quiachon Jr. :

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SECTION: STANDARD LESSON PLAN SUBJECT: Lesson Plan: CHEM 2M (Industrial Chemistry) LESSON PLAN Cross-Reference No. Course Name Pre-requisite Course TOPICS TIME ALLOCATED LEARNING OBJECTIVES OF TOPICS : : : : CMO NO. 13, S.2005 (E31-Chem 2) INDUSTRIAL CHEMISTRY Chemistry 1 Fundamentals of chemistry 180 MINUTES (3 HRS)

1. Define an atom and describe its structure, 2. Define molecule, 3. Define and discuss chemical elements and compounds, 4. Define chemical mixtures, 5. Differentiate chemical compounds from mixtures, 6. Explain how chemical compounds and mixtures are named, 7. Define chemical reaction, 8. Explain how atoms becomes charged, 9. Define an oxide, 10. Define solutions, 11. Define solubility, 12. Define saturated solutions, 13. Define suspension, 14. Define precipitations.
SUB TOPIC Structure of the atom METHOD Interactive Discussion TOOL(S) NOTES ON COURSE DELIVERY Cadets are given reading assignments of ref. T1- pp. 5 and 28-41 to facilitate interactive discussion. Review the basic chemistry fundamentals define and describe: an atom a molecule chemical elements and compounds

TIME (MINUTES) Week 1 60

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Document Code: SLP-BSMARE-01-00 Subject : Lesson Plan: CHEM 2 (Industrial Chemistry) TIME (MINUTES) 40

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SUB TOPIC

METHOD lecture interactive discussion

TOOL(S)

NOTES ON COURSE DELIVERY Defines chemical mixture, gives distinction between chemical compounds from chemical mixtures. (ref. T1 pp.5-8)

Basic Terms

25

(ref. T1 pp.94-97) Discusses the meaning of

45

Naming chemical compounds and mixtures Chemical reactions

lecture interactive discussion lecture Lecture

the following; solutions, solubility, saturated solutions, suspension and, precipitations. Prior reading should be assigned to the cadets on ref.T1 pp. 43-45 Discusses briefly the procedure in naming chemical compounds and mixtures. Defines chemical reaction(ref.T1-pp.71-123) , discusses the types of chemical reaction and its effects Defines an oxide (ref. T1 pp.105-107), gives example on how oxides are formed Cadets are assigned reading assignment on ref. T1 pp.38. Discusses the effects of an atom gaining and losing an electron. Defines hydroxyl and hydrogen ion. Explains how an atom becomes charged (ref.

30 10 60

Ions

lecture interactive discussion lecture Slides, ohp

T1 pp.38)

TOPIC TIME ALLOCATED LEARNING OBJECTIVES OF TOPICS

Acidity and alkalinity 60 MINUTES (1 HR.) 1. 2. 3. 4. Discuss the effects of an atom gaining or losing an electron. Define hydrogen ion. Define hydroxil ion. Given ph values, demonstrate whether a solution is alkaline, neutral or acidic, indicating its strength or weakness. 5. Describe the effects of litmus paper when immersed in an acid or alkaline solution.

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Document Code: SLP-BSMARE-01-00 Subject : Lesson Plan: CHEM 2 (Industrial Chemistry)

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TIME (MINUTES) 60

SUB TOPIC Acidity and Alkalinity

METHOD lecture interactive discussion

TOOL(S)

NOTES ON COURSE DELIVERY Explains that the strength and weaknesses of acids or alkaline can be determined by their pH values. (ref. T1 pp.514-526) Discusses the effects of acids and alkaline on a a litmus paper. Ref. T1 pp. 100. (A laboratory activity which is assumed already done in Chem. 1)

TOPIC Time Allocated Learning Objectives of Topics

Corrosion Process 180 minutes (3 Hrs.)

1. Explain the fundamental process of corrosion 2. Name the components of galvanic cell and apply these to the corrosion of a

metal 3. State the main cause of corrosion, 4. State that boiler water should be alkaline and contain little or no dissolved oxygen 5. Explain how metallic hydroxide is formed when an iron immersed in an acidic solution 6. Enumerate common engineering materials which produce passive oxide films 7. Describe the effect of dissolved oxygen and high acidity on polarization, 8. Explain how seawater is considered electrolyte 9. Describe the effect of dissolved oxygen and high acidity on polarization, 10. Define an anode, and state its properties 11. Identify an anode from a list of common metals 12. Discuss how metals are classified as noble or base in relation with each other 13. Define sacrificial anodes and its function in relation with corrosion prevention 14. Recognize the problems of graphization of cast iron, 15. State the reason why corrosion increases when seawater velocity increases

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Document Code: SLP-BSMARE-01-00 Subject : Lesson Plan: CHEM 2 (Industrial Chemistry) (MINUTES) 40 TIME SUB TOPIC Process of corrosion METHOD Lecture/ Interactive discussion TOOL(S) OHP/ acetates

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NOTES ON COURSE DELIVERY Prior reading of ref. T2 pp. 321-323 on the topic should be done by the cadets. basic principle of corrosion is discussed. Explains how materials corrode, the causes of corrosion and the conditions that accelerates the rate of corrosion on different parts of the ship is discussed. Explain the galvanic cell and enumerate its components. Explain the causes of corrosion and that corrosion is a natural process. The effect of sea water on polarization of metals and the effect of dissolved oxygen are explained. discuss the phenomenon called passivation Explain how metallic hydroxide is formed when an iron immersed in an acidic solution, (ref. T5 pp.7:49) describes the polarization effects of dissolved oxygen and high acidity. Explain and discuss the electrochemical reaction, and the four components of electrochemical cell. (ref. T2 pp. 321-323) Discuss the significance of the arrangement of metals in the table of galvanic series of metals and alloys in sea water. (ref.T2 Explain the function of the sacrificial anode, (ref. T2 pp. 315) how it protects the hull of ships. Discuss the graphitization phenomenon of cast iron (ref. T3 pp.6:15). Explain the effect of water velocity on the rate of corrosion. (ref. T5 pp.12:29)

50

Lecture/ Interactive discussion

20

process of corrosion

Lecture/ Interactive discussion Lecture/ Interactive discussion Lecture/ Interactive discussion Lecture/ Interactive discussion

(ref. T2. pp 323)

20 20

40

pp.323)

TOPIC TIME ALLOCATED LEARNING OBJECTIVES OF

THE TOPIC

CORROSION TYPES 60 MINUTES (1 HR.)

1. 2. 3. 4. 5. 6.

Define stress corrosion and identify the metals in which it commonly occurs Discuss pitting corrosion describe crevice corrosion and explain how it occurs Differentiate intergranular corrosion from uniform corrosion Explain how selective leaching differs from erosion corrosion Explain what is meant by dezincification and de-aluminification
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Document Code : SLP-BSMARE-01-00 Subject : CHEM 2 (Industrial Chemistry) LEARNING OBJECTIVES OF

THE TOPIC

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7. Discuss the prevention measures of the problems stated above 8. Discuss fretting corrosion 9. Discuss corrosion fatigue 10. Identify the factors that affects the corrosion process

TIME (MINUTES) 20

SUB TOPIC

METHOD Lecture discussion

TOOL(S) OHP/ Acetate on galvanic series of metals and alloys Multi-media Projector

NOTES ON COURSE DELIVERY Discuss corrosion problems in boiler and diesel engine with regards to feedwater and cooling water. Explain the significance of galvanic series of metals and alloy table in the selection of materials used for ship construction. explain graphization of cast iron.(ref. T3 pp.6:15). Stress corrosion is defined, (ref. T3 pp.7-62) and the specific metals it commonly attacks is discussed. Dezincification and dealuminification is explained (ref. T5 pp. 12-29), preventive measures and protection of these metals are also discussed. Slide show on this particular metal problem is shown. Other types of corrosion commonly experienced on board ships are discussed with emphasis on the factors that affects the corrosion process.

40

Types of corrosion

Lecture/ discussion

TOPIC TIME ALLOCATED LEARNING OBJECTIVES OF

THE TOPIC

Corrosion protection and prevention 120 MINUTES (2 HRS)

1. 2. 3. 4.

State the methods of protecting metals against corrosion. Discuss the cathodic protection method. Explain the function of the paint components. States the importance of surface preparation prior to the application of protective coatings.

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Document Code : SLP-BSMARE-01-00 Subject : CHEM 2 (Industrial Chemistry) TIME (MINUTES) SUB TOPIC Forms of corrosion control METHOD Lecture/inter active discussion TOOL(S) Projector and slides

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NOTES ON COURSE DELIVERY Discussion on the forms of corrosion control such as: Cathodic protection, Application of protective coating. enumerates differentiates the two types of cathodic protection. Discusses the advantages and disadvantages of each of the cathodic protection method. Enumerate the paint components such as; binders, pigments, solvents discusses the functions of the above components. States the classes of binders, pigments and solvents. ref. T3

60

ref. T3 pp.314-320

30

Protective coatings

Lecture/inter active discussion

30

Application of protective coatings :

Lecture/inter active discussion

pp.317-319

Discusses the methods, equipments and the necessary preparations for the application of protective coatings. (ref. T3

pp.319)

TOPIC TIME ALLOCATED LEARNING OBJECTIVES OF

THE TOPIC

Water Testing and Treatment 300 MINUTES (5 HRS) Discuss the values of controlling the pH values of liquids, Identify the chemical additives that can be used to obtain the required pH values, Discuss the importance of maintaining gas free boiler feed water system or engine cooling water system, 4. Identify the methods of conditioning the water used in marine power plants, 5. State the undesirable properties found in water supplied on ships, 6. Discuss the method in measuring metallic salt content of water, 7. Define permanent and temporary hardness of water, 8. Discuss briefly how scales and sludge are formed in the boiler, 9. Discuss the effects of using different water as boiler feedwater, 10. Sate the objects of treatment of boiler feedwater.

1. 2. 3.

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Document Code : SLP-BSMARE-01-00 Subject : CHEM 2 (Industrial Chemistry) (MINUTES) 60 TIME SUB TOPIC pH values of liquids METHOD lecture/ discussion TOOL(S) flip chart

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NOTES ON COURSE DELIVERY Define pH as the negative logarithm of the hydrogen ion concentration. (ref. T5 pp. 751), explains the relevance of the pH on the quality of boiler feedwater and diesel engine cooling water. explains the reason why pH values of the boiler feedwater or the diesel engine cooling water should be controlled. (ref. T5 pp.7:52) Enumerate the chemicals commonly used to improve the quality of boiler feedwater.

20 30

boiler chemicals

lecture/ discussion lecture/ discussion

ref. T5 pp. 7-61-63

75

Boiler water conditioning

lecture/ discussion

15 100

Salinity
Boiler water problems

Lecture Lecture/ Interactive discussion Multimedia projector, PPT.

States the different methods in conditioning the water used in marine power plants. (ref. T5 pp.7-63-7 - 71) Discuss the undesirable properties present in water supplied in ships. methods of measuring salinity of water is discussed (ref. T5 pp. 7-75 - 7-76) Cadets are assigned to read ref.T5 pp. 775 prior to this discussion, they should be able to define temporary and permanent water hardness. (ref. T5 pp. 7:43) Explains the object of boiler water treatment. Formation of sludge and scales on boilers are discussed and explained. The effects of using different water as feed water is discussed. (ref. T5 pp.7:59-

55

States the reason for maintaining a gas free boiler feed water system or engine cooling water system. Ref.T5 pp. 7-53, 7-

63)

TOPIC : TIME ALLOCATED LEARNING OBJECTIVES OF

THE TOPIC

Fuel and Lubricants Crude oil refining 180 MINUTES (3 HRS)

1. 2. 3. 4. 5. 6. 7. 8.

Define crude oil State the compounds and elements that makes up crude oil Define hydrocarbons State the classes of hydrocarbons State the products derived from crude oil Explain how crude oil are separated into its various components Discuss the influence of the refining process on fuel oil properties Discuss the various processes of separating crude oil components
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Document Code : SLP-BSMARE-01-00 Subject : CHEM 2 (Industrial Chemistry) TIME (MINUTES) 60

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SUB TOPIC Crude oil

METHOD Lecture/ Interactive disc ussion

TOOL(S) Multimedia projector, PPT.

NOTES ON COURSE DELIVERY Cadets are given reading assignment on basic crude oil properties (ref. T7 pp. 7) . They should be able to define crude oil and hydrocarbon and state the four classes of hydrocarbons that are found in an average marine fuel oil at the end of the lecture session. Power point presentation of the various processes of crude oil refining is shown supplemented by interactive discussion and lecture. State the various products of crude oil refining. Describe the methods of crude oil refining such as; Straight run distillation, Vacuum distillation, Cracking, etc. Discuss how different grades of fuel are separated in a fractionating column. Explain how marine diesel oils quality deteriorates as the refining process becomes more efficient. (ref. T7 pp.8-13)

120

Crude Oil Refining

Lecture/ Interactive disc ussion

PPT presentn

TOPIC TIME ALLOCATED LEARNING OBJECTIVES OF

THE TOPIC

Fuel and Lubricants Properties of Fuel Oil 144 MINUTES (2.40HRS.)

1. 2. 3. 4.

Enumerate the properties of fuel oil, Discuss the properties of fuel oil, Enumerate and discuss impurities of HFO, Discuss the adverse effects of undesirable properties of fuel oil in diesel engines, METHOD Lecture/ Interactive discussion TOOL(S) NOTES ON COURSE DELIVERY Discussion on the properties of fuel oil; (ref. T7 pp.17-28) State the properties of fuel oil such as viscosity, pour point, specific gravity, and etc. as well as the impurities or contaminants as carry over of the refining process and its effects on overall efficiency and on diesel engine parts.

TIME (MINUTES) 80

SUB TOPIC Properties of fuel oil

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Document Code : SLP-BSMARE-01-00 Subject : CHEM 2 (Industrial Chemistry) (MINUTES) 64 TIME SUB TOPIC Relationship between API and specific gravity METHOD Lecture TOOL(S)

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NOTES ON COURSE DELIVERY calculation of; heating values of fuel, specific gravity using API index, viscosity in various units, Discussion of fuel specifications and standards on the standpoint of fuel supply standard and engine manufacturers standards (BSI and CIMAC)

TOPIC TIME ALLOCATED LEARNING OBJECTIVES OF

THE TOPIC

Fuel and Lubricating Oil Treatment and Testing 160 MINUTES (2.66 HRS.)

1. Describe the different types of filter, which are used in the fuel and lubricating oil 2. State the importance of fuel oil testing and analysis. 3. State that accurate determination of fuel oil characteristics are best performed in 4. 5. 6. 7. 8. 9.
lines,

shore side laboratories. State the benefits in complete and accurate shoreside analysis. Explain the importance of taking a representative sample of the bunkered fuel. Discuss the usefulness of drawing samples from the various points in the ships fuel oil processing system. Name the two documents available to the owner for the use in specifying fuel quality. State the object of lubricating oil analysis State the correct and safe and correct procedures of taking samples,

TIME (MINUTES) 20

SUB TOPIC Types of filter

METHOD Lecture/ interactive discussion

TOOL(S)

NOTES ON COURSE DELIVERY Explain the need for improving the quality of marine fuel oil. State the equipments used for this purpose. Different types of filter an strainer is discussed. (ref. T7 pp.47 and T5

90

Fuel testing and sampling

Lecture

pp. 8-65) Discuss the importance of both the shipboard and shoreside analysis (ref. T7pp.4&5). Discuss the sampling method on board ships

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Document Code: SLP-BSMARE-01-00 Subject : CHEM 2 (Industrial Chemistry)

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75

Fuel and Lube oil sampling

Lecture

Discuss the purpose of taking fuel and lube oil samples from various points in the ships fuel oil processing system. (ref. T7pp.4) Discuss the shipboard practices in taking samples in the ships fuel processing system. Discuss the two specification system standards on fuel oil(ref.T7pp.4). Discussion of lube oil sampling and analysis and procedures.

75

Fuel oil Lecture specification standards

TOPIC TIME ALLOCATED LEARNING OBJECTIVES OF

THE TOPIC

Combustion Process 160 MINUTES (2.66 HRS.)

1. 2. 3. 4.

Describe the combustion process, Define calorific value, State the purpose of supplying excess air for efficient combustion, Discuss the regulations pertaining to emission,

5. State the percentage range of CO 2 and its indications, 6. Explain the importance of atomization, 7. Explain the relationship between viscosity and atomization characteristic of a fuel, 8. State the theoretical air/fuel ratio for a typical boiler fuel, 9. Explain how fuel viscosity can be varied, 10. State the actual air/fuel ratio allowing for normal excess air, 11. Explain how sulfur dioxide transforms into sulfuric acid inside a combustion
chamber, 12. Describe the effects of ash on atomizing equipment, 13. State the types of filter used in the fuel lines.

(MINUTES) 45

TIME

SUB TOPIC Combustion theory

METHOD Lecture/ interactive discussion

TOOL(S)

NOTES ON COURSE DELIVERY Cadets are assigned to read in advance the combustion theory. (ref. T4 pp. 180-190) Defines combustion and describe the process of combustion. Defines calorific value, discuss the significance of this property on combustion.

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SUB TOPIC

METHOD Lecture/ interactive discussion

TOOL(S)

NOTES ON COURSE DELIVERY Discuss the regulation pertaining to emission (Annex VI of MARPOL 73/78). Discuss the effects of; inefficient combustion, viscosity, other fuel impurities, poorly atomized fuel, Discuss the requisite for good combustion. Explain the importance of flu gas analysis, the importance of atomization and its relationship with fuel oil viscosity. Discussion of the theoretical air/fuel ratio for a typical boiler fuel.(ref. T5 pp. 8-7 8-10) Explain how fuel viscosity can be made to vary. State the ideal air/fuel ratio. Explain how CO2 turns into sulfuric acid in the combustion chamber (ref. T5 pp. 8-12). Discuss the effects of ash on atomizing equipment, and the means of preventing fuel oil impurities from getting inside the combustion chamber.

30

Air/fuel ratio

Lecture/ interactive discussion Lecture discussion

30

Flu gas analysis

TOPIC TIME ALLOCATED LEARNING OBJECTIVES OF

THE TOPIC

Centrifugal Purifiers 210 MINUTES (3.5 HRS.)

1. Discuss how the force of gravity is used to separate out liquids and solids of 2. 3. 4. 5. 6. 7. 8.

different densities Explain the advantages of centrifugal separation over other methods State the difference between the bowl over the tube separator and describe each with the aid of an illustration Differentiate the process of purifying and clarifying Describe the purification process of fuel and lubricating oil Describe the aide of simple sketches, a bowl separator and a tube separator, showing the main components and the principal differences between the two State the rotation speeds used in the equipment describes in the above objective State the difference bet purifying and clarifying

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Document Code: SLP-BSMARE-01-00 Subject : CHEM 2 (Industrial Chemistry) TIME ALLOCATED LEARNING OBJECTIVES OF
THE TOPIC

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160 MINUTES (2.66 HRS.)

9. Describe the purification process of a fuel and lubricating oil, stating the

approximate temperatures of the oil necessary both in the supply tank and immediately prior to centrifuging 10. Describe the correct and safe operating procedures for centrifuges 11. Describe the correct procedures for the disposal of waste oil, sludge residue, etc.

TIME (MINUTES) 45

SUB TOPIC Centrifugal purifier

METHOD Lecture / discussion PPT presentation Lecture/ interactive discussion

TOOL(S) Multi-media Projector, PC,

NOTES ON COURSE DELIVERY Explains the operating principles of centrifugal purifier (ref. T5 pp.4-30 - 4-32 The advantages of using purifiers over other equipment is discussed, shows the main components of a centrifugal separator with the aid of slides. Explain the clarifier and separator operation of the centrifugal purifiers, stating the difference between these two functions. Discuss the purification process. (ref. T5 pp.4-30 - 4-32 and stating the requirements for safe and efficient operation of purifiers. Describe the purification process of lubricating and fuel oil and explain the need for maintaining the desired temperature for efficient purification. The procedure for the disposal of waste oil on board is discussed with reference to the regulation dealing with oil pollution. Annex 6

65

Function of the Purifiers

15

Waste oil disposal Purifier 0perating procedure Waste oil disposal

Lecture/ interactive discussion Lecture Lecture/ interactive discussion

25 25

Film showing Discuss the correct and safe operating

procedure of centrifugal purifiers.

MARPOL 73/78

(ref.T7pp.4-30)

Describes the correct procedure for the disposal of waste oil, sludge, residue, and etc.(Annex 6 MARPOL 73/78)

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Document Code: SLP-BSMARE-01-00 Subject : CHEM 2 (Industrial Chemistry)

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Checked and Verified by: ____________________________________________ UC-DNV-SEASKILL ACADEMIC COORDINATOR

Date: ______________________

Noted by: _________________________________ DEAN/ACADEMIC HEAD _______________________

Legend:

CMO NO. 13, S.2005 SCS SLP SEA SLG

(CHED MEMORANDUM ORDER NO. 13, SERIES 2005) (STANDARD COURSE SYLLABUS) (STANDARD LESSON PLAN) (STANDARD EXAMINATION AND ASSESSMENT) (STANDARD LEARNING GUIDE)

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