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B)
2 1 1 2
1 2 2 1
b c b c
a b a b
+
C)
1 2 1 2
1 2 2 1
b c b c
a b a b
+
D)
1 2 2 1
2 1 1 2
a b a b
b c b c
+
+
2 . If
1 1 1
a x b y c 0 + + and
2 2 2
a x b y c 0 + + are cons is t ent , t hen y =
A)
1 2 2 1
1 2 2 1
b c b c
a b a b
B)
1 2 1 2
1 2 2 1
b c b c
a b a b
+
C)
2 1 1 2
1 2 2 1
a c a c
a b a b
D)
2 1 1 2
1 2 2 1
a c a c
a b a b
+
+
3 . If t he lines
1 1 1
a x b y c 0 + + and
2 2 2
a x b y c 0 + + are int ers ect ing t hen
A)
1 1
2 2
a b
a b
B)
1 1
2 2
a b
a b
C)
1 1
2 2
a c
a c
B)
1 1
2 2
b c
b c
C)
1 1
2 2
b c
b c
B)
2 2 2 2
a ,b,c
a b a b b c c a + +
C)
( )
2
2
a ,b,c
a a b c
_
+ +
,
D) All of t h es e
14.
3 3
a b =
A) ( )
( )
2 2
a b a ab b + +
B) ( )
( )
2 2
a b a ab b + +
C) ( )
( )
2 2
a b a ab b + + +
D) ( )
( )
2 2
a b a ab b +
15.
2 2
a b a b
2 2
+
_ _
, ,
A) ab B)
a b
2
C)
a b
4
D)
( )
2
ab
16.
( )
3
a b c + +
A)
( )( )( )
3 3 3
a b c 3 b c c a a b + + + + +
B)
( )( )( )
3 3 3
a b c 3 b c c a a b + + + + + +
C)
( )( )( )
3 3 3
a b c 3 b c c a a b + + + +
D)
( )( )( )
3 3 3
a b c 3 b c c a a b + + +
Narayan a IIT Olympiad Sch ool 7
VIII- MPC SHP _ E - 5
17. Which of t he following is called a pure quadrat ic equat ion.
A)
( )
2
a x bx c 0, a 0 + + B)
( )
2
a x bx c 0, b 0 + +
C)
( )
2
a x c 0 a 0 + D)
2
a x bx 0 +
18. The root s of quadrat ic equat ion
( )
2
ax bx c 0, a 0 + + are
A)
2
b b 4a c
2a
+
B)
2
b b 4ac
2a
+
C)
2
b b 4a c
2a
D) Bot h (A) an d (C)
19. The quadrat ic equat ion
( )
2
ax bx c 0, a 0 + + a, b, c are real and
0 >
,
t hen t he root s are
A) real B) dis t in ct C) equ al D) Bot h (A) an d (B)
2 0 . The quadrat ic equat ion
( )
2
ax bx c 0, a 0 + + a, b, c are rat ional and
0 >
, and
A) Bot h s t at emen t s I an d II ar e t r u e
B) Bot h s t at emen t s I an d II ar e fals e
C) St at emen t I is t r u e bu t s t at emen t II is fals e.
D) St at emen t I is fals e bu t s t at emen t II is t r u e.
2 7 . St at ement -I : If
a b
0
x y
, ( )
2 2
2 2
a b a b
a b
x y
+ +
, where x
0, and y
0, then x = a.
St at ement -II: The syst em of a pair of linear equ at ions a
1
c + b
1
y + c
1
= 0,
a
2
x + b
2
y + c
2
= 0, h as n o s olu t ion if
1 1 1
2 2 2
a b c
a b c
.
A) Bot h s t at emen t s I an d II ar e t r u e
B) Bot h s t at emen t s I an d II ar e fals e
C) St at emen t I is t r u e bu t s t at emen t II is fals e.
D) St at emen t I is fals e bu t s t at emen t II is t r u e.
2 8 . St at ement -I: Th e s qu ar e r oot of
2
2
20x 15
x +10 +
x 4x + 4
is
2
x + 2x 5
x 2
={1,2,3,4,5}
Statement-II: Th e r elat ion
( ) ( ) { }
1
R b, a : a , b R
A) Bot h s t at emen t s I an d II ar e t r u e
B) Bot h s t at emen t s I an d II ar e fals e
C) St at emen t I is t r u e bu t s t at emen t II is fals e.
D) St at emen t I is fals e bu t s t at emen t II is t r u e.
Narayan a IIT Olympiad Sch ool 10
VIII- MPC SHP _ E - 5
3 5 . St at ement -I: Th e r elat ion is par allel t o is equ ivalen ce r elat ion
Statement-II: Th e r elat ion is r eflexive, s ymmet r ic, t r an s t ive t h en it s is
equ iva len ce r ela t ion
A) Bot h s t at emen t s I an d II ar e t r u e
B) Bot h s t at emen t s I an d II ar e fals e
C) St at emen t I is t r u e bu t s t at emen t II is fals e.
D) St at emen t I is fals e bu t s t at emen t II is t r u e.
MULTIPLE CORRECT ANSWERS TYPE
3 6 . The pos it ive s quare root of
( )
( )
2
2
1
x + 2 x 1 +
x + 2 x +1
is
A)
( )
( )
1
x+1
x 1
+
+
B)
( )
( )
1
x+1
x 1
+
C)
( )
( )
1
x+2
x 1
+
D)
( )
( )
1
x+2
x 1
+
+
3 7 . If x
4
+ ax
3
+ bx
2
+ c x + d = (x
2
+ px + q)
2
, t hen 2 q =
A)
2
a
b
4
B)
2c
a
C)
2
a
2b
D)
a
4b
3 8 . One of t he fact or of
3 2 2 3
a x a b(x y) ab (y z ) b z
A) a b B) a+b C)
2 2
a x aby b z + +
D) a+b+c
3 9 . If a +b+c =0 , t h e n
3 3 3
a b c + + i s
A) 3a (c +a ) (a + b) B) 3b (c +a ) (a b) C) 3c (c +a ) (c + b) D) 3 abc
4 0 . If
3 2
2 7 x 1 8 x 9 x 3 divided by 3 x 2 , t hen t he
A) Remain der 9 B) quotient
2
9x 5 + C) qu otient
2
9x 3 D) remain der 8
41. If the quadratic expression
( ) ( )
2
x + a - 4 x + a + 4 = 0 is a perfect square, then a =
A) 0 B) 12 C) 6 D) mu lt iple of 3
4 2 . The value of x whi c h s at i s fyi ng t he e quat i on are
( ) ( )
2 2
x 3 x 3
5 + 2 6 + 5 2 6 = 1 0
are
A) 2 B) 2 C)
2
D)
2
4 3 . Whi c h o f t he fo l l o wi ng s t at e me nt s are t rue ?
A) If
2
A {x : x 4, x N}, B { 2}
, t h en
A B
.
B) If A = {x:| x| < 2 , x
Z}, B = {1 , 0 , 1 }, t h en
A B
.
C) If A {1, 2, 3, 4, 5 }, B {2,1, 3, 4, 5, 6 } , t h en
A B
.
D) If
2
A {x : x 5 x 7 0, x R}, B + , t h en
A B
.
4 4 . Let X be a nonempt y s et and P(X) be t he s et of all s ubs et s of X. For A,
( ) B P X , A R B if and only if A B t hen t he relat ion
A) R is n ot r eflexive B) R is s ymmet r ic
C) R is n ot t r an s it ive D) R is an equ ivalen ce r elat ion
Narayan a IIT Olympiad Sch ool 11
VIII- MPC SHP _ E - 5
4 5 . If R= { (x, y)/ x+2 y=1 0 } is a relat ion in A={1 , 2 , 3 , 4 , . . . . 1 0 } t hen find t he
domain and range of R
A) Domain of R is {2,4,6,8} B) Ran ge of R is {2,5,6,8}
C) Ran ge of R is {1,2,3,4} D) Domain of R is {2,3,4,5,6}
LINKED COMPREHENSION TYPE
Paragraph for Ques t ion Nos . 4 6 t o 4 8
Given
( ) ( )
1 5 3
2 x 2 y 3 3 x 2 y 2
+
+
,
( ) ( )
5 3 6 1
4 x 2 y 5 3 x 2 y 6 0
+
wh er e x + 2y
0 an d 3x 2y
0
Bas ed on t he above dat a ans wer t he following ques t ions .
4 6 . x + y = __________.
A)
5
4
B)
7
4
C)
9
4
D)
11
4
4 7 . x + 2 y = _________.
A) 3 B) 4 C)
1
2
D)
1
3
4 8 . 2 x + 5 y = _________.
A)
3
4
B)
5
4
C)
29
4
D)
11
4
Paragraph for Ques t ion Nos . 4 9 t o 5 1
2 2
a b (a b )(a b ) +
3 3 2 2
a b (a b )(a a b b ) + +
Bas ed on t he above dat a ans wer t he following ques t ions .
4 9 . One of t he fact or of
8 8
x y is
A) x y + B)
3 3
x y +
C)
2 2
x y xy + +
D)
2 2
x y xy
5 0 . One of t he fact or
3 3
a 2 2 b is
A)
(a 2b)
B)
2 2
(a 2ab 2b ) +
C)
2 2
(a 2ab b ) + +
D)
(a 2b) +
51. One of t he fact or of
( ) ( )
2 2
ac bd ad bc + +
is
A) (a b) + B) (b c ) + C) (b c) D) (a d ) +
Paragraph for Ques t ion Nos . 5 2 t o 5 4
If
2
ax bx c 0; a , b, c R an d a 0 + + t h en t h e r oot s of
2
a x bx c 0 + + are
equ al if
2
b 4a c 0
.
Bas ed on t he above dat a ans wer t he following ques t ions .
Narayan a IIT Olympiad Sch ool 12
VIII- MPC SHP _ E - 5
5 2 . If
( )( ) ( )( ) ( )( ) x a x b x b x c x c x a 0 + + has equal root s , t hen t he
relat ion bet ween a, b and c is
A) a + b + c = 0 B) a = b = c C) b
2
= ac D) a + c = 2b
5 3 . If t he root s of
( ) ( ) ( )
2 2 2 2
c ab x 2 a bc x b ac 0 +
are equal, t hen
A)
3 3 3
a b c 3abc or a 0 + +
B)
2 2 2
a b c ab bc ca + + + +
C)
abc a b c + +
D) a = b = c
5 4 . If
( ) ( ) ( )
2
p q r x q r p x r p q 0 + + has equal root s t hen 2 / q =
A)
1 1
p r
+
B)
1 1
p r
C) p + r D) pr
Paragraph for Ques t ion Nos . 5 5 t o 5 7
Th e u n ion of t wo s et s A an d B is t h e s et of all t h os e elemen t s wh ich ar e
eit h er in A or in B.
Th e in t er s ect ion of t wo s et s A an d B den ot ed by A
1
B is t h e s et of all elemen t s
common t o bot h A an d B.
={1,2,3,4,5,6,7,8,9,10}; A={1,2,3,4,5}; B={3,4,5,6,7,8}
Bas ed on t he above dat a ans wer t he following ques t ions .
5 5 .
( )
c
A B 7 =
A) {x/ x, x
N, 9
x<11} B) {9,10}
C) Bot h A an d B D) Non e of t h es e
5 6 . Symmet ric difference of A and B is
A) {1,2,6,7,8,9} B) {8,7,6,2} C) Bot h A an d B D) Non e of t h es e
5 7 .
( )
1 1
n A B = 1
________
A) 2 B) 3 C) 1 D) 4
Paragraph for Ques t ion Nos . 5 8 t o 6 0
If R is a r elat ion in A an d for ever y a
A, (a,a)
R t h en R is s aid t o be a r eflexive
r ela t ion .
If R is a r elat ion in A an d (a,b)
R an d (b,c)
R implies (a,c)
R t h en R is called
a t r an s t ive r elat ion
If R is a r elat ion in A. If (a,b)
R an d (b,c)
R implies (a,c)
R t h en R is called
t r an s t ive r elat ion .
A r elat ion R in a s et A is s aid t o be on equ ivalen ce r elat ion if it is r eflexive,
s ymmet ric an d t ran s t ive
Narayan a IIT Olympiad Sch ool 13
VIII- MPC SHP _ E - 5
Bas ed on t he above dat a ans wer t he following ques t ions .
5 8 . The relat ion R={(1 , 1 ), (2 , 2 ), (3 , 3 ), (1 , 2 ), (2 , 3 ), (1 , 3 )} on t he s et A={1 , 2 , 3 } is
A) Reflexive bu t n ot s ymmet r ic B) r eflexive bu t n ot t r an s live
C) Symmet r ic an d t r an s t ive D) Neit h er s ymmet r ic n or t r an s t ive
5 9 . Let A={1 , 2 , 3 , 4 } and R={(2 , 2 ), (3 , 3 ), (4 , 4 ), (1 , 2 )} be a relat ion on A t hen R is
A) Reflexive B) Symmet r ic C) Tr an s t ive D) Non e of t h es e
6 0 . For real number x and y, define a relat ion R, xRy if and only if
x y 2 +
is
an irrat ional number. Then t he relat ion R is
A) Reflexive on ly B) Symmet ric on ly
C) Tran s t ive on ly D) An equ ivalen ce relat ion
MATRIX MATCHING TYPE QUESTIONS
61. Column - I Column - II
a) If
2x 5 y
6
xy
+
,
x 5 y
3
xy
4
, wh er e x
0, y
0 p) 27
t h en x + y is
b) If
2x 5 y
6
xy
+
,
x 5 y
3
xy
4
, where x
0, y
0 then y = q) 11
c) If
57 6 38 21
5, 9
x y x y x y x y
+ +
+ +
t h en x = r ) 2
d) If
57 6 38 21
5, 9
x y x y x y x y
+ +
+ +
t h en x + 2y = s ) 3
6 2 . Column - I Column - II
a) a( x + y) +b is p) n on s ymmet r ic
b)
3 2 2 3
ax y bx y cxy + +
is q) n on h omogen iou s
c) ax + by + c is r ) h omogen iou s
d)
2 2
(x y)(x y ) + +
is s ) s ymmet ric
6 3 . Find t he Remainder
Column - I Column - II
a)
4 3 2
2x 6x 3x 3x 2 + + divided by
2
x 3x 2 + p) 20.95
b)
3 2
0.2x 5.7 x 0.75 x 1.25 + + + divided by x + 2 q) 0
c)
3 2
25 x 8 x 4x 10 + + divided by x+ 1 r) 3
d)
5 4 2
3x 11x 90 x 19x 53 + + + divided by x + 5 s ) 102
Narayan a IIT Olympiad Sch ool 14
VIII- MPC SHP _ E - 5
6 4 . Column - I Column - II
a) , are roots of
2
3 x 2x 8 0 , then
2 2
+ p)
2a b +
b) , ar e r oot s ( ) > of
2
2x 5 x 2 0 + t h en q) 76/ 9
( )
1
1
c) On e of t h e r oot s of
2 2 2
x 4a x 4a b 0 + is r) 1
d) On e of t h e r oot of
2 2 2
a x 3a bx 2b 0 + is s )
2b
a
6 5 . Column - I Column - II
a)
1 2 3 4 5
, , , ,
2 3 4 5 6
' ;
p)
1
x / x , n Nan d n 5
n
' ;
b)
1 1 3
, ,
3 2 5
' ;
q)
3
3
n 1
x : x , n Wa n d n 3
n 1
' ;
+
c)
7 26
1, 0, ,
9 28
' ;
r)
n
x : x , n 3, n N
n 2
' ;
+
d)
1 1 1 1
1, , , ,
2 3 4 5
' ;
s )
n
x / x , n N a n d n 6
n 1
<
' ;
+
6 6 . If A= {2 , 3 , 4 }; B= {3 , 4 , 5 }; C= {5 , 6 }
Column - I Column - II
a) (A C) (B C) 1 = p) {(2,5), (2,6)}
b) (A
B) (A
m
1
m
2 F
s m oot h
From t he figure, t he maximum accelerat ion for which t he blocks have
combined mot ion is
A)
2
m g B) ( )
1 2
m m g + C)
1
m g D) g
2 5 . In t he above ques t ion, t he maximum force for which t he blocks have
combined mot ion is
A) g B) ( )
1 2
m m g + C)
1
m g D)
2
m g
Reas oning Type
2 6 . St at ement -I : A block is pulled along a horizont al frict ionles s s urface by a
t hick rope. The t ens ion in t he rope will not always be t he
s ame at all point s on it .
St at ement -II: The t ens ion in t he rope depends on t he accelearat ion of t he
block -rope s ys t em and mas s of t he rope.
A) Bot h s t at emen t s I an d s t at emen t II ar e t r u e
B) Bot h s t at emen t s I an d s t at emen t II ar e fals e
C) St at emen t I is t r u e an d s t at emen t II is fals e
D) St at emen t I is fals e an d s t at emen t II is t r u e.
2 7 . St at ement -I : A clot h covers a t able. Some dis hes are kept on it . The clot h
can be pulled out wit hout dis loding t he dis hes from t he t able.
St at ement -II: For every act ion t here is an equal and oppos it e react ion.
A) Bot h s t at emen t s I an d s t at emen t II ar e t r u e
B) Bot h s t at emen t s I an d s t at emen t II ar e fals e
C) St at emen t I is t r u e an d s t at emen t II is fals e
D) St at emen t I is fals e an d s t at emen t II is t r u e.
2 8 . St at ement -I : A concept of ps eudo forces is valid bot hfor inert ial as well as
non-inert ial frame of reference.
St at ement -II: A frame acceleret ed wit h res pect t o an inert ial frame is a non-
inert ial frame.
A) Bot h s t at emen t s I an d s t at emen t II ar e t r u e
B) Bot h s t at emen t s I an d s t at emen t II ar e fals e
C) St at emen t I is t r u e an d s t at emen t II is fals e
D) St at emen t I is fals e an d s t at emen t II is t r u e.
2 9 . St at ement -I : In figure, t he ground is s moot h and t he mas s es of bot h t he
blocks are different . Net force act ing on each of t he block is
not s ame.
St at ement -II: Accelerat ion of t he blocks bot h will be different
Narayan a IIT Olympiad Sch ool 19
VIII- MPC SHP _ E - 5
A
B
S MOOTH
A) Bot h s t at emen t s I an d s t at emen t II ar e t r u e
B) Bot h s t at emen t s I an d s t at emen t II ar e fals e
C) St at emen t I is t r u e an d s t at emen t II is fals e
D) St at emen t I is fals e an d s t at emen t II is t r u e.
3 0 . St at ement -I : Co-efficient of s t at ic frict ion can be great er t han unit y.
St at ement -II: St at ic frict ion is independent of t he area of cont act .
A) Bot h s t at emen t s I an d s t at emen t II ar e t r u e
B) Bot h s t at emen t s I an d s t at emen t II ar e fals e
C) St at emen t I is t r u e an d s t at emen t II is fals e
D) St at emen t I is fals e an d s t at emen t II is t r u e.
31. St at ement -I : On rainy day, it is difficult t o drive a car at high s peed.
St at ement -II: The value of coefficient of frict ion is lowered due t o wet t ing
of t he s urface.
A) Bot h s t at emen t s I an d s t at emen t II ar e t r u e
B) Bot h s t at emen t s I an d s t at emen t II ar e fals e
C) St at emen t I is t r u e an d s t at emen t II is fals e
D) St at emen t I is fals e an d s t at emen t II is t r u e.
3 2 . St at ement -I : The frict ional force act ing on a body of mas s m which is at
res t on a horizont al s urface of coefficient of s t at ic f ri c t i o n
s
is
s
mg in t he abs ence of ext ernal force.
St at ement -II: The frict ional force act ing on a body of mas s m which is at
res t on a rough inclined s urface of angle of inclinat ion
is
mgs in .
A) Bot h s t at emen t s I an d s t at emen t II ar e t r u e
B) Bot h s t at emen t s I an d s t at emen t II ar e fals e
C) St at emen t I is t r u e an d s t at emen t II is fals e
D) St at emen t I is fals e an d s t at emen t II is t r u e.
3 3 . St at ement -I : Two blocks of mas s es m and M are placed on a horizont al
s urface as s hown in t he fig.
M
F
m
The c oe ffi c i e nt of fri c t i on be t we e n t he bloc k M and t he
horizont al s urface is
2
and bet ween t he blocks is
1
. The
maximum force t hat can be applied t o block M s o t hat t he
t wo blocks move wit hout s lipping is ( )( )
1 2
F = - M+m g .
Narayan a IIT Olympiad Sch ool 20
VIII- MPC SHP _ E - 5
St at ement -II: Maximum force = t ot al mas s + maximum accelerat ion
A) Bot h s t at emen t s I an d s t at emen t II ar e t r u e
B) Bot h s t at emen t s I an d s t at emen t II ar e fals e
C) St at emen t I is t r u e an d s t at emen t II is fals e
D) St at emen t I is fals e an d s t at emen t II is t r u e.
Mult iple Ans wer Ques t ions
3 4 . For t he s ys t em in equilibrium s hown in figure. [Pully is fixed. Pulley and
s t rings are mas s les s and frict ion les s )
6 0
6 0
m
6 k g
T
1
T
3
T
2
A) Th e t en s ion T
1
is 34N B) Th e t en s ion T
2
is 58.8 N
C) Th e t en s ion T
3
is 34N D) Th e mas s m is 3.46 kg
3 5 . Three boys , each of mas s 7 0 . 0 kg, pull s imult aneous ly a block on a s moot h
s urface. Mas s of block is 2 0 . 0 kg. Then t he (nearly)
F = 1 2 5 N
2
F = 9 0 N
1
F = 1 7 5 N
3 4 5
3 0
A) h or izon t a l a cceler a t ion of t h e block is 10.1 m/ s
2
B) ver t ica l a cceler a t ion of t h e block is 2.31 m/ s
2
C) a cceler a t ion of t h e block is 5.13 m/ s
2
D) in s t a n t a n eou s a cceler a t ion of t h e boy exer t in g t h e for ce F
1
is
3 6 . The accelerat ion of a part icle as obs erved from t wo different frames S
1
and
S
2
have equal magnit udes of 2 ms
2
.
A) Th e r elat ive acceler at ion of t h e fr ame is always eit h er be 0 or 4m/ s
2
.
B) Th eir r elat ive acceler at ion may h ave an y valu e bet ween 0 or 4 m/ s
2
.
C) Bot h of t h e fr ames may be s t at ion ar y wit h r es pect t o ear t h .
D) Th e fr ames may be movin g wit h s ame acceler at ion in s ame dir ect ion .
3 7 . In fig . a man of t rue mas s M is s t anding on a weighing machine placed in a
cabin. t he cabin is joined by a s t ring wit h a body of mas s m. as s uming no
frict ion, and negliglible mas s of cabin and weighing machine. Then t he
(normal force bet ween t he man and t he machine is proport ional t o t he mass)
Narayan a IIT Olympiad Sch ool 21
VIII- MPC SHP _ E - 5
m
O
A) Meas u r ed mas s of man is
( )
Mm
M+m
B) Acceler at ion of man is
( )
mg
M+m
C) Acceler at ion of man is
( )
Mg
M+m
D) Meas u r ed mas s of man is M.
3 8 . Two ident ical blocks each having a mas s of 2 0 kg are connect ed t o each
ot her by a light inext ens ible s t ring as s hown and are placed over a rough
s urface. Pulleys are connect ed t o t he blocks . Then t he
=0 . 0 4
=0 . 0 4
2 0 k g
2 0 k g
F =4 0 N
A
B
A) acceler at ion of block A is
2
4
m / s
13
B) acceler at ion of block B is
2
6
m / s
13
C) acceler at ion of block B is
2
4
m / s
13
D) t en s ion in t h e s t r in g is 8.61N.
3 9 . In t he figure, t he block A, B and C of mas s m each, have accelerat ion a
1
, a
2
and a
3
res pect ively. F
1
and F
2
are ext ernal forces of magnit ude 2 mg and mg
res pect ively. Then which of t he following are correct .
m
2 m
B
m
A F =2 m g
1
m
m
C
F =m g
2
A) a
1
> a
2
, a
2
= a
3
B) a
1
= a
2
, a
2
= a
3
C) a
1
= a
2
= a
3
D) a
1
> a
3
> a
2
Narayan a IIT Olympiad Sch ool 22
VIII- MPC SHP _ E - 5
4 0 .
D
(I)
A
(II)
F
B
1
(III)
F
A
A
1
(IV)
F
B
C
From t he figures , choos e t he correct one from t he following.
A) Dir ect ion of fr ict ion on block A in fig.II alon g (-ve) x-axis
B)Dir ect ion of fr ict ion on block B in fig.III alon g (-ve) x-axis
C)Dir ect ion of fr ict ion on block C in fig.IV alon g (+ve) x-axis
D) Dir ect ion of fr ict ion on block D in fig.I alon g (+ve) x-axis
41. The t ens ion in t he s t ring in figure is 1 6 N and t he accelerat ion of each
block is 0 . 5 m/ s
2
. Then (g=1 0 m/ s
2
)
2 k g
2
4 k g
3 0
A) t h e coefficien t of fr ict ion ( )
1
is 0.75
B) t h e coefficien t of fr ict ion ( )
2
is apr oximat ely 0.06
C) t h e coefficien t of fr ict ion ( )
1
is 0.06
D) t h e coefficien t of fr ict ion ( )
2
is 0.75
Comprehens ion Type
Paragraph for Ques t ion Nos . 4 2 t o 4 4
Two par t icles of mas s es 10 kg an d 35 kg ar e con n ect ed wit h fou r mas s les s
s t r in gs at poin t s B an d D as s h own in figu r e.(g=10m/ s
2
)
4 5
3 0
3 7
C
T
2
T
4
T
3
A T
1
B
1 0 k g
E
D 3 5 k g
4 2 . The t ens ion in t he s t ring T
3
is
A)
150 2
N B) ( )
50 3 2 3 N +
C)
200 3
N D) 250N
4 3 . The t ens ion in t he s t ring T
4
is
A)
150 2
N B) ( )
50 3 2 3 N +
C)
200 3
N D) 250N
Narayan a IIT Olympiad Sch ool 23
VIII- MPC SHP _ E - 5
4 4 . The t ens ion in t he s t ring T
1
is
A)
150 2
N B) ( )
50 3 2 3 N +
C)
200 3
N D) 250N
Paragraph for Ques t ion Nos . 4 5 t o 4 7
Con s ider t h e s it u at ion s h own in fig. Bot h t h e pu lleys an d t h e s t r in g ar e ligh t
an d all t h e s u r faces ar e fr ict ion les s .
2 M
M
A
B
4 5 . The acceleret ion of mas s M.
A) g/ 3 B) 2g/ 3 C) g D)5g/ 3
4 6 . The t ens ion in t he s t ring for t he block M is
A) Mg/ 2 B) Mg/ 4 C) Mg/ 3 D) Mg
4 7 . The force exert ed by t he clamp on t he pulley A in t he figure
A) Mg/ 2 B) Mg/ 4 C) Mg/ 3 D)
2Mg / 3
Paragraph for Ques t ion Nos . 4 8 t o 5 0
Th r ee blocks s h own in figu r e mor e ver t ically wit h con s t an t velocit ies . Th e
r elat ive velocit y of A wit h r es pect ive t o C is 100 m/ s u pwar d an d t h e r elat ive
velocit y of B wit h r es pect ive t o A is 50 m/ s down war d. All t h e s t r in g ar e ideal
an d fr ict ion les s .
A
B
C
4 8 . The magnit ude of velocit y of A wit h res pect ive t o ground is
A) 37.5 m/ s B) 12.5 m/ s
C) 62.5 m/ s D) 137.5 m/ s
4 9 . The magnit ude of velocit y of B wit h res pect ive t o ground is
A) 37.5 m/ s B) 12.5 m/ s
C) 62.5 m/ s D) 137.5 m/ s
5 0 . Find t he velocit y of C wit h res pect ive t o ground is
A) 37.5 m/ s B) 12.5 m/ s
C) 62.5 m/ s D) 137.5 m/ s
Narayan a IIT Olympiad Sch ool 24
VIII- MPC SHP _ E - 5
Paragraph for Ques t ion Nos . 5 1 t o 5 3
Mas s es M
1,
M
2
an d M
3
ar e con n ect ed by s t r in gs of n egligible mas s wh ich
pas s over mas s les s an d fr ict ion les s pu lleys P
1
an d P
2
as s h own in figu r e.
Th e mas s es move s u ch t h at t h e por t ion of t h e s t r in g bet ween P
1
an d P
2
is
par allel t o t h e in clin ed plan e an d t h e por t ion of t h e s t r in g bet ween P
2
and
M
3
is h or izon t al. Th e mas s es M
2
an d M
3
ar e 4.0 kg each an d t h e coefficien t of
kin et ic fr ict ion bet ween t h e mas s es an d t h e s u r face is 0.25. Th e in clin ed
plan e makes an an gle of 37 wit h t h e h or izon t al. If t h e mas s M
1
moves
down war ds wit h a u n ifor m velocit y, t h en an s wer t h e followin g.
[sin 37 = 3/ 5]
M
2
M
1 M
3
P
1
P
2
T
1
T
2
3 7
51. Find t he mas s of t he block M
1
.
A) 4.2 kg B) 9.8 kg C) 2.3 kg D) 6 kg
5 2 . Find t he t ens ion T
1
.
A) 41.16 N B) 9.8 N C) 12.36 N D) 16.2 N
5 3 . Find t he t ens ion T
2
.
A) 41.16 N B) 9.8 N C) 12.36 N D) 16.2 N
Mat rix Mat ching t ype ques t ions
5 4 . Column-I Column-II
a) in er t ia of r es t p) Newt on s I law
b) in er t ia of mot ion q) Newt on s II law
c) F=ma r) Newt on s III law
d) Act ion =r eact ion s ) Pas cals law
5 5 . Column I gives four different s it uat ions involving t wo blocks of mas s m
1
and m
2
placed in different ways on a s moot h horizont al s urface as s hown.
In each of t he s it uat ions horizont al forces F
1
and F
2
are applied on blocks
of mass m
1
and m
2
respect ively and also m
2
F
1
< m
1
F
2
. Mat ch t he st at ement s
in column I wit h corres ponding res ult s in column II.
Narayan a IIT Olympiad Sch ool 25
VIII- MPC SHP _ E - 5
Column-I Column-II
a)
F
1
F
2
m
1
m
2
p)
1 2 2 1
1 2 1 2
m m F F
m m m m
_
+
,
Bot h t h e blocks ar e con n ect ed by mas s les s
in elas t ic s t r in g. Th e magn it u de of t en s ion
r es u lt s in t h e s t r in g is
b)
F
1
F
2
m
1
m
2
q)
1 2 2 1
1 2 1 2
m m F F
m m m m
_
+
+
,
Bot h t h e blocks ar e con n ect ed by
mas s les s in elas t ic s t r in g. Th e
magn it u de of t en s ion in t h e s t r in g is
c)
F
1 F
2
m
1
m
2
r)
1 2 2 1
1 2 2 1
m m F F
m m m m
_
+
,
Th e magn it u de of n or mal r eact ion
bet ween t h e blocks is
d)
F
1
F
2
m
1
m
2
s )
1 2
1 2
1 2
F F
m m
m m
_ +
+
,
Th e magn it u de of n or mal r eact ion
bet ween t h e blocks is
5 6 . In t he s ys t em s hown in fig. mas s es of t he blocks are s uch t hat when s ys t em
is releas ed , accelerat ion of pulley P
1
is a upwards and accelerat ion of block
1 is a
1
upwards . It is found t hat accelerat ion of block 3 is s ame as t hat of 1
bot h in magnit ude and direct ion. Given t hat
1
1
a
a > a >
2
1 k g
2 k g
3 k g
4 k g
P
1
P
2
a
a
1
Column-I Column-II
a) acceler at ion of 2 p) 2a + a
1
b) acceler at ion of 4 q) 2a a
1
c) acceler at ion of 2 w.r .t .3 r ) u pwar ds
d) acceler at ion of 2 w.r .t .4 s )down war ds
Narayan a IIT Olympiad Sch ool 26
VIII- MPC SHP _ E - 5
5 7 . All t h e s u r faces s h own in figu r e ar e as s u med t o be fr ict ion les s . Th e block of
mas s m s lides on t h e pr is m wh ich in t u r n s lides backwar d on t h e h or izon t al
s u r face wit h acceler at ion a
0
.
m
M
Column-I Column-II
a) Nor mal for ce on m per pen dicu lar t o p)
2
mg s in cos
M msin
+
in clin ed plan e
b) acceler at ion [a
0
] of t h e pr is m is q)
( )
( )
2 M m g
4M m
+
+
c) Acceler at ion of s maller block m wit h r es pect r )
( )
2
M m g s in
M m s in
+
+
t o t h e pr is m
d) If
30
t h en acceler at ion of s maller block s )
0
mg cos ma s in
wit h r es pect t o t h e pr is m is
5 8 . Two blocks A an d B of mas s es 5/ 3 kg an d 5/ 6 kg ar e placed on an in clin ed
plan e of in clin at ion 37 (wit h t h e h orizon t al) wit h in it ial n ormal react ion bet ween
t h e blocks is zer o an d coefficien t of fr ict ion bet ween t h e blocks an d t h e s u r face
is 0.9. A for ce F is applied on block A alon g t h e in clin ed plan e as s h own . (g=
10m/ s
2
;
t an 37=3/ 4)
B
A
3 7
F
Column-I Column-II
a) Min imu m valu e of F t o keep t h e blocks s t at ion ar y p) 11
is in SI u n it
b) Maximu m valu e of F t o keep t h e blocks s t at ion ar y q) 50/ 3
is in SI u n it
c) Th e acceler at ion of t h e block A, wh en applied for ce F r) 33
is min imu m is in SI u n it
d) Nor mal for ce bet ween blocks wh en applied for ce s ) zer o
is maximu m, is in SI u n it
5 9 . Th e blocks A,B an d C ar e ar r an ged as s h own . Pu lleys an d s t r in gs ar e ideal. All
s u r faces ar e fr ict ion les s . If block C is obs er ved movin g down alon g t h e in clin e
at 1m/ s
2
. If t h e s ys t em is r eleas ed fr om r es t , t h e mat ch t h e followin g.
Narayan a IIT Olympiad Sch ool 27
VIII- MPC SHP _ E - 5
6 k g
A
B
C
3 7
3 k g
1 m / s
2
Column-I Column-II
a) mas s of t h e block B is in SI u n it p) 5
b) t en s ion in t h e s t r in g at t ach ed t o Block B is in SI u n it q) 9
c) acceler at ion of t h e block A is in SI u n it r ) 15
d) acceler at ion of t h e block B is in SI u n it s ) 12
6 0 . In t h e figu r e t h e blocks A,B an d C weigh ar e 3kg, 4kg an d 8 kg r es pect ively.
Th e coefficien t of s lidin g fr ict ion bet ween an y t wo s u r faces is 0.25. A is h eld at
r es t by a mas s les s r igid r od fixed t o t h e wall, wh ile B an d C ar e con n ect ed by a
ligh t flexible cor d pa s s in g a r ou n d a fixed fr ict ion les s pu lley. Th e for ce P is
n eces s ar y t o dr ag C alon g t h e h or izon t al s u r face t o t h e left at a con s t an t s peed.
As s u me t h at t h e arran gemen t s h own in t h e diagram, B on C an d A on B is
main t ain ed all t h e t h rou gh ou t .
B
C
P
A
Column-I Column-II
a) fr ict ion al for ce bet ween A an d B is p) 0.75 kg.wt
b) fr ict ion al for ce bet ween C an d s u r face q) 3.75 kg.wt
c) t en s ion in t h e cor d at t ach ed t o B is r ) 2.5 kg.wt
d) Force P is s ) 78.4 N
61. Refer r in g t o figu r e, t h e block B moves on a fr ict ion les s s u r fa ce, wh ile t h e
coefficien t of fr ict ion bet ween A an d t h e s u r face on wh ich it moves is 0.2.
4 k g
8 k g
T
1
T
2
A B
C
2 0 k g
Column-I Column-II
a) Acceler at ion of t h e block A is SI u n it p) 47.04
b) Acceler at ion of t h e block B is in SI u n it q) 5.88
c) Ten s ion in t h e s t rin g T
1
is in SI u n it r ) 31.36
d) Ten s ion in t h e s t r in g T
2
is in SI u n it s ) 12.58
Narayan a IIT Olympiad Sch ool 28
VIII- MPC SHP _ E - 5
CHEMISTRY E-5
CLASS : VIII
STRAIGHT OBJECTIVE TYPE
1. The bond formed bet ween t wo at oms by t he mut ual s haring of t heir valenvy
elect rons is known as :
A) Covalen t bon d B) Ion ic bon d
C) Bot h 1 & 2 D) Non e of t h es e
2 . In which of t he following polar covalent bond is pres ent ?
A) HF B) HCl
C) CO
2
D) All of t h es e
3 . The bond formed by t he mut ual s haring of one pair of elect rons bet ween
t wo at oms is known as :
A) Sin gle bon d B) Dou ble bon d
C) Tr iple bon d D) All of t h es e
4 . Which of t he following are propert ies of covalent compounds ?
A) Covalen t s u bs t an ces exis t as s olids , liqu ids an d gas es .
B) Covalen t s u bs t an ces h ave low melt in g an d boilin g poin t s .
C) Covalen t s u bs t an ces dis s olve in n on -polar poin t s .
D) All t h e above
5 . The bond be t we e n li gand and me t al at om (or) me t al i on i n c omple x
compounds is called:
A) Ion ic bon d B) Dat ive bon d
C) Dou ble bon d D) Tr iple bon d
6 . The t ot al number of covalent bonds and dat ive bonds made by an at om is
known as it s :
A) Elect rovalen cy B) Covalen cy
C) Variable valen cy D) Bot h 1 & 2
7 . The dis t ance bet ween t he nuclei of t wo covalent ly bonded at oms is known
as :________
A) Bon d an gle B) Bon d en ergy
C) Bon d len gt h D) Bon d
8 . The bond lengt h________ if t he s ize of bonded at oms increas es :
A) Decreas es B) In creas es
C) Remain s s ame D) Non e of t h es e
9 . In which of t he following molecules co-ordinat e covalent bond is pres ent ?
A) N
2
O B) O
3
C) N
2
O
4
D) All of t h es e
10. The increas ing order of bond energy for t he at omic orbit als is :
A) s p
3
< s p
2
< s p < s B) s < s p < s p
2
< s p
3
C) s p < s p
3
< s > s p
2
D) s p
2
< s p
3
< s < s p
Narayan a IIT Olympiad Sch ool 29
VIII- MPC SHP _ E - 5
11. The orbit als formed in hybridis at ion proces s are called:
A) Pu r e at omic or bit als B) Hybr id or bit als
C) Pu r e or bit als D) Sh ells
12. What is t he s -charact er in s p
3
hybridis at ion?
A) 25% B) 50% C) 75% D) 33.33%
13. Which of t he order is correct regarding s t rengt h of t he bonds ?
A) Sin gle bon d > Dou ble bon d > Tr iple bon d
B) Dou ble bon d > Sin gle bon d > Tr iple bon d
C) Tr iple bon d > Dou ble bon d > Sin gle bon d
D) Sin gle bon d > Tr iple bon d > Dou ble bon d
14. The angle bet ween t he t wo s p-hybrid orbit als in an at om is :
A) 90 B) 120 C) 109.28 D) 180
15. According t o Dalt ons law of part ial pres s ures :
A)
t ot a l 1 2 3 4 n
P p p p p ......xp B)
t ot al 1 2 3 4 n
P p p p p ...... p + + + + +
C)
1
t ot al
n
p
P
p
D)
1 2 3 n
p p p p
16. What is t he s hape of ammonia molecule?
A) Oct ah edral B) Pyramidal
C) T - s h ape D) Tet rah edral
17. Lat eral overlapping of at omic orbit als res ult s in t he format ion of ________
bond.
A) Sigma B) Pi - bon d
C) Tr iple bon d D) All t h e above
18. Which of t he following are t he meas urable propert ies of gas es ?
A) Pres s u re B) Mas s C) Volu me D) All of t h es e
19. The at mos pheric pres s ure can be meas ured by:
A) Man omet er B) Bar omet er
C) Th er momet er D) Alt imet er
2 0 . The rat es of diffus ion or effus ion of gas es , under s imilar condit ions of
t emperat ure and pres s ure, are invers ely proport ional t o t he s quare root of
t heir dens it ies t his is :
A) Dalt on s law B) Gr ah ams law of diffu s ion
C) Pau lis law D) Au fbau s law
21. What is t he s -charact er in s p
2
hybridis at ion?
A) 25% B) 50% C) 75% D) 33.33%
2 2 . Which of t he following are propert ies of gas es ?
A) Gas es h ave ver y low den s it ies .
B) Gas es ar e h igh ly compr es s ible.
C) Gas es exer t pr es s u r e on t h e walls of t h e con t ain er .
D) All t h e above.
Narayan a IIT Olympiad Sch ool 30
VIII- MPC SHP _ E - 5
2 3 . Pres s ure in t erms of mole fract ion is given by:
x
1
= mole fract ion of firs t gas
P
T
= Tot al pres s ure
p
1
= part ial pres s ure of firs t gas
A)
1
1
T
x
p
p
B)
T 1 1
p p x C)
1 1 T
p x P D) Non e of t h es e
2 4 . Which of t he following equat ion is correct regarding t he Grahams law of
di ffus i on?
A)
2 1
2 1
d r
r d
B)
1 1
2 2
r d
r d
C)
1
1 2
2
r
d d
r
D) Bot h 1 an d 3
2 5 . Number of s igma bonds in P
4
O
10
is :
A) 6 B) 7 C) 17 D) 16
2 6 . A s t udent report ed t he gas pres s ure as 1 . 4 x 1 0
5
kg m
1
s
2
. Report t his value in
ki lopas c al. [1 0 1 3 2 5 kgm
1
s
2
=1 0 1 3 2 5 pas c al]
A) 1.4 x 10
4
kPa B) 1.4 x 10
2
kPa
C) 1.4 x 10
3
kPa D) 1.4 x 10
1
kPa
2 7 . Whi c h of t he followi ng phe nome non wi ll oc c ur whe n t wo at oms of an
element wit h s ame s pin of elect ron approach each ot her?
A) Or bit als over lap will occu r .
B) Bon din g will occu r .
C) Or bit als over lap will n ot occu r .
D) A diat omic molecu le will be for med.
2 8 . The net dipole moment ( ) of H
2
O is 1 . 8 5 D. The value of dipole moment in
coulomb met re is :
A) 4.13 x 10
-20
B) 6.17 x 10
-30
C) 5.14 x 10
-18
D) 8.19 x 10
-21
2 9 . Rat io of lone pair-bond pair elect rons on cent ral at om in
3
-
I and XeF
4
are
res pect ively:
A) 2.66, 0.5 B) 1.5, 0.5 C) 2, 0.5 D) 0.5, 2
3 0 . Hydrogen and helium are mixed in a 2 0 l flas k at room t emperat ure of 2 0 C.
The part ial pres s ure of hydrogen is 2 5 0 mm Hg and t hat of helium is 7 5
mm Hg.
i ) Calculat e t he res pect ive mole fract ion of H
2
and He.
i i ) How many grams of H
2
and He are pres ent res pect ively?
(i ) (i i )
A) 0.23 an d 0.23 0.75 grams an d 0.23 grams
B) 0.77 an d 0.23 0.55 grams an d 0.33 grams
C) 0.67 an d 0.23 0.33 grams an d 0.53 grams
D) 0.88 an d 0.13 0.44 grams an d 0.22 grams
Narayan a IIT Olympiad Sch ool 31
VIII- MPC SHP _ E - 5
Reas oning t ype
31. St at ement I : The bond energy of P Cl bond in PCl
3
and PCl
5
is different .
St at ement II: In PCl
3
s p
3
p overlapping whereas in PCl
5
s p
3
dp overlapping
in not icied.
A) Bot h St at emen t -I an d St at emen t -II ar e t r u e.
B) Bot h St at emen t -I an d St at emen t -II ar e fals e.
C) St at emen t I is t r u e, St at emen t II is fals e.
D) St at emen t I is fals e, St at emen t II is t r u e.
3 2 . St at ement I : If difference of elect ronegat ivit y bet ween t wo at oms is zero,
t he res ult ant molecule will be non polar covalent .
St at ement II : In polar covalent molecule, t he s hared pair of elect ron lies in
t he middle of t wo at oms .
A) Bot h St at emen t -I an d St at emen t -II ar e t r u e.
B) Bot h St at emen t -I an d St at emen t -II ar e fals e.
C) St at emen t I is t r u e, St at emen t II is fals e.
D) St at emen t I is fals e, St at emen t II is t r u e.
3 3 . St at ement I : The dipole moment of NH
3
is les s t han NF
3
.
St at ement II : The lone pair of elect rons pres ent on nit rogen at om s hows
addit ive nat ure t o NH vect or whereas it is s ubt ract ive t o N
F vect or.
A) Bot h St at emen t -I an d St at emen t -II ar e t r u e.
B) Bot h St at emen t -I an d St at emen t -II ar e fals e.
C) St at emen t I is t r u e, St at emen t II is fals e.
D) St at emen t I is fals e, St at emen t II is t r u e.
3 4 . SSt at e me nt I : SF
4
has lone pai r of e le c t ron at e quat ori al pos i t i on i n
preference t o axial posit ion in t he overall t rigonal bipyramidal
geomet ry.
St at ement II : If lone pair is at equat orial pos it ion, t hen only repuls ion is
mi ni mum.
A) Bot h St at emen t -I an d St at emen t -II ar e t r u e.
B) Bot h St at emen t -I an d St at emen t -II ar e fals e.
C) St at emen t I is t r u e, St at emen t II is fals e.
D) St at emen t I is fals e, St at emen t II is t r u e.
3 5 . St at ement I: When pres s ure is expres s ed in pas cals and volume in M
3
, R
value will be 8 . 3 1 4 JK
1
mol
1
.
St at ement II: When pres s ure is expres s ed in dynes per s quare cent imet ere
and volume in cubic cent imet er, t hen R has unit s of ergs
per degree per mole.
Narayan a IIT Olympiad Sch ool 32
VIII- MPC SHP _ E - 5
A) Bot h St at emen t -I an d St at emen t -II ar e t r u e.
B) Bot h St at emen t -I an d St at emen t -II ar e fals e.
C) St at emen t I is t r u e, St at emen t II is fals e.
D) St at emen t I is fals e, St at emen t II is t r u e.
3 6 . St at ement I : CO
2
and N
2
O pair of gas es will have s ame rat e of diffus ion
under s imilar condit ions .
St at ement II :
_
,
dV
= K
dT
p
is according t o charles law.
A) Bot h St at emen t -I an d St at emen t -II ar e t r u e.
B) Bot h St at emen t -I an d St at emen t -II ar e fals e.
C) St at emen t I is t r u e, St at emen t II is fals e.
D) St at emen t I is fals e, St at emen t II is t r u e.
3 7 . St at ement I : If H
2
and Cl
2
enclos ed s eparat ely in t he s ame ves s el
exert pres s ures of 1 0 0 and 2 0 0 mm res pect ively,
t heir mixt ure in t he s ame ves s el at t he s ame
t emperat ure will exert a pres s ure of 3 0 0 mm.
St at ement II: Dalt ons law of part ial pres s ures s t at es t hat t ot al pres s ure is
t he s um of part ial pres s ures .
A) Bot h St a t emen t -I a n d St a t emen t -II a r e t r u e.
B) Bot h St at emen t -I an d St at emen t -II ar e fals e.
C) St at emen t I is t r u e, St at emen t II is fals e.
D) St at emen t I is fals e, St at emen t II is t r u e.
3 8 . St at ement I : Boyles law according t o kinet ic gas can be given by
2
pv = KT
3
.
St at ement II :The collis ions bet ween molecules in gas are in elas t ic.
A) Bot h St at emen t -I, an d St at emen t -II ar e t r u e.
B) Bot h St at emen t -I, an d St at emen t -II ar e fals e.
C) St at emen t I is t r u e, St at emen t II is fals e.
D) St at emen t I is fals e, St at emen t II is t r u e.
Mult iple Ans wer Ques t ions
3 9 . Which of t he following s t at ement (s ) is / are not t rue?
A) HF is les s polar t h an HBr .
B) Dis t illed wat er is a good con du ct or of elect r icit y.
C) Ch emical bon d for mat ion t akes place wh en for ces of at t r act ion over come
t h e for ces of r epu ls ion .
D) In covalen ce t r an s fer of elect r on s t akes place.
Narayan a IIT Olympiad Sch ool 33
VIII- MPC SHP _ E - 5
4 0 . Which of t he following are correct regarding bond lengt h?
A) Th e bon d len gt h in cr eas es wit h in cr eas e in t h e s ize of t h e at oms .
B) Th e bon d len gt h decr eas es wit h t h e mu lt iplicit y of t h e bon d.
C) Th e bon d len gt h in cr eas es if t h e p-ch ar act er in a h ydr id or bit al in cr eas es .
D) Bon d len gt h is u s u ally expr es s ed in an gs t r om u n it s (or ) picomet er s .
41. Which of t he following molecules pos s es s s p
3
d hybridis at ion?
A) TeCl
4
B) ICl
2
C) PH
3
D) HCN
4 2 . Which combinat ion of compounds and t heir geomet ry are correct ?
A) HgCl
2
-lin ear B)ClF
3
-lin ea r s h a pe
C) ClF
3
-T-s h ape D)
4
squareplanar
ICl
4 3 . In wh i c h o f t h e f o l l o wi n g c o mpo un d v ac an t o rbi t al t ake part i n
hybri di zat i on?
A) Al
2
Cl
6
B) C
2
H
5
Cl C) B
2
H
6
D) H
3
BO
3
4 4 . Which of t he following mas s es of gas would occupy about 3 dm
3
at 2 5 C
and one at mos phere?
A) 2.25g of Neon B) 8.0g of SO
2
C) 5.5g of CO
2
10 D) 4.0g of O
2
4 5 . 4 . 4 grams of CO
2
gas and 2 . 2 4 l of H
2
are t aken in one lit re cont ainer at
3 0 0 K. The t ot al pres s ure of t he gas in cont ainer will be:
A) 14.856 at m B) 4378.15 mm of Hg
C) 4.926 at m D) 3743.76 mm of Hg
4 6 . Which of t he following do not obey Dalt ons law of part ial pres s ure?
A) CO
2
an d CO at room t emperat u re B) NH
3
an d HCl at room t emperat u re
C) NH
3
an d s t eam at r oom t emper at u r e D) He an d H
2
COMPREHENSION TYPE
Lewis con cept of covalen cy of an elemen t in volved oct et r u le. Lat er on it was
fou n d t h a t ma n y elemen t s in t h eir compou n ds e. g. , BeF
2
, BF
3
et c. h a ve
in complet e oct et wh er ea s PCl
5
, SF
6
et c. h a ve expa n ded oct et . Th is cla s s ica l
con cept als o failed in pr edict in g t h e geomet r y of molecu les . Man y bon d an gles
can be explain ed by eit h er elect r on egat ivit y or s ize ar gu men t s . As t h e cen t r al
at om becomes more elect ronegat ive, bond pair is s hift ed t owards cent ral at om.
It res u lt s an increas e in elect ron dens it y near cent ral at om cau s ing s t ronger
bond pair-bond pair repu lsion and enlarged angle. For example bond angle of
NO
2
+
> NO
2
> NO
2
.
Narayan a IIT Olympiad Sch ool 34
VIII- MPC SHP _ E - 5
4 7 . Cons ider t he following iodides : PI
3
=102
O
, As I
3
= 1 0 0 . 2
o
, SbI
3
=9 9
o
The bond angle is maximum in PI
3
which is :
A) du e t o mor e bp-bp r epu ls ion in PI
3
B) du e t o s mall s ize of ph os ph or u s .
C) du e t o les s elect r on egat ivit y of P.
D) Non e of t h e above.
4 8 . The correct order of bond angles is :
A) H
2
S < NH
3
< SiH
4
< BF
3
B) NH
3
< H
2
S < SiH
4
< BF
3
C) H
2
S < NH
3
< BF
3
< SiH
4
D) H
2
S < SiH
4
< NH
3
< BF
3
4 9 . Which of t he following s t at ement s are correct ?
A) Bon d an gle of PF
3
> PCl
3
. B) Bon d an gle of PCl
3
< PBr
3
.
C) PCl
5
is s u per oct et molecu le. D) All t h e above.
Pr es en ce of lon e pair of elect r on on cen t r al at om give r is e t o con t r act ion in
bon d an gles du e t o r epu ls ion in bet ween lon e pair of elect r on s an d bon d pair
of elect r on s .
i) Th e elect r on pa ir s s u r r ou n din g t h e cen t r a l a t om r epel on e a n ot h er a s
t h eir or bit als / elect r on clou ds ar e n egat ively ch ar ged.
ii) In or der t o min imis e r epu ls ion , t h es e elect r on pair s t en d t o occu py s u ch
pos it ion s in s pa ce wh er e t h e dis t a n ce bet ween t h em is ma ximu m. In
ot h er wor ds , if valen ce s h ell of cen t r al at om is t aken as s ph er e t h e elect r on
pair s ar e localis ed on t h is s ph er ical s u r face at maximu m dis t an ce fr om
on e a n ot h er .
iii) Th e r epu ls ive in t er act ion s bet ween t wo lon e pair s (lp) ar e differ en t fr om
t h os e bet ween t wo bon d pa ir s (bp) or t h os e bet ween a lon e pa ir a n d a
bon d pair.
5 0 . Number of lone pair of elect rons on Xe at om in XeF
2
, XeF
4
and XeF
6
molecules res pect ively are:
A) 3, 2 an d 1 B) 4, 3 an d 2 C) 2, 3 an d 1 D) 4, 2 an d 3
51. The correct order of repuls ive forces bet ween various orbit als is :
A) Lon e pair lon e pair > lon e pair bon d pair > bon d pair bon d pair
B) Lon e pair lon e pair < lon e pair bon d pair < bon d pair bon d pair
C) Lon e pair lon e pair > bon d pair bon d pair > bon d pair lon e pair
D) Lon e pair lon e pair < bon d pair bon d pair < bon d pair lon e pair
5 2 . Molecular s hapes of PbCl
2
, CF
4
and Cl F
3
are:
A) Th e s ame wit h 2, 0 an d 1 lon e pair of elect r on s .
B) Differ en t wit h 0, 1 an d 2 lon e pair of elect r on s .
C) Differ en t wit h 1, 0 an d 2 lon e pair of elect r on s .
D) Th e s ame wit h 1, 1 an d 1 lon e pair of elect r on s .
Narayan a IIT Olympiad Sch ool 35
VIII- MPC SHP _ E - 5
PV = n RT equ a t ion h elps u s t o ca lcu la t e volu me u n der a n y con dit ion s of
t emper a t u r e a n d pr es s u r e. Th is equ a t ion is obt a in ed by combin in g a ll t h e
t h r ee gas laws i.e., Boyles law, Ch ar les law an d Avogadr os law.
n T
V PV n T Pb nRT
P
Volu me r emain in g con s t an t , t h e pr es s u r e of a given mas s of a gas in cr eas es
or decr eas es by
1
273
of it s pr es s u r e at 0C, for ever y 1C r is e or fall in
t emper a t u r e.
( )
P P
P
2 1
P T con s t a n t or a t con s t a n t volu me
T T T
1 2
5 3 . A ves s el of volume 8 . 0 1 0
3
cont ains ideal gas at 3 0 0 K and 2 0 0 kPa. The
gas is allowed t o leak t ill t he pres s ure fails t o 1 2 5 kPa. Calculat e t he moles
of gas leaked out if t emperat ure remains cons t ant . As s ume ideal nat ure.
A) 0.24 B) 0.25 C) 0.26 D) 0.27
5 4 . V vs T curves at cons t ant pres s ure P
1
and P
2
for an ideal gas are s hown in
figure. Which is correct ?
V
P
1
P
2
T
A) P
1
> P
2
B) P
1
< P
2
C) P
1
= P
2
D) All t h e above
5 5 . At 1 0 0
0
C and 1 at ms , if t he dens it y of liquid wat er is 1 . 0 g/ cm
3
and t hat of
wat er vapour is 0.0006 g/ cm
3
, t hen t he volume occupied by wat er molecules
in 1 lt of s t eam at t hat t emperat ure is :
A) 6 cm
3
B) 60 cm
3
C) 0.6 cm
3
D) 0.06 cm
3
Relat ive at omic mas s of an elemen t
Ma s s of on e a t om of t h a t elemen t
RAM=
1
mas s of C-12 a t om
12
5 6 . Boron has t wo is ot opes of boron-1 0 and boron -1 1 whos e
percent age abundance are 1 9 . 6 % and 8 0 . 4 % res pect ively. What is t he
average at omic mas s of boron?
A) 11 B) 10 C) 10.804 D) 11.796
5 7 . Calculat e t he gram at oms in 2 . 3 gms of s odium.
A) 0.01 B) 1 C) 10 D) 0.1
Narayan a IIT Olympiad Sch ool 36
VIII- MPC SHP _ E - 5
5 8 . Molecular weight of haemoglobin is 6 7 , 2 0 0 . If haemoglobin
cont ains 0 . 3 3 % of iron, t he number of iron at oms t hat pres ent in
one molecule of haemoglobin is : ( At . Wt of iron=5 6 )
A) 6 B) 224 C) 4 D) 120
Mat rix Mat ching t ype ques t ions
5 9 . Column-I Column-II
Bond angle Geomet ry
a) 180
0
p) Lin ear
b) 109
0
5