MATERIAL SAFETY DATA SHEET POTASSIUM SILICO FLUORIDE

1.
1.1.

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

PRODUCT IDENTIFIER
Product Use: IUPAC Name: EC Name: Chemical Formula: EC No.: RTECS: Potassium Silico Fluoride Dipotassium hexafluorosilicate Dipotassium hexafluorosilicate K2SiF6 240-896-2 VV8400000 ICSC: 1242 UN No.: 2655 CAS No.: 16871-90-2 REACH Registration No.: State/Form: Solid, powder

1.2.

RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST
Uses by workers in industrial settings, for industrial use only, used as flux for metal and glass industries, opalizing agent in glass production (Manufacture of glass and glass products)(Manufacture of other porcelain and ceramic poducts), brazing and soldering flux for aluminium, latex manufacturing additive, treatment of wooden pallets, textiles Industry, water fluoridation Uses advised against: not fit for use in anything related to human consumption Reason why uses advised against: Is harmful if consumed

1.3.

DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:

S.B.CHEMICALS Plot No 5003, Lane 52, IV Phase, G.I.D.C. Vapi Gujarat INDIA, Pin Code: 396195 Telephone: +91 260 2426915 e-mail address: s.yadav@sbfluorochem.com National contact: +91 260 2426915 1.4.

EMERGENCY TELEPHONE NUMBER:

+91 260 2426915 Opening hours: 2.30 am GMT 2.30 pm GMT Other comments (e.g. language(s) of the phone service): English

2.
2.1. 2.1.1.

HAZARDS IDENTIFICATION
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
REACH Index number 009-012-00-0, alkali fluorosilicates(K)

2.1.2.

Classification According To Regulation (EC) No 1272/2008 [CLP] Acute Toxicity: Category 3 Acute toxicity dermal Category 3 Acute toxicity inhalation Category 3 Repeated Exposure target organ toxicity: conclusive but not sufficient for classification. Hazardous to the aquatic environment: conclusive but not sufficient for classification. Classification According To Directive 67/548/EEC H301: Toxic if swallowed H311: Toxic in contact with skin H331: Toxic if inhaled

2.2.

L ABEL ELEMENTS
Labelling According To Regulation (EC) No 1272/2008 [CLP] :

Hazard Pictogram: GHS06: Skull and Crossbones Signal Word: DANGER Hazard Statements: Precautionary Statements: H301: Toxic if swallowed Hazard statement: P261: Avoid breathing dust/fume/gas/mist/vapours/spray. H311: Toxic in contact Hazard statement: P280: Wear protective gloves/protective clothing/eye protection/face with skin protection. H331: Toxic if inhaled Hazard statement: P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Hazard statement: P302+P352: IF ON SKIN: Wash with plenty of soap and water. Hazard statement: P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Hazard statement: P405: Store locked up.

Labelling Indication of danger: T - toxic Risk phrases: R23/24/25 - toxic by inhalation, in contact with skin and if swallowed Safety phrases S1/2 - keep locked up and out of reach of children S26 - in case of contact with eyes, rinse immediately with plenty of water and seek medical advice S45 - in case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible) Specific concentration limits: Concentration range (%)>= 1.0 < 10.0 ClassificationXn; R20/21/22 Harmful; Harmful by inhalation, in contact with skin and if swallowed. 2.3 2.4

SUPPLEMENTAL HAZARD INFORMATION (EU): Not applicable. OTHER HAZARDS

In case of inhalation: mucous membrane irritation: Symptoms: coughing, sore throat, nose bleeding In case of higher conc.: Chemical pneumonia

3.
3.1.

COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCES
Synonyms: Potassium Silico Fluoride, Potassium Fluorosilicate Formulae: K2SiF6 Active agent: dipotassium hexafluorosilicate: min. 98% Other haz contaminant: none Relative molar mass: 220.2699 g/mol Inorganic substance

4.
4.1.

FIRST AID MEASURES

DESCRIPTION OF FIRST AID MEASURES
If in contact with skin: Wash immediately with large amounts with water. Wash hands and all contaminated areas with water. Remove clothes and shoes. Gently wash with plenty of soap and water. If in contact with eyes: Rinse immediately with large amounts of water. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation occurs or persists. If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention immediately. If swallowed: Rinse mouth. Get medical attention immediately.

4.2.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED

In case of inhalation: mucous membrane irritation: Symptoms: coughing, sore throat, nose bleeding In case of higher conc.: Chemical pneumonia

5.
5.1. 5.1.1. 5.1.2. 5.1.3. 5.2.

FIREFIGHTING MEASURES
EXTINGUISHING MEDIA:
Suitable Extinguishing Media: Dipotassium hexafluorosilicate is not combustible, in case of fire use extinguishing media appropriate for the nearby materials. Unsuitable Extinguishing Media: None know. Incase of fire: Evacuate area. Fight fire with normal precautions from a reasonable distance. Wear suitable respiratory equipment. Total impervious protective suits, gloves, and boots must be worn. Keep public away from danger area.

SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE

Hazardous combustion products: Toxic gases may be formed.

5.3.

ADVICE FOR FIREFIGHTERS. Wear full protective clothing and self-contained breathing apparatus. The containers exposed to fire
should be cooled with water spray.

6.
6.1. 6.1.1. 6.1.2. 6.2.

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
For Non-Emergency Personnel: Keep unprotected people away, allow only trained personals to handle the material. For Emergency Responders: Avoid contact with skin & eye. Do not inhale the dusts, avoid formation of dust. Avoid formation of dust. The spilled product forms slippery film on the floor

ENVIRONMENTAL PRECAUTIONS: Dispose of spillage and waste (product/packaging) in accordance with all applicable
environmental laws. Do not allow to enter sewers/soil/surface or ground water. Notify the respective authorities in accordance with local law in the case of environmental pollution immediately.

6.3. 6.3.1.

METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP

For Containment: Collect the spilled material in mechnical way then place into a suitable, closed, properly labelled chemical waste container for disposal. During disposal wear suitable personal protective equipment.

6.3.2. 6.3.3. 6.4.

For Cleaning Up: Collect the material in a suitable container, clean with water Other Information:

REFERENCE TO OTHER SECTION: For further and detailed information see section 8 and 13.

7.
7.1. 7.1.1.

HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING
PROTECTIVE MEASURES: Observe conventional hygiene precautions. Avoid the direct contact with the product. After the work hours wash your hands thoroughly. TECHNICAL MEASURES: Ensure adequate ventilation. Avoid formation of dust. The wet product should be handled with special care, because it may damage the skin and the mucuous membranes. Do not eat and smoke in the workplace. Use adequate dust proof mask.

7.1.2.

Keep the unused containers closed. The emptied containers may contain residues of the product, which can be hazardous.

7.2. 7.3.

PRECAUTIONS AGAINST FIRE AND EXPLOSION: E Flammability class, no special measure is required. Keep away from heat. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
Keep in original, closed and labelled container. The place of storage has to be properly ventilated and cleanable. Store in cool and dry place. Keep away from food, beverages, luxury goods, feed, pharmacies. Follow all instructions on the label.

7.4.

STORAGE: For indefinite time

Incompatible materials: strong acids and strong oxidants. Packaging material: well closable container. Recommended packaging material: Paper.

8.
8.1.

EXPOSURE CONTROLS/PERSONAL PROTECTION

CONTROL PARAMETERS
DNEL WORKER CONSUMER 3 2.5 mg/m 3 2.5 mg/m 3 2.5 mg/m ROUTES EXPOSURE Dermal Inhalative Oral OF EXPOSURE FREQUENCY Short Term(acute) Short Term(acute) Short Term(acute) REMARKS DNEL (Derived No Effect Level) DNEL (Derived No Effect Level) DNEL (Derived No Effect Level)

Use gloves, eye protection and wear suitable protective clothing. Do not use contact lenses. Avoid inhalation of dust. Wear respiratory protection mask (type P3 or FFP3) 8.2.

TECHNICAL MEASURES:
Occupational Exposure Limit Value - (8h, TWA) as F= 2,5 mg/m. Use in a well-ventilated area. Provide a local exhaust ventilation system at the sources of emission. Do not eat, drink or smoke when using the substance.

8.3.

EXPOSURE CONTROLS
In case of a hazardous material with no controlled concentration limit it is the employer's duty to keep concentration levels down to a minimum achievable by existing scientific and technological means, where the hazardous substance poses no harm to workers. Appropriate Engineering Controls In pursuance of work is proper foresight needed to avoid spilling onto clothes and floors and to avoid contact with eyes and skin. Avoid the inhalation of dust. Avoid the contact with skin and eyes. In the vicinity of the workplace safety shower and eye washing fountain has to be installed. Do not eat, smoke, store food in the workplace. Ensure cold-warm water washing facilities. Observe conventional hygiene precautions. Ensure adequate ventilation. The ventilation system should be corrosion proof. Individual Protection Measures, Such As Personal Protective Equipment: 1. Eye/face protection: use adequate face mask. 2. Skin protection: a. Hand protection: Use appropriate protective gloves. b. Other: use appropriate, closed protective clothes and protective boots. 3. Respiratory protection in case of sufficient ventilation, not necessary. 4. Thermal hazard. Environmental Exposure Controls: No specific prescription. The requirements detailed in Section 8 assume skilled work under normal conditions and usage of the product for appropriate aims. If conditions differ from normal or work is carried out under extreme conditions an expert's advice should be sought out before deciding upon further protective measures.

8.3.1.

8.3.2.

8.3.3.

9.
9.1.

PHYSICAL AND CHEMICAL PROPERTIES

INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
a. b. c. d. e. f. g. h. i. Parameter Appearance: solid (crystalline), clean or white to yellowish. Odour: odourless Odour threshold: no data available pH value: 5.0 in 1% aqueous solution Melting point/freezing point: not applicable Initial boiling point and boiling range: Decomposes @ O O 500 C (932 F) Flash point: not applicable Evaporation rate: no data available Flammability: non flammable. Upper/lower flammability or explosive limits: not explosive k. Vapour pressure: not applicable l. Density: 2.6 g/L m. Solubility(ies): In water: slightly soluble in water n. Partition coefficient: n-octanol/water: not applicable o. Auto-ignition temperature: not applicable O O p. Decomposition temperature: 500 C (932 F) q. Viscosity: not applicable r. Explosive properties: Not Explosive s. Oxidizing properties: Non Oxidising j.

9.2.

OTHER INFORMATION:

10. STABILITY AND REACTIVITY

10.1. 10.2. 10.3. 10.4.

REACTIVITY: None known. CHEMICAL STABILITY: At normal temperature: stable at general conditions of work. POSSIBILITY OF HAZARDOUS REACTIONS:
In case of heating (> 390 C) it decomposes, and toxic tetrafluorosilicat (SiF4) gas, tripotassium Heptafluorosilicate (K3SiF7) solid, and potassium Fluoride (KF) solid are formed. It decomposes to the effect of heat and strong acids. Avoid contact with water, acids, oxidising agents, cyanides. active metals,s uch as Al or Mg. O CONDITIONS TO AVOID: Avoid heating above 390 C. INCOMPATIBLE MATERIALS: Strong acids and strong oxidants. Avoid contact with water, acids, oxidising agents, cyanides, active metals, such as Al or Mg. HAZARDOUS DECOMPOSITION PRODUCTS: Tetrafluorosilicat (SiF4) gas, Tripotassium Heptafluorosilicate (K3SiF7) solid, and Potassium Fluoride (KF) solid INFORMATION ON TOXICOLOGICAL EFFECTS: Acute toxicity: Category 3 Acute toxicity: T; R23/24/25 Toxic; Toxic by inhalation, in contact with skin and if swallowed Acute toxicity: irreversible damage after single exposure data lacking Occupational Exposure: TLV: ppm; 2.5 mg/m3 as F (as TWA) (ACGIH 1994-1995). Repeated dose toxicity: data lacking Irritation / Corrosion: conclusive but not sufficient for classification Sensitisation: data lacking Carcinogenicity: data lacking Mutagenicity - Genetic Toxicity: conclusive but not sufficient for classification Toxicity to reproduction: fertility data lacking Toxicity to reproduction: development data lacking Toxicity to reproduction: breastfed babies data lacking Environment: conclusive but not sufficient for classification For Substances Subject To Registration, Brief Summaries Of The Information Derived From The Test Conducted: For detailed test results contact the supplier of the substance. Relevant Toxicological Properties Of The Hazardous Substances: Data not available Information On Likely Routes Of Exposure: ingestion, inhalation, skin contact, eye contact. Symptoms Related To The Physical, Chemical And Toxicological Characteristics: Its permanent exposure might cause teeth and bone structure deformation. Due to its poor solubility in water it hardly irritates the mocous membranes, eyes and respiratory organs. Its intoxication is unknown when it is swallowed, due to its faint solubility the material is discharged from the body in time. Although it might cause significant deformation in teeth and bones. Deformation usually begins at hip-bone and lumbar. In metallurgical processes and in case of contacting the reaction partners, hydrogen fluoride or other soluble, volatile fluorides might be emitted, the toxicity of which is much higher. In case of inhalation: mucous membrane irritation. Symptoms: coughing, sore throat, nose bleeding. Concentration: chemical pneumonia.
O

10.5. 10.6. 10.7.

11. TOXICOLOGICAL INFORMATION

11.1.

11.1.1. 11.1.2. 11.1.3. 11.1.4.

11.2.

IN CASE OF REPEATED OR LONG TERM EXPOSURE: chronic bronchitis.

In case of skin contact: In case of eye contact: In case of ingestion: slight irritation. slight irritation. risk of hypocalcemia with nervous problems (tetany) and cardiac arrhythmia. Liver injury may occur. Nausea, Vomiting, Abdominal pain, Diarrhoea

11.3.

SYMPTOMS:

11.4.

DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND LONG-TERM EXPOSURE: may be irritating to
skin, may be slightly irritating to the eyes. Interactive effects: Absence of specific data: No data available. No information.

11.5.

OTHER INFORMATION:
Test Type Route Reported Dose (Normalized Dose) 448mg/kg (448mg/kg) 500mg/kg (500mg/kg) 500mg/kg (500mg/kg) ? Effect Source

Organism

frog

LDLo

subcutaneous

Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. Vol. 124, Pg. 133, 1937. "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 4, Pg. 327, 1969. Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. Vol. 124, Pg. 133, 1937. Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(11), Pg. 80, 1988.

guinea pig

LD50

oral

guinea pig

LDLo

subcutaneous

? PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) BEHAVIORAL: ATAXIA BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) BEHAVIORAL: ATAXIA BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)

mouse

LD50

oral

70mg/kg (70mg/kg)

rat

LD50

oral

156mg/kg (156mg/kg)

Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(11), Pg. 80, 1988.

12. ECOLOGICAL INFORMATION

12.1.

TOXICITY: Data is conclusive but not sufficient enough for classification.

EXPOSURE REMARKS FREQUENCY Short Term(acute) Predicted no effect concentration 11 mg/kg soil dw 51 mg/L Short Term(acute) Predicted no effect concentration PERSISTENCE AND DEGRADABILITY: Biodegradability: since the substance is inorganic, no studies have to be conducted. Water 0.9 mg/L freshwater 0.9 mg/L marine STP PNEC Soil

12.2. 12.3. 12.4. 12.5. 12.6.

BIOACCUMULATION POTENTIAL: Bioaccumulation potential is not expected since the substance dissolves into several ions. MOBILITY IN SOIL: It spreads in the form of aerosol. Faint solubility and spreading. Adsorption in deposits or organic
sediments.

RESULTS OF PBT AND VPVB ASSESSMENT: Not applicable for inorganic substances. OTHER ADVERSE EFFECTS: No data available.

13. DISPOSAL CONSIDERATIONS

13.1.

WASTE TREATMENT METHODS: Disposal according to the local regulations.

13.1.1. Information Regarding The Disposal Of The Product: Do not dispose together with domestic waste. Do not enter into drains, watercourses and soil. Recycle is possible or incinerate in a licensed incinerator. During the disposal of the product, its residue and its packaging the national and local prescriptions should be observed. The EWC codes indicated below are only recommendations, but they may have to be changed due to special circumstances, in such cases new classification may be needed. 13.1.2. Information Regarding The Disposal Of The Packaging: According to the consideration regarding the product. Empty the containers as much as possible. 13.1.3. Physical/Chemical Properties That May Affect Waste Treatment Options Shall Be Specified: None known. 13.1.4. Sewage Disposal: It should not get into waste water or sewer without dilution and neutralisation. Lime is suggested for neutralisation. 13.1.5. Special Precautions For Any Recommended Waste Treatment: No data available.

14. TRANSPORT INFORMATIONS

14.1. 14.2. 14.3. 14.4. 14.5.

UN NUMBER: 2655 UN PROPER SHIPPING NAME: Dipotassium

Hexafluoroaluminate

14.6. 14.7.

SPECIAL PRECAUTIONS FOR USER:No Data Available TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE": No Data
Availabe WGK Germany: 2

TRANSPORT HAZARD CLASS(ES):6.1 PACKING GROUP III ENVIRONMENTAL HAZARDS: No Data Available

14.8.

14.9. 14.10.

RTECS: VV8400000 F: 21

14.11. 14.12.

Hazard Note: Irritant TSCA: Yes

15. REGULATORY INFORMATION

15.1.

SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE
a. REGULATION (EC) No ]907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive] 999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No ]488/94 as well as Council Directive 76/769/EEC and Commission Directives 9]/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC

15.2 CHEMICAL SAFETY ASSESSMENT: No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier

16. OTHER INFORMATION

16.1.

INFORMATION REGARDING THE REVISION OF THE SAFETY DATA SHEET: FULL TEXT OF THE ABBREVIATIONS IN THE SAFETY DATA SHEET:
DNEL: Derived no effect level. PNEC: Predicted no effect concentration. CMR effects: Carcinogenity, Mutagenicity and reproduction toxicity. PBT: Persistent, bioaccumulative and toxic . . n.d.: not defined .. n.a.: Not applicable .. Data sources: Indication of danger T - toxic Risk phrases R23/24/25 - toxic by inhalation, in contact with skin and if swallowed Safety phrases S1/2 - keep locked up and out of reach of children S26 - in case of contact with eyes, rinse immediately with plenty of water and seek medical advice S45 - in case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible) Specific concentration limits Concentration range (%)>= 1.0 < 10.0 Classification: Xn; R20/21/22 Harmful; Harmful by inhalation, in contact with skin and if swallowed.

16.2. 16.3.

TRAINING INSTRUCTIONSRECOMMENDED RESTRICTIONS ON USE (NON-STATUTORY RECOMMENDATIONS BY SUPPLIER): This safety data sheet had been prepared by the manufacturer on the basis of information available via internet. The information, data and recommendations contained herein are provided in good faith, obtained from reliable sources and believed to be true and accurate as of the date issued; however, no representation is made as to the comprehensiveness of the information. The SDS shall be used only as a guide for handling the product; in the course of handling and using the product other considerations may arise or be required. Since the conditions or the handling, the storage and the disposal of this product are beyond the control of the manufacturer, the distributor or the preparer of this SDS, no warranty, expressed or implied, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. No responsibility is assumed regarding the accuracy, completeness or suitability of all or any of the information contained herein or the results to be obtained from the use thereof at the time of use. In no way shall the manufacturer, the distributor or the preparer of the be liable for any claims, losses or damages of third parties, personal injury, property damage, lost profits or any special, direct, indirect, incidental, consequential or exemplary damages resulting from the use of or reliance upon such information. Users are cautioned to determine the appropriateness and applicability of the above information to their particular circumstances and purposes and assume all risk associated with the use of this product. It is the responsibility of the user to fully comply with local, national and international regulations concerning the use of this product.