Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
2004 Update
by
Kelly Brinkler
Acknowledgements
I would like to thank Peter Stokes (CARE Group) and the other members of the CARE Group for their support
continued support and guidance throughout this project and the constructive feedback received. Finally I would
like to thank Peter Pennells, Rebecca Cocking and the members of WRAP for their valuable input and feedback
in finalising the report.
2
Table of Contents
Executive Summary....................................................................................................................5
Executive Summary....................................................................................................................5
INTRODUCTION......................................................................................................................7
Types of Glass.........................................................................................................................7
Glass Production – the process...............................................................................................7
Container glass....................................................................................................................7
Flat glass.............................................................................................................................7
Glass Production – the figures................................................................................................8
Figure 1 – UK Glass Production figures by sector.....................................................................8
Waste Glass and Glass Recycling.............................................................................................10
UK Waste Arisings................................................................................................................10
Why Recycle Glass?.............................................................................................................10
Packaging waste regulations.............................................................................................10
End-of-Life Vehicles Directive.........................................................................................10
How is glass recycled?..........................................................................................................10
Waste Glass processing.........................................................................................................11
Benefits.............................................................................................................................11
Problems associated with recycling glass.........................................................................11
Figure 2 – Production v recycling: the UK’s colour imbalance................................................12
Economics and fluctuations in market price instability....................................................12
The markets...............................................................................................................................13
Existing and Potential markets for waste glass.....................................................................13
Figure 3 – Potential routes for waste glass...............................................................................13
Glass Markets........................................................................................................................13
Figure 4 – Present cullet use by glass sectors...................................................................14
Table 1 – Cullet Contamination Specifications for re-use in the glass sector...........................14
Table 2 – Cullet colour contamination specifications for re-use in the glass sector.................14
Alternative Markets...............................................................................................................15
Aggregates........................................................................................................................15
Table 3 – Aggregates: current status with respect to glass cullet use........................................15
Table 4 – Aggregate Specifications...........................................................................................17
Table 5 – Specifications for filtration applications...................................................................18
Table 6 – Abrasive specifications..............................................................................................19
Bricks and Ceramics.........................................................................................................20
Table 7 – Brick specifications...................................................................................................20
Niche Markets and Other potentials..................................................................................21
Table 8 – Niche market company products...............................................................................21
Summary of Volume Potentials and market routes...............................................................22
Figure 5 - recycled glass market – current players and market dominance..............................22
Figure 6 - recycled glass market – the potential picture...........................................................22
Barriers to Entry....................................................................................................................23
Glass and the Automotive Industry...........................................................................................24
Why glass?............................................................................................................................24
Table 9 – Composition of an average automobile.....................................................................24
Automotive Glass..................................................................................................................24
Structure and Function......................................................................................................24
Standards and Specifications............................................................................................24
Automotive Glass as Waste...................................................................................................25
ELV glass..........................................................................................................................25
Figure 7 – ELV disposal routes.................................................................................................25
Dismantling in the UK......................................................................................................26
3
Shredding in the UK.........................................................................................................26
Technical and Economic Barriers to recovery ELV glass.....................................................26
4
EXECUTIVE SUMMARY
In 1999 (published Feb 2000) CARE produced a report which looked at the challenges for industry in the
recycling of automotive glass, against the backdrop of competing glass waste streams and limited recycling
opportunities. Since Glass approximates to 3% of an average vehicle’s weight and is relatively easy to remove,
store and transport, it is viewed as an important material en-route to the attainment of the End of Life Vehicle
Directive targets. Four years have passed since the original report and this second report is designed to ascertain
how that backdrop has changed and to flag up the challenges yet to be overcome, as well as emerging
opportunities.
Glass still remains a significant contributor to the UK’s waste stream and as such is still a primary focus in
nationwide initiatives for recycling and re-use. In recent years, however, the adoption of new legislation into the
UK has increased the mandatory requirements on certain industries to recycle this material. The Packaging
Waste Directive and the ELV Directives impose set targets to the applicable industries for recycling and recovery
rates.
The technologies associated with the variety of glass types made remain relatively unchanged in recent years.
Glass manufacturers are becoming increasingly aware of the pressure on them to accept recycled glass cullet and
as such investments in newer technologies are occurring. The process of re-processing glass to form cullet and
the removal of contaminants also remains relatively unchanged with the main advances and research effort in the
separation of the fine fractions of materials in the mix.
Although advances in the technological side of glass making and re-processing may appear slow in terms of
enhancing the ability to consume increased amounts of variable quality cullet, the developments in the market
place for recycled material have been steadily ongoing. In 1999 the dominant route for recycled glass cullet
would have been back into the glass sector, with the container sector consuming the main proportion of total
recycled glass. However, at that time the emergence of the aggregates sector was beginning, using glass cullet as
an aggregate substitute, primarily for highway construction. There is now a changing picture of the market
structure for recycled glass. Although the container sector still remains the dominant consumer of glass cullet,
the flat and fibre glass sectors are increasingly conscious that they need to increase their use of post-consumer
glass. In addition to this the aggregates sector (ranging from top end use in Glassphalt to bottom end use as a
substitute for gravel) has grown and new market entrants include niche markets such as decorative glass
products, filtration and abrasives.
Although the market situation is looking stronger than in past years with an increasing number of routes for glass
cullet the increasing production of glass continues to put pressure on these recycled markets to consume more
recycled material. The container sector at this point in time is probably the only sector that consumes a
significant proportion of the total possible and this is primarily due to the green glass making industry, whilst
there is still room for improvement in the amber and particularly clear glass making sectors. The other glass
sectors are severely limited by quality specifications and as such tend to source recyclate from downstream
processing rather than post-consumer supplies but continually aim to increase this where possible. There is
significant potential for the aggregates sector to consume far more of the UK’s waste glass stream than it does at
present potentially making this sector the dominant waste glass consumer in the recycled glass markets, followed
by the container glass sector and filtration. The abrasives market is also already established in the UK offering
another significant potential to consume waste glass. There are likely to be new entrants into the recycled glass
market soon and in future years as technologies continue to advance and raw materials become scarce. There is
significant future potential from the brick and ceramics industries, not only due to the replacement of raw
materials, but similar to the glass sector, the energy and emissions saving advantages of using waste glass. This
has led to increasing research in these areas to assess the economic advantages.
With regard to automotive glazing the recent adoption of the End-of Life Vehicle Directive has now brought the
potential issues considered in the 1999 report into sharper focus and although prior to adoption the recycling
industry was already recycling a significant amount of the material from post-consumer vehicles, the new
Directive sets specific mandatory targets.
By January 1, 2006
• Reuse and recovery: Min. 85% by weight on average
• Reuse and recycling: Min. 80% by weight on average
By January 1, 2015
• Reuse and recovery: Min. 95% by weight on average
• Reuse and recycling: Min. 85% by weight on average
5
The industry is arguably already on target for reaching the figures set out for 2006; however, it is necessary that
the distinction between recovery and recycling is adhered to in reaching these targets. These targets are very high
and therefore require a high percentage of the material that makes up an automotive vehicle to be recycled.
Current estimates for the percentage recycled material are anywhere between 72% (EMR/SIMMS study 2003)
and 77+% depending on the data source (ACORD annual reports.) and therefore include the main components of
the vehicle, for example metals, and those which are easily removed, for example tyres and batteries. However,
the industry now has to look into the ways and means of recycling the more difficult components such as glass
and plastics in order to continue to increase the recycled and recovered weights to reach future targets.
Increasing research and feasibility experiments have been ongoing in the automotive sector in terms of removing
the vehicle glass. Though some advances have been made, it is still the case that the cost of removing the glass
from vehicles at the dismantling stage (which ultimately gives the higher value product as quality is higher)
mean it is still an uneconomic process. The cost of removing the glass from one vehicle ranges between £2.50
and £3.50 and with the current market price for cullet ranging from £5/tonne to £45/tonne (dependent on quality)
ELV glass generated at the dismantling stage (i.e. high cost stage requiring high cost end markets) is
economically infeasible at present. The resultant cullet would have to fetch a minimum price of £102/tonne to
make the process economically feasible. However, this figure is based on potential ELV waste glass arisings
from dismantling all ELV vehicles in a year. This figure is unrealistic due to the loss of glass in removal and
ELV’s only suitable for immediate shredding and so with dismantled vehicles and glass tonnages only a
percentage of the total the realistic figure is likely to be significantly higher between £278/tonne and £389/tonne.
Such high prices would require high value end markets often found in the niche market areas such as decorative
aggregates. However, these often only require small tonnages (100’s to 1000’s) and demand is intermittent.
Alternatively, the cost of removing the glass must fall to at least half of the current ‘best case’ dismantling cost
and that is only if increasing volumes can be removed. More realistically the cost of glass removal must fall to
less than 1/5 of the present day costs to be become viable for the higher priced end markets. But, again, the
problems of contamination in this source often render the cullet only suitable for lower priced end markets such
as use in the aggregates sector as a substitute for gravel, as the glass can be left in the vehicle and separated at a
later stage.
Although the situation remains complex and costly at present there are emerging markets that not only are able
to produce high value products but also use lower quality cullet. One of these markets is the foam glass market
which at present does not penetrate the UK. However this product is ideally suited to consume contaminated
glass which would include glass from ELV sources. It is estimated that a 1% penetration into the UK market
would allow this industry to consume 50,000 tonnes/annum (t/a) of waste glass. There has been increasing
research on the feasibility of penetration of the foam glass market into the UK and there is significant potential
for this to occur in the near future although currently there is no manufacture in the UK as the cost of setting up a
facility is too high.
In summary, the advances made since 1999 have been significant in the overall glass recycling arena although
for the automotive sector the quality restrictions and costs of dismantling are still problems that need to be
overcome. At present, the main route for ELV glass is into the aggregates sector which is steadily increasing in
size in terms of cullet use. However, the low price value of this end market in conjunction with the high costs of
glass cullet production from ELVs will be such that the process may remain uneconomic. New markets are
continually emerging and research is ongoing in many areas particularly concentrated in fields where
contaminated cullet can be used. Here, the foam glass market has extreme potential and it only requires a small
penetration in the UK for this market to be able to consume even the maximum potential quantities of ELV glass
produced.
6
INTRODUCTION 70-74% silica (sand)
12-16% sodium oxide
The 1999 CARE Report on Glass Recycling 5-11% calcium oxide
addresses several issues to establish the situation at 1-3% magnesium oxide (higher in flat glass)
that time for automotive glass recycling. Five years 1-3% aluminium oxide
on, the following report aims to re-address the
situation highlighting developments in technology These proportions may alter slightly for the
associated with glass production and glass alternative glass types and in some cases additional
recycling, the change in market structure for components are added for special effects such as
recycled glass, new and potential market entrants colouring the glass. For lead glass the calcium
and the up to date situation in the ELV disposal oxide is replace by lead oxide to give the final
chain with respect to overcoming the problems product a high refractive index creating the
raised in the 1999 report. characteristic sparkle of crystal when cut.
The report is in four main sections:
GLASS PRODUCTION – THE PROCESS
SECTION 1: Focuses on re-establishing the basic
types of glass, glass production processes and The four basic stages of the glass making process
associated volumes in the UK. remain the same in all types of glass production
SECTION 2: Focuses on glass recycling. which are1:
SECTION 3: Focuses on the current market
situation and potential entrants. Melting
SECTION 4: Focuses on the role that ELV glass Refining
can play in the automotive industry’s attempt to Working
reach mandatory recycling targets and minimise Annealing
disposal.
The general glass making process has remained
TYPES OF GLASS relatively unchanged in present years. However, it
is necessary to briefly understand the different
There are several types of glass distinguished by mechanical principles behind the production of the
their chemical composition. The alteration of the final products that distinguish the form of the final
chemical constituents in the glass making mix products.
allows manufacturers to alter the properties of the
glass to suit the required function of the end Container glass
product. Container glass is predominantly made by the
There are three main categories of what is termed automatic process which may more commonly be
‘commercial glass’ the most common of which is known as the ‘press and blow’ or ‘blow and blow’.
soda-lime glass. This is used in the majority of In these processes a ‘gob’ of glass is delivered into
applications within the container and flat glass the respective mould for creation. In the former
sectors typically for bottles, jars, automotive and process a plunger presses the ‘gob’ into the mould
structural glazing among others. Soda-lime glass whilst the latter uses compressed air to blow the
tends to dominate the market in terms of glass ‘gob’ into the mould. The second stage in each
made, however, the other two types of commercial process uses a blast of compressed air to form the
glass are: pre-formed shape against the mould walls, hence
the second term is ‘blow’ in each case. This process
Lead glass – more commonly know as lead crystal, is now the dominantly used process in container
this is used for decorative objects and is the second glass manufacture and delivery of two ‘gobs’ at the
most common type of commercial glass same time is the most common. There is an increase
Borosilicate glass – commonly used in ovenware in the use of triple and quadruple gob machines
and heat resistant ware this glass type is more which ultimately aids production efficiency.
commonly know under the trade name Pyrex
Flat glass
In addition to these, there are numerous small The two main processes involved in the production
volume alternative glass types used in applications of flat glass are the float and rolled processes. The
including glass fibre, filtration, television screens, float process allows the production of clear, tinted
glass ceramics, sealing, optical and technical and coated glass for buildings and clear and tinted
applications. glass for vehicles. There are 6 integrated stages that
allow the formation of the end product which are as
Although the chemical composition of these follows:
various types of glass varies the most common
commercial glasses including the dominating soda-
lime glass have similar chemical compositions in 1
For more information on these processes please
the following proportions: refer to the British glass website at
www.britglass.co.uk/
7
1. Melting and refining – raw materials enter the with the container sector dominating the glass
furnace and through a series of complex flow market with nearly two thirds of the total market
patterns the molten glass becomes free of inclusions share and the majority of the remainder in the flat
and bubbles and passes smoothly and continuously glass sector (Figure 1).
to the next stage.
2. Float bath – the molten glass is literally floated
along a bed of molten tin and although the principle
of this process remains unchanged developments
now allow variations in thickness and a marked
improvement in the optical quality of the final
product.
3. Coating - the most significant advance in the
coating process is the on-line chemical vapour
deposition (CVD) that allows a variety of coating
less than a micron thick to be applied to the ribbon
of glass. These can have varying functions
including reflection of light of specified
wavelengths. Further developments in this area
could replace the present day method of carrying
the optical properties of the float glass.
4. Annealing – the glass ribbon undergoes
secondary treatment to relieve stresses to avoid
breakage on cutting.
5. Inspection – advances in the inspection
technology aid the efficiency of the float process
allowing avoidance of imperfections undetectable
by the human eye whilst avoiding excess waste.
6. Cutting to order – this helps to minimise waste.
2
For more information on these processes please
refer to the British Glass website at
www.britglass.co.uk/
3
For more information on these processes please
refer to the British Glass website at
www.britglass.co.uk/
8
9
WASTE GLASS AND GLASS RECYCLING which time they will be responsible for recycling
all vehicles regardless of age.
UK WASTE ARISINGS
Household packaging waste forms the dominant 2. It sets recycling requirements as follows:
proportion of the UK glass waste stream. Reports
estimate waste glass arisings in the container sector By January 1st 2006
to be in excess of 2.4million tonnes per year. With • Reuse and recovery: Min. 85% by weight on
the addition of the commercial waste streams, average
automotive arisings estimated at 80,000 tonnes per • Reuse and recycling: Min. 80% by weight on
year (45,000 tonnes of ELV waste plus 15,000 average
tonnes of windscreen replacements) and up to
500,000 tonnes per year of flat glass from end-of- Reuse specifies materials or components for the
life buildings it appears that waste glass arisings in same purpose for which they were made; recycling
the UK have increased from those recorded in the refers to the reprocessing of the original or an
1999 report. This in addition to the 180,000 tonnes alternative use; recovery includes recycling with
of process scrap per year and glass arisings from energy recovery (i.e. combustion).
other sources such as lighting, cahode ray tubes and
tableware result in total UK waste glass arisings in By January 1st 2015
the region of 3.4million tonnes per year. • Reuse and recovery: Min. 95% by weight on
average
WHY RECYCLE GLASS? • Reuse and recycling: Min. 85% by weight on
average
Glass is a significant contributor to the UK’s total
waste particularly as the majority goes to landfill. All vehicles post December 31st 2004 must:
Although glass poses no significant problems in • Be reusable and/or recyclable at a minimum of
terms of decomposition it does require significant 85% by weight
amounts of void space which is very limited in the • Be reusable and/or recoverable at a minimum
UK. As one of the less problematic waste streams it of 95% by weight
has therefore been a primary target in recycling
strategies to reduce the UK’s waste. Voluntary 3. It requires the established phase out of certain
initiatives have been encouraged in the past but it is heavy metals and those elements exempt from
the increasing pressure from legislation at a phase-outs must be labelled so that they can be
European level that necessitates the UK to advance stripped before shredding.
in re-use and recycling initiatives in order to meet
mandatory targets set out in directives such as the 4. Other provisions:
Packaging and Packaging Waste Directive • Member states must encourage Design for the
(94/62/EC) and the End of Life Vehicles Directive. Environment (DFE) practices
Producer responsibility has always been a key part • Vehicle manufacturers and their suppliers must
of the Government initiatives and remains as such code components and materials to facilitate
in these European wide Directives. product identification for material reuse and
recovery
Packaging waste regulations • Producers must provide dismantling
Current figures specify an overall target of 60% information for every vehicle they build
recovery as a minimum by weight with overall • Producers and member states must report on
recycling at 55% (maximum 80%). Glass specific ELV management and product design measures
recycling targets are set at 60% and targets are to be that enhance reuse and recycling
achieved by December 31st 2008. • ELV management systems must be upgraded in
accordance with more stringent environmental
End-of-Life Vehicles Directive standards that call for:
The ELV Directive (2000/53/EC) was adopted by o Registration of collection and
the EU in September 2000 and in summary imposes treatment facilities
responsibility for End-of-Life vehicles onto vehicle o Improvements in treatment facility
manufacturers. The key aspects of Directive are as design
follows: o Removal of fluids, hazardous
materials and recyclable materials
1. Establishes Extended Producer Responsibility for from ELV’s before shredding
ELV Management – manufacturers and importers
of automobiles are responsible for the costs of end- HOW IS GLASS RECYCLED?
of-life management. Specifically, producers are
responsible for the costs of recycling vehicles put The general recycling of glass involves a strategic
on the market after July 1st 2002. They will not be network incorporating four main aspects
responsible for the recycling of vehicles put on the (collection, delivery to the processors, processing
market before July 1st 2002 until January 1st 2007 at
10
and deliver to the consumer), although specific reduce expense in carbon taxes and to achieve
glass waste streams can involve an increased the standards required by them for carbon
number of steps e.g. ELV Glass. reducing initiatives.
The container industry is probably the best • Using recycled materials reduces the burden on
established sector for recycling at present due to the landfills particularly in this case as glass takes
vast network of bottle banks situated across the UK. up a considerable amount of void space.
These are then routinely emptied and transported by • Reduces the use of raw materials and so the
various companies on a contract basis for delivery depletion of natural resources and degradation
to the glass re-processors. In some cases the waste of the land – for each 1 tonne of cullet used an
glass is re-used in the same plant as the generated approximate equivalent of 1.2 tonnes of raw
waste or in larger operations primary glass materials are saved.
producers will possess the necessary re-processing
equipment for waste glass therefore excluding the Problems associated with recycling glass
final delivery stage. However, in some instances the The glass recycling process, at first, appears fairly
waste glass may not be suitable for re-use in the straightforward. However, there are certain
glass sector and so will be transported to other problems associated with this waste stream that
markets such as aggregates, or if completely must be eliminated in order for the final product
unsuitable, to landfill. (‘cullet’) to be of use. There are three main
The main companies involved in the collection and problems associated with glass re-processing:
processing are T Berryman & Son and Glass
Recycling UK although some alternative markets 1. Contamination from other waste sources
are introducing their own reprocessing capabilities. During the collection process it is easy for non-
glass products including plastics, stones, metals and
WASTE GLASS PROCESSING ceramics to be included within the glass waste
stream. Although technologies have been developed
Benefits to minimise these in the final cullet product any
It is always the case that in the absence of excess presence can lead to load rejection during
mandatory legislation the benefits of recycling any processing and then landfill. However, if the waste
waste product must at least equal the cost of stream is significantly crushed then some
recycling to make it economically feasible. contaminants can be so small that the technologies
However, the benefits of glass recycling are not for removal can be ineffective and unless a high
purely economic but also very beneficial degree of certainty can be given for the level of
environmentally and socially. Glass recycling contamination of the final product the cullet will be
therefore has a multitude of benefits for those rendered useless to the glass sector at least, and
companies aspiring to sustainable business. The potentially to the alternative markets. In the event
following are some of the benefits associated with that such contaminants enter the glass production
glass recycling: stage they can lead to a severe loss in production
and therefore wasted costs detrimental to business.
• The use of cullet in glass production saves This is one of the primary reasons for the reluctance
energy as the melting temperature is reduced. of float glass manufacturers to introduce external
This therefore lowers the costs associated with sources of cullet into the production process.
fuel for the virgin producers.
• The use of cullet increases the furnace load by 2. Colour contamination
up to 15% and as such either results in an The UK’s major glass production is in clear glass
increased efficiency or an increase in overall (66% clear, 16% brown, and 18% green in 2001)
capacity. although as a significant importer of bottled
• The reduction in fuel and raw materials used products from Europe which are dominantly green
reduces carbon emissions not only beneficial to glass there is a colour imbalance in the colours of
the environment but also helping business to products versus waste (Figure 2).
11
Figure 2 – Production v recycling: the UK’s colour imbalance
Amber
Clear
12
THE MARKETS
Container
Flat
Glass
Markets
Fibre
Other
Cullet
Aggregates
Filtration
Alternativ Abrasives
e Markets
Bricks & Ceramics
Niche Markets
13
sources and whilst the flat glass sector at present made and the respective specifications. The
only uses flat glass sources (of which it presently proportions of container and flat glass consumed by
uses 40,000t/a and has the potential to increase this the container and flat glass sectors are illustrated
to 70,000t/a) the proportions used by the other two below (Figure 4).
sectors varies in accordance with the product to be
Figure 4 – Present cullet use by glass sectors
800000
Flat
700000 Container
600000
Cullet Use (ta)
500000
400000
300000
200000
100000
0
Container Flat Fibre Other
Sector
14
Amber Green <10% Clear <12% Green 0-10% Clear 2-8%
Green Amber <10% Clear <12% Amber 0-10% Clear 0-10%
15
Bunkers – 9,000t/a
Golf Course top dressing – 111,000t/a hockey
Fairways – 160,000t/a
16
Economics as reduced quality in cullet reflects on the price
The typical costs of aggregates are between fetched per tonne.
£5/tonne and £10/tonne. In 2002 an Aggregates Tax
of £1.60/tonne was introduced to encourage use of Specifications
recycled materials, which also applies to quarried The main consideration of the glass cullet used in
material. Cullet of low grade (often higher in these applications is that it can rival or better
contamination) is able to compete with these prices traditional aggregates in terms of its mechanical
and chemical properties set out below ().
NB Although the above highlights the basic property requirements of glass, specifications are often
application dependent and therefore it is necessary to refer to the specific British Standards applicable. Some
of these give reference to the use of specific materials and therefore if glass is not listed it may not be used.
Others list performance criteria and therefore if glass proves suitable it may be used.
17
FILTRATION hundred tonnes per year) the volumes of sand used
Research into the use of glass as a substitute for for which glass might act as a substitute were
sand in filtration systems such as those used for estimated to be between 45,000 and 67,000 tonnes
drinking waster and waste water purification in 2002. However, it is anticipated that the volumes
processes continues to address the feasibility of this of glass required for such applications could be
method on a commercial basis and waste glass is even greater ranging from 175,000 as far as
now being used extensively in these applications. In 220,000 tonnes per year.
addition to basic waste purification, research has
also shown that waste glass provided a suitable Specifications
substitute in swimming pool filtration systems and The main specification of critical importance is the
there is also potential in the aquaculture and fish particle size. The other specifications are detailed
farming industries. below () but generally it is important that the glass
achieve the ultimate results of clean and purified
Volume Potential water to the required standard.
Although at present there is only a small market in
this field for glass cullet (current sales of a few
Standard Specifications
Contamination
Agreed between processor and customer
limits
Grade 0 - 0.63mm (95% passing), 0.25mm (10% passing), 0.25mm (5% passing) Grade
Particle Size 1 - 1mm (95% passing), 0.5-1mm (10% passing), 0.5mm (5% passing) Grade 3 -
2mm (95% passing), 1-2mm (10% passing), 1mm (5% passing)
Particle Shape Aspect ratio of greater than 5:1
Entirely brown glass with clear and blue <5% in total
Colour Specs
Entirely of green glass with brown, clear and blue <5% in total
Economics
As seen above the sand used in such filtration
systems is of high specification and in the market
place is priced between £50 and £125/tonne. If the
consistency in glass in terms of specification and
supply can be guaranteed there is a great potential
in this field for cullet use. Cullet prices are
extremely competitive with filtration sand but only
providing re-processing costs to achieve such high
specifications do not significantly increase cullet
price.
18
ABRASIVES formation of a significant market in this area.
There are a variety of abrasives for which glass However, at present, there is a current market
could be used as a substitute. These include blast consumption of approximately 3,500t/a and this
abrasives, bonded abrasives and frictionaters. Blast market area is growing.
abrasives are commonly used in the cleaning of
buildings and masonry and can be either recyclable Economics
or expendable. The major factors for consideration If the varying problems are overcome the price of
in using glass as a substitute is that in the areas of cullet could be extremely competitive with
cost (purchase and disposal), cleaning rate and abrasives as current glass abrasives for grit blasting
consumption rate glass can equal or better the sell at £50-£100 per tonne. The cost of conventional
original material. Research has taken place to recyclable abrasives is in excess of £200/tonne
evaluate these aspects particularly in comparison to whilst although lower in price, expendable
the expendable abrasive, copper slag. Glass does abrasives still fetch a good price of between £50
equally well and in some cases is better. The and £100/tonne. A common expendable abrasive
chemical content of copper slag makes it unusable used is copper slag which although available at
in environmentally sensitive areas and in this factor virtually no cost is not available in the UK and as
glass is clearly more competitive as it may be used such costs approximately £70/tonne to import.
in such areas. Bonded abrasives use crushed glass Glass abrasives can therefore compete in cost with
for the production of paper bonded abrasive sheets the major conventional abrasives used in this
particularly by Naylors Abrasives. Frictionaters use market.
glass for the production of matches and
ammunition. Specifications
The specifications for these materials are similar to
Volume Potential those for container cullet () and as the container
The main market players in the blast abrasives industry accept a wide variety and vast amount of
sector include Wolverhampton Abrasives, Minelco both flat and container cullet such specifications
(previously known as Ferguson Wild Ltd.), Scangrit must be economically viable from the re-processing
and Krysteline. The estimated UK market potential perspective. With specifications such as those
for waste glass is between 10,000t/a and 50,000t/a detailed below there is significant market potential
although the problems described later (ref: Barriers for consuming glass cullet.
to entry) have so far caused resistance to the
19
BRICKS & CERAMICS This is in addition to the volumes that could
The inclusion of sodium oxide in most plate and potentially be used in the brick making industry
container glass types allows finely ground crushed (using a figure of 5% glass inclusion in the
glass to act as a fluxing agent and bind with clay in economic analysis) make the combined brick and
the production of bricks and ceramics. This results ceramics markets a significant potential consumer
in a reduction of the firing temperature and so has of waste glass.
the energy saving benefits described earlier which
are particularly attractive in this industry. Research Specifications
has shown that the inclusion of glass in bricks The specifications for glass in order for its use in
results in increased frost resistance, greater this sector (Table 7) are relatively easy to achieve
compressive strength and a lower water absorption. and in particular the ability of this industry to
consume any colour and both flat and container
Volume potential glass gives this sector significant potential in the
The estimated UK domestic market in ceramics has UK’s waste glass market.
the potential to use up to 20,000t/a of waste glass.
20
NICHE MARKETS & OTHER POTENTIALS waste glass which include paint filler, zeolites,
There a number of niche markets for recycled glass foam glass and glass tiles. Paint filler can use finely
that use it for a variety of applications. Although ground glass for a specialist exterior paint with a
the total volume potential for these markets is small sand textured finish, whilst foam glass is used in
in comparison to the others described it is often in the construction industry and glass tiles are popular
these applications that the selling price is high. particularly in the Scandinavian market (Table 8).
There are a number of other potential markets for
Volume potential
In addition to the companies and respective Economics
volumes they use the paint filler market within the The nature of such small specialist markets means
UK at present is only small whilst the use of waste that the final products often demand high prices.
glass in zeolites is currently in the development They are therefore very attractive for industries
stage in the UK and currently no UK producers of wishing to find a high value end market for their
Foam Glass at present with the main market players waste glass. The list below gives a brief look at
in North America and Europe. This market has some of the prices that these products fetch:
great potential in the use of glass cullet using up to Crystal paving: Finished product £150/m2 with top
98% post consumer glass. It is also well suited to range products fetching up to £1000/ m2.
the more difficult glass types able to consume Eight Inch: High value work tops sell at £350/m-
contaminated glass such as lighting, ELV glass and £400/m.
CRT glass which combined have a waste arising Paint filler: General filler may be cost competitive
volume of approximately 165,000t/a. A 1% with CaCO3 at £50-100/tonne whilst another
penetration into the UK market would be the common filler, TiO2, can fetch prices up to
equivalent of an approximate production of £350/tonne.
2million tonnes per year of foam glass products Zeolites: Have applications in high value end
with the potential to consume 50,000t/a of waste. markets at approximately £70/tonne.
Glass Tiles currently make products in the Foam Glass: Sells at £30-65/m3 in its loose form
Scandinavian market which is predicted to make whilst pre-shaped insulation products can reach
30,000m2 in 2005. This could consume 1200t/a of prices of £200/m3.
waste glass and has the ability to use CRT glass
solely for this product in the glazing. If all tiles are
glazed there is a potential use for 48t/a of CRT
glass. However, at present, in Finland, the dominant
glass type used is container glass.
21
SUMMARY OF VOLUME POTENTIALS AND MARKET ROUTES filtration and abrasives sectors that show increasing
potential as research continues and new markets
The following section summarises the development emerge. However, there is not only an increasing
in markets from 1999 to present and in the future potential of current market players to take in greater
for the use of glass cullet. In addition to this with loads of recycled glass but advances in research are
the current waste glass arisings exceeding 3 million giving rise to realise potentials for new market
tonnes per year this section summarises the present entrants that could consume significant proportions
total market capacity by sector for waste glass and of waste glass. If current market players realise
the potential capacity for waste glass (taking into their potential for consuming glass cullet and the
account increases in actual market capacity and potential entrants realise their potential for
potential market entrants). In 1999 the primary consuming waste glass the market structure could
markets for recycled glass were in the glass sector change significantly (Figure 6). The aggregates
itself with the dominant intake in the container sector would theoretically be the dominant market
sector. However, the aggregates sector was player. However, the realistic view is that the
emerging in the reuse of glass cullet. The 2002 change in market structure although continuing to
figures (Figure 5) show that although the container develop form the 2002 figures is unlikely to reach
sector still remains the dominant player in the the proposed state in Figure 6. The main barriers to
recycled glass market the aggregates sector is this are the specifications for each and the
increasing steadily in its use of glass cullet. In economic feasibility of using glass in low value end
addition to this there are emerging markets in the markets such as the aggregates sector.
10%
Flat
0%
0% Fibre
0%
Aggregate
Filtration
Abrasives
77%
Niche Markets
3% 3% Container
26% Flat
Fibre
Aggregate
Filtration
0%
Abrasives
2%
50% Bricks & Ceramics
0%
5% Niche Markets
2% 9% Foam Glass
Glass Tiles
22
BARRIERS TO ENTRY abrasive sector to make use of the alternative but
recently this has become more available. The recent
Every sector is subject to a variation of emergence of a UK Market for recycled glass
specifications to which the glass cullet must adhere however still faces problems such as an apparent
to be used. However, there are additional barriers to weak enforcement of the sand blasting legislation
entry in some sectors and some factors are more that limits the benefits of glass in environmentally
critical than others. The following section sensitive areas. In addition to this the overall
highlights the main factors that pose problems in abrasive market is declining although the market
the entry of glass cullet into that market. share for glass abrasives is increasing.
Aggregates
The major drawback in the use of glass cullet in the
aggregates sector is the alkali content in the cement.
This can react with the silica in the glass which can
produce a gel that may cause the concrete to swell
and crack over time. This problem can be overcome
by using a fine glass aggregate of less than 1mm, a
low alkali cement, the use of suppressing additives
and a fine glass powder of less than 45µm.
Filtration
The main factors for consideration are that the
silica content in the glass is not too low and the
organics contamination must be extremely low.
Abrasives
There are three main barriers at present to the entry
of glass as a substitute for abrasives in addition to
the quality specifications which as noted above can
be met. In past years, there have been insufficient
supplies of competitively priced glass to enable the
23
GLASS AND THE AUTOMOTIVE INDUSTRY
WHY GLASS?
Table 9 – Composition of an average automobile
Material Average Weight (kg) % Weight
Ferrous Metal 780 68.3
Light Non-Ferrous Metal 72 6.3
Heavy Non-Ferrous Metal 17 1.5
Electrical/Electronics 8 0.7
Fluids 24 2.1
Plastics 104 9.1
Carpet 4 0.4
Process Polymers 12 1.1
Tyres 40 3.5
Rubber 18 1.6
Glass 33 2.9
Batter 13 1.1
Other 17 1.5
TOTAL 1142 100
24
construction applications (most commonly 6mm). and as such delivers a relatively low contaminated
Flat glass is rejected at production if any optical cullet at virtually no cost to the cullet processor.
defects greater than 0.5mm are found and therefore The final fate of glass in motor vehicles is at the
it is mandatory that contaminants are less than End-of-Life stage which could be through the
0.3mm in size to present production loss. natural expiration of the vehicle or premature
through road incidents. The following sections
AUTOMOTIVE GLASS AS WASTE address the fate of glass at the ELV stage.
Premature Natural
Salvage Operators
Dismantlers
Shredders
25
Salvage operators work on behalf of insurance crushed and shredded into pieces. These are then
companies in cases where an ELV has been sorted using a variety of methods into product
subjected to an incident of some sort that involves streams. The main product fraction is shredded steel
an insurance claim. After this as with natural ELV’s which accounts for approximately 70% of the
the vehicle passes to the dismantlers most often for output whilst the remaining 30% is primary
recovery of used parts. shredder fluff (25%) and heavy media. The
shredder fluff is comprised mainly of foam in
Dismantling in the UK addition to light weight non-metallic materials
In contrast to the 1999 figures, estimates form the whilst the heavy material is often a variable mix of
Department of trade and Industry (DTI) in 2002 materials such as rubber and concrete. Modern
quote the numbers of dismantling companies in the plants use floatation methods for separation of the
UK to be between 2000 and 3500. Under the materials (Dense Media Separation) and following
Environmental Protection Act 1990 UK operating separation the heavy fraction can be processed
dismantlers are required to be authorised or further at heavy media plants at which stage some
registered exempt so the apparent reduction in materials such as copper, aluminium, magnesium,
figures may be due to the increasingly stringent glass and plastics can be removed whilst the
environmental standards on these companies. remainder shredder fluff is currently land filled.
However, as the majority are small family run firms There is ongoing research into the possibility of
within only a few (approximately 1000) larger further separating the materials in shredder fluff.
firms it is unfortunately more likely to be the case
that there are those companies still operating If the glass is separated sufficiently form the other
outside the required standards and therefore not materials with contamination below the limits set
registered in the above way. At present there are out in the glass sector specifications and the
1553 dismantlers and scrap yards affiliated to trade alternative markets then it may follow one of these
associations. routes to fetch a reasonable market price. However,
If the automotive glass is to be recycled at the in most cases the concrete contamination is too
dismantling stage it must first be removed from the significant and the only real market available for
vehicle. The ease of removal is dependent upon the the waste is in the aggregates sector. In the event
method of sealing used in manufacture. The use of that this is still unsuitable the only option left is
a rubberised gasket seal is comparatively easy when landfill.
considering removal of the whole window however
the direct bonding method (more commonly used in TECHNICAL AND ECONOMIC BARRIERS TO RECOVERING
modern day vehicles) is particularly time ELV GLASS
consuming. In order to minimise the time taken it is
possible to cut the glass using a ‘cheese-wire’ to cut Using the most current data available the estimates
a disc at the largest size possible but this still leaves for total ELV arisings in the UK is 2.1
a significant proportion of the glass in contact with million/annum (2,109,967 Defra). Of this
the car. There are increased problems in removing approximately 0.4 million/annum premature, 1.5
the glass from the side windows due to the locking million/annum natural disposed of responsibly, 0.2
mechanism. million/annum abandoned and the remaining 1% is
After removal the glass must then be sorted into the illegal parts form stolen vehicles.
different types (laminated, silver printed rear The estimated weight of ELV arisings each year is
windows etc.). The waste glass is then sometimes 1,733,842 tonnes in total taking into account both
resold if appropriate but more likely will be premature and natural ELVs.
available to cullet processors and in the event that it On average the glazing in motor vehicle contributes
cannot be sold will ultimately be land filled. 3% towards the total composition of the vehicle and
therefore in its fullest extent would give an
Shredding in the UK approximate weight of 52,000t/a of glazing for
2002 data shows that there were 37 shredding potential recycling.
facilities in the UK (a slight decrease from the 1999 However, due to the technical problems of
figures) of which EMR and Sims Metal dominated removing the glazing particularly if directly bonded
the market. Shredding facilities are large, capital- CARE studies have shown in a project using 179
intensive sites whose primary function remains to ELVs, that only 1.75 tonnes of glass were removed
recover the valuable metal components. which is the equivalent of 9kg per vehicle. The
common practice to remove laminated glass is by
It is possible that natural ELV’s may pass straight to use of a cutter and can leave up to 20% of the glass
the shredder particularly in cases where the vehicle attached to the body aperture. This would therefore
has been demolished and abandoned such as to reduce the estimated potential figure of glass
make proving ownership impossible. Also, those available for recycling at the dismantling stage (the
cars who have suffered severe glass breakage or higher value product) to approximately less than
where dismantlers cannot economically remove the 19,000t/a in total.
glass fraction will also pass to the shredder with the The average time taken to remove bonded glazing
glass fraction. At the shredding stage the vehicle is from a motor vehicle at the dismantling stage is 5
minutes/vehicle. The main cost incurred at this likely to be the car manufacturers that must absorb
stage is the labour cost of dismantling and the cost the cost of this process as it becomes necessary to
equivalent of this ranges between approximately recycle glass in order to reach ELV Directive
£2.50 and £3.50 per vehicle. targets at least at present if not for some
Toughened glass, which cannot be cut out, is considerable time into the future. The solution to
removed by breaking the glass in situ using a the problem may therefore lie in the manufacturing
pointed implement and the subsequent small stage such that bonding methods are changed and
fragments are collected. However, even with this developed to make glass removal more efficient at
technique much of the glass is lost and there is an the ELV stage of a cars’ life cycle.
increased chance of contamination with other small
fragments.
Department of Trade & Industry (2002) End of Life Vehicles (ELV)Waste Arisings and Recycling Rates.
Enviros (May 2004) Recycled Glass Market Study & Standards Review – 2004 Update. The Waste & Resources
Action Programme (Published May 2004).
Glass Stakeholder Update. (2003). The Waste & Resources Action Programme.
Hurley, J (2003) A Market Survey for Foam Glass. The Waste & Resources Action Programme (Published April
2003).
Kollamthodi, S, Bird, A. B., Elghali, L, Johnstone, K, Wayman, M & McColl, V, A N (TRL Limited) (2003)
Data Required To Monitor Compliance With The End Of Life Vehicles Directive. Prepared for DEFRA project
report PR SE/483/02.
Kollamthodi, S, Johnstone, K & Elghali, L, (TRL Limited) (2003) Data Required To Monitor Compliance With
The End Of Life Vehicles Directive. Part 2 Report – Demonstrating compliance. Prepared for DEFRA project
report PR SE/518/02.
Recovered container glass – specification for quality and guidance for good practice in collection (PAS 101)
(2003). The Waste & Resources Action Programme.
Smith, Dr. A. S. (CERAM Building Technology 2004) To demonstrate commercial viability of incorporating
ground glass in bricks with reduced emissions and energy savings. The Waste & Resources Action
Programme (Published March 2004).
Specification for processed glass markets for selected secondary end markets (PAS 102) (2004). The Waste &
Resources Action Programme.
Staudinger, J & Keoleian, G. A (2001) Management of End-of Life Vehicles (ELVs) in the US. (Report No.
CSS01-01) Centre for Sustainable Systems, University of Michigan in cooperation with Flynn, M. S., Office
for the Study of Automotive Transportation. Prepared for Japan External Trade Organisation (JETRO).
www.britglass.co.uk (05/08/2004)
www.caregroup.org.uk (05/08/2004)
www.acea.be (05/08/2004)
www.plastics-in-elv.org (05/08/2004)
www.wasteonline.org.uk (05/08/2004)
www.defra.org.uk (05/08/2004)
www.dti.gov.uk (06/08/2004)
www.detr.gov.uk (06/08/2004)
www.gepvp.org (06/08/2004)
www.wrap.org.uk (General info - 06/08/2004)
www.wrap.org.uk/reports.asp (Additional Reports - 06/08/2004)
APPENDIX I
Dismantling costs reduction needed to bring cullet back into range of market prices
Realistic revenue based on realistic glass tonnages available
Market Price (£) of cullet Cost of dismantling/vehicle Total Cost of dismantling Net income
Realistic Revenue
/tonne Threshold (red) Threshold (black) Red Black Red Black
5 £95,000 0.05 0.04 £105,498 £84,399 -£10,498 £10,601
10 £190,000 0.10 0.09 £210,997 £189,897 -£20,997 £103
15 £285,000 0.14 0.13 £295,395 £274,296 -£10,395 £10,704
20 £380,000 0.19 0.18 £400,894 £379,794 -£20,894 £206
25 £475,000 0.23 0.22 £485,292 £464,193 -£10,292 £10,807
30 £570,000 0.28 0.27 £590,791 £569,691 -£20,791 £309
35 £665,000 0.32 0.31 £675,189 £654,090 -£10,189 £10,910
40 £760,000 0.37 0.36 £780,688 £759,588 -£20,688 £412
45 £855,000 0.41 0.40 £865,086 £843,987 -£10,086 £11,013
50 £950,000 0.46 0.45 £970,585 £949,485 -£20,585 £515