CHEMISTRY

81. 82. (d) (c) Higher is the bond order, less is the bond length. Therefore number with bond order 2.5 has greater bond length as compared to NO+ having bond order 3. The electron deficient B atom in BF3 can accept the two electrons from F to form BF4 with regular tetrahedral geometry. Kp = Kc(RT) n CO(g) + Cl2(g) n=1
KP KC

83.

(a)

COCl2(g)

2= 1
1 . RT

84.

(d)

4KI + 2CuSO4 Cu2I2 + I2 + 2K2SO4 I2 + Na2S2O3 NaI + Na2S4O6 CuI2 is not formed. NH3 is a strong field legand but Ni2+ has a configuration of d8. Therefore, Ni forms outer orbital complex [Ni(NH3)6]2+.

85.

(b)

86.

(c)
HO

The IUPAC name of the compound is: 3,3 dimethyl 1 cyclohexanol.

COOH NO2 COOH COOH COOH

87.

(b)
NO2 (III) NO2 (IV) (I)

(II)

(II) has maximum acidic strength because of ortho effect, ( R) and ( I) effects of NO2 group. In (III), both resonance ( R), and inductive ( I) effect of NO2 group increase the acidic character. While in (IV), only inductive ( I) effects of NO2 operates. Thus, its acidic strength is less than that of (III). (II) > (III) > (IV) > (I). 88. 89. 90. (c) (a) (b)

O O

O Cr

O O

91.

(b)

CHO + (CH3CO)2O
(X)

CH3COONa

CH=CH COOH

Since, the given reaction is a Perkin reaction, it requires reaction between an aromatic aldehyde and acid anhydride in the presence of corresponding acid carboxylate. As the acid carboxylate is sodium acetate, so the acid anhydride would be acetic anhydride. 92. (d) Reactivity of carbonyl compounds with PhMgBr is based on electrophilicity of carbonyl group and steric crowding around it. Based on electrophilicity and crowding, CH3CHO is the most reactive. The least reactive would be PhCOPh due to excessive steric crowding.

93.

(a)
COCH3 CH2CH3
NH2NH2 KOH

54.

(b)
OH

OH

In presence of base OH will not participate in the reaction. 95. 96. (d) (b) Rate1 = K[A] 1/2 [B]3/2 On doubling the concentrations of each reactant. Rate2 = K[2] 1/2 [2]3/2 [A] or Rate2 = 2 Rate1 97. 98. (b) (c) 2Ag(s) + O2(g) H = U + ng RT H= U 99. 100. 101. (b) (a) (a) With the increase in the volume the reaction moves in the direction in which the number of moles increases. N2O4(g) (1 ) 2NO2 2 RT H < U. 2Ag2O(s)
1/2

[B]3/2

2 [2 ]2 4 4 (0.01) 2 ~ 4 10 4 = 0.4 10 3. Kc = = = [1 ] [1 0.01] (1 0.01)

102.

(b)

103. 104.

(d) (c)

The total vapour pressure of a mixture of two volatile liquids is given by PTotal = PA X A + PB X A = 100

0.4 + 200

0.6 = 160 mm Hg.

Let X A be the mole fraction of A in the vapour phase.

XA
105. (c)

P P X 40 1 = A = A A= = = 0.25. PT otal PT otal 160 4

Tf = i KCl (1 )

Kf

m [Here molality m = molarity M] K+ + Cl

i = (1 + ) = 2 ; ( = 1) Tf = 2 1.86 0.1 = 0.372 0.372 = 0.372C.

Freezing point of water = 0 106. (c) Effective number of anions = 12 Effective number of cations =

1 +2 6

1 +3=6 2

2 6 =4 3 So, general formula of the compound will be C4A6 or C2A3 Hence, (C) is correct.
107. (b)

1 1 8 = 1 ; Number of O atoms = 12 = 3. 8 4 Number of Na atom = 1 ; Formula is NaWO3.

Number of W atoms = Meq. of KMnO4 = 100 0.1 = 10 W 1000 = 10 E W 1000 = 10 [ n factor in basic medium is 1] 158 1 W = 1.58.

108.

(a)

109. 110.

(a) (a) =

h 2mE

or E

1 m
10

(since
31

is same for all three)

Mass of an electron = 9.1 Mass of an alpha particle = Mass of a proton = 1.6 10

kg
23

4 10 3 6.023 10
27

= 6.64

10

27

kg.

kg.

Hence, answer = E1 > E3 > E2. 111. (d)

CH3
112. (a)

CH3 C=C=C

H H This compound is devoid of elements of symmetry. So, this is optically active.

113. (a)

C CH
114. (c)
H2O Hg2+/H+

COCH3

115.

(c)

Given: S(s) + 3F2(g) S(s) F2(g) SF6(g) ; S(g) F(g) ; ; H = 1100 kJ mol H = +275 kJ mol H = 80 kJ mol
1 1 1

Required SF6(g) S(g) + 6F(g) ; H = 1100+ 275+6 80 =1855 1 S-F = H/ 6 ~ 309 kJ mol . 116. (a)

MnO 4
+2

C2O2 4

CO 2

Mn

H2O

Mn acts as auto catalyst. 117. (c) Ni Ni Ni(CO)4

Ni
+2

3d84s2
3d 4s

3d
8

sp
3

diatomic

[Ni(Cl)4]

sp
3

paramagnetic

[Ni(CN)4] Fe+2 3d6

dsp
2

diamagnetic

[Fe(H2O)6]+2

sp d
3 2

paramagnetic

118. 119. 120.

(c) (c) (a)

Cl A
1 Cl 2 + e 2
Ecell =

1 Cl 2 (g) + e 2
Cl C

C [Cl ]C 0.059 = 0.059 log 2 log C1 1 [Cl ]A

For the Ecell to be positive C1 > C2.