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PROB:9.

BUBBLE POINT &


pressure comnpound a
b
7600
1 15.6637 1511.42
2 15.7260 1872.46
3 15.5381 2032.73
4 15.6782 2154.90
5 15.6338 2348.67

BUBBLE AND DEW POINT CALCULATION:


In Bubble point calculations,(given 5 compounds,initial molefrac
of reference compound).Find temp by using antoinne equation.
The Above procedure can be repeated with corresponding equa
RESULTS bubble point :57.95 deg c.
Dew point :69.22 deg c.
FLASH CALCULATIONS:
The given values are taken as Zi.The vapour fraction is given.Ass
correct temperature.
RESULTS Compositions are
0.005208
0.373639
0.177391
0.444595
0.001055.

BUBBLE POINT & DEW POINT CALCULATION


c
x
p
estimated t
-17.16
0.0025 56992.50006
337.85
-25.16
0.25 16945.6907
337.85
-33.15
0.185 7092.900192
337.85
-34.42
0.56 5304.958763
337.85
-40.05
0.0025 2314.766125
337.85

alpha
alpha*x
calc temp
10.74325034 0.026858126 332.3357645
3.194311484 0.798577871 332.3357645
1.337032107 0.24735094 332.3357645
1
0.56 332.3357645
0.436340079 0.00109085 332.3357645
1.633877787

5 compounds,initial molefractions)assume t as in coloumn M ,calculate alpha(w.r.t. reference compound),summation of alpha*x,find kr(v


by using antoinne equation.The obtained temp must tally with estimated.
ted with corresponding equations for Dew point Calculations.

e vapour fraction is given.Assume a temperature.Calculate value of K=psat/pressure. Yi is calculated and summation must yield 1 if we ass

Y
0.0025
0.25
0.185
0.56
0.0025

nd),summation of alpha*x,find kr(value

nd summation must yield 1 if we assume

y/alpha
0.000233
0.078264
0.138366
0.56
0.005729
0.782592

calc temp
342.8162
342.8162
342.8162
342.8162
342.8162

FLASH CALCULATIONS
v
k
0.0025
0.4 7.499013
0.25
0.4 2.229696
0.185
0.4 0.933276
0.56
0.4 0.698021
0.0025
0.4 0.304574

yi
0.005208
0.373639
0.177391
0.444595
0.001055
1.001888

PROB 9.5
p

A
760 acetone
760 water

ANTIONNE CONSTANTS
B
C
temperature
16.6513 2940.46
-35.93
345.17
18.3036 3816.44
-46.13
345.17

The compounds,their mole fractions are given.pressure is 1 atmosphere.vapourization fractio


zero.this will give correct temperature.Obtain compositions as in colomn N.
RESULT:
yi
0.832599172
0.167629765
Xi
0.500314641
0.499587244
Temperature is 72.07 deg c.

vapour pressure z
1264.754855
255.0077544

v
0.6
0.4

l
0.3
0.3

ki
yi
Xi
temp indeg c
0.7 1.66415113 0.832599172 0.500314641
72.02
0.7 0.33553652 0.167629765 0.499587244
1.000228937

re is 1 atmosphere.vapourization fraction is given .Assume a temperature and calculate Yi and check summation tends to
sitions as in colomn N.

PROB 9.1

The calculations were

temperature

pressure(mm Hg)

337.68
338.68
339.68
340.68
341.68
342.68
343.68
344.68
345.68
346.68
347.68
348.68
349.68
350.68
351.5

psat1

760
760
760
760
760
760
760
760
760
760
760
760
760
760
760

psat2

760.5742325
791.036269
822.5067922
855.0115696
888.576802
923.2291259
958.9956151
995.9037827
1033.981583
1073.257415
1113.760119
1155.518986
1198.563751
1242.924601
1280.304037

428.6394901
447.5939823
467.2509329
487.6309466
508.7550519
530.6447046
553.3217923
576.8086377
601.1280027
626.3030919
652.357556
679.3154961
707.2014661
736.0404771
760.4174768

XY FROM CONST ALPHA


1.2

0.8

0.6

XY FROM CONST A

0.4

0.2

0
0

0.2

0.4

0.6

0.8

1.2

0
0

0.2

0.4

0.6

0.8

1.2

The calculations were done at 1 atmosphere pressure

y
1
0.909631777
0.824051341
0.741381108
0.661481203
0.584219044
0.509468928
0.437111631
0.367034038
0.299128795
0.233293988
0.169432828
0.107453371
0.047268245
0

relative volatility
1.000755569
0.946778589
0.891826085
0.834065033
0.773390594
0.709694786
0.642866405
0.572790956
0.499350573
0.422423944
0.341886237
0.257609012
0.169460152
0.077303769
0

y calculated from
relative volatility

1.774391418
1.76730765
1.760310647
1.753398909
1.746570965
1.739825382
1.733160755
1.726575709
1.720068901
1.713639017
1.707284769
1.701004898
1.694798171
1.688663382
1.683685707
1.727379085

1
0.909631777
0.824051341
0.741381108
0.661481203
0.584219044
0.509468928
0.437111631
0.367034038
0.299128795
0.233293988
0.169432828
0.107453371
0.047268245
0

1
0.945615275
0.889990677
0.831985478
0.771448302
0.708213389
0.64209887
0.572904785
0.500410805
0.424373603
0.344523818
0.260562506
0.172157027
0.078936199
0

XY DIAGRAM
1
0.9
0.8
0.7
0.6
XY FROM CONST ALPHA

0.5

XY DIAGRAM

0.4
0.3
0.2
0.1
0
0

0.2

0.4

0.6

0.8

0.2

0.4

0.6

0.8

Initially,a temperature starting with normal boiling point(since the process asked goes at 1 atm) of one component to
NBP of other.Calculate vapour pressures.values of liquid ,gas compositions are calculated by
x=(pt-psat2)/(psat1-psat2)
y=(pt-psat1)/(psat2-psat1)
The graphs are to show X-Y,T-XY diagrams from data as shown.
Calculate the average value of relative volatility and corresponding vapour compositions are obtained.
Graph i sagain plotted to get new X-Y plot.

354
352
350
348
346

XY DIAGRAM

344
342
340
338
336

336
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

s at 1 atm) of one component to

ons are obtained.

T-X DIAGRAM
T-Y DIAGRAM

0.9

PROB 9.7

p
760 acetone
760 water

ANTIONNE CONSTANTS
A
B
C
temperature
16.6513 2940.46
-35.93
345.17
18.3036 3816.44
-46.13
345.17

The compounds are given along with vapour fractions to be converted.The constants are done to g
Constant 1 is log(z1/L).
Constant 2 is alpha*log((1-z1)/L)
graph is plotted or trail and error is made to get x.
RESULT:x1,w
y1,v
0.490024 0.856611
0.509976 0.143389

vapour pressure
z
1264.754855
255.0077544

v
0.6
0.4

L
0.3
0.3

alpha
constant1 constant2 x1,w
y1,v
0.7 4.959672 -0.15415 -2.77551 0.490024 0.856611
0.7
1
0.509976 0.143389

e converted.The constants are done to get coinciding value of x1,w.

PROB 9.2
A
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562

B
C
A
B
C
p1
1746.586 201.783 16.3872
3885.7
230.17
101.32
1746.586 201.783 16.3872
3885.7
230.17
91.32
1746.586 201.783 16.3872
3885.7
230.17
81.32
1746.586 201.783 16.3872
3885.7
230.17
71.32
1746.586 201.783 16.3872
3885.7
230.17
61.32
1746.586 201.783 16.3872
3885.7
230.17
51.32
1746.586 201.783 16.3872
3885.7
230.17
41.32
1746.586 201.783 16.3872
3885.7
230.17
31.32
1746.586 201.783 16.3872
3885.7
230.17
21.32
1746.586 201.783 16.3872
3885.7
230.17
11.32
1746.586 201.783 16.3872
3885.7
230.17
1.32

160
140
120
100
80
60
40
20
0
0

20

40

60

80

100

120

p2
0
10
20
30
40
50
60
70
80
90
100

temperature
temperature
psat1 at 95.2 psat2 at 95.2
140.0196805
#NUM!
17.1602033 85.18249608
137.0274115
45.71258718
133.7490258
59.99236901
130.1155869
69.052179
126.0285892
75.83109565
121.3397172
81.30453873
115.8092908
85.92417516
109.0085842
89.93828811
100.0377127
93.49879526
86.34818453
96.70578116
47.90599173
99.6288599

The intersecting point from two plots will be 95.2 deg c.


mass of water vapourised along with nito benzene will be M=(psat2/psat1)(1000*18/123)=726 kg
of water
Mass of steam will be calculated by energy balance
Mass of steam =Mwater((Cwater)(Tbp-Ti)+Lw)+Mnb((Cnb)(Tbp-Ti)+Lnb)/Lwater=327.599kg.

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