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alpha
alpha*x
calc temp
10.74325034 0.026858126 332.3357645
3.194311484 0.798577871 332.3357645
1.337032107 0.24735094 332.3357645
1
0.56 332.3357645
0.436340079 0.00109085 332.3357645
1.633877787
e vapour fraction is given.Assume a temperature.Calculate value of K=psat/pressure. Yi is calculated and summation must yield 1 if we ass
Y
0.0025
0.25
0.185
0.56
0.0025
y/alpha
0.000233
0.078264
0.138366
0.56
0.005729
0.782592
calc temp
342.8162
342.8162
342.8162
342.8162
342.8162
FLASH CALCULATIONS
v
k
0.0025
0.4 7.499013
0.25
0.4 2.229696
0.185
0.4 0.933276
0.56
0.4 0.698021
0.0025
0.4 0.304574
yi
0.005208
0.373639
0.177391
0.444595
0.001055
1.001888
PROB 9.5
p
A
760 acetone
760 water
ANTIONNE CONSTANTS
B
C
temperature
16.6513 2940.46
-35.93
345.17
18.3036 3816.44
-46.13
345.17
vapour pressure z
1264.754855
255.0077544
v
0.6
0.4
l
0.3
0.3
ki
yi
Xi
temp indeg c
0.7 1.66415113 0.832599172 0.500314641
72.02
0.7 0.33553652 0.167629765 0.499587244
1.000228937
re is 1 atmosphere.vapourization fraction is given .Assume a temperature and calculate Yi and check summation tends to
sitions as in colomn N.
PROB 9.1
temperature
pressure(mm Hg)
337.68
338.68
339.68
340.68
341.68
342.68
343.68
344.68
345.68
346.68
347.68
348.68
349.68
350.68
351.5
psat1
760
760
760
760
760
760
760
760
760
760
760
760
760
760
760
psat2
760.5742325
791.036269
822.5067922
855.0115696
888.576802
923.2291259
958.9956151
995.9037827
1033.981583
1073.257415
1113.760119
1155.518986
1198.563751
1242.924601
1280.304037
428.6394901
447.5939823
467.2509329
487.6309466
508.7550519
530.6447046
553.3217923
576.8086377
601.1280027
626.3030919
652.357556
679.3154961
707.2014661
736.0404771
760.4174768
0.8
0.6
XY FROM CONST A
0.4
0.2
0
0
0.2
0.4
0.6
0.8
1.2
0
0
0.2
0.4
0.6
0.8
1.2
y
1
0.909631777
0.824051341
0.741381108
0.661481203
0.584219044
0.509468928
0.437111631
0.367034038
0.299128795
0.233293988
0.169432828
0.107453371
0.047268245
0
relative volatility
1.000755569
0.946778589
0.891826085
0.834065033
0.773390594
0.709694786
0.642866405
0.572790956
0.499350573
0.422423944
0.341886237
0.257609012
0.169460152
0.077303769
0
y calculated from
relative volatility
1.774391418
1.76730765
1.760310647
1.753398909
1.746570965
1.739825382
1.733160755
1.726575709
1.720068901
1.713639017
1.707284769
1.701004898
1.694798171
1.688663382
1.683685707
1.727379085
1
0.909631777
0.824051341
0.741381108
0.661481203
0.584219044
0.509468928
0.437111631
0.367034038
0.299128795
0.233293988
0.169432828
0.107453371
0.047268245
0
1
0.945615275
0.889990677
0.831985478
0.771448302
0.708213389
0.64209887
0.572904785
0.500410805
0.424373603
0.344523818
0.260562506
0.172157027
0.078936199
0
XY DIAGRAM
1
0.9
0.8
0.7
0.6
XY FROM CONST ALPHA
0.5
XY DIAGRAM
0.4
0.3
0.2
0.1
0
0
0.2
0.4
0.6
0.8
0.2
0.4
0.6
0.8
Initially,a temperature starting with normal boiling point(since the process asked goes at 1 atm) of one component to
NBP of other.Calculate vapour pressures.values of liquid ,gas compositions are calculated by
x=(pt-psat2)/(psat1-psat2)
y=(pt-psat1)/(psat2-psat1)
The graphs are to show X-Y,T-XY diagrams from data as shown.
Calculate the average value of relative volatility and corresponding vapour compositions are obtained.
Graph i sagain plotted to get new X-Y plot.
354
352
350
348
346
XY DIAGRAM
344
342
340
338
336
336
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
T-X DIAGRAM
T-Y DIAGRAM
0.9
PROB 9.7
p
760 acetone
760 water
ANTIONNE CONSTANTS
A
B
C
temperature
16.6513 2940.46
-35.93
345.17
18.3036 3816.44
-46.13
345.17
The compounds are given along with vapour fractions to be converted.The constants are done to g
Constant 1 is log(z1/L).
Constant 2 is alpha*log((1-z1)/L)
graph is plotted or trail and error is made to get x.
RESULT:x1,w
y1,v
0.490024 0.856611
0.509976 0.143389
vapour pressure
z
1264.754855
255.0077544
v
0.6
0.4
L
0.3
0.3
alpha
constant1 constant2 x1,w
y1,v
0.7 4.959672 -0.15415 -2.77551 0.490024 0.856611
0.7
1
0.509976 0.143389
PROB 9.2
A
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
7.11562
B
C
A
B
C
p1
1746.586 201.783 16.3872
3885.7
230.17
101.32
1746.586 201.783 16.3872
3885.7
230.17
91.32
1746.586 201.783 16.3872
3885.7
230.17
81.32
1746.586 201.783 16.3872
3885.7
230.17
71.32
1746.586 201.783 16.3872
3885.7
230.17
61.32
1746.586 201.783 16.3872
3885.7
230.17
51.32
1746.586 201.783 16.3872
3885.7
230.17
41.32
1746.586 201.783 16.3872
3885.7
230.17
31.32
1746.586 201.783 16.3872
3885.7
230.17
21.32
1746.586 201.783 16.3872
3885.7
230.17
11.32
1746.586 201.783 16.3872
3885.7
230.17
1.32
160
140
120
100
80
60
40
20
0
0
20
40
60
80
100
120
p2
0
10
20
30
40
50
60
70
80
90
100
temperature
temperature
psat1 at 95.2 psat2 at 95.2
140.0196805
#NUM!
17.1602033 85.18249608
137.0274115
45.71258718
133.7490258
59.99236901
130.1155869
69.052179
126.0285892
75.83109565
121.3397172
81.30453873
115.8092908
85.92417516
109.0085842
89.93828811
100.0377127
93.49879526
86.34818453
96.70578116
47.90599173
99.6288599