Documento: VBoy09044

Mxico - Direccin de Tecnologa

SOLUBILIDAD DEL FOSFATO MONOAMNICO EN AGUA Y

COMPOSICIN DE LAS DISOLUCIONES SATURADAS

Preparado por:

Vctor Manuel Boy Orlaineta

Fecha de impresin:

22-Sep-09

Hoja 2 de 8

SOLUBILIDAD DEL FOSFATO MONOAMNICO EN AGUA Y COMPOSICIN DE LAS DISOLUCIONES

SATURADAS
DE DATOS EXPERIMENTALES DE LA LITERATURA:
Temperatura,
C

Solubilidad,
Solubilidad,
Solubilidad,
g/100gH2O g/100gsolucin gP2O5/100gH2O

0
10
20
25
30
40
50
60
75
80
100
110.5

22.7
29.5
37.4
40.3
46.4
56.7
68.0
82.5
108.8
118.3
173.2
215.0

18.5
22.8
27.2
28.7
31.7
36.2
40.5
45.2
52.1
54.2
63.4
68.3
% FMA

14.01
18.20
23.08
24.87
28.63
34.99
41.96
50.91
67.14
73.00
106.88
132.68

% P2O5

% H2O

Relacin,
kgH2O/kgP2O5

11.42
14.06
16.80
17.73
19.56
22.33
24.98
27.90
32.16
33.44
39.12
42.12

81.50
77.22
72.78
71.28
68.31
63.82
59.52
54.79
47.89
45.81
36.60
31.75

7.14
5.49
4.33
4.02
3.49
2.86
2.38
1.96
1.49
1.37
0.94
0.75

ECUACIONES DE AJUSTE PARA LOS DATOS EXPERIMENTALES:

Estadsticos de la regresin % FMA vs C
R mltiple
R cuadrada
R cuad. ajustada
Error estndard
Observaciones

0.9999
0.9997
0.9997
0.2768
12

Anlisis de varianza
df
Regresin
Residual
Total

1
10
11
Coeficientes

Ord. al origen
Temperatura, C

18.0900
0.4524

Suma de
cuadrados
2846.6768
0.7664
2847.4432
Error estndard
0.1421
0.0023

Cuadrado
medio
2846.6768
0.0766

Estadstico t
127.3351
192.7307

Significancia
de F
37145.1249 3.47581E-19
F

valor P
8.7725E-19
9.20309E-21

95 % inferior
17.7735
0.4471

95 % superior
18.4065
0.4576

Estadsticos de la regresin % P 2 O 5 vs C
R mltiple
R cuadrada
R cuad. ajustada
Error estndard
Observaciones

0.9999
0.9997
0.9997
0.1708
12

Fecha impresin: 22/09/2009

Documento: VBoy09044

Direccin de Tecnologa

Hoja 3 de 8

Anlisis de varianza
df
Regresin
Residual
Total

1
10
11
Coeficientes

Ord. al origen
Temperatura, C

11.1633
0.2792

Suma de
cuadrados
1084.0499
0.2918
1084.3417
Error estndard
0.0877
0.0014

Cuadrado
medio
1084.0499
0.0292

Estadstico t
127.3351
192.7307

Significancia
de F
37145.1249 3.47581E-19
F

valor P
8.7725E-19
9.20309E-21

95 % inferior
10.9680
0.2759

95 % superior
11.3587
0.2824

% FMA = 0.4524(T) + 18.0900

% P 2 O 5 = 0.2792(T) + 11.1633
T = Temperatura en C

Fecha impresin: 22/09/2009

Documento: VBoy09044

Direccin de Tecnologa

Hoja 4 de 8

DATOS CALCULADOS A PARTIR DE LA ECUACION DE REGRESION:

Temperatura,
C

Solubilidad,
g/100gH2O

% FMA

Solubilidad,
gP2O5/100gH2O

% P2O5

% H2O

Relacin,
kgH2O/kgP2O5

0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46

22.1
22.8
23.4
24.1
24.8
25.6
26.3
27.0
27.7
28.5
29.2
30.0
30.8
31.5
32.3
33.1
33.9
34.7
35.6
36.4
37.2
38.1
39.0
39.8
40.7
41.6
42.6
43.5
44.4
45.4
46.3
47.3
48.3
49.3
50.3
51.3
52.4
53.4
54.5
55.6
56.7
57.8
59.0
60.1
61.3
62.5
63.7

18.09
18.54
18.99
19.45
19.90
20.35
20.80
21.26
21.71
22.16
22.61
23.07
23.52
23.97
24.42
24.88
25.33
25.78
26.23
26.69
27.14
27.59
28.04
28.49
28.95
29.40
29.85
30.30
30.76
31.21
31.66
32.11
32.57
33.02
33.47
33.92
34.38
34.83
35.28
35.73
36.19
36.64
37.09
37.54
37.99
38.45
38.90

13.6
14.0
14.5
14.9
15.3
15.8
16.2
16.7
17.1
17.6
18.0
18.5
19.0
19.5
19.9
20.4
20.9
21.4
21.9
22.5
23.0
23.5
24.0
24.6
25.1
25.7
26.3
26.8
27.4
28.0
28.6
29.2
29.8
30.4
31.0
31.7
32.3
33.0
33.6
34.3
35.0
35.7
36.4
37.1
37.8
38.5
39.3

11.16
11.44
11.72
12.00
12.28
12.56
12.84
13.12
13.40
13.68
13.95
14.23
14.51
14.79
15.07
15.35
15.63
15.91
16.19
16.47
16.75
17.03
17.30
17.58
17.86
18.14
18.42
18.70
18.98
19.26
19.54
19.82
20.10
20.38
20.65
20.93
21.21
21.49
21.77
22.05
22.33
22.61
22.89
23.17
23.45
23.73
24.00

81.91
81.46
81.01
80.55
80.10
79.65
79.20
78.74
78.29
77.84
77.39
76.93
76.48
76.03
75.58
75.12
74.67
74.22
73.77
73.31
72.86
72.41
71.96
71.51
71.05
70.60
70.15
69.70
69.24
68.79
68.34
67.89
67.43
66.98
66.53
66.08
65.62
65.17
64.72
64.27
63.81
63.36
62.91
62.46
62.01
61.55
61.10

7.34
7.12
6.91
6.71
6.52
6.34
6.17
6.00
5.84
5.69
5.55
5.40
5.27
5.14
5.01
4.89
4.78
4.67
4.56
4.45
4.35
4.25
4.16
4.07
3.98
3.89
3.81
3.73
3.65
3.57
3.50
3.43
3.36
3.29
3.22
3.16
3.09
3.03
2.97
2.91
2.86
2.80
2.75
2.70
2.64
2.59
2.55

Fecha impresin: 22/09/2009

Documento: VBoy09044

Direccin de Tecnologa

Hoja 5 de 8

Temperatura,
C

Solubilidad,
g/100gH2O

% FMA

Solubilidad,
gP2O5/100gH2O

% P2O5

% H2O

Relacin,
kgH2O/kgP2O5

47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95

64.9
66.1
67.4
68.7
70.0
71.3
72.6
74.0
75.3
76.8
78.2
79.6
81.1
82.6
84.1
85.7
87.2
88.8
90.5
92.1
93.8
95.5
97.3
99.0
100.8
102.7
104.6
106.5
108.4
110.4
112.4
114.5
116.6
118.7
120.9
123.1
125.4
127.7
130.1
132.5
135.0
137.5
140.1
142.7
145.4
148.2
151.0
153.9
156.8

39.35
39.80
40.26
40.71
41.16
41.61
42.07
42.52
42.97
43.42
43.88
44.33
44.78
45.23
45.69
46.14
46.59
47.04
47.49
47.95
48.40
48.85
49.30
49.76
50.21
50.66
51.11
51.57
52.02
52.47
52.92
53.38
53.83
54.28
54.73
55.19
55.64
56.09
56.54
56.99
57.45
57.90
58.35
58.80
59.26
59.71
60.16
60.61
61.07

40.0
40.8
41.6
42.4
43.2
44.0
44.8
45.6
46.5
47.4
48.2
49.1
50.0
51.0
51.9
52.9
53.8
54.8
55.8
56.8
57.9
58.9
60.0
61.1
62.2
63.4
64.5
65.7
66.9
68.1
69.4
70.6
71.9
73.3
74.6
76.0
77.4
78.8
80.3
81.8
83.3
84.9
86.5
88.1
89.7
91.5
93.2
95.0
96.8

24.28
24.56
24.84
25.12
25.40
25.68
25.96
26.24
26.52
26.80
27.08
27.35
27.63
27.91
28.19
28.47
28.75
29.03
29.31
29.59
29.87
30.15
30.43
30.70
30.98
31.26
31.54
31.82
32.10
32.38
32.66
32.94
33.22
33.50
33.78
34.05
34.33
34.61
34.89
35.17
35.45
35.73
36.01
36.29
36.57
36.85
37.13
37.40
37.68

60.65
60.20
59.74
59.29
58.84
58.39
57.93
57.48
57.03
56.58
56.12
55.67
55.22
54.77
54.31
53.86
53.41
52.96
52.51
52.05
51.60
51.15
50.70
50.24
49.79
49.34
48.89
48.43
47.98
47.53
47.08
46.62
46.17
45.72
45.27
44.81
44.36
43.91
43.46
43.01
42.55
42.10
41.65
41.20
40.74
40.29
39.84
39.39
38.93

2.50
2.45
2.40
2.36
2.32
2.27
2.23
2.19
2.15
2.11
2.07
2.04
2.00
1.96
1.93
1.89
1.86
1.82
1.79
1.76
1.73
1.70
1.67
1.64
1.61
1.58
1.55
1.52
1.49
1.47
1.44
1.42
1.39
1.36
1.34
1.32
1.29
1.27
1.25
1.22
1.20
1.18
1.16
1.14
1.11
1.09
1.07
1.05
1.03

Fecha impresin: 22/09/2009

Documento: VBoy09044

Direccin de Tecnologa

Solubilidad del fosfato monoamnico, g FMA/100 g H 2O

Hoja 6 de 8

170

160

150

140

130

Gramos de FMA por 100 gramos de agua

120

110

100

90

80

70

60

50

40

30

20

10

0
0

10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100
Temperatura, C

Fecha impresin: 22/09/2009

Documento: VBoy09044

Direccin de Tecnologa

Solubilidad del fosfato monoamnico, g P 2O5/100 g H2O

Hoja 7 de 8

110

100

90

Gramos de P2O5 por 100 gramos de agua

80

70

60

50

40

30

20

10

0
0

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95 100

Temperatura, C

Fecha impresin: 22/09/2009

Documento: VBoy09044

Direccin de Tecnologa

Hoja 8 de 8

Disoluciones saturadas de fosfato monoamnico, % FMA

65

60

55

% FMA en la disolucin saturada

50

45

40

35

30

25

20

15
0

10

15

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95 100

Temperatura, C

Fecha impresin: 22/09/2009

Documento: VBoy09044

Direccin de Tecnologa