Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Presentation Overview
What is Raman spectroscopy? What can Raman tell you about Carbon? What is involved in a collecting a Raman measurement?
R H
3
H
R
The Diamond spectrum is very similar to that of crystalline Silicon and Germanium except that the lighter weight Carbon bonds vibrate at higher frequency.
Silicon
Raman tells us that C60 bonds are much more uniform than C70
8
G'
Graphite
10
1587.94
1581.72
1584.16
Graphite
OMNIC
1620
1610
1600
1570
1560
1550
11
1700
1650
1550
1500
1450
12
In t
Multi Layer
2800 600
2750
2700 Ram an s h i ft (c m -1 )
2650
2600
550
500
450
400
350
In t
300 250
Three Layer
200
150
100
600
550
500
450
400
350
In t
300 250 200
Two Layer
In t
150
100
2650 s h i ft (c m -1 )
2600
1000
900
800
700
600
500
400
300
Single Layer
200
100
2800
2750
2700 Ram an s h i ft (c m -1 )
2650
2600
13
I2D/IG= 2
2600
2400
2200
1800
1600
14
Graphene
SWCNT
15
2D
G D
RBM
iTOLA
G D
RBM
19
20
21
22
23
Decomposition products
Thermal baseline
C60 excited over a range of laser power peak height not normalized
26
Legend: Zone A: The Laser Power Regulator controls the laser power reaching the sample to ensure reproducible results. Zone B: As the laser power declines over its lifetime, measurements become non-reproducible on instruments lacking a Laser Power Regulator. Zone C: Beyond the expected laser lifetime. The Raman instrument can still be used reproducibly at lower power levels.
27
2D
D
Blowup of RBM bands
RBM
28
Bulk measurements
Only applicable if sample is densely packed Sometimes this applicable to liquid suspensions Even investigation of single CNTs
29
1
3000 2500 2000 Raman s h ift (c m-1) 1500 1000 500
4 3
3000 2500 2000 Raman s h ift (c m-1) 1500 1000 500
3000
2500
1500
1000
500
3000
2500
1500
1000
500
30
260 cm-1
P os i ti on (m i c rom eters )=-321 m ;-206 m Num b er: 473
150 cm-1
Pos ition (mic rometers )=-71 m ;-176 m Numbe r: 753
400
350
300
200
150
260
240
220
200
180
160
140
120
100
80
1nm SWCNT
32
1.7nm SWCNT
3000
2500
2000
1500
1000
500
Ram an s h i ft (c m -1)
Average Variance
3000
2500
2000
1500
1000
500
Ram an s h i ft (c m -1)
33
34
VDPS Map
3000
2500
2000
1500
1000
500
35
Sm
Diameter
Lg
SWCNT with a peak near 239 cm-1
G'
37
Conclusions
Raman is an extremely powerful tool for characterizing Carbon nanomaterials Raman sampling is easy and faster than many other techniques Raman has a role to play in both research and QC The limits to the information that Raman can provide on Carbon materials are still unfolding
As this field continues to develop, the role of Raman is most likely going to increase
38
39
Questions?
Thank You For Your Time! Email survey Your feedback is important Presentation slides and recording will be available on the Materials Today website Additional Thermo Fisher Scientific Raman webinars
www.thermoscientific.com/ramanwebinars
Mark Wall