1. 1L of a gas at S.T.P weighs 1.97g. what is the vapour density of the gas? 2.

How much copper can be obtained from 100g of copper sulphate (CuSo4)? Atomic mass of (Cu=63.5 amu). 3. What physical meaning is attributed to the square of the absolute value of wave function ||2 4. what is the basic difference between the terms election gain enthalpy and electronegativity? 5. Wrie down the lewis structures of CO2. 6. Given the number of electrons which occupy the bonding orbitals in H2+, H2and O2+. 7. What is the SI unit of coefficient of viscosity? How is it related to poise? 8. Separate out the following into extensive and intensive properties. Volume, Temperature, Pressure Boiling Point, Free energy. 9. Calculate the number of kJ necessary to raise the temperature of 60.0g of aluminium from 35c to 55c. molar heat capacity of aluminium is 24J mol-1 k-1. 10. Why does ice melt slowly at higher altitudes? 11. Arrange the following in order of their increasing basicity. H2O,OH-,CH3OH, CH3O12. write the conjugate acids for the following bronsted bases. 13. Calculate the oxidation number of sulphur and chromium in H2SO5, CrO5. 14. Distinguish between (a) hard and soft water, (b) temporary and permanent hardness. 15. Potassium carbonate cannot be prepared by prepared by solvay process. Why? 16. Explain what happens when basic acid is heated. 17. Identify the electrophilic centres in the following: CH2=C=O, CH3CN 18. Write resonance structure of CH3COO- and shown the movement of electrons by curved arrows. 19. 0.3780g of an organic chloro compound gave 0.5740g of silver chloride in cariusestmation. Calculate the percentage of chlorite present in the compound. 20. Give reason for the following: ) The boiling of alkanes decrease with branching. ) The melting point of alkanes with odd number of carbon atoms are lower than those with even number of carbon atoms. C) straight chain alkanes possess higher boiling points than the corresponding branched chain isomers. 21. Draw the orbital diagram for methane and ethane molecules indicating the hybridisation involved. 22. How are freons creating a hole in the ozone layer? 23. Derive the relationship between pressure, temprature and density of the gas (i.e., M = dRT/P) 24. for the reaction N2(g) + CO(g) 2NH3(g) The partial pressure of N2 and H2 are 0.80, and 0.40 atmosphere respectively at equilibrium. The pressure of the system is 2.80 atmosphere. What is kp for the above reaction? 25. under what conditions will the reaction occur, if (a) bothH and S are positive (b) butH and S are negative? 26. using molecular orbital theory, explain why the Be2 molecule does not exist?

27. electrons are emitted with zero velocity from a metal surface when it is exposed to radiation of wavelength 6800 . Calculate the threshold frequency and the work function (w0) of the metal. 28. what are lewis structures? Write the lewis structures of H2, F2, H2O,NH3, C2H4 and C2H2. 29. compare the alkali metals and alkaline earth metals with respect to ionization enthalpy (b) basicity of oxides and (c) solubility of hydroxides. 30. (a) why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty? (b) Arrange benzene, n-hexane and ethyne in decreasing order of acidic behavior. Also give reason for this behavior. ___________________________________________________________________________ 1. How are 0.50 mol Na2Co3 and 0.50 M Na2Co3 different? 2. What is the number of photons of light with a wavelength of 4000 Pm that provide 1J of energy? 3. What are the various factors due to which the ionization enthalpy of the main group element tends to decrease down a group? 4. Define the bond length. 5. Calculate the total number of electrons present in 1.4g of dinitrogen gas. 6. For an isolated system, u=0 what will be s? 7. Which of the following are lewis acids? H2O, BF3, H+ and NH4+ 8. How does the change in velocity of a moving particle alter the wavelength related to the particle? 9. Explain the following: 1. Ionization enthalpy of Mg is more than that of Na and Al. 2. Ionization enthalpy of nitrogen is more than than of oxygen. 10. what is the total number of sigma and pi-bond in the following molecules? (a) C2H2 (b) C2H2 11. Density of a gas is found to be 5.46g/dm3 at 27c and at 2 bar pressure. What will be its density at S.T.P.? 12. Under what condition, the heat evolved or absorbed in a neutron is equal to its free energy change? 13. The following system is in equilibrium SO2 CL2 + Heat SO2 + Cl2 What will happen to the temperatures of the system if some Cl2 is added to it at constant volume? Give reason. 14. the compound AgF2 is unstable, however, the compound act as a very strong oxidizing agent. Why? 15. Write balanced equations for the reaction between (a) Na2O2 and water (b) KO2 and water (c) Na2O and CO2. 16. [SiF6]2- is known where as [SiCl6]2- not. Give possible reasons. 17. Given the IUPAC name of the following poly-functional compounds. (a) (b) 18. what are electrophiles are nucleophiles? Examples. 19. In the estimation of sulphur by carius method, 0.468g of an organic sulphur compound afforded 0.668g of barium sulphate. Find the percentage of sulphur in the given compound. 20. what are the necessary conditions for any system to be aromatic? 21. how will you convert benzene in to: (a) pnitrobromobenzene (b) toluene (c) acetophenone. 22. what is Acid Rain? what are its harmful effect?

23. what is the shape of the following compounds? (a) H2C = O (b) CH2F (c) HC = N 24. what happens when H2O2 is treated with: (a) acidified potassium permanate (b) leadsulphide (c) acidified ferrous sulphate. 25. complete the following reactions: (a) H2(g) + CO(g) (b) Zn(s) + NaOH(aq) heat (c) C3H8(g) + 3H2O(g) catalyst 26. Depict the galvanic cell in which the reaction Zn(s) + 2Ag+ (aq) Zn2+(aq) + 2Ag(s) Takes place. Further shown: (a) which of the electrode is negatively charged, (b) the carriers of current in the cell, (c) individual reaction at each electrode. 27. In the reaction A + B2 AB2, identify the limiting reagent, if any in the following mixtures. (a) 300 atoms of A + 200 molecules of B. (b) 2 mol A + 3 mol B. (c) 100 atoms of A + 100 molecules of B. (d) 5 mol A + 2.5 mol B. (e) 2.5 mol A + 5 mol B. 28. the wavelength of the first line in the balmer series. 29. (a) How bond energy varies from N2- to N2+ and why? (b) on the basis of molecular orbital theory what is similarty between (1) F2, O2(2) CO, N2, NO+ (3) how does bond energy vary from N2- to N2+ and why? 1. What is one a.m.u or one u? 2. What is the difference between (a) normality and molarity. (b) Atoms and molecules? 3. Which out of Cu2+, Fl2+ and Cr3+ has highest paramagnetism and why? 4. Why do element in the same group have similar physical and chemical properties? 5. Define lattice enthalpy. How is t related to the stability of the ionic compound? 6. Why liquids diffuse slowly as compared to gases? 7. What does free energy change signify? 8. Write the conjugate acids from the following bronsted bases: NH2-,NH3, and HCOO9. Justify that the reaction: 2Na(s) + H2(g) 2NaH(s) is redox reaction. 10. What is syngas? Why is it called so? 11. Write balanced equations for the reaction between (a) Na2O2 and water (b) Na2O and CO2. 12. How does BF3 act as a catalyst in industrial processes? 13. How does NaBH4 react with iodine? 14. Define the term elution as applied to column chromatography. 15. Give two methods of preparation of carbanions. 16. Give the IUPAC name of the following compounds:

17.

write the major product in each case.

18. what effect does branching of an alkene chain have on its boiling point? 19. In the reaction given below, identify the species undergoing oxidation and reduction: (a)H2S(g) + Cl2(g) 2HCl(g) + S(s) (b) 3Fe3 O4 (s) + 8Al(s) 9Fe(s) + 4 Al2 O2(s) (c) Na(s) + H2(g) 2Na H(s) 20. Give one example of the reaction in which dihydrogen acts (a) as an oxidizing agent. (b) as a reducing agent. 21. Give reasons: (a) graphite is used as lubricant. (b) aluminium wire is used to make transmission cables. (c) a mixture of dilute NaOH and aluminium pieces is used to open drain. 22. (a) In which c-c bond of CH3CH2CH2Br the inductive effect is expected to be the least? (b) write resonance structure of CH3COO-and show the movement of electrons by curved arrows. 23. an organic compound C8H18 on monochlorination gives a single monochloride. Write the structure of the hydrocarbon. 24.the following concentrations were obtained for the formation of NH3 from N2 and H2 at equilibrium at 500 k [N2] = 1.510-2M[NH3] = 1.210-2 M [H2] = 3.010-2 M calculate equilibrium constant. 25. Justify the following statements: (a) an exothermic reaction is always thermodynamically spontaneous. (b) The entropy of a substance increases on going from liquid to vapour state at any temperature. 26. A vessel of 120mL capacity contains a certain amount of gas at 35C and 1.2 bar pressure. The gas is transferred to another vessel of volume 108mL at 35C. what would be its pressure? 27. what is bond order? How is it related to bond length and bond dissociation energy? 28. (a) state the type of hydrid orbitals to bond length and bond dissociation energy? (b) use molecular orbiral theory to explain why Be2 molecule does not exist. 29. Give a brief description of the principles of the following techniques talking an example in each case: (a) crystallization (b) chromatograph 30. In the estimation of sulphur by carius method, 0.468g of an organic sulphur compound afforded 0.668g of barium sulphate. Find the percentage of sulphur in the give compound. ______________________________________________________________________________

1. Calculate the number of molecules and number of atoms present n 11.2

litre of oxygen (O2) at NTP. 2. Write the empirical formula of (a) C2H6 (b) H2O2 3. Write van der waals equation for n moles of gas. 4. Why are bohrs orbits called stationary states? 5. If the quantum number n has a value of 3, what are the permitted vales of quantum number I? 6. Explain why bond is stronger than -bond. 7. Distinguish between isothermal and adiabatic process. 8. What happens to a reversible reaction if a catalyst is added to it? 9. Calculate the oxidation number of sulphur in (a) H2SO4 (b) H2S2O8 10. complete the following chemical reactions. (a) PbS(s) + H2O2(aq)

(b) AlCl3(g) + H2O(l) 11. what is meant by diagonal relationship in the periodic table? What is it due to? 12. Account for the following: (a) alkali metals show only +, oxidation state. (b) Na and K impart colour to the flame but Mg does not. 13. What happens when. (a) borox is heated strongly. (b) Boric acid is added to water. 14. Account for the following. (a) CO2 is a gas but SiO2 is a solid. (b) C and Si are tetravalent but Ge, Sn and Pb show divalency. 15. (a) Explain tetravalent of carbon. (c) why does carbon undergo hybridization prior to bond formation? 16. How will you detect the presence of carbon and hydrogen in an organic compound? 17. Write the structure formula of the following compounds: (a) 3, 4, 4, 5 Tetramethylheptane (b) 2, 5-Dimethyl hexane 18. How will you convert benzene into (a) p-nitrobromobenzene (b) p-nitrotoluene (c) acetophenone? 19. Why is wurtz reaction not preffered for the preparation of alkanes containing odd number of carbon atoms? Illustrate your by taking one example. _________________________________________________________________ 1. What does LPG stand for?
2. Calculate the molecular mass of glucose. 3. Calculate the number of atoms in 4.25g of NH3. 4. State de Broglie relationship. 5. Explain why cation are smaller and anion and larger in radii than their parent atom. 6. Why is NaCl a bad conductor of electricity in he solid state? 7. Explain how the valence bond theory accounts for (a) a c-c doble bond (b) a c-c triple bond 8. Explain the effect of temperature on (a) surfacetention (b) viscosity (c) density 9. (a) write mathematical statement of first law of thermodynamics. (B)give a statement which includes the main ideas for the first and second law of thermodynamics. 10. The equilibrium contant for the reaction H2(g) + Br2(g) 2HBr(g) At 1024k is 1.6105. Find the equilibrium pressure of all the gas if 10.0 bar of HBr is introduced into a sealed container at 1024k. 11. Calculate the oxidation number of (a) S in H2S (b) C in CO2. 12. Complete the following reaction. (a) CaO(s) + H2O(l) (b)Na2O(s) + H2O(l) 13. Discuss the various reactions that occur in the Solvay process.

14. Write reactions to justify amphoteric nature of aluminium. 15. Explain what happens when boric acid is heated. 16. Explain the following giving examples. (a) Functional group (b) Homologous series and its charateristics. 17. Discuss the reactions and principle underlying the estimation of the following. (a) Dumas method for the estimation of hydrogen. (b) Carius method for the estimation of halogen. 18. Discuss briefly the mechanism of addition of Br2to alkenes. 19. Predict the products of the following reactions. (1) Alk MnO4 (a) Toluene (2) H+/H2O Conc HNO3 (b)Nitro benzene +Conc H2SO4 (c) C6H5OH + H2SO4 (Conc) 20. Sodium salt of which acid will be needed for preparation of propane? Write Chemical equation for the reaction.