NOMBRE: ________________________________________ CDULA: _____________________ SECCIN: _____

PROFESOR: ____________________________ PREPARADOR: _____________________________ NOTA: _____

INFORME No. 10
CELDAS ELECTROQUMICAS Y CORROSIN
Indique la temperatura en el laboratorio: ____________________
EXPERIMENTO No. 1: Espontaneidad de algunas reacciones de xido-reduccin
Para cada uno de los casos a continuacin, describa el proceso observado, escriba la ecuacin qumica que represente
las reacciones espontneas observadas, indicando el elemento oxidado y el reducido. Compare los resultados obtenidos
con los esperados de acuerdo con la tabla de potenciales.
a. Al aadir un pedacito de Zn al tubo A ______________________________________________________________
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b. Al aadir un pedacito de Cu al tubo B ______________________________________________________________
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c. Al calentar el tubo con HNO3 6M y un pedacito de Cu _________________________________________________
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d. Al aadir un pedacito de Cu al tubo ________________________________________________________________
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e. Al aadir un pedacito de Zn al tubo ________________________________________________________________
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f. Al aadir un pedacito de Zn al tubo ________________________________________________________________
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2+

2+

EXPERIMENTO No. 2: Construccin de la celda Zn/Zn (0,1 M)//Cu (0,1 M)/Cu

a. Anote el voltaje medido: _____________
b. Compare los resultados experimentales con los esperados de acuerdo con la tabla de potenciales. Analice las posibles
fuentes de error experimental para justificar cualquier discrepancia _______________________________________
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EXPERIMENTO No. 3: Efecto de la concentracin sobre el potencial de la celda

2+

2+

3.1.- Celda Pb/Pb (ac)//Cu (ac)/Cu

a. Complete la Tabla I, indicando las concentraciones de las soluciones en la notacin simblica
Tabla I
CELDA

E (V)

NOTACIN SIMBLICA

A
B
C
Compare los resultados experimentales con los esperados de acuerdo con la tabla de potenciales. Analice las posibles
fuentes de error experimental para justificar cualquier discrepancia. Relaciones los potenciales medidos con la
concentracin de las soluciones. Relacione el potencial de la celda A con el de la celda del experimento 2 y compare el
poder reductor del Pb y del Zn ______________________________________________________________________
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3.2.- Celdas de Concentracin
a. Complete la Tabla II
Tabla II
CELDA
2+
Cu/Cu (0,01 M)//Cu (0,1 M)/Cu
+2

2+

2+

Pb/Pb (0,01 M)//Pb (0,1 M)/Pb

E (V)

Compare los resultados experimentales con los esperados de acuerdo con la tabla de potenciales. Analice las posibles
fuentes de error experimental para justificar cualquier discrepancia. Relaciones los potenciales medidos en ambas
celdas con la concentracin de las soluciones ___________________________________________________________
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EXPERIMENTO No. 4: Estudio de la corrosin
4.1.- Corrosin de dos metales en contacto
Describa las transformaciones iniciales observadas al sumergir los clavos en agar-agar contentivo de ferricianuro y
fenolftalena y la evolucin de los experimentos:________________________________________________________
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4.2.- Corrosin de dos metales en contacto
Indique el pH en los tubos E:___________ y F:____________
Describa las transformaciones iniciales observadas y su evolucin durante una semana:
E:______________________________________________________________________________________________
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F:______________________________________________________________________________________________
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G:_____________________________________________________________________________________________
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H:_____________________________________________________________________________________________
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EXPERIMENTO No. 5: Resultados del experimento N4 (Despus de una semana)

5.1.- Describa los cambios observados en la superficie de cada clavo:
A:_____________________________________________________________________________________________
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B:_____________________________________________________________________________________________
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C:_____________________________________________________________________________________________
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D:_____________________________________________________________________________________________
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E:______________________________________________________________________________________________
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F:______________________________________________________________________________________________
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G:_____________________________________________________________________________________________
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5.2.- Indique el pH de los tubos E:_______ y F:________
5.3.- Complete la tabla III
Tabla III
TUBO

SOLUCIN

DESCRIPCIN

2+

Fe

Fe

Fe

Fe

2+
3+
3+

Tubo E

Tubo E

Tubo F

Tubo F

Indique las discusiones sobre sus observaciones de los experimentos 4 y 5. Escriba las ecuaciones de xido-reduccin
balanceadas que representen los cambios qumicos observados: ___________________________________________
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CONCLUSIONES
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BIBLIOGRAFIA