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04/13/2005
2 x2
2 y2
2 z2
& 0 V (x ) =
Search energies E for which functions (x ) with & ( x ) = 0 at the surface of the box and inside:
&
( x 2 + y 2 + z 2 ) = E 2m
2 2 2 2
2m
2
& ( x ) = f ( x) g ( y )h( z ) 1 2 1 2 1 2 f g h [ x 2 f ( x) + y 2 g ( y ) + z 2 h( z )] = E f g h f g h
F (x)
G( y)
H (z)
F ( x) + G ( y ) + H ( z ) = 2 m E = const. F ( x), G ( y ), H ( z ) 2
are constant.
2m
2
2 2 F ( x) = k x2 , G ( y ) = k y , H ( z ) = k z2 , k x2 + k y + k z2 = 2 x2
f ( x) = k x2 f ( x) ,
f (0) = f (a) = 0
Georg.Hoffstaetter@Cornell.edu
140
04/13/2005
f ( x) = k x2 f ( x) ,
f (0) = f (a ) = 0
b c
2 nx
n2 y
2 nz
then also )
) ) is a solution.
Any linear combination of states for the energy E is also a state for the energy E. Degeneracy: There two or more stationary wave functions which do not only differ by a phase factor.
Georg.Hoffstaetter@Cornell.edu
141
Normalization
y ) sin( nz
z)
04/13/2005
| |2 dxdydz = 1
0 0 0
c b a
a 2
& n x n y nz ( x ) =
2 a
sin(nx x) a
2 b
sin(n y
y)
2 c
sin(nz z ) c
) is a product of stationary states of a one dimensional wave functions. a These are orthogonal for different quantum numbers. f n*x ( x) f mx ( x) dx Two three dimensional wave functions ) are therefore 0 orthogonal when one of their three quantum numbers differ.
= nx mx
c b a
Georg.Hoffstaetter@Cornell.edu
142
04/13/2005 Spherically symmetric potentials and wave functions & + y + z ) + V ( x ) = E 3D Schrdinger equation: 2 m ( x & & & & & & dx = (dr er + rd e + r sin d e ) = dr r + d + d & & & & & & & & & & ek ek , er = e , e = er , er = sin e , e = cos e k & & & & 1 & 1 all other k e j = 0 = er r + e r + e r sin
2 2 2 2
&2 (r , , ) =
1 2 r r 2
(r ) +
1 2 r sin
(sin
) +
1 2 sin 2 r 2 2
Search for only those wave functions for a spherically symmetric potential that are spherically symmetric. The other wave functions will be found later.
2m
2
1 2 r r 2
[r (r )] + V (r ) (r ) = E (r )
u ( r ) = r (r )
2 r 2
u (r ) =
2m
2
[V (r ) E ]u (r )