THESAURUS OF INFRARED (IR)

Compound Identification Assignment Nila Huda (1408100045) Kelas A

Infrared (IR) Spectroscopy is one of the most common spectroscopic techniques used by organic and inorganic chemists for identification of functional group. Infrared Spectrum is the pattern of absorption (a plot of % infrared absorption intensity/transmittance as function of wavenumber). Infrared Absorption Intensities are rarely described quantitatively, except for the general classifications of s (strong), m (medium) or w (weak). Monochromator is a device used to disperse a broad spectrum of radiation and provide a continuous calibrated series of electromagnetic energy bands of determinable wavelength or frequency range. Prisms or Gratings are the dispersive components used in conjunction with variable-slit mechanisms, mirrors, and filters. For example, a grating rotates to focus a narrow band of frequencies on a mechanical slit. Detector is generally a photomultiplier tube that recovers information of interest contained in a modulated wave. Fourier Transform Infrared (FTIR) is the type instrument that can separate the individual absorption frequencies from interferogram, producing a spectrum virtually identical to that obtained with dispersive spectrometer. Interferogram is the design of the optical pathway produces a pattern, essentially a plot of intensity versus time.

Thesaurus of Infrared Nila Huda - 1408100045

Hooke Law is approximation that states that the extension of a spring is in direct proportion with the load
applied to it

Moment Dipole
can be defined as the product of magnitude of charge & distance of separation between the charges

Wavenumber is another way to describe the frequency of electromagnetic radiation, and the one most often used in infrared spectroscopy. Wavelengths () is Inversely proportional to frequencies and their associated energy Transmittance (T) is the ratio of radiant power transmitted by the sample (I) to the radiant power incident on the sample (I0). Absorbance (A) is the logarithm to the base 10 of the reciprocal of the transmittance (T). Stretching Vibration is a vibration occurring along the line of the bond that changes the bond length. Bending Vibration is a vibration that does not occur along the line of the bond, but changes the bond angle. Functional Group Region is the left-hand two-thirds of an IR spectrum (from 4000 to 1300 cm1) usually comes from
stretching vibrations between hydrogen and some other atoms.

Fingerprint Region is The right-hand third of the IR (from about 1300 to 500 cm-1) usually contains a very
complicated series of absorptions. These are mainly due to all manner of bending vibrations within the molecule.

Fundamental Absorption is downward spike in the IR spectrum represents absorption of energy at normal frequencies. Overtone is any frequency higher than the fundamental frequency of a sound resulted from excitation.

Thesaurus of Infrared Nila Huda - 1408100045

Combination Band is the band observed when more than two or more fundamental vibrations are excited simultaneously the sum of two interacting band fundamental and overtone, Vcomb = V1 + V2 Difference Band is the band observed from difference between two interacting band fundamental and overtone, Vdiff = V1 - V2 Fermi Resonance is the coupled vibration it results in the splitting of two vibrational bands that have nearly the same energy and symmetry. The two bands are usually a fundamental vibration and either an overtone or combination band.

Thesaurus of Infrared Nila Huda - 1408100045