Chemistry Practice Set Section A (Attempt ALL questions from this section.) Q.

1 (a) Name the following(i) An indicator which is colourless and remains colourless in acidic medium. (ii) An alkali metal in period 3. (iii) Elements of the shortest period. (iv) Covalent molecule with 2 lone pairs of electrons. (v) Periodic property which relates ti the release of energy upon addition of an electron to an isolated gaseous atom. (vi) Law which states that when gases react the do so volumes which bear a simple ratio to each other. (vii) A substance which forms hydronium ions when added to water. (viii) Gas released at cathode when an aqueous solution of NaCl is electrolyzed using Platinum electrodes. Given below are the melting point and atomic radii of three elements x, y and z each having N electrons in the outermost shell of their atom Element X Y Z MP 180.5 97.5 63.4 At. Radius 1.23 1.57 2.02 (i) Do these elements belong to the same period or the group? (ii) Which element is least metallic? A solution P has a pH of 13, a solution Q has pH=6 and solution R has pH=2. (i) Which solution will liberate ammonia gas from ammonium sulphate on heating. (ii) Which solution is a strong acid? (iii) Which solution will react with vegetable oil to produce soap? (iv) Which reaction will take place between P and R? (v) Write the effect of each on red litmus paper. Explain why(i) Solid lead bromide does not conduct electricity but molten conducts. (ii) HCl dissolved in carbon tetra chloride does not conduct electricity. (iii) Atomic radius increases as we move down a group. (iv) Colour of aqueous solution of CuSO4 fades when electrolysed using Pt electrodes (v) A temperature in the range of 170 -190oC needs to be maintained while carrying out dehydration of ethanol using concH2SO4. Write the IUPAC and trivial name of the following organic compounds(i) CH3CH=C=CH2 (ii) CH3CCCH=CH2 (iii) (CH3)3CCH2CH3 (iv) BrCH2(CH2)4CH2CH3 (v) CH3CH(OH)CH2CHO A colorless sweet smelling gas A when passed through Br2 in CCl4 changes its colour from red to colourless and Alkaline KMnO4 pink to colourless. A when polymerized forms a thermoplastic B. (i) Identify A and B. (ii) Show the chemical reaction between A and Br2 in CCl4. (iii) Write the IUPAC name of A and the product formed in the previous question. Choose from letters A,B, C, D, E to match the descriptions given belowANH4Cl BAgCl CFeCl2 DPbCl2 E[Ag(NH3)2Cl] (i) A soluble salt obtained on reaction of a metallic chloride with ammonia. (ii) A salt which is insoluble in dilute nitric acid but soluble in ammonium hydroxide. (iii) A salt obtained on reaction of an active metal with HCl. (iv) A salt obtained when a basic gas reacts with hydrogen chloride. (v) A salt soluble in hot water but not in cold, obtained on heating an oxidizing agent with conc HCl. Calculate(i) Percentage of water in MgCl2.6H2O [Mg=24, Cl=35.5] (ii) Weight of quicklime formed when .04g of CaCO3 is heated.[Ca=40, C=12, O=16] (iii) Molecular weight of a gas whose vapour density is 35.5. [8]

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Please turn over 2 Section B (Attempt any FOUR )

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(c) Q.5 (a)

(b) Q.6 (c) (a)

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Name the products formed at anode and cathode when the following are electrolysed[4] (i) Molten NaCl (ii) Acidulated water Given below are the ores of some metals suggest the most appropriate method for concentration and [4] reduction for the following(i) Haematite (ii) Alumina What is a co-ordinate bond? Give two examples studied by you [2] Explain the following[5] (i) Esterification (ii) Saponification (iii) Decarboxylation (iv) Polymerization (v) Catenation When a reddish orange compound A is heated strongly in a hard glass test tube, makes the wall of the test tube [5] silvery along with evolution of a colourless odourless gas B. Gas B when reacted with alkaline pyrogallol makes it brown. (i) Identify the substance A and gas B. (ii) Show the relevant and balanced reaction for conversion of A to B. (iii) What will happen if a glowing splinter is brought near the mouth of the test tube. Describe the following in brief[3] (i) Froth Floatation process (ii) Gravity separation or hydraulic washing (iii) Aluminium utensils are never washed with soap. Select the most probable substance from A, B, C, D and E which need to be added to distinguish: [5] (i) Ammonium sulphate and ammonium chloride A. Conc. HCl (ii) Potassium sulphate and ammonium sulphate B. Ammonia gas (iii) Liq. Ammonia and liquid ammonia C. BaCl2 (iv) Ammonia and sulphur dioxide gas D. Phenolpthalein. (v) Copper (II) oxide and copper (II) chloride E. Sodium hydroxide. Write the structures of the following[2] (i) 2,methyl propanol-2 (ii) 1,1,2,2 tetrachloroethanol. Write balanced chemical equations for the conversions A to E. [5] Mg A MgO B Mg(NO3)2 C Mg(OH)2 E D MgCO3 A metal M forms a volatile chloride containing 65.5% chlorine. If the density of the chloride relative to hydrogen[3] Is 162.6, find the molecular formula of the chloride [M=56, Cl= 35.5] Calculate the number of atoms in 60g of Neon (Ne=20, N= 6.023 x 1023) [2] (i) Write the correct equation for CCl4 from methane. [2] (ii) Draw the structural formula for ethyne. [1] (iii) Define the following[2] (1) Power alcohol (2) Methylated spirit What happens when[5] (i) Sucrose is reacted with conc. H2SO4. (ii) AgCl is reacted with Ammonia solution. (iii) Ethyl chloride is reacted with alcoholic KOH. (iv) Sodium Acetate is heated with soda lime (v) Ethane is catalytically oxidized using MoO. deekaylucknow@gmail.com ******