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1. Lithium is a Group I element in the Periodic Table. It occurs naturally in two isotopic
forms. The relative abundance of the each of these isotopes is shown in the table below:
Istope 6
Li 7
Li
Relative abundance (%) 7.4 92.6
(a) What is the meaning of the term 'isotope'?
(b) Calculate the relative atomic mass of lithium.
(c) A piece of freshly cut lithium metal is placed in air.
(i) What would be observed on the surface of the metal after some time? Write the
relevent chemical equation.
(ii) Draw the electronic diagram of the product in (i), showing electrons in the
outermost shells only.
(6 marks)
1. (a) Atoms with the same atomic number but different mass number/atoms with
the same no. of protons but different no. of neutrons 1
(Accept any correct definition of isotope.)
(b) Relative atomic mass = 6×0.074 + 7×0.926 1
= 6.93 1
(Also accept 6.9 and 6.926)
(c) (i) The metal surface will tarnish/turn dull 1
4 Li + O 2 → 2 Li 2 O 1
(ii)
2. For each of the following experiments, state the expected observation and write a relevent
chemical equation.
(a) Ethene is passed into an acidified potassium permanganate solution.
(b) A mixture of butane and bromine vapour is exposed to diffused sunlight.
(c) A sodium sulphite solution is added to an iodine solution (iodine dissolved in aqueous
potassium iodide).
(6 marks)
For questions 4 and 5, candidates are required to give paragraph-length answers. 3 of the
marks for each of these two questions will be awarded for effective communication of
knowledge in Chemistry.
4. On a hot summer day, the engine of a moving bus suddenly caught fire. When the firemen
arrived, they used foam, instead of water, to put out the fire. After the fire was extinguished,
the firemen sprayed a lot of water onto the hot engine.
Discuss the conditions required for the fire to occur and explain the underlying principles
of the actions taken by the firemen.
(9 marks)
6. (a) (i) A student prepared sodium nitrate solution by reacting 1 M sodium hydroxide
solution with dilute nitric acid. The student carried out a titration to determine
the amount of dilute nitric acid required to react with a known volume of 1 M
sodium hydroxide solution.
(1) Write the chemical equation for the reaction. (An ionic equation will
NOT be accepted for this question.)
(2) Draw a labelled diagram for the set-up of the titration.
(3) Phenolphthalein can be used to determine the end point of the titration.
State the colour change at the end point.
(4) Suggest how the student can prepare a sodium nitrate solution using the
titration results.
(ii) Sodium nitrate is a nitrogenous fertilizer.
(1) Calculate the percentage by mass of nitrogen in sodium nitrate.
(2) Explain why nitrogen is essential for the growth of plants.
(Relative atomic masses: N = 14.0, O = 16.0, Na = 23.0)
(9 marks)
(Criteria for marking the labels: 2 marks for all four labels; 1
mark for three labels / two labels of which one should be a
reagent.)
(3) from pink / purple / red to colourless 1
(4) Add dilute nitric acid to 1 M sodium hydroxide solution in the
same volume ratio so that in the titration result, without adding
the indicator 1
or, repeat the titration procedure without adding the indicator (1)
(ii) (1) Formula mass of NaNO 3 = 23 + 14 + 16×3 1
= 85 (1)
14
% by mass of N = × 100%
85
= 16.5% (or 16.47%) 1
(2) Nitrogen is used in plants to produce amino acids / proteins /
cytoplasm / chlorophyll / nucleotide 1
(b) The table below includes some information about three types of dry cells. The
voltahge of each type of cell is 1.5 V.
Type Voltage over Price per Shelf Life/minutes
discharge cell/$ life/years
Zinc-carbon cell falls quite 2.5 1.5 70
(AA size) rapidly
Alkaline remains steady 5.0 3 90
manganese cell
(AA size)
Silver oxide cell remains steady 8.0 2 30
(button type)
(The life of a cell has been determined from its use in a test with a motorized toy.)
(i) Decide and explain which type of cell should be used in a small CD-player
(Discman).
(ii) A package of 24 zinc-carbon cells is now being offered at a special price of
$49.90. Assuming that your radio consumes one zinc-carbon cell per month,
would you buy a package of these specially-priced cells for the use of your
radio? Explain your answer.
(iii) The half-equations below show the changes at the two electrodes, A and B, of a
silver oxide cell during discharge:
Zn ( s) + 2OH − ( aq ) → ZnO ( s) + H 2 O ( l ) + 2e −
A:
Ag 2 O ( s) + H 2 O ( l ) + 2e − → 2Ag ( s) + 2OH − ( l )
B:
(1) Decide and explain which electrode, A or B, is the anode.
(2) Write the overall equation for the reaction that would occur in the cell during
discharge.
(iv) The following information was found on the packaging of a brand of zinc-carbon
cells:
Caution: 1. Do not dispose of used cells in fire.
2. Remove cells when not in use for prolonged periods.
(1) Explain why used cells should not be disposed of in fire.
(2) Explain why the cells should be removed when not in use for prolonged
periods.
(9 marks)
7. (a) Both carbon and silicon are Group IV elements in the Periodic Table. The diagram
below show the structures of dry ice (solid carbon dioxide) and quartz (a form of
silicon dioxide).
dry ice quartz
(i) With reference to the structures of the two substances, explain why quartz is a
solid which melts at a high temperature, while carbon dioxide is a gas at room
temperature.
(ii) With the help of a labelled diagram, suggest how to show experimentally that
dry ice sublimes to give gaseous carbon dioxide.
(iii) Sand (an impure form of quartz) and limestone are raw materials used for
making glass.
(1) Name the main chemical constituent of limestone.
(2) Suggest ONE reason why glass had been used by mankind for a long
time.
(3) Suggest ONE reason why glass bottles are preferred to plastic bottles for
the storage of champagne.
(9 marks)
observation: lime water turns milky, no liquid residue remains (in the
test tube) 1+1
(iii) (1) †calcium carbonate 1
(2) the materials for making glass are easily available / abundant in
the earth crust. 1
or, Glass can easily be manufactured by heating sand, limestone
and sodium hydroxide. (1)
(3) champagne contains a pressurized carbon dioxide solution.
Glass can withstand the pressure. 1
or, the ethanol solution (champagne) can dissolve
unpolymerized monomers in plastic (1)
(b) Polyvinyl chloride (PVC) is a plastic which has a wide range of uses.
(i) Write the chemical equation for the formation of PVC from its monomers.
(ii) Plastic products made of PVC may vary greatly in rigidity.
(1) Give ONE flexible product made of PVC.
(2) Give ONE rigid product made of PVC.
(3) Explain whether PVC is suitable for making electric sockets or not.
(iii) Incineration of PVC wastes produces hydrogen chloride which causes air
pollution.
(1) State ONE harmful effect of the discharge of hydrogen chloride into the
atmosphere.
(2) Suggest how hydrogen chloride can be removed from incinerator flue gas
prior to its discharge to the atmosphere.
(3) Suppose that all the chlorine in PVC is converted to hydrogen chloride
upon incineration. Calculate the volume of hydrogen chloride produced,
measured at room temperature and pressure, when a plastic waste
containing 1000 kg of PVC is incinerated.
8. (a) A student added concentrated sulphuric acid dropwise to some sugar cubes as
illustrated in the diagram below:
(i) (1) State the observable changes in the above experiment and write the
chemical equation for the reaction involved.
(2) What property of concentrated sulphuric acid is responsible for the
reaction?
(ii) When there was no further change, the student added excess concentrated
sulphuric acid to the reaction mixture. Upon heating, carbon dioxide, sulphur
dioxide and water were produced.
(1) Write the chemical equation for the reaction that occurred during heating.
(2) What property of concentrated sulphuric acid is responsible for this
reaction?
(3) State ONE safety precaution that should be taken. Explain your answer.
(iii) Draw ONE hazard warning label which should be displayed on a bottle of
concentrated sulphuric acid.
(9 marks)
(1)
C O R R O S IV E
(The label should show the corrosive property of H 2SO 4 on skin and
/ or on materials such as metal or wooden surface.)
or, oxidizing (1)
O X ID IS IN G
(b) The photograph below shows a can of fruit juice. The body of the can is made of iron
coated with another metal. The top of the can and the ring-pull are made of
aluminium.
(i) (1) Suggest ONE reason why the iron body is coated with another metal.
(2) Name ONE metal commonly used for coating the iron body.
(ii) Suggest ONE reason why aluminium, rather than iron, is used for making the
top of the can and the ring-pull.
(iii) Explain why it is not advisable to buy cans of fruit juice
(1) if the cans have scratches on the iron body;
(2) if the cans are swollen.
(iv) There is an increasing tendency for manufacturers to use cans made entirely of
aluminium for the storage of fruit juice. Suggest ONE advantage and ONE
disadvantage of using aluminium cans for the storage of fruit juice.
(9 marks)
water out
X
water in
heat
(i) Name apparatus X.
(ii) Explain why some pumice stones were added to the reaction mixture before
heating.
(iii) Write the chemical equation for the reaction involved.
(iv) Suggest a method to obtain propanoic acid from the reaction mixture.
The student used the propanoic acid obtained to carry out the following experiment:
(v) Why is a water bath, instead of a naked flame, used for heating the test tube and
its contents?
(vi) (1) State TWO observable changes when the contents of the test tube were
added to the sodium carbonate solution.
(2) Give the systematic name of the carbon compound formed in the
experiment.
(8 marks)
experiment II
Electrolysis of brine
(i) What would be observed when a small piece of sodium is added to water?
(ii) Explain whether experiment I or experiment II is preferred for preparing a
sodium hydroxide solution.
(iii) During the electrolysis of brine, chlorine and hydrogen are liberated at the
anode and cathode respectively. A sodium hydroxide solution remains in the
electrolytic cell after some time.
(1) Explain why hydrogen, instead of sodium, is liberated at the cathode.
3
(2) Suppose that 50.0 cm of hydrogen is liberated at the cathode at room
temperature and pressure. Deduce the theoretical volume of chlorine
liberated at the anode under the same conditions.
(3) Explain why a sodium hydroxide solution remains in the electrolytic cell.
(iv) Draw a labelled diagram to show the laboratory set-up for the electrolysis of
brine and the collection of the gaseous products.
(10 marks)
(1 mark for labelling the two electrodes; 1 mark for showing the
collection of gaseous products at the electrodes; 1 mark for
labelling the correct products.)
END OF PAPER