866 Handbook of Paint Raw Materials

DUPONT CO.: TI-PURE Titanium Dioxide: DUPONT white pigments for Coatings Rutile Titanium Dioxide: Grade: R-100: Sp. Gr.: 4.2 % Min. Ti02: 97 Meets ASTM D-476 Spec: Type I1 Principal Applications: Interior gloss finishes--trade sales and industrial R-900: Sp. Gr.: 4.0 8 Min. Ti02: 94 Meets ASTM D-476 Spec: Type I1 Principal Applications: General purpose--especially high gloss finishes
R-901: Sp. Gr.: 3.8 % Min. Ti02: 85 Meets ASTM D-47b Spec: Type 111 Principal Applications: General purpose trade sales--especially emulsion flats

R-902: Sp. Gr.: 4.0 % Min. Ti02: 91 Meets ASTM D-476 Spec: Type IV Principal Applications: General purpose for interior and exterior finishes R-931: Sp. Gr.: 3.6 8 Min. Ti02: 80 Meets ASTM D-476 Spec: Type I11 Principal Applications: High PVC interior and exterior flat emulsion and alkyd paints R-960: Sp. Gr.: 3.9 % Min. Ti02: 89 Meets ASTM D-476 Spec: Type IV Principal Applications: Exterior finishes requiring outstanding gloss, tint retention and chalk resistance.

Titanium Dioxides

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DUPONT CO.: TI-PURE Titanium Dioxide(Continued): DuPont white pigments for Coatings(Continued) Rutile-Slurries: Grade: R-940: Slurry Density: Lb/Gal: 19.5 % Solids: 76.5 Brookfield Viscosity cp: <lo00 Principal Applications: Aqueous coatings--gloss and semigloss. Slurry counterpart of R-900 R-941: Slurry Density: L b / G a l : 15.8 % Solids: 64.5 Brookfield Viscosity cp: <SO0 Principal Applications: Aqueous coatings--high PVC flats. Slurry counterpart of R-931 R-942: Slurry Density: Lb/Gal: 19.4 % Solids: 76.5 Brookfield Viscosity cp: <lo00 Principal Applications: Exterior aqueous coatings. Slurry counterpart of R-902.

868 Handbook of Paint Raw Materials

DUPONT CO.: TI-PURE Titanium Dioxide(Continued): Product Description: TI-PURE R-100 is a very low binder demand, easy dispersing pigment of interest for interior industrial and trade sales applications. TI-PURE R-900 (R-940 Slurry) offers particular advantage in high gloss and semi-gloss finishes because of its high hiding power at low pigment volume concentrations plus excellent brightness, ease of dispersion, gloss and cleanness of tint. Its chalk resistance is satisfactory for many exterior trade sales paints. Accordingly, it can be considered as general purpose pigment. TI-PURE H-901 has outstanding hiding efficiency in all types of flat paints and finds wide acceptance in emulsion paints. TI-PURE R-902 (R-942 Slurry) has an excellent balance of chalk resistance and optical values in a broad range of exterior finishes. It is recommended for its high quality performance in automotive refinish and exterior trade sales paint. High level of chalk resistance in addition to its optical properties make it a multipurpose pigment for both interior and exterior coatings. TI-PURE R-931 (R-941 Slurry) provide hiding power and film integrity in high are most efficient in paints containing gallon with the PVC ranging between 45% a good balance between PVC flat pigments. They 2.0 lb. or more Ti02 per and 608.

TI-PURE R-960 provides outstanding chalk resistance, tint retention and gloss retention along with excellent low-shear dispersion, color acceptance (resists flocculation) and hiding power. Because of its excellent exterior durability, it is the pigment of choice for automotive OEM topcoats and coil coatings for residential and industrial siding. TI-PURE Rutile Slurries retain the performance properties of their respective dry TI-PURE counterparts. However, they offer significant advantages in ease of handling, reduced waste, lower raw materials and dispersion costs.

Titanium Dioxides

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KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides: TRONOX Chloride Process Titanium Dioxide CR-800: TRONOX CR-800 is a low oil absorption treated rutile pigment produced by the chloride process. It has high gloss producing properties for interior trade sales paints and industrial coatings. It may be used in exterior applications where the maximum chalk resistance of CR-822 is not required. It exhibits high brightness and excellent tint strength in gloss and semi-gloss enamels. CR-800 is also recommended as high gloss, low abrasivity pigment for letter press, gravure, polyamid, and other inks. Typical Properties: Ti02 content, minimum Density Specific gravity As pounds per gallon One pound bulks-gallons Oil absorption Water demand PH Specific resistance Average particle diameter Chalk resistance Specification 95% 4.1 34.4 lb/gal 0.0291 gal/lb 17 lb oi1/100 lb pigment 18 lb water/100 lb pigment 7.0 11,000 ohms 0.23 um medium ASTM D 476-73, type 1 1 , 1 1 1

TRONOX Chloride Process Titanium Dioxide CR-800PG: TRONOX CR-800PG is of great advantage when used in those plastics applications requiring a blue white, excellent dispersing Ti02. In addition to its high tinting strength it also exhibits comparatively low abrasivity. CR-800PG has found wide acceptance in powder coatings, polyethylene film and vinyl sheet goods. It is also used in most other common plastics applications. It meets the Plastic Pipe Institute's guide-lines for formulation substitution and is authorized by the National Sanitation Foundation for general interchangeability in NSF-listed formulations. Typical Properties: Ti02, content, minimum Solid density Bulk density Oil absorption Average particle size Specific resistance Grit on 325 mesh, maximum
PH

95% 4.1 g/ml 40-55 lb/cu ft 17 lb o i l / l O O lb pigment 0.19 um 6 .O-8.0 7600 ohms 0.004%

870 Handbook of Paint Raw Materials

KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides(C0ntinued): TRONOX Chloride Process Titanium Dioxide CR-800s: TRONOX C R - 8 0 0 s is the slurry counterpart of TRONOX CR-800. The high gloss producing and strength properties of CR-800 have been preserved in its slurry form. TRONOX CR-800s is recommended for interior gloss and semigloss water-borne coatings, as well as exterior water-borne coatings where the maximum durability of CR-822 is not required TRONOX CR-800s may also be used in flat coatings when it is supplemented with functional extenders to obtain the required dry hiding properties. Specifications: Solids Volatile Density Viscosity @ 100 RPM PH Typical Viscosity Profile: RPM 100 50 20 10 76.5+-1% water 19.3-19.9 lb/gal 300-500 CP 8.5-9.5 Viscosity, cp 400 650 1300 2300

TRONOX Chloride Process Titanium Dioxide CR-801: TRONOX CR-801 is a medium oil absorption treated rutile pigment produced by the chloride process and is designed as a general purpose trade sales pigment. It is characterized by high brightness and high strength at all pigments volume concentrations such as in gloss enamels, semi-gloss enamels, satin and flat latex paints, and flat solvent thinned paints. It may be used in exterior coatings where the chalk resistance of CR-821 or CR-822 is not required. Typical Properties: Ti02 content, minimum 93% Density Specific gravity 4.0 Scattering coefficient per pound Ti02 In enamels 4.2 In flat latex 3.7 Oil absorption 26 lb oi1/100 lb pigment Water demand 30 lb water/100 lb pigment PH 7.5 6000 ohms Specific resistance Average particle diameter 0.24 um Chalk resistance medium Specification ASTM D476-73 Type 11, 1 1 1

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KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides(Continued): TRONOX Chloride Process Titanium Dioxide CR-813: TRONOX CR-813 is a high oil absorption treated rutile pigment which has been designed specifically for interior flat architectural paints, both latex and solvent based, where it exhibits outstanding brightness, highest strength and an exceptionally clean tint tone. A change to CR-813 from lower dry hiding pigments in such finishes permits formulators to achieve equal opacity at lower cost, with no loss of film integrity. TRONOX CR-813 is also recommended as the highest hiding pigment for low gloss water based flexographic inks. Typical Properties: Ti02 content, minimum 87% Density Specific Gravity 3.85 Scattering coefficient per pound Ti02 In enamels 3.9 In flat latex 4.4 36.5 lb oi1/100 lb pigment Oil absorption 44 Ib water/100 lb pigment Water demand 7.5 PH Specific resistance 6000 ohms 0.25 um Average particle diameter medium Chalk resistance Specification ASTM 476-73 Type I11 TRONOX Chloride Process Titanium Dioxide CR-813s: TRONOX CR-813s is the slurry counterpart of TRONOX CR-813. The excellent high dry hiding properties of CR-813 have been preserved in its slurry form. TRONOX CR-813s is recommended for interior flat water-borne coatings, such as flat latex wall paints and ceiling tile and paper coatings. Specifications: Solids Vola ti le Density Viscosity k 100 RPM ?
PH

64.5+-1% water 15.6-16.2 lb/gal 125-250 CP 8.5-9.5 Viscosity, cp

170

Typical Viscosity Profile RPM

100

50 20
10

270 490 800

872 Handbook of Paint Raw Materials

KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides(Continued): TRONOX Chloride Process Titanium Dioxide CR-821: TRONOX CR-821 is a treated rutile pigment produced by the chloride process. It has been designed to be a universal high gloss pigment for both interior and exterior film application. It has a high initial gloss, ease of dispersion, opacifying power and good exterior weathering properties. CR-821 is recommended for all classes of coatings: architectural, industrial and maintenance; solvent thinned or water thinned; interior or exterior. Typical Properties: Ti02 content, minimum 928 Density Specific gravity 4.0 Scattering coefficient per pound Ti02 In enamels 4.1 In flat latex 3.0 18.6 lb oil/LOO lb pigment Oil absorption 21.0 lb water/100 lb Water demand pigment 7.8 PH 6,500 ohms Specific resistance 0.22 um Average particle diameter high Chalk resistance ASTM D 476-84 Type II1,IV Spec if ication TRONOX CR-821s TRONOX CR-821s titanium dioxide pigment slurry is a water dispersion of TRONOX CR-821. It is recommended for all classes of interior or exterior water thinned coatings, inks, and adhesives. TRONOX CR-821's major application will be in architectural latex paints. Its high gloss and strength properties make it especially suitable for gloss and semigloss finishes. With selected functional extenders it gives high hiding in eggshell and flat finishes also. Because of its good weather resistance properties it is recommended for exterior house paints of all types as well. Typical Properties: Solids, 5 Volatile Density, lbs./gals. Viscosity @ 60 RPM, cp PH 76.5+-1 water 19.2-19.9 200-300 8.5-9.5

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KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides(Continued): TRONOX Chloride Process Titanium Dioxide CR-822: TRONOX CR-822 is a treated rutile pigment produced by the chloride process. It has been designed to have the highest degree of gloss and tint retention properties in exterior film applications. It is characterized by an optimum balance of high initial gloss, ease of dispersion, opacifying power and exterior weathering properties. CR-822 is recommended for all interior and exterior enamels and lacquers in architectural, industrial and maintenance finishes. It is also recommended for exterior plastics applications, particularly tinted vinyl siding. Typical Properties: Ti02 content, minimum 90% Density Specific Gravity 4.01 Scattering coefficient per pound Ti02 In enamels 4.1 In flat latex 3.1 Oil absorption 19 lb oi1/100 lb pigment Water demand 21 lb water/100 lb pigment 7.7 PH Specific resistance 7,500 ohms Average particle diameter 0.22 um Chalk resistance highest Specification ASTM D476-73 Type II1,IV TRONOX Chloride Process Titanium Dioxide CR-822s: TRONOX CR-822s is the slurry counterpart of TRONOX CR-822. The excellent durability, strength, and gloss producing properties of CR-822 have been preserved in its slurry form. TRONOX CR-822s is recommended primarily for maximum durability in gloss and semi-gloss exterior water-borne coatings. However, it may also be used in interior coatings advantageously and may even be used in flat coatings when it is supplemented with functional extenders to obtain the required dry hiding properties. Specifications: Sol ids Vo 1ati le Density Viscosity @ 100 RPM Typical Viscosity Profile: RPM
100

76.5+-1% water 19.1-19.7 lb/gal 175-300 CP

8.5-9.5

PH

50 20
10

Viscosity, cp 225 350 650

1100

874

Handbook of Paint Raw Materials

KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides(Continued): TRONOX Chloride Process Titanium Dioxide CR-834: TRONOX CR-834 is specifically designed for plastics and plastisol applications. While used with most all resins it is widely accepted in rigid vinyl pipe and siding formulations, ABS and polystyrene. It meets the Plastic Pipe Institute guidelines for formulation substitution and is authorized by the National Sanitation Foundation for general interchangeability in NSF listed formulations. It is characterized by: * good dispersibility * high tinting strength and opacity * blue tint tone * excellent color retention after processing wi.th problem resins such as polyvinyl chloride and ABS Typical Values Ti02 content, minimum Density, solid Oil absorption Average particle size Lightfastness Rutile content of contained Ti02 pH Specific resistance Resistance to anti-oxidant d isco 1 oration Bulk density
979

4.2 g/ml 15 lb oi1/100 lb pigment 0.19 um excel lent 100% 6 to 7 7,600 ohms excel lent 40-55 lbs/ft 3

Titanium Dioxides 875

NL CHEMICALS, INC.: TITANOX Titanium Dioxide Pigment: Anatase pigmentary: Physical Properties:
1000 Paper: Specific Gravity: 3.9 Percent Ti02, Min.: 98.5 Oil Absorption: 25.0 Percent Retained on 325 Mesh: 0.05 Chalk Resistance: None pH: 7-9 A.S.T.M. D476-73 Type: I General Product Applications: Paint, Exterior, Flat/Paint, Traffic. Paper: Filler, Coating. White Sidewall Tires. 1070 General Purpose: Specific Gravity: 3.8 Percent Ti02, Min.: 95.0 Remainder: A1 Oil Absorption: 20.5 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: None pH: 7-8 A.S.T.M. D476-73 Type: I General Product Applications: Paint: Exterior, Flat/Paint: Traffic. Paper: Coating. Ceramic Mill Add. Synthetic Fibers.

1072 Fibers: Specific Gravity: 3.9 Percent Ti02: 98.5 Oil Absorption: 19.0 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: None pH: 7-8 A.S.T.M. D476-73 Type: I General Product Applications: Synthetic Fibers Rutile Pigmentary: 2020 General Purpose: Specific Gravity: 4.1 Percent Ti02, Min.: 94.0 Remainder: A1 Oil Absorption: 18.5 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: Mod. pH: 7-8 A.S.T.M. D476 Type: 11, 111 General Product Applications: Paint, Interior: Gloss, SerniGloss, Flat/Exterior: Gloss, Semi-Gloss, Flat/Other: Masonry, Product Finishes. Plastics & Rubber: Polyvinyl Chloride, Plastisol. Printing Inks: Flexographic, Metal Decorating.

876 Handbook of Paint Raw Materials

NL CHEMICALS, INC.: TITANOX Titanium Dioxide Pigment(C0ntinued): Rutile Pigrnentary(C0ntinued): 2071 Plastics: Specific Gravity: 4.1 Percent Ti02, idin.: 96.5 Remainder: A 1 Oil Assorption: 16.5 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: None pH: 6-8 A.S.T.X. D476-73 Type: I1 General Product Applications: Plastics Chloride, Polyethylene, Polystyrene 2073 Plastics: Specific Gravity: 4.2 Percent TiO2, Min.: 97.5 Remainder: A I 011 Absorption: 17.0 Percent Retained on 325 Mesn: 0.01 Chalk Resistance: None # : 7-8 I H.S.T.M. D476-73 Type: I 1 tieneral Product AppllCdtlOnS: Plastics Chloride, Polyethylene, Polystyrene

&

Rubber: Polyvinyl

&

Rubber: Polyvinyl

2081 Laminates: Specific Gravity: 4.0 Percent Ti02, Min.: 91.0 Remainder: A l , Si O i l Absorption: 28.0 Chalk Resistance: tiigh p ~ 7-8 : A.S.T.M. D476-73 Type: 111, IV General Product Applications: Melamine Laminate 2030 Printing Inks: Specific Gravity: 4.1 Percent Ti02, Min.: 94.0 Remainder: A 1 Oil Absorption: 19.5 Percent Retained on 325 Mesh: 0.01. Chalk Resistance: Mod. pH: 7-8 A.S.T.M. D476-73 Type: SI, I11 General Product Applications: Printing Inks: Plexographic, Gravure, Metal Decorating.

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NL CHEMICALS: TITANOX Titanium Dioxide Pigment(C0ntinued):

Rutile, Pigrnentary(Continued): 2101 Multi-Purpose: Specific Gravity: 4.0 Percent Ti02, Min.: 92.0 Remainder: Al, Si Oil Absorption: 21.0 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: High PH: 7-a A.S.T.M. D476-73 Type: 11, 111, IV General Product Applications: Paint: Interior, Gloss, SemiGloss, Flat/Paint: Exterior, Gloss, Semi-Gloss, Flat/Traffic, Masonry, Product Finishes, Automotive 2131 Multi-Purpose: Specific Gravity: 3.7 Percent TiO2, Min.: 80.0 Remainder: Al, Si Oil Absorption: 44.0 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: Mod. p H : 7-9 A.S.T.M. D476-73 Type: I11 General Product Applications: Paint: Interior, Semi-Gloss, Flat/Exterior: Flat/Traffic, Masonry, Product Finishes/Paper: Filler, Coating 2160 Chalk Resistance: Specific Gravity: 4.0 Percent Ti02, Min.: 90.0 Remainder: Al, Si Oil Absorption: 18.0 Percent Hetained on 325 Mesh: 0.01 Chalk Resistance: V. High pH: 7-8 A.S.T.M. D476-73 Type: 111, IV General Product Applications: Paint: Interior, Gloss, Semi-Gloss, Flat/Exterior, Gloss, Semi-Gloss, Flat, Masonry, Product Finishes, Automotive/Plastics & Rubber: Polyvinyl Cnloride, Plastisol. Non-Pigmentary: 3020: Percent Ti02, Min.: 99.5 Percent Retained on 325 Mesh: 80.0 General Product Applications: Glass Pre-Dispersed Anatase: Slurry Properties: 1050 Slurry: Solids: 73.0 Viscosity: 600 cps p H : 9-10 TiOZ#/g: 13.3 Counterpart: 1000 General Product Applications: Paper: Filler, Coating