Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
He ady, Howard H
Assaying ores, concentrates, and bullion. Revision of
information circutar 7695. by H. H. Heady and K. G. Broad-
head. (Washtngton) U.S. Bureau of Mines (1977)
Page
Abstract. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Introduction. . . .... .. . .... ... . .... . . .. ... ... .... ... ... . ... ...... ... " . .. 1
Federa 1 and State agencies.............................................. 1
Procedure for obtaining ore samples..................................... 2
Procedure for sampling bullion and scrap................................ 3
Description of testing techniques....................................... 4
Chemical analysis............... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Fire assay analysis.. ;.... ... .. . . ... . ....... ..... .... ..... .... .. ... 5
Optical emission spectrographic analysis........................... 5
X-ray analysis..................................................... 6
Atomic absorption analysis.... ... ....... ....... ... ... ..... .. . . . . ... 7
Neutron activation analysis... ...... .... ... ... ......... ... .... ... .. 7
Bullion assay. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Prices and fees......................................................... 9
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Appendix A. --State Liaison Offices. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Appendix B. --Coircial assay laboratories.............................. 17
ASSAYING ORES, CONCENTRATES, AND BULLION
by
ABSTRACT
Sharp increases in the world market prices of gold and silver have gen-
erated a renewed interest in prospecting and mining. Almost simultaneously
there has been an upsurge of interest in the platinum-group metals owing not
only to a shortage of these metals but also to prospecting activity--partic-
ulárly in the Western United States. Still another factor contributing to the
booming interest in the noble metals is the recent legislation (Public
Law 93-373) effective December 31, 1974, that permits citizens of the United
States to buy and possess gold. As a result of this situation, many citizens
are seeking informtion and advice regarding investing, prospecting, mining,
milling, refining, and analyzing the noble metals.
Many mineral samples are sent to Governmnt agencies with the request
that they be assayed or chemically analyzed. It should be emphasized that
there are no Federal agencies, except for the U.S. Mints, where assays and
quantitative analyses are made for the public.
The U.S. Mint, Denver, Colo., provides assays of ores for gold, silver,
copper, lead, and zinc. The U.S. Mints also perform assays of gold and silver
bullion. The special services provided, the charges involved, and the loca-
tions of U.S. Mints are presented in the Code of Federal Regulations,
Title 3l--Money and Finance, published by the Office of the Federal Register,
General Services Administration. A copy of this regulation can be obtained
from the Superintendent of Documnts, U.S. Government Printing Office,
Washington, D.C. 20402.
First method: With a hammr, knock off chips of approximately equal size
at regular intervals over the whole width of the mineral occurrence.
Second method: Draw two parallel lines 3 inches apart, marking the width
to be sampled. With a cold chisel, or a moil of tempered steel, cut out a
groove, one-half inch or so in depth, for the whole length between the two
lines. The material thus chiseled out will constitute the sample. It is very
important to carefully collect the whole of the detached material, both chips
and dust, on a sheet of canvas, strong cotton, or cloth.
Chemical Analysis
Although there are many advantages to the use of fire assay, probably
the most important is that there are no ores, concentrates, or alloys that
cannot be analyzed by this method if it is properly performed. Furthermore,
large and, consequently, more representative samples may be analyzed. In
addition, the procedure has excellent sensitivity, less than,O.OOS oz/ton of
gold may be determined, and the method is specific for the noble metals. The
detection limit for each of the platinum group metals is about 0.001 oz/ton,
based on the analysis of an assay ton (29.2 grams) by a fire-as say-
spectrographic procedure. The disadvantages are that the technique is normlly
applied only to the noble metals. It requires more time and therefore is more
costly than som other procedures. It also requires special balances and
furnaces not normlly found in a chemical laboratory.
Optical Emission Spectrographic Analysis
This analysis technique is based upon the principle that when a sample
is heated to high temperature in an electrical arc, causing the sample to be
volatilized completely, each element present in the sample emits a unique
6
X-Ray Analysis
Bullion Assay
The general method of assaying gold bullion is by cupe llation and parting
accompanied by check or proof assays on synthetic alloys corresponding to the
composition and weight of the bullion (2, 10). Therefore, the method usually
requires a preliminary assay to obtain an approximte analysis. As in the
case of silver bullion analysis, the check and bullion samples are cupelled
side by side, and any loss or gain in the check sample, which is called the
surcharge, is applied to the bullion sample. In the parting process, which
separates the silver from the gold, the silver-gold ratio must be kept between
9
The trade generally recognizes three qualities of work. The first and
lowest priced analysis is designated by such terms as routine, engineer's
survey, and preliminary. A higher priced, more careful analysis is called
control, and third and most expensive is called umpire. Unfortunately,
there is no way of setting up standards of quality on the basis of accuracy
because some elements, such as iron or copper, can be determined in the
usual samples with little effort to a high degree of accuracy, whereas others
require time-consuming procedures and great skill, in spite of which accuracy
of results is only fair.
The price ranges listed are typical of the prices being quoted by commr-
cial laboratories as of January 1, 1977, for routine analyses. The listed
values are for single, finely ground samples. An extra charge of $1 to $5
per sample is assessed if the sample has to be prepared for analysis.
Discounts are usually granted if many samples of the same type are submitted
at one time.
Fire Atomic
assav absorDtion
Gold. . . . . . . . . . . . . . . . . . . . . . . $4- $8 $3-$7
Silver..................... 4- 8 3- 7
Gold and silver............ 6- 9 4- 8
Platinum. .. .......... ... ... 20-170 25-35
Platinum-~roun....... . ... .. 7- 30
1A comination fire assay-chemical analysis.
Higher prices are charged for the assay of the richer samples, such as
bullion, sweepings, and jewelry. Control and umpire analyses cost two to
three times the price of routine analyses.
REFERENCES
Alabama Arkansas
State Liaison Office State Liaison Office
Bureau of Mines Bureau of Mines
U. S. Department of the Interior U.S. Department of the Interior
P.O. Box L Room 3331, Federal Office Bldg.
University, Ala. 35486 Little Rock, Ark. 72201
(205) 758-0491 (501) 378-5965
Alaska California
State Liaison Office State Liaison Office
Bureau of Mines Bureau of Mines
U. S. Department of the Interior U.S. Department of the Interior
Room G-8l, Federal Bldg. Room 3046
Anchorage, Alaska 99501 650 Capitol Mall
(206) 442-0151 Sacramento, Calif. 95814
(916) 440-2417
Arizona
State Liaison Office Colorado
Bureau of Mines State Liaison Office
U.S. Department of the Interiar Bureau of Mines
Room 1012 U.S. Departmnt of the Interior
2721 North Central Ave. Room 820, Bldg. 67
Phoenix, Ariz. 85004 Denver Federal Center
(602) 261-3357 Denver, Colo. 80225
(303) 234-4205
13
Connecticut Indiana
See New Hampshire State Liaison Office
Bureau of Mines
Delaware U.S. Department of the Interior
See Maryland Room 113
Seventh and College Sts.
Florida Bloomington, Ind. 47401
State Liaison Office (812) 339-6139
Bureau of Mines
U.S. Department of the Interior Iowa
Room 204 See Mis s ouri
547 North Monroe St.
Tallahassee, Fla. 32301 Kansas
(904) 222-6218 State Liaison Office
Bureau of Mines
Georgia U .S. Departmnt of the Interior
State Liaison Office Suite 220, Federal Bldg./
Bureau of Mines U.S. Courthouse
U.S. Department of the Interior 444 S.E. Quincy
Room 431 Topeka, Kans. 66603
19 Martin Luther King. Jr., Dr., SW (913) 295-2520
Atlanta, Ga. 30334
(404) 221-6204 Kentucky
State Liaison Office
Hawaii Bureau of Mines
See Ca lifornia U.S. Department of the Interior
Room 269
Idaho John C. Watts Federal Bldg.
State Liais on Office 330 West Broadway
Bureau of Mines Frankfort, Ky. 40601
U.S. Department of the Interior (502) 875-4120
Room 203
4620 Overland Rd. Louisiana
Boise, Idaho 83705 State Liaison Office
(208) 384- 1084 Bureau of Mines
U.S. Department of the Interior
Illinois Room 119, Federal Bldg. and
State Liaison Office Courthouse
Bureau of Mines 707 Florida St.
-
V.8. Department of the Interior Baton Rouge, La. 70801
100m 102, Jefferson West No. 1 (504) 387-0181, ext. 374
525 W. Jefferson St.
Springfield, ILL. 62702 Maine
(217) 525-4368 State Liaison Office
Bureau of Mines
U.S. Department of the Interior
P.O. Box 228
Augusta, Maine 04330
(207) 622-6171, ext. 292
14
Maryland Montana
State Liaison Office State Liaison Office
Bureau of Mines Bureau of Mines
U . S. Department of the Interior U.S. Department of the Interior
Columia Plaza 636 North Logan
Room 907 Helena, Mont. 59601
2401 ESt., N.W. (406) 449-5297
Washington, D.C. 20241
(202) 634-1272 Nebraska
See Kansas
Massachusetts
See New Hampshire Nevada
State Liaison Office
Michigan Bureau of Mines
State Liaison Office U.s. Department of the Interior
Bureau of Mines Room 306, Post Office Bldg.
U.S. Department of the Interior 705 North Plaza St.
Room 1121, Comrce Center Bldg. Carson City, Nev. 89701
300 Capitol St. (702) 882-9380
Lansing, Mich. 48933
(517) 372-1910, ext. 681 New Hampshire
State Liaison Office
Minnesota Bureau of Mines
State Liaison Office U.S. Department of the Interior
Bureau of Mines Post Office and Federal Bldg.
U.S. Department of the Interior Newmrket, N.H. 03857
P.O. Box 1660 (603) 659-3101
Twin Cities, Minn. 55111
(612) 725-4535 New Jersey
See Pennsylvania
Mississippi
State Liaison Office New Mexico
Bureau of Mines State Liais on Office
U. S. Department of the Interior Bureau of Mines
Room 408, 301 Bldg. U.S. Department of the Interior
301 North Lamar St. Room 104, U.S. Courthouse/
Jackson, Miss. 39202 Federal Bldg.
(601) 969-4208 Santa Fe, N. Mex. 87501
(505) 988-6624
Missouri
State Liaison Office New York
Bureau of Mines State Liaison Office
U. S. Department of the Interior Bureau of Mines
P.O. Box 1187 U.S. Department of the Interior
Rolla, Mo. 65401 Suite 203
(314) 364-5555 1659 Central Ave.
Albany, N.Y. 12205
(518) 869-9536
15
Oklahom Tennessee
State Liaison Office State Liaison Office
Bureau of Mines Bureau of Mines
U. S. Department of the Interior U.S. Department of the Interior
168 Post Office Bldg. 1109 Parkway Towers
N.W. Third St. 404 James Robertson Parkway
Oklahoma City, Okla. 73102 Nashville, Tenn. 37219
(405) 231-4521 (615) 749-7254
Oregon Texas
State Liaison Office State Liaison Office
Bureau of Mines Bureau of Mines
U.S. Department of the Interior U.S. Department of the Interior
Suite 7, Standard Insurance Bldg. Room 782, Federal Bldg.
475 Cottage St., NE Austin, Tex. 78701
Sa lem, Oreg. 97301 (512) 397-5781
(503) 399-5755
Utah
Pennsylvania State Liaison Office
State Liais on Office Bureau of Mines
Bureau of Mines U.S. Department of the Interior
U.S. Department of the Interior 1600 East First South St.
P.O. Box 783 Salt Lake City, Utah 84112
Federal Square Station (801) 524-5383
Harrisburg, Pa. 17108
(717) 782-4474 Vermont
See New Hampshire
Puerto Rico
See Florida Virginia
See North Carolina
Rhode Is land
See New Hampshire
16
Washington Wisconsin
State Liaison Office See Minnesota
Bureau of Mines
U. S. Department of the Interior Wyoming
Room 205 State Liaison Office
Evergreen Plaza Bldg. Bureau of Mines
711 S. Capitol Way U.S. Department of the Interior
Olympia, Wash. 98501 P.O. Box 1796
(206) 753-9445 Cheyenne, Wyo. 82001
(307) 778-2220, ext. 2481
West Virginia
State Liaison Office
Bureau of Mines
U.S. Departmnt of the Interior
P.O. Box 428
Charleston, W. Va. 25322
(304) 343-6181, ext. 443
Headquarters Office
Washington, D.C.
Kem's Colorado
14039 Eas t Don Julio Rd. Accu-Labs Research, Inc.
La Puente, Calif. 91747 11485 West 48th Ave.
Golden, Colo. 80401
Metallurgical Laboratories, Inc.
1142 Howa rd St. Alan D. Breese, Sr.
San Francisco, Ca lif. 94103 1947 South Decatur St.
Denver, Colo. 80219
Miles D. Romough Laboratories
3069 Del Paso Blvd. Brow Laboratory
Sacramento, Calif. 95815 2263 Broadway
Grand Junction, Colo. 81501
Minerals Engineering
417 South Hill St. Room 1099 CDC Associates, Inc.
Los Angeles, Calif. 90013 5401 Western Ave.
Boulder, Colo. 80301
Morse Laboratories
1525 Fulton Ave. Colorado Analytical Laboratory
Sacramento, Calif. 95825 240 South Main
Brighton, Colo. 80601
19
-
Hawaii Taussig Metallurgical Associates,
None Inc.
6955 North Hamlin
Idaho Chicago, Ill. 60645
Boise Assayers & Metallurgy
1519 Main Indiana
Boise, Idaho 83706 ATEC Associates of Indiana
5150 East 65th St.
Idaho Assaying & Metallurgy Indianapolis, Ind. 46220
707 North 27th
Boise, Idaho 83702 o A Laboratories, Inc.
1437 Sadlier Circle, West Drive
Peter Mack Indianapolis, Ind. 46239
166 King
Wallace, Idaho 83873 Sherry John M. Laboratories
2112 Kilgore Ave.
Silver Valley Laboratory Muncie, Ind. 47304
308 North Taylor
Osburn, Idaho 83849 Iowa
Analytical and Testing Laboratories
Illinois 7004 Carpenter
Charles C. Kawin Company Des Moines, Iowa 50311
2671 Gardner
Broadview, ill. 60153 Patzig Testing Labs, Inc.
2215 Ingersoll
Chicago Spec tro Services Des Moines, Iowa 50311
Labora tories, Inc.
4846 South Kedzie Twin City Testing and Engineering
Chicago, ILL. 60632 Labs, Inc.
529 Logan
Comrcial Testing and Engineering Waterloo, Iowa 50703
Company
228 North LaSa 1 Ie
Chicago, Ill. 60601
21
Kansas Massachusetts
Arrow Laboratories, Inc. Arnold Green Testing Laboratories, Inc.
123 W. 12th East Natick Industrial Park
Wichita, Kans. 67201 6 Huron Dr.
Natick, Mass. 01760
Means Laboratories, Inc.
419 N. Handley Arnold Green Testing Laboratories, Inc.
Wichita, Kans. 67213 2 Millbury St.
Auburn, Mass. 01501
Topeka Testing Laboratories
101 N. Kansas Arnold Green Testing Laboratories, Inc.
Topeka, Kans. 66603 98 Paris St.
Everett, Mass. 02149
Kentuckr
Frazier s Laboratory Arnold Green Testing Laboratories, Inc.
Marion, Ky. 42064 Springfield, Mass. 01104
Maryland Minnesota
Penniman and Browe, Inc. Lerch Brothers, Inc.
6252 Falls Rd. P.O. Box 8
Baltimore Md. 21209 Hibbing, Minn. 55746
West Virginia
Comrcial Testing & Engineering Co.
626 Broad St.
Charleston. W. Va. 25323