23, Write reactions and conditions for the following conversions : (i) 2-Propanone into 2-methyl-2-propanol (ii)_n-Propyl alcohol into n-hexane. 24, Compound ‘A’ with molecular formula C,HyBr is treated with aqueous KOH solution. ‘The rate of this reaction depends upon the concentration of the compound ‘A’ only. When another optically active isomer ‘B of this compound was treated with aqueous KOH solution, the rate of reaction was found to be dependent on concentration of compound and KOH both. (i) Write down the structural formula of both compounds ‘A’ and ‘B’ (ii) Out of these two compounds, which one will be converted to the product with inverted configuration, 25, (a) State how does osmotic pressure vary with temperature. (b) An aqueous solution of glucose boils at 100.02°C. What is the number of glucose molecules in the solution containing 1000 g of water? What will be the osmotic pressure of this glucose solution at 27°C? (Given Ky for H,O = 0.5 K kg mol”!, Ny = 6.02 x 10° mol, R= 0.0821 Latm mol K"!) 26. (i) Name the products obtained when an amide containing three carbon atoms is (a) reduced by LiAIH, (b)_ treated with Br, + KOH. (ii) p-Methoxyaniline is a stronger base than aniline but p-nitroaniline is a weaker base than aniline. Give reason. 27. FeSO, solution mixed with (NH,),SO, solution in 1:1 molar ratio gives the test of Fe* ion but CuSO, solution mixed with aqueous ammonia in 1 : 4 molar ratio does not give the test of Cu2* ion. Explain why? 28. (a) What type of battery is lead storage battery? Write the anode and the cathode reactions and the overall reaction occurring in a lead storage battery. (b)_ What is limiting molar conductivity? SECTION D The following questions are case-based questions. Each question has an internal choice and carries 4 (14142) marks each. Read the passage carefully and answer the questions that follow. 29. Anucleophile attacks the electrophilic carbon atom of a carbonyl compound from a direction perpendicular to the plane of sp” hybridised orbital of carbonyl carbon. ‘The hybridisation of carbon changes from sp” to sp’ in this process and a tetrahedral alkoxide intermediate is produced, ‘This intermediate captures a proton from the reaction medium to give the electrically neutral product. The net result is addition of Nu” and Hi across the carbon oxygen double bond. Nucleophile attacks from the top face Nut abs x] Se Fa sar fh] Ma Planar Tetrahedral intermediate Addition product Answer the following questions : (a) Benzaldehyde is les reactive than acetaldehyde towards nucleophilic substitution reaction, Why? oR (a) The reaction of carbonyl compound with pure HCN is very slow and becomes fast in presence of a base. (b) What is the role of dry HCI in the addition of alcohol to carbonyl group? (©) Aldehydes are more reactive than ketones towards nucleophiles, 30, ‘The quantitative relationship between rate constant of a reaction and temperature proposed by Arrhenius is known as arrhenius equation. es ‘The rate constant of a reaction at any given temperature Tis given by Arrhenius equation k= ActAT fi) where, k= Rate constant of a reaction Ce Class 12A= Arrhenius factor ot frequency factor. Its value is constant for a particular reaction. . E, = Activation energy (Joules/mole) R= Gas constant. ‘Taking logarithm of equation (i) Or pnt! -E,(1 Ink =InA- 35 or Ink = (z}+ima Answer the following questions : (a) Define activation energy of a reaction. (b)_ What is the effect of adding a catalyst on Activation energy (E,) (c) A reaction proceeds five times more at 60°C as it does at 30°C. Estimate energy of activation. OR ‘The rate constant of a first order reaction increases from 2x 10°? to 4 x 10"? when the temperature changes from 300 K to 310 K. Calculate the energy of activation (E,). (log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021) SECTION E The following questions are long answer type and carry 5 marks each. All questions have an internal choice. 31. Attempt any five of the following: (a) Name two disaccharides which are reducing sugar. (b) How is glucose and galactose linked in lactose? (©) Name the components of starch. (4) What type of linkage holds together the monomers (nucleotide) of DNA? (©) Whatis the difference between a nucleoside and nucleotide? (8) Whats the effect of denaturation on the structure of protein? (g)_ What do you mean by primary structure of protein? 32. (a) Transition metals can act as catalysts because these can change their oxidation state. How does Fe(III) catalyse the reaction between iodide and persulphate ions? (b) Mention any three processes where transition metals act as catalysts. (©) The outer electronic configuration of two members of the lanthanoids are as follows : af! 5d! 6s? and af Sd° 6s. What are their atomic numbers? Predict the oxidation states exhibited by these elements in their compounds. OR (a) In what way is the electronic configuration of the transition elements different from that of the non-transition elements? (b) Explain (i) Why is europium (11) more stable than cerium (11)? (i) Why is +3 oxidation state of gadolinium (Z = 64) and lutetium (Z = 71) especially stable? 33. (i) Calculate e.m,fand AG for the cell : Mgiy | Mg”* (0.001 M) || Cu* (0.0001 M) | Cuy Elsagt nag) 227 VF yey FOV (ii) Give reason : Conductivity of CHyCOOH decreases on dilution, OR | (i) The E° values in respect of electrodes of chromium (Z = 24), manganese (Z = 25) and iron (Z = 26) are: | Cr*/Cr°* = - 0.4 V ;Mn™*/Mn** = + 1.5 V ; Fe/Re?* = 0.8 V. On the basis of the above information ‘compare the feasibilities of further oxidation of their + 2 oxidation states. | (i) Calculate standard electrode potential for the half-cell Fe** + 3¢" == Fe from the following data : Fel? +e Fe" B= 0.77V | Fe™* + 2c" Fe; B= -044V Chemistry reSubject Code: 043 CHEMISTRY Time Allowed : 3 Hours Maximum Marks : 70 General Instructions : Read the following instructions carefully. (a) () ) (@ CO) o @ (h) ‘There are 33 questions in this question paper with internal choice. SECTION A consists of 16 multiple-choice questions carrying I mark each SECTION B consists of 5 short answer questions carrying 2 marks each. SECTION C consists of 7 short answer questions carrying 3 marks each. SECTION D consists of 2 case-based questions carrying 4 marks each, SECTION E consists of 3 long answer questions carrying 5 marks each. Alll questions are compulsory. Use of log tables and calculators is not allowed. SECTION A The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. ‘The conversion of m-nitrophenol to resorcinol involves respectively (@) hydrolysis, diazotization and reduction _—_(b)_diazotization, reduction and hydrolysis (©) hydrolysis, reduction and diazotization _ (4) reduction, diazotization and hydrolysis. ‘The final product P in the following reaction is PhMgBr + CO, 2° p (a) acetophenone (b)_ benzene (©) benzoic acid (A) phenol. Which of the following ions are colourless? Ti, Sc*, Ag’, Cd?*, Cu?* 1 on om wey (a) Tand V only (b) 11,11 and IV only (©) 1, Uland V only (@) Mand IV only ‘Variation of resistance with increase in I/A gives graph of the type " i () : (a) (b) ) i (d) i i i l =, u> ee ua Class 125. Which of the following is the correct structure of maltose? 6. Which of the following gives Hell-Volhard-Zelinsky (HVZ) reaction? (a) CH;CHO (b) HCHO (0) CH,COOH (4) CH,COCH, 7. Consider the following reaction : 2A +B + C—+ Products How will the rate of reaction change when the concentration of A is doubled and that of B is tripled while Cis taken in excess? (a) The rate reduces to 8 times of its original value. (b) The rate reduces to 12 times ofits original value. (©) The rate increases by 8 times ofits original value. (4) The rate increases by 12 times ofits original value. 8 Mn,(CO);9 isan organometallic compound due to the presence of (@) C—Obond (>) Mn—O bond (© Mn—Cbond (4) Mn—Mn bond 9. Product Cin the reaction, C,H,Br OH, 4 Bp SH, c will be (a) propane (b) ethyl iodide (©) ethane (d)_ ethyl methyl ether. 10. Cu’ ion is not stable in aqueous solution because (a) Cu?* (qq) is less stable than Cu" aq) (b) Cu** (aq) can form interstitial compounds in aqueous solution (©) the equilibrium constant for + Cu (aq) + Cu is very high @ 11, CHjCH, —C — CH, cannot be prepared by 1 Ph (a) PhCOCH, + CH;CH.MgX (b) HCHO + PhCH(CH;)CH,MgX (©) PhCOCH,CH, + CHsMgX (@_CH,CH,COCH, + PhMgx Chemistry Res12, -NH2group in aniline is (a) m-directing and deactivating (b) 0, p-directing and deactivating (©) 0, p-directing and activating (d)_m-directing and activating. 13. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : For the first order reaction, half-life period is expressed as (1), = ad log 2. Reason (R) : The half-life period of a first order reaction is not always constant and it depends upon the initial concentration of reactants, Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (0) Aistrue but Ris false, (d) A is false but R is true. 14. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : First nine aliphatic monocarboxylic acids are colourless, Reason (R) : Carboxylic acids with more than five carbon atoms are highly soluble in water. Select the most appropriate answer from the options given below: (a) Both A and R are true and Ris the correct explanation of A. (b) Both A and Rare true but R is not the correct explanation of A. (©) Aistrue but R is false. (d) Ais false but R is true. 15. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : -Amino acids exist as dipolar ions or zwitter ions. Reason (R) : d-Amino acids are the building blocks of proteins. Select the most appropriate answer from the options given below: (a) Both A and Rare true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (Q) Aistrue but R is false. (d) Ais false but R is true. 16. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : The [Ni(en);]Cl, has higher stability than [Ni(NH3),]Cl, Reason (R) : In [Ni(en)s]Cl,, the geometry around Ni is octahedral. Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (6) Both A and R are true but R is not the correct explanation of A. (c) Aistrue but Ris false. (d) Ais false but R is true. SECTION B This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. Illustrate the following reactions giving suitable example in each case ()Ammonolysis (ii) Acetylation of amines Cla18. 19. 20. 2. Give reasons : (i) Racemic mixture is optically inactive, (ii) The presence of nitro group (—NO,) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions. ‘What is meant by pyranose structure of glucose? Complete the following chemical equations : (MnO ¥(aq) + S:0¥aq) + HzO) > (i) Cr OFaq) + Fey + Hag) > oR ‘What happens when (W__ potassium dichromate reacts with sulphur dioxide in acidic medium? (ii) potassium dichromate reacts with Mohs salt in presence of dil. H,S0,? For the reaction A + B > C + D, AH = 20kJ mol". If activation energy of the forward reaction is 85 kJ/mol, calculate the activation energy of the reverse reaction. SECTION C This section contains 7 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each. 22. Chemistry Assign reason for each of the following : (i) Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4, (ii) E° for Mn™*/Mn** couple is more positive than for Fe**/Fe*. (iii) “The transition elements form interstitial compounds. (a) Express the relationship between the rate of production of HCI and the rate of disappear -ance of H, in the following reaction : H+ Cl, > 2HCI (b) The rate of formation of a dimer in a second order dimerisation reaction is 9.5 x 10°° mol L"! s at 0.01 mol L"' monomer concentration. Calculate the rate constant. Answer the following questions (any 2) : (a) Write the structure of the product when chlorobenzene is treated with methyl chloride in the presence of sodium metal and dry ether. (b) Write the structures ofthe alkene formed by dehydrohalogenation of 1-bromo-1-methylcyclohexane with alcoholic KOH. (©) A chloro derivative (A) on treatment with zinc-copper couple gives a hydrocarbon with five carbon atoms. When (A) is dissolved in ether and treated with sodium then 2, 2, 5, 5 -tetramethylhexane is obtained. What is the original compound (A)? Chromium metal is electroplated using an acidic solution containing CrO according to the following equation : CrOsiqq) + 6H? + 6€” —> Cry) +3H,0 Calculate how many grams of chromium wil be electroplated by 24,000 coulombs. How long will it take to electroplate 1.5 g chromium using 12.5 A current? [Atomic mass of Cr = 52.g mol", 1 F = 96500 C mol"!}26, Give the structures of products A, B and Cin the following reactions KON, | ual @ CHCH,Be “Sp 4 yy HNO, 6 xu * (i) CH,COOH-TH> 4 MOH eBs, 5 _cHey ele nvoHt , 27. (a) Define reverse osmosis, (b) What happens when a peeled egg is placed in a 10% aqueous solution of NaCl? (©)_ Why do mechanics suggest to add ethylene glycol in car radiators? 28, (a) Amino acids show amphoteric behaviour. Why? (b) Write one difference between a-helix and f-pleated structures of proteins. SECTION D The following questions are case-based questions. Each question has an internal choice and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that follow. 29. The reactions of phenol with metals and sodium hydroxide indicate its acidic nature. The hydroxyl group, in phenol is directly attached to the sp* hybridised carbon of benzene ring which acts as an electron withdrawing. group. Duc to this, the charge distribution in phenol molecule, as depicted in its resonance structure, causes the oxygen of -OH group tobe positive. The reaction of phenol with aqueous sodium hydroxide indicates that phenols are stronger acids than alcohols and water. Phenol also reacts with carboxylic acids, acid chlorides and acid anhydrides to form esters. Answer the following questions : (a) Phenols are stronger acids than alcohols, why? OR Draw resonance structures of phenol and phenoxide ion. (b)_ Whatis aspirin? How is aspirin prepared? (©) How do you convert the following : (i) Phenol to anisole (ii) Phenol to 2-hydroxybenzoic acid 30. Colligative properties depend on the number of solute particles irrespective on their nature, they are, relative lowering in vapour pressure, elevation in boiling point, depression in freezing point and osmotic pressure. Abnormal molecular weights and colligative properties are observed in some cases where the experimental and theoretical values differ considerably. Due to dissociation of solute in water (solvent) the number of particles in the solution increases, resulting in increase in experimental values, since 1 Molecular weight Experimental molecular weight < Normal molecular weight. Answer the following questions : (a) Why is osmotic pressure considered as a coligative property? (b) What happens when a pressure greater than osmotic pressure is applied on the solution side separated from solvent by a semi-permeable membrane? (6) Write two advantages of osmotic pressure method over boiling point elevation method for determining molecular masses. Colligative property = OR Calculate the boiling point of solution when 4 g of MgSO, (M = 120 g mol") was dissolved in 100 g of water, assuming MgSO, undergoes complete ionization. (K;, for water = 0.52 K kg mol") SOR CuesSECTION E ‘The following questions are long answer type and carry $ marks each. All questions have an internal choice, 3. 32. 33, Chemistry Attempt any five of the following: (a) Write the names of the following complexes using IUPAC norms : (i) Nas[AIF¢] (ii) [CoCKen),(ONO)|C1 (b) What is crystal field splitting? (©) Explain the difference between a weak field ligand and a strong field ligand. (d) How many ions are produced from the complex, [Co(NH3)¢]Cl; in solution? (e) Which isomer, cis- or trans- of the complex {Co(en);Cl]*, does not show optical isomerism? (f) The magnetic moment of a transition metal ion is found to be 3.87 B.M. Calculate the number of unpaired electrons present init. (g) Arrange the following complexes in order of increasing electrical conducti (Co(NH5) Cls],(Co(NH,),CIJCl,[Co(NH;).]Cls, (Co(NH;),Ch]Cl (a) _Accidently chewing ofa stray fragment of aluminium foil can cause a sharp tooth pain if the aluminium ‘comes in contact with an amalgam filling. An electric current passes from the aluminium to the filling (of cavity), which is sensed by a nerve in the tooth. Based on the above passage, answer the following questions. How does electric current pass? ‘Write balanced equations taking placed at anode, cathode and overall. ‘Write the Nernst equation in a form that applies at body temperature (37°C). Calculate E.. at 37°C, [Al’*] = 1.0 x 10M, Po, = 0.20 atm in a saliva that has a pH of 7.0. 89V ty: (b) ‘On the basis of E* values, O, gas should be liberated at anode but it is Cl, gas which is liberated in the electrolysis of aqueous NaCl. OR (a) A steady current of 2 amperes was passed through two electrolytic cells X and ¥ connected in series containing electrolytes FeSO, and ZnSO, until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y. (Molar mass : Fe = 56 g mol", Zn = 65.3 g mol, 1 F = 96500 C mol") (b) Why does silver nitrate solution becomes bluish when copper rod is placed in it? (a) Give a chemical test to distinguish between the following : (i Benzoic acid and ethyl benzoate (ii) Benzophenone and acetophenone, (b) Complete the following reaction : on = aa, ‘coon (©) Identify A, B and Cin the following sequence: COOH Co + NH, AEs BSP ‘COOH OR Write down functional isomers of a carbonyl compound with molecular formula CH,0. Which isomer will react faster with HCN and why? Explain the mechanism of the reaction also, Will the reaction lead to the completion with the conversion of whole reactant into product at reaction conditions? If a strong acid is added to the reaction mixture what wll be the effect on concentration of the product and why?Subject Code: 043 CHEMISTRY Time Allowed : 3 Hours Maximum Marks: 70 General Instructions : Read the following instructions carefully. (a) @) © @ © oO @ h) ‘There are 33 questions in this question paper with internal choice. SECTION A consists of 16 multiple-choice questions carrying 1 mark each. SECTION B consists of 5 short answer questions carrying 2 marks each. SECTION C consists of 7 short answer questions carrying 3 marks each. SECTION D consists of 2 case-based questions carrying 4 marks each. SECTION E consists of 3 long answer questions carrying 5 marks each, Alll questions are compulsory. Use of log tables and calculators is not allowed. SECTION A ‘The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. Which of the following plots correctly represents variation of molar conductance (A) with dilution for a weak electrolyte? ‘Concentration Concentration he An © @ oF Concentration Concentration “The synthesis of alkyl fluorides is best accomplished by (a) Finkelstein reaction (b)_ Swarts reaction (©) Free radical fluorination (4). Sandmeyer's reaction. ‘Among the following series of transition metal ions, the one where all metal ions have 3d” electronic configuration is (a) Tv, Ce*,Ma* () TV", Cr, Mn”* ( T,v*,cP*, Mn (@) TH*,V*, Cr, Mn? Which of the following is the correct representation of relative lowering of vapour pressure? pe Pe -P ) AP _P-P° o Pe PP. @ ap_p°-P @ PP PP AP p_p po pe Class 125. Among the following which is least acidic? (a) Phenol (0) 0-Cresol (©) p-Nitrophenol — (d)_p-Chlorophenol (6 _ Predict the order of, for the following compounds and select the correct option. 1, [Re(H,O)6)" TL. [e(CN),(H,0),] M11. [Fe(CN),(H,0),1” @ M P, the variation in the concentration [R] vs. time (is given then IN => (i) _ predict the order of the reaction. l) what is the slope of the curve? Lili) Give one example of such type of reactions. OR (i) Fora reaction, A + B > product, the rate law is given by, rate = k[A]'[B]*. What is the order of the reaction? (ii) Write the integrated rate expression and unit of rate constant‘ for the first order reaction. 18, ‘The vapour pressure of pure benzene at a certain temperature is 640 mm Hg. A non-volatile, non-electrolyte solid weighing 2.175 g is added to 39.0 g of benzene. The vapour pressure ofthe solution is 600 mm Hg. What is the molar mass of solid substance? 19. The geometry of [Ni(CO)4] is not same as that of [Ni(CN),]*. Give reason. 20. How are the following reactions carried out? Write the equations and conditions, (i) Acetic acid to ethylamine (ii) Bromocyclohexane to cyclohexanamine. 21. What are the points of differences between Sy1 and Sy? reactions? eras) paseSECTION C ‘This section contains 7 questions with internal choice in one question. ‘The following questions are short answer type and carry 3 marks each, 22. Calculate the depression in freezing point of water when 20.0 g of CHsCH,CHCICOOH is added to 500 g of water. [Given : Ky = 1.4 x 10°, Ky= 1.86 K kg mol” !] 23. Compound (A) with molecular formula, C,HsBr was treated with aq. KOH solution. The rate of this reaction depends upon the concentration of the compound ‘A’ only. When another optically active isomer ‘B° of this compound was treated with aq. KOH solution, the rate of reaction was found to be dependent on the concentration of compound and KOH both. (i) Write down the structural formula of both compounds ‘A’ and ‘B: (ii) Out of these two compounds, which one will be converted to the product with inverted configuration? 24, (a) How will you prepare picric acid from phenol? () Explain (i) Reimer-Tiemann reaction. (ii) Kolbe reaction. 25. Suggest chemical reactions for the following conversions : (a) Aniline to benzoic acid, (b) n-Hexanenitrile to 1-aminopentane. (©) p-Chloroaniline to p-chlorobenzylamine. 26, The electrical resistance of a column of 0.05 M NaOH solution of diameter 1 cm and length 50 cm is 5.5 x 10° ohm, Calculate its resistivity, conductivity and molar conductivity. 27. Write the structures of compounds A, B and Cin each of the following reactions : ©) Cabigpr MEATS, 4 BOS BC (i) CHCN-SEIEG, 4 aL NWOH, gd, ¢ 28, Explain the following cases giving appropriate reasons (any 2) : (i) _ Nickel does not form low spin octahedral complexes. i) The n-complexes are known for the transition metals only. (ii) Co”* is easily oxidised to Co™ in the presence of a strong ligand. SECTION D The following questions are case-based questions. Each question has an internal choice and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that follow. 29, The rate of reaction is directly proportional to the product of the define mass (molar concentration) of the reactants raised to powers equal to the numbers of their respective molecules in the stoichiometric equation describing the reaction. A + B—> C + D, Rate « [A] (B], Rate = k{A] [B] (Law of mass action) ‘Where, k is constant of proportionality or rate constant. If [A] = [B] = 1 then rate of reaction = k So, rate constant is the rate of the reaction when concentration of each of the reactants is unity. It is also known as specific rate. Consider a general reaction, A + bB + cC—> product Rate = k [A]? [B] [C] (law of mass action) Rate = k [A]? [B] [CI (rate law expression) P.qand rare determined experimentally and may or may not be equal to a, b and c. p,q, r represents the order of reaction with respect to A, B,C. Chemistry SES(a) Fora reaction A + B— P, the / reKal tale the rate law is given by, What is the order of this reaction? (>) Explain why the rate of a reaction in the remaining mixture is not affected when a portion is removed for analysis. (©) The gas phase decomposition of acetaldehyde, CH CHO@ —+ CHyg) + CO follows the rate expression : Rate = -d[CHsCHO] / dt = k|CH;CHO}?” In terms of the partial pressure of acetaldehyde, it can be expressed as eA Heevo =Kpcucu0)? If the pressures are measured in the units ‘of atmosphere and time in minutes then, (i) what is the unit of rate of reaction? (ii) what is the unit of the rate constant, k? OR ‘The rate constant for a first order reaction is 60 s"!. How much time will it take to reduce the initial concentration of the reactant to its 1/16" value? 30. In semicarbazide the lone pair of nitrogen attached to carbonyl group is involved in resonance and not available for attack on the electrophilic centre. Hence 2™ nitrogen attacks on the carbonyl carbon. e és HN tuoi dN NM ot, All the products i-e., oxime and hydrazones are crystalline solids with sharp melting points. Therefore these reactions are used for identification and characterisation of aldehydes and ketones. ‘These derivatives can be decomposed by boiling with dilute mineral acids to regenerate the original carbonyl compounds. Therefore these derivatives are used for the purification and separation of aldehydes and ketones. (a) Give chemical reaction to illustrate the acylation reaction. (b) How is the following obtained : 2-Phenyl-2-butanol from acetophenone. (c)_ What happens when CH;CHO reacts with HCN and the products are hydrolysed? Give chemical ‘equation and state whether the product formed is optically active or not and why? OR ‘Complete the following equations : (i) +CHyCHO + C,H;NHNH; > (i, 3(CH,),.C=0 SH, SECTION E ‘The following questions are long answer type and carry 5 marks each. All questions have an internal choice. 31. Attempt any five of the following. @) Mention two main functions of earboydrates in plant. (b) Give one example each for reducing and non-reducing sugars, (©) Which of the two components of starch is water soluble? (4) Amino acids may be acidic, alkaline or neutral. How does this happen? (©) Write the name of linkage joining two amino acids. (), Write down the structure of sugar present in DNA. (g) | What are the products of hydrolysis of sucrose? EE Sareitt32. (a) Account for the following : (i) Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4. (ii) Cr** isa strong reducing agent. (ili) Cu?* salts are coloured while Zn” salt are white. (b) Complete the following equations : () 2MnO, + 4KOH +0,-4 (il) Cr,0,?" + 14H + 6 —> OR (a) Following are the transition metal ions of 3d series : Ti, V*, Mn, Cet (Atomic numbers : Ti = 22, V = 23, Mn = 25, Cr = 24) Answer the following : (Which ion is most stable in aqueous solution and why? (i) Which ion is strong oxidising agent and why? (iii) Which ion is colourless and why? (b) Complete the following equations : (i) 2MnO; + 16H* + 58> —> (i) KMno, 45 33, (a) State Kohlrausch’s law of independent migration of ions. How can the degree of dissociation of acetic acid in a solution be calculated from its molar conductivity data? (b) (i) Formulate the electrochemical cell representing the reaction : 2Crig) + 3Pefdy) > 2Cria + IF) (ii) Calculate Fey. (iii) Calculate Egy at 25°C if [Cr**] = 0.1 Mand Fe** = 0.01 M. [Given : ec, = -0.74 Vi Bb asp, = 0.44 V) OR Write the cell reaction and calculate the e.m., of the following cell at 298 K ‘Snip | Sn** (0.004 M) || H* (0.020 M) | Hyyp(1 bar) | Pty (Given : Bq2%/5q = -0.14V) (b) Give reasons : (®) On the basis of E values, O, gas should be liberated at anode but itis Cl, gas which is liberated in the electrolysis of aqueous NaCl. (ii) Conductivity of CHsCOOH decreases on dilution. Chemistry PannaSubject Code: 043 CHEMISTRY Time Allowed : 3 Hours Maximum Marks : 70 General Instructions : Read the following instructions carefully. (@) There are 33 questions in this question paper with internal choice. (b) SECTION A consists of 16 multiple-choice questions carrying ! mark each, (©) SECTION B consists of 5 short answer questions carrying 2 marks each, (a) SECTION C consists of 7 short answer questions carrying 3 marks each. (¢) SECTION D consists of 2 case-based questions carrying 4 marks each. (P_ SECTION E consists of 3 long answer questions carrying 5 marks each. @ All questions are compulsory. (h) Use of log tables and calculators is not allowed. SECTION A ‘The following questions are multiple-choice questions with one correct answer. Each question carries A mark. There is no internal choice in this section. 1. Which of the following solutions will have the highest conductivity at 298 K? (@) 0.01 M HCI solution (b) 0.1 MHC solution (©) 0.01 MCH;COOH solution (@_0.1MCH,COOH solution a sen i8Ot, O) comcet Identify A and B, (@) A= 1-Phenylethanal, B= Acetophenone (b), A= Benzophenone, B= Formaldehyde (©) A=Benzaldehyde, B= Acetophenone (d)_ A=Benzophenone, B= Acetophenone 3. The vitamins which can be stored in our body are (a) Vitamin A, B, D and E (b) Vitamin A, C, D and K (©) Vitamin A,B, Cand D (@)_ Vitamin A, D, E and K. 4, Whatis IUPAC name of the ketone A, which undergoes iodoform reaction to give CH;CH=C(CH3)COONa and yellow precipitate of CHI;? (a) 3-Methyipent-3-en-2-one (b) 3-Methyibut-2-en-one (©) 2,3-Dimethylethanone (@)_3-Methylpent-4-one 5. Which of the following is not correct? (a) Imhaloarenes, the electron pairs on halogen atom are in conjugation with n-electrons of the ring. (©) The carbon-magnesium bond is covalent and non-polar in nature. (©), During $y1 reaction, the carbocation formed in the slow step being sp* hybridised is planar. (d) Out of CHj=CH—Cl and CgHsCH,Cl, CeHsCH,C1 is more reactive towards Sy1 reaction. Sag Class 12a ‘Chemistry Match the properties with the elements of 3d series: (i) Lowest enthalpy of atomisation (p) Se (ii) Shows maximum number of oxidation states. (q)_ Mn (iil) Transition metal that does not () Zn form coloured compounds 6) Ti (a) (i)-(r), (Hi)-(q), (iti)-(p) (b) (i)-(2), (ti)-(s), (iti)-(p) (©) G)-(p), (ii)-(q), (iit)-(r) (4) (i)-(s), (ii)-(2), (iti) -(p) Which of the following statement is true? (a) Molecularity of reaction can be zero or a fraction. (b) Molecularity has no meaning for complex reactions. (c)_ Molecularity of a reaction is an experimental quantity. (d) Reactions with the molecularity three are very rare but are fast. In which of the following solvents, the C\HyNH}X is soluble? (a) Ether (b) Acetone (©) Water (d) Bromine water Which of the following observation is shown by 2-phenyl ethanol with Lucas reagent? (a) Turbidity will be observed within five minutes. (b) No turbidity will be observed. (©) Turbidity will be observed immediately. (d) Turbidity will be observed at room temperature but will disappear after five minutes. |. If the initial concentration of substance A is 1.5 M and after 120 seconds the concentration of substance A is 0.75 M, the rate constant for the reaction ifit follows zero - order kinetics is (a) 0.00625 mol L-'s* (b) 0.00625 s* (©) 0.00578 mol L“'s* (d) 0.00578 =. |. Anisole undergoes bromination with bromine in ethanoic acid even in the absence of iron (III) bromide catalyst (a) Due to the activation of benzene ring by the methoxy group. () Due to the de-activation of benzene ring by the methoxy group. (c) Due to the increase in electron density at ortho and para positions. (@) Due to the formation of stable carbocation. ‘The trend of which property is represented by the following graph? ScTi V Cr Mn Fe Co Ni Gu Za (a) Ionization enthalpy (b) Atomic radii (©) Enthalpy of atomization (€) Melting point Given below are two statements labelled as Assertion (A) and Reason (R).. Assertion (A) : Alcohols react both as nucleophiles and electrophiles. Reason (R) : The bond between C-0 is broken when alcohols react as nucleophiles.‘ Select the most appropriate answer from the options given below: @) Both A and R are true and Ris the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (c) Ais true but R is false. a(@) Ais false but Ris true. 14. Given below are two statements labelled as Assertion (A) and Reason (R). _ Assertion (A) : Strong oxidising agents oxidise toluene and its derivatives to benzoic acids. Reason (R) It is possible to stop the oxidation of toluene at the aldehyde stage with suitable reagents, «Select the most appropriate answer from the options given below: a(a)_ Both A and Rare true and Ris the correct explanation of A. (b) Both A and R are true but Ris not the correct explanation of A. (©) Aistrue but Ris false. “(d) Ais false but Ris true, 15. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : Enzymes are very specific for a particular reaction and for a particular substrate. Reason (R) : Enzymes are biocatalysts, Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. s(b) Both A and R are true but R is not the correct explanation of A. a(c) Aistrue but Ris false. (@)_Aisfalse but R is true. 16. ,Given below are two statements labelled as Assertion (A) and Reason (R), Assertion (A) : During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen ‘gas is released at the cathode. ‘Reason (R) : The electrode potential of Cu?"/Cu is greater than that of H*/H. Sclect the most appropriate answer from the options given below: “{a) Both A and Rare true and Ris the correct explanation of A. Ris half order wart. ‘P’ and zero order wrt.“ of rate constant for this reaction? 18. 4A 5% solution of Na;SO,:10H,0 (M.W. = 322) is isotonic with 2% solution of non-electrolytic, non-volatile substance X. Find out the molecular weight of X. 19. (a) Arrange the isomeric dichlorobenzene in the increasing order of their boiling point and melting points. (b) Explain why the electrophilic substitution reactions in haloarenes occur slowly and require more drastic + conditions as compared to those in benzene. 20. %(a) Out of p-tolualdehyde and p-nitrobenzaldehyde, which one is more reactive towards nucleophilic addition reactions, why? 4b) Write the structure of the product formed when acetone reacts with 2,4-DNP reagent. a Class 12 ”: What is the unitConvert the following : (a) Benzene to m-nitrobenzaldehyde (b) Bromobenzene to benzoic acid 21. (a) DNA fingerprinting is used to determine paternity of an individual. Which property of DNA helps in the procedure? (b) What structural change will occur when a native protein is subjected to change in pH? SECTION C ‘This section contains 7 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each. 22, (a) Write the formula for the following coordination compound : Bis(ethane-1,2-diamine) dihydroxidochromium(II1) chloride (b) Does ionization isomer for the following compound exist? Justify your answer. Hg[Co(SCN),} (c)__Is the central metal atom in coordination complexes a Lewis acid or a Lewis base? Explain. 23. (a) Can we construct an electrochemical cell with two half-cells composed of ZnSO, solution and zinc electrodes? Explain your answer. (b) Calculate the 3, for CI" ion from the data given below: ‘AS, MgCl, = 258.6 S cm? mol"! and A%, Mg”* = 106 $ cm” mol (©) The cell constant of a conductivity cell is 0.146 cm”. What is the conductivity of 0.01 M solution of an electrolyte at 298 K, if the resistance of the cell is 1000 chm? 24, Write the name of the reaction, structure and IUPAC name of the product formed when (any 2): (a) phenol reacts with CHCl; in the presence of NaOH followed by hydrolysis. (b) | CHsCH,CH(CH,)CH(CH,)ONa reacts with CyH or [CrBg]** and why? (Given : If 560-570 nm of light is absorbed, the colour of the complex observed is violet.) (©) If the ligands attached to Cr** ion in the complexes given in the table above are water, cyanide ion, chloride ion, and ammonia (not in this order) Identify the ligand, write the formula and IUPAC name of the following : [Crag (i) (ere) 30. Thelead-acid battery represents the oldest rechargeable battery technology. Lead acid batteries can be found in a wide variety of applications including small-scale power storage such as UPS systems, ignition power sources for automobiles, along with large, grid-scale power systems. The spongy lead act as the anode and lead dioxide as the cathode. Aqueous sulphuric acid is used as an electrolyte. The half-reactions during discharging of lead storage cells are : Anode : Pb) + SO%aq) > PSOyi,) + 2e~ Cathode : PbO 24.) + 4H fag) +SO%aq) + 26” > PbSOq( + 2H,0 “There is no safe way of disposal and these batteries end-up in landfills. Lead and sulphuric acid are extremely hazardous and pollute soil, water as well as air. Irrespective of the environmental challenges it poses, lead- acid batteries have remained an important source of energy. Designing green and sustainable battery systems as alternatives to conventional means remains relevant. Fuel cells are seen as the future source of energy. Hydrogen is considered a green fuel. Problem with fuel cells at present is the storage of hydrogen. Currently, ammonia and methanol are being used as a source of hydrogen for fuel cell. These are obtained industrially, so add to the environmental issues, Ifthe problem of storage of hydrogen is overcome, is it still “green fuel?” Despite being the most abundant ‘element in the Universe, hydrogen does not exist on its own so needs to be extracted from the water using electrolysis or separated from carbon fossil fuels. Both of these processes require a significant amount of ‘energy which is currently more than that gained from the hydrogen itself. In addition, this extraction typically requires the use of fossil fuels. More research is being conducted in this field to solve these problems. Despite the problem of no good means to extract hydrogen, itis uniquely abundant and renewable source of energy, perfect for our future zero-carbon needs. Answer the following questions : (a) How many coulombs have been transferred from anode to cathode in order to consume one mole of sulphuric acid during the discharging of lead storage cell? TED) Class 12(b) How much work can be extracted by using lead storage cel ifeach cell delivers about 2.0 V of voltage? (1 F = 96500C) (c)_ Do you agree with the statement ~ “Hydrogen is a green fuel” Give your comments for and against this statement and justify your views. OR Imagine you are a member of an agency funding scientific research. Which of the following projects will you fund and why? (i) Safe recycling of lead batteries (ii) Extraction of hydrogen SECTION E ‘The following questions are long answer type and carry 5 marks each. All questions have an internal choice. 31, Attempt any five of the following : (a) Which of the following ions will have a magnetic moment value of 1.73 BM. so TH, TH" cu” fn? (b) In order to protect iron from corrosion, which one will you prefer as a sacrificial electrode, Ni or Zn? Why? (Given: standard electrode potentials of Ni, Fe and Zn are -0.25 V, -0.44 V and -0.76 V respectively.) (©) The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Ma. (d)_ Give two similarities in the properties of Sc and Zn. (e) What is actinoid contraction? What causes actinoid contraction? (£)_ What is the oxidation state of chromium in chromate ion and dichromate ion? (g) Write the ionic equation for reaction of KI with acidified KMnO,. 32. (a) Whats the effect of temperature on the solubility of glucose in water? (b) Ibrahim collected a 10 mL each of fresh water and ocean water. He observed that one sample labelled “P” froze at 0°C while the other “Q" at -1.3 °C. Ibrahim forgot which of the two, “P” or “Q” was ocean ‘water. Help him identify which container contains ocean water, giving rationalization for your answer. (©) Calculate van't Hoff factor for an aqueous solution of K3{Fe(CN)4] if the degree of dissociation (ct) is (0.852. What will be boiling point of this solution if its concentration is 1 molal? (K,=0.52 K kg/mol) oR (a) What type of deviation from Raoult’s Law is expected when phenol and aniline are mixed with each other? What change in the net volume of the mixture is expected? Graphically represent the deviation. (b) ‘The vapour pressure of pure water ata certain temperature is 23.80 mm Hg, If | mole of a non-volatile nnon-electrolytic solute is dissolved in 100 g water, calculate the resultant vapour pressure of the solution. 33. An organic compound with molecular formula C;H,NO) exists in three isomeric forms, the isomer ‘A’ has the highest melting point of the three. ‘A” on reduction gives compound ‘B’ with molecular formula C7HN. ‘B’ on treatment with NaNO,/HCI at 0-5 °C to form compound ‘C: On treating C with HyPO,,it gets converted to D with formula C7Hy, which on further reaction with CrO,Cl, followed by hydrolysis forms ‘E’ C,HgO. Write the structure of compounds A to E. Write the chemical equations involved. oR (a) Account for the following (i) N-ethylbenzenesulphonyl amide is soluble in alkali : (ii) Reduction of nitrobenzene using Fe and HCl is preferred over Sn and HCL. (b) Arrange the following in (i) decreasing order of pK, values: CgHsNH3, CgHsNHCH,, CgHsCH,NH;, CHjNH, NH (ii) increasing order of solubility in water : CHCl, CHsNH3, CyH;OH (iii) decreasing boiling point : CH;COOH, C,HsOH, CH,NH;, CH;OCH, Chemistry MIE