10. 1. 12. 13, 4. ‘Which factor has no influence on the rate of reaction? (a) Molecularity (b) Temperature (c) Concentration of reactant (d) Nature of reactant ‘Which of the following statements is not correct for amines? (a) Most alkyl amines are more basic than ammonia solution, (>) pK, value of ethylamine is lower than benzylamine. (c)_ CHyNH; on reaction with nitrous acid releases NO. gas. (a) Hinsberg’s reagent reacts with secondary amines to form sulphonamides. What te the freezing point of a 0.5 m KCI solution? The molal freezing point constant of water is (a) -1.86°C (b) -0.372°C () -3.2°C (@) oc Which of the following pair represents anomers? CHO cho, ‘CHO CHO. notu H—-OH Hy HoH ? @ v0 Hy ‘OH H H H cH,0H cH,0H cH,08 cH,0H Arrhenius equation can be represented graphically as follows : Ink] BR The (i) intercept and (ii) slope of the graph are (a) @InAGE/R — (b) GA GI) E, () @InA(il)-EJR (4) (A Gi) -E, Given below are two statements labelled as Assertion (A) and Reason (R). ‘Assertion (A) : The two strands in double strand helix structure of DNA are complementary to each other. Reason (R) : Disulphide bonds are formed between specific pairs of bases. Sclect the most appropriate answer from the options given below : (a) Both A and R are true and Ris the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (©) Ais true but Ris false. (d) Ais false but Ris true. Given below are two statements labelled as Assertion (A) and Reason (R). “Assertion (A) : Corrosion causes enormous damage to buildings, bridges, ships and to all objects made of metals. Reason (R) : Corrosion changes the chemical composition of metals. Select the most appropriate answer from the options given below (a) Both A and Rare true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A, (©) Ais true but Ris false. (d) Ais false but R is true. Class 1215. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : Catalytic reduction of butanal gives butanol. Reason (R) : Aldehydes on reduction give corresponding primary alcohols. Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (6) Aistrue but Ris false, (d)_ Ais false but Ris true. below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) :{Ti(H0)«]°* is coloured while [Se(H,0),]** is colourless. Reason (R) : d ~ d transition is not possible in [Sc(H,0),]”*. Select the most appropriate answer from the options given below : (a) Both A and R are true and Ris the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (©) Aistrue but Ris false. (@) Ais false but R is true. SECTION B This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. On the basis of which evidences D-glucose was assigned the following structure? GHO (CHOW), CH,OH 18. (i) Identify A, Band C. CgHs-CONH, SEEOH, 4 SOPHO, pK 5c (ii) Give the decreasing order of reactivity for the following compounds towards coupling with PhN3CT. 1. Toluene IL Nitrobenzene TL. Chlorobenzene 19. (i) Identify the final product B. cHtyaigbr SACs 4 SCA, 5 (ii) Identify X in the given reaction : CH,CHO 20. Which reaction, in each pair shown below, will show the faster rate of disappearance of starting material? (@) @ (CHy);cBr BH, (i) (CH,),CBr 2245 70 ® o X aS om Xa ees, OR Why is SOC, (thionyl chloride) preferred for the preparation of alkyl chloride from alkyl alcohol? 21, Find the molality of a solution containing a non-volatile solute if the vapour pressure is 2% lower than the vapour pressure of pure water. Chemistry fe ara aSECTION C This section contains 7 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each, 22, Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is 23. 24, 2. (a) a stronger acid than phenol. Why? (a) What is osmotic pressure? (b) A solution containing 4 g of a non-volatile organic solute per 100 cm’ was found to have an osmotic Pressure equal to 500 cm Hg, at 27 °C. Calculate the molar mass of the solute. (a) Aromatic 1° amines cannot be prepared by Gabriel phthalimide reaction, Explain, (b) Select the amine which is most reactive towards dil. HCl among the following. Explain. (CH,NH;, (CHs),NH,(CH,)3N, CgHsNHy . Consider the figure and answer the questions (i) to (vi) given below: Zine pa pte Satbrge T eT (i) Redraw the diagram to show the direction of electron flow. (ii) Does silver plate act as the anode or cathode? (iii) What will happen if salt bridge is removed? (iv) When will the cell stop functioning? (v) How will concentration of Zn™* ions and Ag* ions be affected when the cell functions? (vi) How will the concentration of Zn** ions and Ag* ions be affected after the cell becomes ‘dead’? Give the plausible explanation for the following (any 2) : (a) Glucose doesn't give 2,4-DNP test. (b) The two strands in DNA are not identical but are complementary. (C)_ Starch and cellulose both contain glucose unit as monomer, yet they are structurally different. (a) Select the species with the highest melting point. Explain. CH; CH; CH; ca on a Ww aia CH, CH; CH; oO a «am (b)_ Select the species that undergoes faster Syl reaction. Explain. Oycna O-cac © a “The outer clectronic configuration of two members of the lanthanoids are as follows : 4f' Sd! 6s? and 4f7 5d° 6s”. ; What are their atomic numbers? Predict the oxidation states exhibited by these elements in their compounds. zi (b) Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. Why? (©). Describe the variability of oxidation states in the first row of the transition elements (Sc - Cu) and indicate the general trend. Class 12SECTION D ‘The following questions are case-based questions. Each question has an internal choice and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that follow. 29, The Edison storage cell is represented as : Fey, | FeO, | KOH (aq) | NizO,) | Nig ‘The half-cell reactions are : NiOy) + HyO(p + 2e” —9 2NiOfy + 20Hiay ; EP = 40.40 V FeOyy + H,Oyp + 26° —> Fey + 20Hjay i E° = - 087 V Answer the following questions : (a) Write the cell reaction taking place at anode. OR ‘What is the cell EMF? (b) How does cell EMF depend on the concentration of KOH? (©) What is the maximum amount of electrical energy that can be obtained from one mole of Ni,O,? 30. The lanthanoid series is a unique class of 15 elements with relatively similar chemical properties. They have atomic number ranging from 57 to 71, which corresponds to the filling of the 4f orbitals with 14 electrons. This configuration leads to phenomenon known as lanthanoid contraction. The lanthanoids are sometimes referred to asthe ‘rare earth elements; leading to misconception that they are rare. Infact, many of the rare earth elements are more common than gold, silver and in some cases, lead. The lanthanoids are ‘commonly found in nature as a mixture in a number of monazite (LnPO,) and bastnaesite (LnCO,F) in the +3 oxidation state. ‘The chemical and physical properties of lanthanoids provide the unique features that set them apart from other elements. Lanthanoids are most stable in the +3 oxidation state. Yb and Sm though stable in the +3 state, also have accessible +2 oxidation states. The ease of accessibility of both oxidation states is quite important in chemical synthesis and these elements act as Lewis acid in the +3 oxidation state and single electron reductant in the +2 oxidation state. Answer the following questions : (a) Name a member of the lanthanoid series which is well known to exhibit +2 oxidation state. (b) Ces used as an oxidising agent in volumetric analysis. Give reason. (© (How would you account for the following : Among lanthanoids, Ln(I11) compounds are predominant. However, occasionally in solutions or in solid compounds, +2 and +4 ions are also obtained. (ii) Name a member of the lanthanoid series which is well known to exhibit +4 oxidation state. OR On the basis of Lanthanoid contraction, explain the following : (@ Nature of bonding in La,O, and Lu,O,. (il) Radii of 4d and 5d elements. SECTION E ‘The following questions are long answer type and carry 5 marks each. All questions have an internal choice. 31. Attempt any five of the following : (a) Name the starting material used in the industrial preparation of phenol. (b) Write complete reaction for the bromination of phenol in aqueous and non aqueous medium. (©) Explain why Lewis acid is not required in bromination of phenol? (d) Boiling point of ethanol is higher in comparison to methoxymethane. Give reason. Chemistry EE32. 33. ©) (a) (b) © @ (b) © @ (a) (b) @) (b) (CH))\C—O—CH on reaction with HI gives CHOH and (CH;)yC—Ias the main products and not (CH,);C—OH and CHgL. Write the mechanism of the following reaction : 2CH,CH,OH 73> CH,CH,OCH,CH, + H,0 Account for the following : Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method, ‘The activation energy of a reaction is 75.2 kJ mol” in the absence of a catalyst and 50.14 kj mol”! with a catalyst. How many times will the rate of reaction increase in the presence of the catalyst if the reaction proceeds at 25°C? (R = 8314) K” mol”) Explain the following terms : (i) Rate of a reaction (ii) Activation energy of a reaction ‘The decomposition of phosphine (PH), proceeds according to the following equation : APH) Pug) + FHayp) It is found that the reaction follows the following rate equation : Rate = k{PH,) ‘The half-life period of PH, is 37.9 s at 120°C. (How much time is required for 3th of PH; to decompose? Gi) What fraction of the original sample of PH, remains behind after 1 minute? OR How much time is required for the completion of a zero order reaction? How does the value of rate constant vary with reaction concentration? Draw a schematic graph showing how the rate of a first order reaction changes with change in concentration of the reactant. Rate of a reaction is given by Rate = k{AJ"[B) ‘What are the units for the rate and the rate constant for this reaction? Draw the structures of optical isomers of each of the following complex ions : (Ce(C,0,)5}*[PeCl,(en)2}**,{Ce(NH3),Cl(en)]. Draw the structure and write the hybridisation state of Co in cis-[Co(NH),Cl,]*. OR Using crystal field theory, draw energy level diagram, write electronic configuration of the central metal atom/ion and determine the magnetic moment value for the following : [FeF¢]?”, [Fe(H0)<]°"- Explain with example homoleptic and heteroleptic complexes. Class 12Subject Code: 043 CHEMISTRY Time Allowed : 3 Hours Maximum Marks: 70 General Instructions : Read the following instructions carefully, (a) There are 33 questions in this question paper with internal choice. (b) SECTION A consists of 16 multiple-choice questions carrying 1 mark each. (c) SECTION B consists of5 short answer questions carrying 2 marks each. (d) SECTION C consists of 7 short answer questions carrying 3 marks each (e) SECTION D consists of 2 case-based questions carrying 4 marks each. ()_ SECTION E consists of 3 long answer questions carrying 5 marks each. (All questions are compulsory. (h) Use of log tables and calculators is not allowed. SECTION A ‘The following questions are multiple -choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. Inwhich of the following complexes, primary and secondary valencies are not correctly marked against the compound? (a) [Ce(NH3)gICly: p (b) Ky[Ptcly: p (© [PUNH,),ChICls p=4,s=4 (d) [Cu(NH,),]805 p=4,5=4 2. Given below are few mixtures formed by mixing two components. Which of the following binary mixtures will have same composition in liquid and vapour phase? (Ethanol + Chloroform (ii) Nitric acid + Water (ii) Benzene + Toluene (iv) Ethyl chloride + Ethyl bromide (@) (and (ii) (b) (and (il) (©) (i), (ii) and (it) (4) (it) and (iv) 3. Ina set of reactions, acetic acid yielded a product S. The structure of $ would be CH,COOH 222, p__Bemene_,Q_HEN , p_HOH 5 Ta oy on oon @ ore ) ori cH, OH On e I fo ot a4 orm ov on 4. Which of the following is correct statement? (a) Starch is a polymer of ot-glucose. (b) Amylose is a component of cellulose. (©) Proteins are compounds of only one type of amino acids. (@)_ Sucrose is a reducing sugar. Chemistry Ly eae10. 11. 12, 13. An organic compound of molecular formula CyH,O did not give a silver mirror with Tollens’ reagent but give an oxime with hydroxylamine. It may be (a) CH,=CH—CH,—OH (b) CHyCOCH; (©) CH\CH,CHO (@) CHj=CH-OCH A student set up the following apparatus to determine the hydrogen ion concentration of solution X, The cell is, M|Haq | 2Hjaq) |] Cu.) | Cus, The best material for electrode M would be igh npedanc voluneter Prion off SEL cope Solution x of Tf 4-10 M copper (I) sulphate unknown (H") (a) polished copper metal (b) platinum metal coated with platinum oxide (c)_ copper metal coated with oxide (d) platinum metal coated with finely divided platinum, A 0.0020 m aqueous solution of an ionic compound [Co(NHs)s(NO,)]CI freezes at - 0.00732 °C, Number of moles of ions which 1 mol of ionic compound produces on being dissolved in water will be (Ky= -1.86 *C/m) (@) 3 (b) 4 @1 (a) 2 In context with the transition elements, which of the following statements is incorrect? (a) In addition to the normal oxidation states, the zero oxidation state is also shown by these elements in complexes. (b) Inthe highest oxidation states, the transition metals show basic character and form cationic complexes. (©)_ Inthe highest oxidation states of the first five transition elements (Sc to Mn), all the 4s and 3d electrons are used for bonding. (4) Once the configuration is exceeded, the tendency to involve all the 3d electrons in bonding decreases Which of the following is the major species in a solution of lysine at pH = 3.5? COOH COOH coo" coo7 (@) “HN H (b) HN: H | (HN | Hd) HN. | HO (Fae (Hh), Hs (Hy +NHy #8 *NHy NH Which of the following complexes will have four isomers? (a) [Co(en)(NH3),Cl,]Cl (b) [Co(PPh;),(NH3),CI,]C1 () [Co(en);]Cl, (d)_ [Cofen),CI,]C1 ‘The end product (Z) in the given sequence of reaction is ict KCN CH,CH=CHCHO My x HE ¥ AZ (a) CH;CH=CHCH,COOH (b) CH3;CH,CH),COOH (9 CHj;CH=CHCOOH (@) CH;CH(CNCH,COOH Phenol on treatment with excess of conc. HNOs gives (a) 0-nitrophenol (b) p-nitrophenol (©) o-and p-nitrophenol (4) 2,4,6-trinitrophenol, Given below are two statements labelled as Assertion (A) and Reason (R). “Assertion (A) : In strongly acidic solutions aniline becomes more reactive towards electrophilic reagents Reason (R) : The amino group being completely protonated in strongly acidic solution, the lone pair of electrons on the nitrogen is no longer available for resonance, Class 12Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (©) Ais true but Ris false, (d)_ Ais false but Ris true, 14. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A): All enzymes found in cells are invariably proteins which catalyse biological reactions. Reason (R): Enzymes act efficiently at a moderate temperature and pH. Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (c) Ais true but Ris false, (a) Ais false but Ris true. 15, Given below are two statements labelled as Assertion (A) and Reason (R). ‘Assertion (A): Replacement of ~Cl group by -OH in chlorobenzene is easier intro group is present in the ring, Reason (R): Nitro group leads to strengthen the C — Cl bond in chlorobenzene. Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (©) Aistrue but Ris false. (d). Ais false but R is true. 16. Given below are two statements labelled as Assertion (A) and Reason (R) Assertion (A) : In transition elements, ns orbital is filled up first and (n-1)d afterwards, during ionization ns electrons are lost prior to (n-1)d electrons. Reason (R) : The effective nuclear charge felt by (n-1)d electrons is higher as compared to that by ns electrons. Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (©) Aistrue but Ris false. (4) Ais false but Ris true. SECTION B This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. Write equations of the following reactions : (a) Oxidation of propan--ol with alkaline KMnO, solution. (b) Treating phenol with chloroform in the presence of aqueous NaOH followed by hydrolysis. OR Illustrate with examples the limitations of Williamson's synthesis for the preparation of certain types of ethers. 18 What are bidentate ligands? Explain with examples. 19. Heptane and octane form an ideal solution. At 373 K, the vapour pressure of the two liquid components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture of 26.0 g of heptane and 35.0 g of octane? 20. ‘Two moles of organic compound ‘A’ on treatment with a strong base gives two compounds ‘B' and ‘C. Compound ‘B' on dehydrogenation with Cu gives ‘A’ while acidification of “C yields carboxylic acid ‘D? with molecular formula of CH,0;. Identify the compounds A, B, C and D and write all chemical reactions involved. Chemistry ee)21. (a) Complete the following reaction : CH;—CH,—CH=CH, + HCl (b) Draw the structure of the compound whose IUPAC name is 4-chloropentan-2-one. SECTION C ‘This section contains 7 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each, | 22, Answer the following questions (any 2) : | (a)_ Show the steps of reactions in the Stephen's method for production of acetaldehyde? | (b) Complete the reactions (i) and (ii). Give name, if any, to the reaction (i) and one medicinal use of the product formed in (i), (@ CH3CHO 20a, (ij) HCHO + NH; (©) Convert: (i) Acetaldchyde to methane (ii) Acetaldehyde to acetone. 23, (a) Calculate A,G° for the reaction : Mg + Cissy —> Mgicy + Cugy Given Ey = +2.71 V, 1 F = 96500 C mol () Why is alternating current used for measuring resistance of an electrolytic solution? 24. Compound (A) with molecular formula, C,HsBr was treated with ag. KOH solution. The rate of this reaction depends upon the concentration of the compound ‘A’ only. When another optically active isomer ‘B? of this compound was treated with ag. KOH solution, the rate of reaction was found to be dependent on the concentration of compound and KOH both. (i) Write down the structural formulae of both compounds ‘A’ and ‘B: (ii) Outofthese two compounds, which one will be converted to the product with inverted configuration? 25. (a) Define order of reaction. (b) A certain reaction takes 5 minutes for initial concentration 0.5 mol L" to become 0.25 mol L™ and another 5 minutes to becomes 0.125 mol L~!, What is the order and specific rate constant of the reaction? 26. (a) Explain the completion of the following reactions with NaBr and conc. H,SO,. () CH,CH,CH,OH (i) €)-0n (b) Phenols and alcohols behave as Bronsted acids. Explain. 27. 1.22,gofbenzoic acid is dissolved in 100 g of acetone (Ky for acetone = 1.7 Kkg mol”) and 100 g of benzene (Ky = 2.6 K kg mol”). The elevations in boiling points AT; is 0.17°C and 0.13°C respectively. (a) What are molar masses of benzoic acids in two solvents? (b) Calculate the value of ‘for benzoic acid in acetone and explain whether it undergoes association or dissociation. 28. Using Valence bond theory, explain the following in relation to the paramagnetic complex, [Min(CN).]”- (a) Type of hybridization () Magnetic moment value (© Type of complex - Inner or outer orbital complex SECTION D 7 Each question has an internal choice and carries 4 (1+1+2) “The following questions are case-based questions. Each q marks each, Read the passage carefully and answer the questions that follow. decomposes as 29, ‘At constant temperature and volume, X Ig — Mig + Begs Pas the partial presse of X- Sa Class 12‘Answer the following questions : (a) What is the molecularity of the reaction ? OR ‘Whaat is the order of reaction with respect to X? (b) Find the time for 75% completion of the reaction. (c) Find the total pressure when pressure of X is 700 mm of Hg. 30. Strengthening the Foundation: Chargaff Formulates His “Rules” Many people believe that James Watson and Francis Crick discovered DNA in the 1950s. In reality, this is not the case. Rather, DNA was first identified inthe late 1860s by Swiss chemist Friedrich Miescher. Then, in the decades following Miescher’s discovery, other scientists-notably, Phoebus Levene and Erwin Chargaff- carried out a series of research efforts that revealed additional details about the DNA molecule, including its primary chemical components and the ways in which they joined with one another. Without the scientific foundation provided by these pioneers, Watson and Crick may never have reached their groundbreaking ‘conclusion of 1953: that the DNA molecule exists in the form of a three-dimensional double helix. Chargaff, an Austrian biochemist, as his first step in this DNA research, set out to see whether there were any differences in DNA among different species. After developing a new paper chromatography method for separating and identifying small amounts of organic material, Chargaff reached two major conclusions: (i) The nucleotide composition of DNA varies among species. (ii) Almost all DNA, no matter what organism or tissue type it comes from maintain certain properties, even as its composition varies. In particular, the amount of adenine (A) is similar to the amount of thymine (T), and the amount of guanine (G) approximates the amount of cytosine (C). In other words, the total amount of purines (A +.G) and the total amount of pyrimidines (C + T) are usually nearly equal. This conclusion is now known as “Chargaff's rule” Chargaff’s rule is not obeyed in some viruses. These either have single- stranded DNA or RNA as their genetic material. Answer the following questions : (a) A segment of DNA has 100 adenine and 150 cytosine bases. What is the total number of nucleotides present in this segment of DNA? (b) A sample of hair and blood was found at two sites. Scientists claim that the samples belong to same species. How did the scientists arrive at this conclusion? (©) The sample of a virus was tested and it was found to contain 20% adenine, 20% thymine, 20% guanine and the rest cytosine. Is the genetic material of this virus (i) DNA- double helix (ii) DNA-single helix (iii) RNA? What do you infer from this data? OR How can Chargaff’s rule be used to infer that the genetic material of an organism is double- helix or single- helix? SECTION E ‘The following questions are long answer type and carry 5 marks each. All questions have an internal choice. 31, Attempt any five ofthe following: (a) Give the structures of A, Band Cin the following reactions. sa+ HCl NaNO, +HCL 4o C HNO, AS Aa BC Chemistry nn32. 33. (b) © (@) (©) (0) ®) (a) (b) © (a) b) (b) fa) (b) (} (d) How is the following conversion carried out? Aniline to p-Hydroxyazobenzene, How will you bring about the following conversion? Nitrobenzene to phenol. ‘Why are the secondary amines more basic than primary amines? Explain. ‘Write the complete chemical reaction for the conversion of aniline to sulphanilic acid. ‘Why is benzenediazonium chloride not stored and is used immediately after its preparation? ‘Under what reaction conditions (acidic/basic), the coupling reaction of aryldiazonium chloride with aniline is carried out? State reasons for the following : (1) Rusting of iron is said to be an electrochemical phenomenon. (ti) For a weak electrolyte, its molar conductance in dilute solutions increases sharply as its concentration in solution is decreased, Equivalent conductance of a 0.0128 N solution of acetic acid is 1.4 mho cm? eq”! and conductance at infinite dilution is 391 mho cm? eq"'. Calculate degree of dissociation and dissociation constant of acetic acid, Calculate the standard cell potential, AG* and equilibrium constant of the following reaction of galvanic cell: 2 + 30d) — 2c + 304 (Given : £8,3+)cr = ~ 0.74 V, E&g2+)ca =~ 0.40 V) OR An aqueous solution of AuCl; was electrolysed with a current of 0.5 A until 1.20 g of gold had been deposited on the cathode. At another electrode in series with this, the only reaction was the evolution of O>. Find (i) number of moles of oxygen (i) the number of coulombs passed through the solution (iii) the duration of electrolysis. (i) Why electrolysis of NaBriqq) and Naljay) gives Br, and I; respectively while that of NaF qq) gives O, instead of F;? (i) Why AS, for acetic acid cannot be determined experimentally? (i) Outof the ions Ag*, Co”* and Ti** which will be coloured in aqueous solution? (ii) If each one of the above ionic species is placed in a magnetic field, how will they respond and why? Explain the following : (i) Acidified K,Cr,0; solution turns green when sodium sulphite is added. (i) A ferrous salt decolourises acidified KMnO, solution. OR Which metal in the first transition series (3d-series) exhibits +1 oxidation state most frequently and why? How would you account for the following : Highest fluoride of Mn is MnF, whereas the highest oxide is Mn,,, Account for the following : Chie (i) The lowest oxide of transition metal is basic whereas the highest oxide is amphoteric or acidic. (ii) Manganese exhibits the highest oxidation state of +7 among the 3" series of transition elements. How is the variability in oxidation states of transition elements different from that of non-transition elements? Illustrate with examples. Class 12Subject Code: 043 SQP-11 CHEMISTRY Time Allowed : 3 Hours Maximum Marks: 70 General Instructions : Read the following instructions carefully. (a) There are 33 questions in this question paper with internal choice. (6) SECTION A consists of 16 multiple-choice questions carrying I mark each. (©) SECTION B consists of 5 short answer questions carrying 2 marks each. (d) SECTION C consists of 7 short answer questions carrying 3 marks each. (e) SECTION D consists of 2 case-based questions carrying 4 marks each. (f) SECTION E consists of 3 long answer questions carrying 5 marks each. (g) All questions are compulsory. (h) Use of log tables and calculators is not allowed. SECTION A ‘The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. _ Variation of resistance with increase in cell constant gives graph of the type . ¢ (b) 3 3 es Calcoatant > Calcot > t t i j © 3 @ 3 2 4 ‘Calan > ‘Calcot > 2, —Aldol condensation will not occur in (a) HCHO. (b) CHjCH,CHO (c) CH;COCH; (d) CH,CHO 3. Which is not a pyrimidine base? (a) Uracil (b) Thymine (co) Cytosine (@) Guanine 4. — The final product of the following reaction is Br im Cy” 2% une (a) benzaldehyde (b) benzene (©) benzoic acid (d)_ phenol. Chemistry cs5 The final products B and C formed in the following sequence of reactions, any. ‘cone. HNO, os (AEN g 4 cy ‘jor minor Ceanbe separted by fractona diilisin} are respectively (a) both bromobenzene (b) _o-bromonitrobenzene and p-bromonitrobenzene (©)_m-bromonitrobenzene and p-bromonitrobenzene (d)_p-bromonitrobenzene and o-bromonitrobenzene. ‘When CO, is passed into aqueous (a) Na;CrO, solution, its yellow colour changes to pink (b) K,MnO, solution, it disproportionates to KMnO, and MnO} (©) Na,Cr,0, solution, its orange colour changes to green (4) _KMn0, solution, its pink colour changes to green. Which of the following statements is in accordance with the Arrhenius equation? (a) Rate of a reaction decrease with increase in temperature. (b) Rate of reaction does not change with increase in activation energy. (©) Rate constant decreases exponentially with increase in temperature. (d)_ Rate of a reaction increases with decrease in activation energy. ‘An organic compound ‘A’ having molecular formula, CzHyN on reduction gave another compound ‘B’ Upon treatment with nitrous acid‘B’ gave ethyl alcohol. On warming with chloroform and alcoholic KOH, ‘B’ forms an offensive smelling compound ‘C: The compound ‘C' is (a) CHyCH,NH, (b) CH,;CH,N2C (¢) CHy;C=N (d) CH,CH,OH Consider the following set of reactions : H,$04° | atkals Bry Cos Ss0K? A Tirm07 8 Ho © The final product, Cis (a) o-bromophenol (b)_ p-bromophenol (©) m-bromophenol (4) 2,4,6-tribromophenol. ‘The rate constant of n" order reaction has units (a) "mot! (b) mol!" L's? (e)_ mol" L's"! (d)_ none of these, In the following sequence of reactions, CH,Br EX, 4 120", p UAL, ¢ ‘The end product C is (a) methane (b) ethyl alcohol (©) acetone (A) acetaldehyde. . In acidic solution, MnO; is (a) oxidised by 3 electrons (b) reduced by 3 electrons (©) oxidised by 5 electrons (d) reduced by 5 electrons. Given below are two statements labelled as Assertion (A) and Reason (R). “Assertion (A) : When the vapours of a primary, secondary or tertiary alcohol are passed over heated copper at 573 K, an aldehyde or ketone is formed. Reason (R) ; Reduction of alcohol takes place. Class 12| Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (b) Both A and Rare true but Ris not the correct explanation of A. (c) Aistrue but Ris false. | (d) Ais false but R is true. 14, Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : p-Chlorobenzoic acid is stronger than benzoic acid. Reason (R) : Chlorine has electron donating resonance (+R)-effect. Select the most appropriate answer from the options given below: (a) Both A and Rare true and R is the correct explanation of A. (b) Both A and Rare true but R is not the correct explanation of A. (©) Ais true but Ris false. (d)_ Ais false but Ris true, 15. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A): A solution of sucrose in water is dextrorotatory but on hydrolysis in presence of little hydrochloric acid, it becomes laevorotatory. Reason (R) : Sucrose on hydrolysis gives unequal amounts of glucose and fructose as a result of which change in sign of rotation is observed. Select the most appropriate answer from the options given below: (@) Both A and R are true and R is the correct explanation of A. | (b) Both A and Rare true but R is not the correct explanation of A. (©) Ais true but Ris false. (d) A is false but Ris true. 16. Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : As a lead storage battery gets discharged, density of electrolyte present in it, decreases. Reason (R) : Lead and lead dioxide both react with sulphuric acid to form lead sulphate. Select the most appropriate answer from the options given below: (a) Both A and Rare true and Ris the correct explanation of A. (b) Both A and Rare true but R is not the correct explanation of A. (©) Ais true but Ris false. (d) Ais false but Ris true. SECTION B ‘This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. Fora certain chemical reaction, variation in the concentration, In{R] vs time (min,) plot is shown below: In{R}] (min) For this reaction (i) What is the order of the reaction? (ii) What is the unit of rate constant, k for this reaction? (iii) Give the relationship between k and t1/» of this reaction, (iv) If initial concentration for this reaction becomes half, how will ty vary? Chemistry eaneaEes18. Whyisitnot possible to obtain pure ethanol by fractional distillation? What general name is given to binary mixtures which show deviation from Raoult’ law and whose components cannot be separated by fractional distillation. How many types of such mixtures are there? 19. Give reasons for the following : (i) _ Ethyl iodide undergoes $2 reaction faster than ethyl bromide, (ii) (4)-2-butanol is optically inactive 20. How are the following conversions carried out : (i) Acetic acid to methylamine (ii) Acetaldehyde to methane? OR ‘Write down the IUPAC names for the following compounds : (i) PhCH,CH,COOH (ii) (CH;);C=CHCOOH 21. (i) Name two fat soluble vitamins, their sources and the diseases caused due to their deficiency in diet. (ii) Write Haworth structure of a-and B-D-(-)-fructose. SECTION C This section contains 7 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each. 22, Answer the following questions (any 2) : (i) Co®* is easily oxidised to Co°* in presence of a strong field ligand. Give reason. (ii) On the basis of crystal field theory, write the electronic configuration of d* if A, 2Fe™* + 4e" At cathode : O, + 4H* + 4e” > 2H,0 ‘Overall reaction : 2Fe + O; + 4H” —> 2Fe** + 2H,0. ‘The ferrous ions further oxidised by atmospheric oxygen to ferric ions which come out as rust in the form of hydrated ferric oxide (Fe,03.xH,0) and with further production of hydrogen ions. Methods used for prevention of corrosion are barrier protection, sacrificial protection and antirust solutions. Answer the following questions : (a) Which type of metal can be used in cathode protection of iron against rusting? (b) What would happen if the protective tin coating over an iron bucket is broken in some place? (c) (i) Whatis the source of H* ion during corrosion? (ii) Rusting of iron is quicker in saline water than in ordinary water. OR Account for the following : (i) Alkaline medium inhibits the rusting of iron, (ii) Iron does not rust even if the zinc coating is broken in a galvanized iron pipe. Chemistry EeeSECTION E ‘The following questions are long answer type and carry 5 marks each. All questions have an internal choice, 3. 32, 33. Attempt any five of the following (a) Which metal in the first series of transition element shows the highest number of oxidation states? (6) Which compound is generally used in making optical glasses such as Crookes lenses which protect, eyes against UV light? ()_ Explain why Zn shows only +2 oxidation state, (d) Actinoids exhibit a greater range of oxidation states than lanthanoids why? (€) Actinoid contraction is greater from element to element than lanthanoid contraction. (6) Why is copper sulphate pentahydrate coloured? (g)_ Why does Ti** ion show diamagnetic behaviour? (@)__ Which type of deviation is shown by the solution formed by mixing cyclohexane and ethanol? (ii) 18 g of glucose, CgH,20¢is dissolved in 1 kg of water in a saucepan. At what temperature will the water boil? K;, for water is 0.52 K kg mol. (iii) A and B liquids on mixing produced a warm solution. Which type of deviation is there and why? OR (Why is camphor preferred as a solvent in determination of depression in freezing point (AT,)? (ii) Aquatic species are more comfortable in cold water rather than in warm water, Why? (iii) A 10% solution (by mass) of sucrose in water has freezing point of 269.15 K. Calculate the freezing point of 10% glucose in water, if freezing point of pure water is 273.15 K. (Given : Molar mass of sucrose = 342 g mol ', molar mass of glucose = 180 g mol”) (Explain why mineral acid is added in excess in the diazotisation of arylamines. (ii) An organic compound ‘A; C;HgN on reaction with nitrous acid gave benzyl alcohol. Predict the structure of the compound and give its various isomeric structures. OR Give reasons for the following : (i) (a) Ethylamine is soluble in water whereas aniline is not soluble in water. (b) Primary amines have higher boiling point than tertiary amines. (ii) Give the structures of A, B and Cin the following reactions : (2) Cetignforr —22L, 4 28 pM ge +Ha ‘NaNO, + HCL H,0/H* (6) CgHgNO, ES AS BC (0) CH;CN—EOML, 4 Mis, pFa KOH 4c Class 12Subject Code: 043, CHEMISTRY Time Allowed : 3 Hours Maximum Marks : 70 General Instructions : Read the following instructions carefully. (a) (6) © (d) (e) oO @ (h) ‘There are 33 questions in this question paper with internal choice. SECTION A consists of 16 multiple-choice questions carrying 1 mark each. SECTION B consists of 5 short answer questions carrying 2 marks each. SECTION C consists of 7 short answer questions carrying 3 marks each. SECTION D consists of 2 case-based questions carrying 4 marks each. SECTION E consists of 3 long answer questions carrying 5 marks each, All questions are compulsory. Use of log tables and calculators isnot allowed. SECTION A ‘The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. “The solubility of common salt is 36.0 g in 100 g of water at 20°C. If systems, I, I and III contain 40.0, 36.0 and 20.0 g of the salt added to 100.0 g of water in each case, the vapour pressures would be in the order (@) I) I>u>ur (©) [=M>I @ I=n Hg” + Cu (b) Hg + Cu > Cut + Hg* (©) Cu+Hg— Culg (d) Cu+ Hg > Cu? + Hg Chemistry10. i 12, 13, 4 Which of the following is most reactive towards aqueous NiOH? (@) CoHsBr 0) CHACH;Br (@) GHsF Cresssier ‘The reagent'Z' in the following reaction is ao oz Neots : oO Oo iO oO 8 ofl tye End product (A) ofthe following sequence of reaction is ws ga CO)>n0, lige i Se 8 i) O-m, © (xe, 0 (-iner @ 5-0 A quantity of iodine was reacted with a large excess of propanone and dilute acid. The equation for the reaction was : 1,+.0H,cocH, 1, icH,cocHy + HI ‘The concentration of iodine in the reaction mixture was recorded at regular time intervals and the result is shown in figure. Rate (hl hl Which one of the following conclusions can be made from this graph? (a) The rate of reaction is directly proportional to [I]. (b) The rate of reaction is inversely proportional to [I]. (©) The rate of reaction is independent of [13]. (@) The rate of reaction is independent of [H*). An aromatic ether is not cleaved by HI even at 525 K. The compound is (a) CoH,OCH; (b) CgHsO - CoH, (CH) (© CgH;OC,H, (@) tetrahydrofuran. ‘What is the correct electronic configuration of the central atom in Ky[Fe(CN)g] based on crystal field theory? @ (b) bee © feeb @ 28 Given below are two statements labelled as Assertion (A) and Reason (R). Assertion (A) : Solubility of proteins is minimum at the isoelectric point. Reason (R) : At isoelectric point, protein molecule behaves as a zwitter ion, Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (©) Aistrue but Ris false. (@) Ais false but R is true. Given below are two statements labelled as Assertion (A) and Reason (1), Assertion (A) : The pressure exerted by a liquid ata given temperature is called its vapour pressure, Reason (R) : If a non-volatile solute is added to a solvent to give a solution, the vapour pressure of the solution is found to be greater than the vapour pressure of the pure solvent, Class 12Select the most appropriate answer from the options given below: (a) Both A and R are true and Ris the correct ‘explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (c) Ais true but Ris false. (d) Ais false but Ris true. 15. Given below are two statements labelled as Assertion (A) and Reason (R)- Assertion (A) : CH3OCH; and C,H,OH has comparable molecular weight but boiling point of C,H;OH is more than dimethyl ether. Reason (R) : CH;OH forms intermolecular H-bonding while CHjOCHS forms intramolecular H-bonding. Select the most appropriate answer from the options given below: (a) Both A and Rare true and R is the correct explanation of A. (b) Both A and R are true but Ris not the correct explanation of A. (©) Aistrue but Ris false. (d) Ais false but R is true. 16. Given below are two statements labelled as Assertion (A) and Reason (R). “Assertion (A) : Transition metals are good: bs Reason (R) : V2; or Pt is used in the preparation of H,SO, by Contact process. Select the most appropriate answer from the options given below: (a) Both A and R are true and Ris the correct explanation of A. (b) Both A and R are true but R is not the correct explanation of A. (©) Ais true but Ris false. (@) Ais false but R is true. SECTION B ‘This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each. 17. Why are alky! halides generally not prepared in the laboratory by free radical halogenation of alkanes? 18. Two solutes X and Y in equal amounts are dissolved separately in 10 moles of solvent C. If X molecule is heavier than ¥ molecule, which solution will have larger relative lowering of vapour pressure? 19. Explain the following observations : (In aqueous solution, the pK, order is Me;NH > MeNH, > Me3N. (ii) Tertiary amines do not undergo acylation reaction. 20. A reaction is of second order with respect to its reactant. How will its reaction rate be affected if the concentration of the reactant is (i) doubled (ii) reduced to half? 21, Explain the structure of [NiCl,]*" on the basis of V.B.T. OR ‘Name the following coordination compounds and draw their structures : (i) [CoCl,(en),]Cl (ti) [PC(NHs)2CI(NO,)] (At. No. Co = 27, Pt= 78) SECTION C This section contains 7 questions with internal choice in one question, The following questions are short answer type and carry 3 marks each. 22. Complete each synthesis by giving missing starting materials, reagents or products (any 2): oO i 0. “O-C0 “Os :