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This paper is based principally on the following references U.S. Department of Energy, Energy Efficiency and Renewable Energy Program - Hydrogen, Fuel Cells & Infrastructure Technologies <www1.eere.energy.gov/hydrogenandfuelcells/> Schatz Energy Research Centre <www.schartzlab.org/> The Hype about Hydrogen, Joseph J Romm, Five Island Press, Washington, 2005. Greenhouse Solutions, Mark Diesendorf, UNSW Press, 2007.
THE SOLAR HYDROGEN CYCLE. The diagram below illustrates the Solar Hydrogen Cycle on the basis of the hydrogen being generated from water using electric power from photovoltaic solar panels. It does not have to be generated that way and most of the [quite considerable quantity] of hydrogen used today in the chemical industry is manufactured chemically. However, this is the only sustainable method and it is possible that a significant industry could be established in the desert regions of Australia, generating hydrogen by the method shown in the diagram and shipping it to points of use [in Australia and overseas] in a manner similar to the way we now ship natural gas.
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A working Group of EcoNetwork, Port Stephens. Process Description In this typical schematic process, electricity from photovoltaic panels is used to power an electrolyzer, a device which splits water (H20) into its elemental parts, hydrogen (H2) and oxygen (O2).
The oxygen is released into the air and the hydrogen is pumped into storage tanks, where it can be kept on site or transported to regions that need energy. At night or in bad weather, when solar energy is not available, the hydrogen is recombined with oxygen from the air in a fuel cell, which directly converts the chemical energy in hydrogen into electricity. The only byproduct of this process is pure water. Electricity from fuel cells can be used in the same ways as power from a utility company or other type of generator, to run appliances and light bulbs, electric motors, and to power cars. Solar hydrogen allows us to use the power from the sun twenty-four hours a day, and provides us with an abundant, clean, efficient, locally produced, sustainable source of energy. AVAILABILITY. Hydrogen is the most common element in the universe it is eminently sustainable since at the end of the process the hydrogen ends up where it began, as water. It is not like carbon fuels where the carbon, at the end ot the cycle is locked away in carbon dioxide, or some even nastier forms such as carbonic acid. BUT. The favoured approach by current policy makers is to make hydrogen in the cheapest way, by distillation from coal. This manufacturing process produces large quantities of CO2 which negates the environmental advantage of the carbon cycle. Only hydrogen produced cleanly and sustainably should be considered. This whole process is still in the experimental stage we do not have enough experience with this technology to implement it on a large scale immediately. In particular, widespread use of hydrogen powered vehicles will require building a network of hydrogen filling stations. All this simply highlights the necessity of motivating our politicians to adopt a more focused and commited attitude to the whole problem of building a sustainable society to replace the temporary, exploitive society which we now have and which is approaching its inevitable end. A big ask !! John M Kelly, BE, BA.
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3 December 2007.
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