7S PR SX DS Fe Section A FOR TEACHERS’ USE ONLY (@) (Chlorine has two isotopes °Cl and "C1 1 Bombardment of e° on chlorine produces atomic ion Cl" The five peaks correspond to the species: CI", "CI roe i (1) relative atomic mass of Cl, = La 1) Abundance of A ty 1 a) eof Ace txt Abundance of Bc 2 1 4 Abundance of Ca ana 3 4 Macks ‘and molecular jon {CI-Cl]" i PCCP, PCC and 1 BEET 55 5¢emu) 2 (mark for method: | mark for answer; deduct | mark forgiving units other than ama.) 4 (sy ratio of relative abundance abundance of = © © & x: Se /pparicte ay r: Be (UD 2: {He sa-particle (i) 10h, = 4x hatttife aetiviy = 12000%(2)* = 750 counts minut 16 16 16 26:9 (1 mark fo the method; 1 mark forthe answer. Deduct % marks for wrong/no unit ) (Gi) Expose food to ionizing radiation suchas fast electrons /y-rays Radiation 2000-AL-CHEM 2-17 RRA ME but will not affect the texture of the 1,1 wa FOR TEACHERS’ USE ONLY7 . CABRANEHBY FOR TEACHERS’ USE ONLY Marks (©) (i) Each line represents the transition of an electron from a higher energy level toa lower energy t level. co) an4 “3 y > 4 & 5 n=2 “The energy difference between energy levels decreases with increase in principal u quantum number. of, The relative increase in energy ofthe photon emitted forthe transition from n=nton=1 (I) becomes progressively smaller as n increases. (iii) Assuming that the frequency of the convergence limit of the Lyman series is v» 1 Energy of photon =h Yo - “This amount of energy equals to the energy required to ionize 1 atom of hydrogen. LE=Lx Avo 1 where L is the Avogadro Constant. (iv) To show the presence the element /to identify an element / to determine the concentration 1 ofan element ina sample _ O) 2000-AL-CHEM 2-18, ARAMEE FOR TEACHERS’ USE ONLY2 @)_ (b) ) @ ARRAS FOR TEACHERS’ USE ONLY Marks (i) "The enthalpy change when ] male of "is removed from gascous atoms of the element under Yeh \ ‘standard conditions, % \ or, the molar enthalpy change involved in the process under standard conditions. (4%) Mig) > M(e) + (4) «w Ne 2 = Ar 5 f Me si ar + atomic number (A marks for indicating Ne and Ar as maxima with LE. of Ne > Ar; ‘A marks for showing Na as minimum; Y marks for showing LE. : Mg> Al> Na; °% marks for showing LE. : P> $> Si "A marks for labeling the axes.) (if the curve carries zero marks; the axes will not be marked. ) o 0@) +e + OW 4% When ane” is added tothe outermost shell of O, the attraction between she nucleus andtheelection % leads to a decrease in energy of the system. 7 First EA. is negative O@) +e 3 O'~ ‘There is repulsive force between the anion O and the negatively charged electron, % Second E.A. is positive. Both Ca and Zn are Period 4 elements / have the same no, of electron shells % From Ca to Zn, the nuclear charge increases (by 10 units) / 10 electrons are added to an inner ‘4 ‘electron shell/d-subshell Due to the poor screening effect of the d clectrons/ the d-orbitals are more diffused, the effect of 7 increase in nuclear charge outweighs the effect of screening effect / the effective nuclear charge ' an c *. size of Ca > size of Zn . Q) CH, CO, B.D structure 4 weMH 1d hi Ihybridization state sp sp th - 7 @ 2000-AL-CHEM 2-19 RARAMEH FOR TEACHERS’ USE ONLY