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Soil Solution
Soil Solution:
Soil solution is the liquid phase of soil retained by soil
micro pores.
Water in exists in the soil partly as combined and bound
water (water of constitution and hygroscopic water) and partly as free water
in the form of films surrounding the soil particles(capillary water). The
soluble products that are liberated as a result of the processes of weathering
and soil formation are dissolved in the free water. The free water also
contains a part of organic matter that is soluble in water. Some of the soil
gases like oxygen and carbon dioxide are also dissolved in this water. In a
cultivated soil, some of the products of excretion and secretion of plant roots
and of the activities of microorganisms are also dissolved in soil moisture.
The free water carrying these various substances and gases in solution is
known as soil solution. By definition,
‘Water is the soil containing soluble salts and hence
whenever this aspect of soil water is relevant it is usually known as the soil
solution’.
According to Brady (1984),
‘The aqueous liquid phase of the soil and its solutes
consisting of ions dissociated from the surfaces of the soil particles and of
other soluble materials are known as soil solution’.
Characteristics of soil solution:
1. Soil solution exists in dynamic equilibrium condition with
the solid phase in which numerous chemical reaction occur
simultaneously.
2. Soil solution can be neutral, acidic or alkaline in nature.
3. In soil solution, various amounts of cations & and anions are
found freely moving from one place to another.
4. Soil solution contains dissolved & suspended colloidal
particles.
5. The composition of soil solution is not constant. The
composition of a particular volume of soil solution depends
not only on materials present that might possibly be included
in the water but on many other factors such as dissolved
gases, solutes, and suspended materials. Infact, it various
continuously only from soil to soil but also for one and the
same soil.
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Transport in Transport in
Xylem phloem
nutrients must move to the root surface. The stages involved in moving a
nutrient from a point in the soil into the plant shoot are:
First, movement of the nutrient from the bulk to the root
surface through absorption;
Second, movement form the root surface into the root;
and
Third, translocation of the nutrients from the root to the
shoot.
The concentration of free ions in the soil solution is
generally low, and many of the cations are adsorbed with varying degrees of
firmness on negatively charged clay particles and organic matter in the soil.
Nutrients anions such as nitrate and sulfate mostly occur in the soil solution
and are relatively mobile except phosphate, which is firmly bound to the soil
matrix. Mobile ions such as nitrate and potassium can be utilized from the
entire root zone, but immobile ions such as phosphate are available only
from soil in the immediate vicinity of the roots.
However, mobile ions in the soil solution are presumably
available to roots from greater distances since water moves to roots from
distances of several centimeters. The nutrient requirements of plants are
related to the amount supplied in the soil solution absorbed to replace water
lost by transpiration.
On the other hand, when plant roots uptake excess
amount of any nutrient, or produce some ions in, they may also be released
back into the soil solution by exchange reaction or efflux through phloem
tissue.
2. Nutrients in plant shoots:
“Transport in xylem and transport in phloem”
Water uptake in plant occurs through xylem tissue. Ions
which reach the xylem sap of the roots are usually carried to the shoots in
the transpiration stream. Here in leaves, some function, i.e. some synthesis
and retranslocation of some synthesized products out of the leaves occur. In
case of excess production, small quantities of plant constituents may also be
releases back into the soil solution, through roots by transpiration in phloem.
Substances released by roots are synthesized products
such as carbohydrate, nucleotide, etc and are designated root exudates. Root
exudates are not always same; they depend on the initial chemicals up taken.
For legumes having much protein, amino acids will be found as root
exudates.
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Anions:
Among the anions, bicarbonate, sulfate and chloride ions are commonly
present in soil solution in large quantities.
(HCO3)ˉ content:
The bicarbonate ions are usually present in greater
quantities than sulfate & chloride ions, except in saline soils.
SO4 content:
In saline soils, a sulfate ion is in preponderance. SO4²ˉ
content varies less than expected. SO4²ˉ content doesn’t change in that level
in which NO3ˉ & Clˉ content changes. That is, somehow soil holds/ captures
sulfate ions and that’s why, the amount of SO4²ˉion is less in soil solution.
Clˉ content:
In saline soils, chloride ion is also in preponderance. The
total Clˉions remain in soil solution, while the content of PO4³ˉ & SO4²ˉ ions
is low.
Po4³ˉcontent:
Of the major plant nutrients, the phosphate content of the
soil solution is the lowest & least variable. P is present in the soil solution as
H2PO4ˉ & HPO4²ˉions, and is generally believed to be taken up by plants
mainly as H2PO4ˉ.
NO3ˉcontent:
The amount of nitrates in soil solution is also very
variable. Usually it is the highest just after a crop is sown and lowest after it
is harvested. (Leaching of NO3ˉ is maximum in soil).
OHˉcontent:
In the case of alkaline soils, hydroxyl ions are generally present
in large quantities.
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The anions so produced are nitrates, sulphates and bicarbonates like calcium
and magnesium.
The microorganisms utilize some of the salts from soil
solution for their own nitrification some of which are liberated again later on
and brought into solution when the microorganisms die and decompose.
Water content, pH, moisture, O2 supply, temperature,
supply of organic matter or the important factors for the activity of
microorganisms.
1-5% organic-nitrogen is mineralized in soil. If there are
thiobacillus bacteria in soil, they oxidize sulfur and then SO4²ˉ can be found
in that soil, and H2SO4 may also form.
We can know about the composition & concentration of
certain soil solution by knowing which microorganisms are active in soil
detecting by the environmental factors.
# Nature of plant material:
The minerals primarily present in certain parent material,
release their components into soil solution by the weathering of that parent
material.
So, if orthoclase is present in a parent material by the
weathering of it, more K+ will be found in soil solution. In this case, pH of
the medium will be increased.
KAlSi3O8 + H-OH HAlSi3O8 + K+ + OHˉ
Likewise, in case of albite, Na+ will be high in soil
solution.
There are acidic, basic, organic parent materials. Natural
parent material detects composition & concentration of soil solution.
Growth stages of plant:
The growing plant which absorbs nutrients from the soil
changes the concentration as well as the composition of soil solution. The
nutrient requirements in vegetative & reproductive stage are not the same.
Plant needs more nutrients in its vegetative stage of growth.
For example, in a crop field nitrogen fertilizer is given in
three steps, because excess nitrogen is removed by leaching. Fertilizer is
added to soil at the beginning, because more nutrients needed for tiller
formation. An analysis showed that, a green rice plant contains 2% N,
whereas there is less than 1% N in straw. It means that, the plant utilizes N,
by storing in grains. After flowering, nutrients accumulate in soil, as plants
do not need them in that stage.
Plants exert considerable selection in the adsorption of
nutrients. While some ions like nitrates are adsorbed almost completely in
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preference to others, some ions are not adsorbed at all or to a much lesser
extent. This selective absorption of ions changes the composition of soil
solution considerably.
On the other hand, the action of carbon dioxide and other
acidic substances exerted by plant roots brings some of the insoluble soil
constituents into solution thereby changing its concentration & composition.
Even plant transpiration affects its concentration.
On all these accounts, the concentration of the soil
solution is always lower in cropped soil than in the same soil that is not
cropped. It is usually higher in the beginning of the growing season than at
its end.
#Plant types:
There are wide differences among plants of different
species in their ability to absorb various ions from the same soil or culture
solution. For instance, sugarcane absorbs more K+ & Ca++ ions, whereas
calcifillus plants growing in high pH soil like to absorb Ca++ ion.
Because roots are selective in their uptake of some ions
the relative ionic composition of the shoot system is often very different
from that of the soil solution. Plants typically contain more phosphate,
potassium and nitrogen relative to calcium than does the soil solution.
The degree of selectivity depends on the plant species.
The ionic composition of the growing leaves of a crop differs between
species and depends also on the ionic composition of the soil solution.
Thus, some species such as Lucerne typically have higher
calcium: potassium ratio in their leaves than do grasses. These differences
between plant species become very noticeable if an ion is in excess of its
normal value in the soil solution, for then plants can often be classified into
accumulators or rejecters of that ion.
Some plants (for example, tea) growing in acid soils high
in aluminum will accumulate high concentration of aluminum in their leaves
without their growth being affected. Some plants growing in salt marshes
will accumulate very high concentrations of sodium in their leaves; yet other
plant species, growing in these same soils, will have compositions little
affected by these high concentrations.
A classic example is the study made by Colander (1941)
of cation adsorption by 21 species of plants from various families and
habitats when grown in the same nutrient medium.
The genus Astragalus is well known as an accumulator of
selenium, but A. mussouriensis accumulated by 3.1 ppm from a soil
containing 2.1 ppm, while A. bislactus accumulated 1250 ppm.
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1. Climatic condition
2. Soil properties
3. Solubility of nutrients &
4. Plant species.
1. Climatic condition:
Climatic conditions such as rainfall & temperature controls the
salt movement in soil solution.
• Rainfall
Water uptake by plants depends on moisture content.
Because of rainfall moisture content in soil increases. When water content in
soil is high above field capacity which is called superflows, plant uptake
more water and mass flow of water including salts in it increases.
It also controls the gravitational pull. Moreover rate of
reaction increases with the increase of rainfall.
• Temperature:
When temperature is high, the rate of evaporation increases
and then the water in soil moves upward into the soil surface, and thus
movement of water increases.
2. Soil properties:
• Soil texture:
Buffer capacity in sandy soil is low whereas in clayey
soil is high.
• Organic matter content:
Buffer capacity increases with the increase of organic
matter in a soil.
3. Solubility of nutrients
4. Plant species
P 35 03 06 94
K 175 02 20 78
Ca 35 171 429 0
Mg 40 38 250 0
S 20 05 95 0
Cu 0.1 10 400 0
Zn 0.3 33 33 33
B 0.2 10 350 0
Fe 1.9 11 53 37
Mn 0.3 33 133 0
Mo 0.01 10 200 0
Labile nutrients:
For plants growing in soil, the concentration of a nutrient at the
root surface depends on the relative rates of uptake by the root and of
transport to the root surface from the bulk soil solution. This introduces a
requirement to replenish the soil solution because the concentrations of
many of the nutrients in the solution are low.
Replacement occurs by desorption from the surfaces of the
mineral & organic components of soil and by mineralization of soil organic
matter. The amount of nutrient