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SOUR SERVICE S series SS series SS-D series HCS series HCSS series HIGH COLLAPSE 13CR/SUPER13CR
Vallourec Group
Hardness
HRC (max)
Color Code
Time Saving Sour Service grades Same chemistry as SS series + 85% SMYS garantied NACE method A + 30 days faster leadtime
VM 90 S VM 95 S 90 - 105 95 - 110 621 - 724 655 - 758 100 105 690 724 24.0 25.0 85% 85% 10% 10% w/o w/o
Enhanced Sour Service grades Fully API compliant * + 85% / 90% SMYS guarantied + test NACE method A provided
VM 80 SS VM 90 SS VM 95 SS VM 110 SS * 80 - 95 90 - 105 95 - 110 110 - 125 552 - 655 621 - 724 655 - 758 758 - 862 95 100 105 120 655 690 724 828 22.0 24.0 25.0 30.0 90% 90% 90% 85% 10% 100% 100% 100% Method A Method A Method A Method A
NACE-D Sour Service grades Fully API compliant * + 85% / 90% SMYS guarantied + K 1SSC guarantied + NACE method D test provided
VM 95 SS-D VM 110 SS-D * 95 - 110 110 -125 655 - 758 758 - 862 105 120 724 828 25.4 30.0 90%** 85% 30 - 33 22 - 24 33 - 36 24 - 27 100% 100% Method D Method D
* VM 110 SS and VM 110 SS-D follow the QA/QC philosophy of T95 ** For very heavy coupling stock, Method A guaranty is 85% SMYS. Please contact us.
Hardness
HRC (max)
Color Code
Time Saving High Collapse & Sour Service grades Same chemistry as HCSS series + 85% SMYS garantied NACE-A + 30 days faster leadtime
VM 90 HCS VM 95 HCS 90 - 105 95 - 110 621 - 724 655 - 758 100 105 690 724 24.0 25.0 85% 85% 10 % 10% w/o w/o
Enhanced High Collapse & Sour Service grades Fully API compliant * + 85% / 90% SMYS guarantied NACE-A + NACE-A tests provided
VM 80 HCSS VM 90 HCSS VM 95 HCSS VM 110 HCSS * 80 - 95 90 - 105 95 - 110 110 - 125 552 - 655 621 - 724 655 - 758 758 - 862 95 100 105 120 655 690 724 828 22.0 24.0 25.0 30.0 90% 90% 90% 85% 10% 100% 100% 100% Method A Method A Method A Method A
Size OD in. 41/2" 41/2" 41/2" 5" 5" 51/2" 51/2" 51/2" 51/2" 65/8" 65/8" 65/8" 7" 7" 7" 7" 7" 7" 7" 7" 75/8" 75/8" 75/8" 75/8" 75/8" 75/8" 75/8" 75/8" 73/4" 85/8" 85/8" 85/8" 85/8" 85/8" 95/8" 95/8" 95/8" 95/8" 95/8" 95/8" 95/8" 95/8" 95/8" 93/4" 97/8"
DIMENSIONS Nominal Weight mm lb/ft 114.3 11.60 114.3 13.50 114.3 15.10 127.0 15.00 127.0 18.00 139.7 17.00 139.7 20.00 139.7 23.00 139.7 26.80 168.3 24.00 168.3 28.00 168.3 32.00 177.8 23.00 177.8 26.00 177.8 29.00 177.8 32.00 177.8 35.00 177.8 38.00 177.8 41.00 177.8 42.70 193.7 26.40 193.7 29.70 193.7 33.70 193.7 39.00 193.7 41.00 193.7 42.80 193.7 45.30 193.7 47.10 196.9 46.10 219.1 36.00 219.1 40.00 219.1 44.00 219.1 49.00 219.1 52.00 244.5 40.00 244.5 43.50 244.5 47.00 244.5 53.50 244.5 58.40 244.5 59.40 244.5 61.10 244.5 64.90 244.5 70.30 247.7 59.20 250.8 62.60
Nominal Wall Thickness in. mm 0.250 6.35 0.290 7.37 0.337 8.56 0.296 7.52 0.362 9.19 0.304 7.72 0.361 9.17 0.415 10.54 0.500 12.70 0.352 8.94 0.417 10.59 0.475 12.07 0.317 8.05 0.362 9.19 0.408 10.36 0.453 11.51 0.498 12.65 0.540 13.72 0.590 14.99 0.625 15.88 0.328 8.33 0.375 9.53 0.430 10.92 0.500 12.70 0.537 13.64 0.562 14.27 0.595 15.11 0.625 15.88 0.595 15.11 0.400 10.16 0.450 11.43 0.500 12.70 0.557 14.15 0.595 15.11 0.395 10.03 0.435 11.05 0.472 11.99 0.545 13.84 0.595 15.11 0.609 15.47 0.625 15.88 0.672 17.07 0.734 18.64 0.595 15.11 0.625 15.88
psi 7490 9280 11390 8220 10890 7430 9520 11500 14550 7000 8980 10740 5420 6720 8040 9340 10630 11840 13280 14290 4960 6200 7660 9510 10490 11150 12020 12810 11770 5640 6810 7980 9310 10200 4480 5400 6180 7710 8750 9050 9380 10370 11660 8590 9050
HCSS
80 ksi
HIGH COLLAPSE RESISTANCE 90 ksi 95 ksi psi 8230 10260 12640 9060 12080 8160 10530 12770 16300 7680 9920 11910 5880 7350 8850 10320 11790 13160 14790 15930 5210 6770 8420 10520 11620 12370 13360 14260 13070 6130 7460 8780 10290 11300 4480 5860 6740 8470 9660 9990 10370 11490 12960 9480 10000
MPa 51.6 64.0 78.5 56.7 75.1 51.3 65.7 79.3 100.3 48.3 61.9 74.1 37.4 46.3 55.4 64.4 73.3 81.7 91.6 98.5 34.2 42.8 52.8 65.6 72.3 76.9 82.9 88.4 81.1 38.9 46.9 55.0 64.2 70.3 30.9 37.2 42.6 53.1 60.3 62.4 64.7 71.5 80.4 59.2 62.4
HCS, HCSS
MPa 56.7 70.7 87.2 62.5 83.3 56.3 72.6 88.1 112.4 52.9 68.4 82.2 40.6 50.7 61.0 71.2 81.3 90.7 102.0 109.8 36.0 46.7 58.1 72.5 80.2 85.3 92.1 98.3 90.1 42.3 51.4 60.5 70.9 77.9 30.9 40.4 46.5 58.4 66.6 68.9 71.5 79.2 89.3 65.4 68.9
psi 8580 11090 13260 9470 12660 8520 11410 13390 17130 8000 10370 12490 6110 7740 9400 11160 12910 13800 15530 16740 5210 7040 8790 11010 12180 12970 14020 14970 13710 6370 7770 9170 10770 11830 4480 6080 7090 8950 10360 10450 10850 12030 13590 9910 10780
HCS, HCSS
110 ksi psi 9590 12100 15050 10620 14350 9510 12440 15210 19570 8910 11680 14150 6110 8510 10370 12180 13990 15690 17700 19120 5210 7800 9830 12420 13790 14720 15940 17050 15580 6580 8640 10280 12140 13390 4480 6080 7570 9900 11360 11770 12240 13620 15440 11140 11780
MPa 59.2 76.5 91.4 65.3 87.3 58.7 78.7 92.4 118.1 55.2 71.5 86.1 42.1 53.4 64.8 77.0 89.0 95.2 107.1 115.4 36.0 48.6 60.6 75.9 84.0 89.4 96.7 103.2 94.6 43.9 53.6 63.2 74.2 81.6 30.9 41.9 48.9 61.7 71.4 72.1 74.8 83.0 93.7 68.3 74.3
HCSS
Size OD in. 10" 10" 10" 103/4" 103/4" 103/4" 103/4" 103/4" 103/4" 103/4" 113/4 113/4 113/4 113/4 113/4 117/8" 12" 12" 12" 12" 123/4" 123/4" 123/4" 127/8" 133/8" 133/8" 133/8" 133/8" 133/8" 133/8" 131/2" 135/8" 135/8" 14" 14" 14" 14" 14" 16" 16" 16" 16" 16" 16" 16"
MPa 66.2 83.5 103.8 73.2 98.9 65.6 85.8 104.9 135.0 61.4 80.5 97.6 42.1 58.7 71.5 84.0 96.5 108.2 122.1 131.8 36.0 53.7 67.8 85.7 95.1 101.5 109.9 117.6 107.5 45.4 59.6 70.9 83.7 92.3 30.9 41.9 52.2 68.2 78.3 81.2 84.4 93.9 106.4 76.8 81.2
DIMENSIONS Nominal Weight mm lb/ft 254.0 54.30 254.0 60.30 254.0 68.90 273.1 51.00 273.1 55.50 273.1 60.70 273.1 65.70 273.1 68.80 273.1 73.20 273.1 79.20 298.5 54.00 298.5 60.00 298.5 65.00 298.5 71.00 298.5 75.00 301.6 71.80 304.8 68.00 304.8 73.00 304.8 76.00 304.8 86.50 323.9 57.60 323.9 65.10 323.9 70.10 327.0 66.60 339.7 61.00 339.7 68.00 339.7 72.00 339.7 77.00 339.7 80.70 339.7 86.00 342.9 81.40 346.1 88.20 346.1 105.00 355.6 82.5 355.6 94.80 355.6 99.30 355.6 103.50 355.6 110.00 406.4 75.00 406.4 84.00 406.4 94.50 406.4 109.00 406.4 118.00 406.4 128.00 406.4 147.00
Nominal Wall Thickness in. mm 0.531 13.49 0.595 15.11 0.688 17.48 0.450 11.43 0.495 12.57 0.545 13.84 0.595 15.11 0.636 16.15 0.672 17.07 0.734 18.64 0.435 11.05 0.489 12.42 0.534 13.56 0.582 14.78 0.618 15.70 0.582 14.78 0.547 13.89 0.589 14.96 0.610 15.49 0.707 17.96 0.433 11.00 0.492 12.50 0.531 13.49 0.495 12.57 0.430 10.92 0.480 12.19 0.514 13.06 0.550 13.97 0.580 14.73 0.625 15.88 0.580 14.73 0.625 15.88 0.760 19.30 0.562 14.27 0.656 16.66 0.688 17.48 0.720 18.29 0.772 19.61 0.438 11.13 0.495 12.57 0.562 14.27 0.656 16.66 0.715 18.16 0.781 19.84 0.906 23.01
psi 7000 8290 10160 4730 5570 6510 7450 8220 8890 10060 3280 4680 5450 6280 6890 6170 5480 6190 6540 8170 2520 3730 4690 3690 2130 2980 3900 4540 5030 5710 4950 5540 7540 4210 5740 6200 6660 7410 1300 1890 2790 4500 5300 6130 7710
HCSS
80 ksi
HIGH COLLAPSE RESISTANCE 90 ksi 95 ksi psi 7670 9130 11250 4790 6060 7120 8180 9050 9820 11130 3280 4710 5920 6850 7550 6730 5950 6750 7150 9000 2520 3730 4720 3690 2130 2980 3900 4540 5350 6210 5190 6010 8280 4210 6240 6770 7290 8140 1300 1890 2790 4500 5750 6690 8470
MPa 48.2 57.1 70.1 32.6 38.4 44.9 51.4 56.7 61.3 69.3 22.6 32.3 37.6 43.3 47.5 42.5 37.8 42.6 45.1 56.3 17.4 25.7 32.3 25.4 14.7 20.6 26.9 31.3 34.7 39.4 34.1 38.2 52.0 29.0 39.6 42.7 45.9 51.1 9.0 13.0 19.3 31.0 36.5 42.3 53.1
HCS, HCSS
MPa 52.9 63.0 77.6 33.1 41.8 49.1 56.4 62.4 67.7 76.8 22.6 32.5 40.8 47.3 52.1 46.4 41.0 46.6 49.3 62.0 17.4 25.7 32.5 25.4 14.7 20.6 26.9 31.3 36.9 42.8 35.8 41.4 57.1 29.0 43.0 46.6 50.2 56.1 9.0 13.0 19.3 31.0 39.6 46.1 58.4
psi 7990 9540 11790 4790 6290 7410 8530 9460 10270 11660 3280 4710 6140 7130 7870 7000 6170 7020 7440 9400 2520 3730 4720 3690 2130 2980 3900 4540 5350 6450 5190 6240 8640 4210 6480 7030 7590 8590 1300 1890 2790 4500 5870 6950 8840
HCS, HCSS
110 ksi psi 8900 10710 13330 4790 6440 8220 9540 10610 11560 13190 3280 4710 6180 7890 8760 7750 6240 7770 8260 10540 2520 3730 4720 3690 2130 2980 3900 4540 5350 6560 5190 6370 9660 4210 6790 7780 8430 9480 1300 1890 2790 4500 5870 7690 9900
MPa 55.1 65.8 81.3 33.1 43.3 51.1 58.8 65.2 70.8 80.4 22.6 32.5 42.3 49.1 54.3 48.3 42.6 48.4 51.3 64.8 17.4 25.7 32.5 25.4 14.7 20.6 26.9 31.3 36.9 44.5 35.8 43.0 59.6 29.0 44.7 48.5 52.3 59.2 9.0 13.0 19.3 31.0 40.5 48.0 61.0
HCSS
MPa 61.4 73.8 91.9 33.1 44.4 56.7 65.8 73.2 79.7 90.9 22.6 32.5 42.6 54.4 60.4 53.4 43.0 53.6 57.0 72.7 17.4 25.7 32.5 25.4 14.7 20.6 26.9 31.3 36.9 45.2 35.8 43.9 66.6 29.0 46.8 53.7 58.1 65.4 9.0 13.0 19.3 31.0 40.5 53.0 68.2
V&M TUBES offers a large range of OCTG material suitable for Sour Service environment where H2S is present. It covers the requirements and parameters of such inhospitable conditions including high pressures, low temperatures, low pH, and more. More than anywhere else, reliability is paramount and V&M TUBES provides the required top-of-the-class expertise and know how.
Full range of products Heavier and higher Yield Strength material Improved Sulfide Stress Cracking resistance Reliable quality and leadtime Fit-for-purpose approach Single source of your complete solution
It is important to note that these crack failures can occur with stresses below the elastic limit of the material.
It introduced pH as an additional major factor influencing how critical the environment is, along with specific tests that have become standard in order to qualify material for Sour Service environment.
In that regard, materials according to API 5CT (ISO 11960) do comply with NACE MR0175, as a function of temperature level. Outside these envelopes proprietary grades are required.
4. Material evaluation
The objective is to assess whether a given material is suitable for Sour Service conditions. NACE TM0177 has defined and normalized several tests: Methods A to D. They typically use a critical and normalized sour service environment calledenvironment A (with the exception of Method B that does not require NaCl addition). They differ by the way the stress is applied to the test specimen and can fit into 2 categories :
6. NACE Method D
A Double Cantilever Beam (DCB) is manufactured from the base material, taken longitudinally. A tapered wedge is used to load the test specimen which is then, enclosed in the sour environment, for 360 hours (15 days).
Go / No Go type tests provide a binary result: Either the material passes the test or not. NACE methods A, B and C belong to this first category. Method D provides a level of performance through the measurement of the crack propagation.
The sample is then retrieved, failed open, and the crack length measured.The resistance to crack propagation K1SSC is calculated, providing a direct numerical rating. Acceptance criterion is defined by API 5CT, for example the K1SSC minimum average value for grade T95 should be not less than 30 ksiV in.
To be considered suitable for Sour Service environments, a material has to pass at least one of these tests. MethodsA and D are the most commonly used in the industry.
V&M TUBESSour Service range is composed of 3 series to fulfil the customersrequirements with regards to the mechanical properties and level of reliability:
V&M Proprietary Grades API reference V & M Guaranty Method D Method A
(SMYS) min single - min avg (ksiV in)
A larger domain of application and an enhanced safety margin through the SSC resistance guaranteed and demonstrated up to 90% of the material Yield Strength v.s. 80% with API (NACE method A test);
NACE TM01 77 method A : tensile test results 100
90% actual YS
90
80
70
S series Time Saving Available in grades 90 and 95 ksi. I Same chemistry and process as SS series. I 85% threshold stress guaranty, higher than 80% in API. I Reduced lead time, as fast as for standard grades, thanks to the mill quality record that proves SSC resistance without additional NACE method A test.
I
60 90 95 100 Yield strength (ksi) 105 110
Higher Strength materials, like VM110SS-D or VM110HCSS with 110 ksi Yield Strength; Enhanced reliability of the product and its delivery thanks to the improved Quality Control and Quality Assurance; Reduced lead time thanks to V&M TUBES proven success record in performing NACE testing, allowing parallel shipping of the material; Heavy pipe and coupling stock up to 2in wall thickness, with the same Sour Service guaranty; Top performance and reliability in HP-HT wells, when combined with V&M High Collapse technology.
SS series Enhanced API Available in grades 80 to 110 ksi. Fully compliant withAPI (or its QA/QC philosophy for VM 110 SS grade). I 85% / 90% threshold stress guaranty, higher than 80% in API. I Delivered with NACE method A test.
I I I
SS-D series NACE-D Available in grades 95 and 110 ksi. Fully compliant withAPI (or its QA/QC philosophy forVM 110 SS-D) I 85% / 90% threshold stress guaranty, higher than API. I K1SSC guaranty, higher than API. I Delivered with NACE method D test.
I I I
Special sizes, for HP-HT wells in particular; V&M SSC data base with more than 10,000 test results, including DCB tests;
Special NACE testing with adapted objectives, parameters and targets; Close coordination with customers and material experts to fit the global Sour Service evaluation into an operating plan; Faster lead time approach extended to higher grades like VM80SS upon request and agreed quality plan.
Pipe finishing for OCTG market includes full length mill threading and stock management in 9 facilities around the world, in France, Germany, UK, USA, Canada, Mexico, Brazil and Indonesia, a VAM Licensee network of more than 100 accessory and repair shops around the world and a quality, documentation and gauge rental system managed by VAM Services.
There are more than 20 scientists and material experts working in our 3 Research & Development laboratories located in France and Germany. They can elaborate mini-heats on their own, perform more than 600 SSC tests per month at full thrust, and rely on the full support of 16 steel and pipe manufacturing mills around the world.
V&M TUBES large spectrum of experience is further illustrated below: 4 1/2 5 6 5/8 7 7 8 5/8 9 5/8 9 5/8 10 1/4 10 3/4 14 0.271 0.408 0.417 0.453 0.498 0.850 0.545 0.595 0.800 0.950 0.800 VM 80 SS VM 95 HCS VM 90 SS VM 95 S VM 110 SS-D C90 VM 110 SS VM 110H CSS T95 VM 110 SS VM 95 SS-D North America Far East Caspian Sea West Africa North Sea Gulf of Mexico Latin America Middle East Caspian Sea North Sea Caspian Sea*
15. References
[1] Development of C110 grade for Sour Service, B. Orlans et al., Paper #147, 1993 NACE Conference [2] Heavy Wall casing in C110 grade for Sour Service, C. Linne et al., Paper #117, 1998 NACE Conference [3] Experience in Corrosion Testing according to NACE standard TM0177 Methods A and D on T95 grade steel for OCTG, R. Poepperling et al. , Paper #151, 2000 NACE Conference [4] NACE TM0177 Method D test procedure (DCB), Learnings from comparative laboratory testing, K. Szklarz et al. , Paper #3104, 2003 NACE Conference
V & M OIL & GAS UK V & M RUS VAM CANADA V & M OIL & GAS FRANCE VAM USA V & M TUBES VAM DUBA V&M DEUTSCHLAND VAM CASPIAN V & M BEIJING
VAM MEXICO
VMOG NIGERIA
Sales offices
VAM ANGOLA V & M DO BRASIL
Steel making plants Manufacturing plants Accessories and repair VAM licensee facilities VAM Field Service International
Mexico
Brazil
Nigeria
Angola
UAE
Indonesia
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SALES OFFICES
VALLOUREC MANNESMANN OIL & GAS FRANCE 27, avenue du Gnral Leclerc 92660 Boulogne Billancourt Cedex France Phone +33 1 49093731 Fax +33 1 49093713 V&M DEUTSCHLAND Oil & Gas Division Theodorstrasse 90 40472 Dsseldorf, Germany Phone +49 211 960-0 Fax +49 211 960-3924 VALLOUREC MANNESMANN OIL & GAS UK Prospect Place Westhill Industrial Estate, Westhill Aberdeenshire, UK - AB32 6SY Phone +44 1224 279340 Fax +44 1224 279341 V&M TUBES 1990 Post Oak Blvd, Suite 1400 Houston, TX 77056-3813, USA Phone +1 713 4793200 Fax +1 713 4793201 V&M BEIJING Room 301, East Ocean Center 24A, Jianguomenwai Avenue Beijing 100004, P.R. China Phone +86 10 5923 3000 Fax +86 10 59 23 3001
VALLOUREC & MANNESMANN RUS Office E02-305 4th Dobryninsky pereulok, 8, Moscow, 119049, Russia Phone +7 495 787-49-30 Fax +7 495 787-49-31 VALLOUREC MANNESMANN OIL & GAS NIGERIA 15B Akanbi Danmola Street South West Ikoyi, Lagos, Nigeria Phone +234 1 463 0840 Fax +234 1 463 0841
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VAM FIELD SERVICE BEIJING Room 1001-1002 Electronic City Science and Technology Building 12A Jiu Xian Qiao Road Chaoyang District Beijing 100016, P.R. China Phone +86 10 6438 3145/4513 Fax +86 10 6438 6402 VAM ANGOLA Sonils Business Centre (Office 015) RUA 6-1L Boavista Luanda, Republic of Angola Phone +244 222 670 439 Fax +244 222 310 910 VAM CASPIAN 340 Nizami Street ISR Plaza 3rd Floor Baku AZ1000, Azerbaijan Phone +994 12 493 2939 Fax +994 12 498 7132 VAM SERVICES Licensee Network 21-23 rue de Leval 59620 Aulnoye Aymeries, France Phone +33 3 27696615 Fax +33 3 27664575
SERVICES OFFICES
VAM FIELD SERVICE INTERNATIONAL Prospect Place Westhill Industrial Estate, Westhill Aberdeenshire, UK - AB32 6SY Phone +44 1224 279380 Fax +44 1224 279384 VAM FAR EAST No. 16, Jalan Kilang Timor #06-05, Redhill Forum Singapore 159308 Phone +65 6736 23 72 Fax +65 6235 11 26
www.vamservices.com
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