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Mini Analyser

Edition 1.0

User Manual

+61 7 4660 1888


Greenspan Customer Service
Technical Support When You Need It
The correct choice of sensor should be supported by professional advice to ensure long term success in the field. Greenspan Technical Services is dedicated to customer support and provides assistance in the selection, installation, deployment and commissioning of sensors with a full range of consulting services. A full technical support and field advice service can be accessed by ringing Customer Service on +61 7 4660 1888 between 8am - 6pm, 5 days a week. All requests for information will be serviced within 24 hours. All Greenspan products are designed, developed and manufactured in Australia and can be supplied at short notice.

Warranty Details
Greenspan warrants all new Greenspan products against defects in materials and workmanship for 12 months from the date of invoice. During the warranty period, we will repair or, at our option, replace at no charge a product that proves to be defective provided that it is returned, shipping prepaid, to Greenspan Technology Pty Ltd. Greenspans liability and obligations in connection with any defects in materials and workmanship are expressly limited to repair or replacement, and the sole and exclusive remedy in the event of such defects shall be repair or replacement. Greenspans obligations under this warranty are conditional upon it receiving prompt written notice of claimed defects within the warranty period and its obligations are expressly limited to repair or replacement. This warranty does not apply to products or parts thereof which have been altered or repaired outside of the Greenspan factory or other authorised service centre, or products damaged by improper installation or application, or subjected to misuse, abuse neglect or accident. This warranty also excludes items such as reference electrodes and Dissolved Oxygen membranes that may degrade during normal use. Greenspan Technology Pty Ltd will not be liable for any incidental or consequential damage or expense incurred by the user due to partial or complete inoperability of its products for any reason whatsoever or due to inaccurate information generated by its products. All Warranty service will be completed as soon possible. If delays are unavoidable customers will be contacted immediately. The sensors should not be dismantled unless under instruction from Greenspan. handling will void the warranty. Incorrect

TABLE OF CONTENTS
TABLE OF CONTENTS 1
1.1

I 1
2

INTRODUCTION
Applications

2
2.1 2.2

SAFETY
Guidelines For Working With Chemicals Other Safety Guidelines

3
3 3

3
3.1 3.2 3.3 3.4 3.5 3.6 3.7

OVERVIEW OF MINI-ANALYSER
The Greenspan Mini-Analyser Communications Interface Serial Communication Port Battery Back-Up Configuration File Sample Delivery Optional 4-20mA Output

4
4 5 5 6 6 7 7

4
4.1 4.2 4.3 4.4 4.5

WATER QUALITY PARAMETERS


Dissolved Oxygen Electrical Conductivity ORP pH Turbidity

8
8 8 8 9 9 9 9 10 10 10

4.6 Ammonia and Ammonium 4.6.1 Ammonia 4.6.2 Ammonium 4.7 4.8 Nitrate Phosphate

5 6

GETTING STARTED CHECKLIST INSTALLATION

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6.1 Choosing the site 6.1.1 Positioning the Analyser 6.1.2 Positioning the pump 6.2 Setting up the Mini-Analyser 6.2.1 Mounting the cabinets 6.2.2 Unpacking the battery and sensors 6.3 Configuring the communications 6.3.1 Connecting the modem 6.4 Installing the sample delivery module 6.4.1 Selecting a position for the module 6.4.2 Mounting the sample delivery module 6.4.3 Connecting The sample delivery and Analyser 6.4.4 Connecting the pump to the sample delivery 6.5 Installing the sample delivery pump control module 6.5.1 Checking the operation of the sample delivery 6.6 Connecting or adding external devices

12 12 12 13 13 13 14 14 14 14 15 15 16 16 17 17 17 17 18

6.7 Getting the Analyser commissioned 6.7.1 Running some test schedules 6.7.2 Testing a known sample

7
7.1

COMMUNICATIONS
Getting Started with the User Interface

19
19 19 20

7.2 Installing a Modem 7.2.1 Setting the modem initialisation string

SCHEDULES

21
21 21 22 22 22 22 22 22 22 23 24 24 25 25 26 26 27 27 27 27 28

8.1 Working With Schedules Using Analyser32 8.1.1 Setting up a schedule 8.1.2 Creating or editing schedules 8.1.3 Entering a name 8.1.4 Viewing and editing tests in the schedule 8.1.5 The schedule duration 8.1.6 Timing a schedule 8.1.7 Enabling the schedule 8.1.8 The scheduler priority 8.1.9 Using periodic triggering 8.1.10 Using timetable triggering 8.1.11 Using event triggering 8.1.12 Using the external trigger 8.1.13 Using initial triggering 8.1.14 Editing the tests for a schedule 8.1.15 Adding fill and clean operations 8.2 Starting a Schedule Using Analyser32 8.2.1 The current date/time display 8.2.2 Inserting comments 8.2.3 Operator identification 8.2.4 Clear memory

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8.3 Stopping a Schedule 8.3.1 The last started display 8.3.2 Current date/time 8.3.3 Inserting a comment 8.3.4 Operator identification 8.3.5 Confirming the end of scheduling

28 28 28 28 29 29

ALARMS

30
30 31 31 32 32 33 33 33 33 34 35 35 36 36

9.1 Setting Alarms With Analyser32 9.1.1 Setting the sample alarms 9.1.2 Memory alarm 9.1.3 The battery alarm 9.1.4 The solutions alarms 9.1.5 Water or liquid ingress 9.1.6 Enabling an external output 9.1.7 Alarms and the data log 9.1.8 Enabling the alarm system 9.1.9 Dialout on alarm 9.1.10 Receiving dialout alarms 9.2 Clearing Alarms With Analyser32 9.2.1 Clearing the alarm 9.2.2 Cancelling a dialout

10 DOWNLOADING DATA
10.1 Downloading Data using Analyser32 10.1.1 Downloading the entire data log 10.1.2 Downloading new data 10.1.3 Downloading data between dates

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36 37 37 37

11 CHEMICAL STORE
11.1 11.2 Changing Solution Bottles Updating Reagents Using Analyser32

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38 40 41 41 41

11.3 Waste Disposal 11.3.1 Unmodified waste 11.3.2 Modified waste

12 CHECKING MEASUREMENTS AND SENSORS


12.1 Dissolved Oxygen 12.1.1 Analysing the DO data 12.2 Electrical Conductivity 12.2.1 Analysing the EC data 12.3 Oxidation-Reduction Potential Analysing the pH data

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42 42 44 44 46 46 46 48 48

12.4 pH 12.4.1

12.5 Turbidity 12.5.1 Analysing the turbidity data

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12.6 Ammonia 12.6.1 Analysing the ammonia data 12.7 Ammonium 12.7.1 Analysing the ammonium data 12.8 Nitrate 12.8.1 Analysing the nitrate data 12.9 Phosphate 12.9.1 Analysing the phosphate data

50 50 52 52 54 54 56 56

13 MAINTENANCE
13.1 General Mini-Analyser Maintenance 13.1.1 Stopping or aborting the schedule 13.1.2 Cabinet 13.1.3 Pump tubing 13.1.4 Setting the pump pressure 13.1.5 Sample/chemical tubing 13.1.6 Valve tubing 13.1.7 Sample delivery pot 13.1.8 The water ingress detector 13.1.9 Running diagnostics 13.1.10 The clean regime 13.2 Sensor Maintenance 13.2.1 Replacing sensor bodies and electrodes 13.2.2 DO 13.2.3 EC 13.2.4 ORP 13.2.5 pH 13.2.6 Turbidity 13.2.7 Ammonia 13.2.8 Ammonium 13.2.9 Nitrate 13.2.10 Reference electrodes. 13.2.11 Phosphate 13.3 Sensor Calibration 13.3.1 Dissolved oxygen 13.3.2 Electrical conductivity 13.3.3 Oxidation-reduction potential 13.3.4 pH 13.3.5 Turbidity 13.4 Maintenance Schedule

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58 58 58 59 59 60 61 61 62 62 64 65 65 66 67 69 70 71 72 74 75 76 77 78 80 82 84 86 87 90

14 UPGRADING FIRMWARE
14.1 14.2 14.3 Direct connection Modem connection. Uploading the firmware

91
91 92 93

15 TROUBLESHOOTING

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15.1 15.2 15.3

Common Mini-Analyser problems. Analyser Problems within the Mini-Analyser Communications Problems

97 98 99

16 SPECIFICATIONS
16.1 16.2 16.3 16.4 16.5 16.6 16.7 16.8 16.9 16.10 16.11 16.12 16.13 16.14 Mechanical Power Supply Communications Telephone Modem GSM Modem Operating Environment Housing Requirements Measurement Range Measurement Accuracy Measurement Times Sensor Life External inputs External Outputs Storage Conditions

101
101 101 101 101 101 102 102 102 102 103 103 103 103 103

17 SPARE PARTS LIST.


17.1 17.2 17.3 17.4 17.5 Sensors Electronics Cables Plastic parts Miscellaneous

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104 105 106 107 108

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1 INTRODUCTION
This manual covers all sensor configurations available for the Mini-Analyser. The analyser you have purchased may not contain all these sensors depending on the configuration that you have purchased. Please refer to the sections that are relevant to your analyser. The setting of new environmental standards worldwide has created a demand for instruments that can provide water quality data for the monitoring of natural water systems. The Greenspan Mini-Analyser offers the maximum features and flexibility of this range of instruments. Aimed at the task of environmental and industrial monitoring the Mini-Analyser is capable of remote communications access and on-line measurement. The most important advantages of on-line measurement are speed and the integrity of results. Many properties can change if the sampled water is exposed to air or sunlight or is stored for a period of time before testing. The Mini-Analyser allows measurements to be taken quickly without the need to add preservatives or to freeze the sample. Between measurements the sensors are automatically cleaned and are either immersed in a suitable storage solution or stored under conditions designed to prolong sensor life. Permanently submerged sensors will generally have shorter lives and therefore need to be replaced more often. The Mini-Analyser is available in several configurations covering most of the important water quality parameters.

PHYSICAL MEASUREMENTS Dissolved Oxygen Electrical Conductivity Oxidation-Reduction Potential pH Temperature Turbidity

OTHER FEATURES 8 external sensor inputs plus rain gauge input can be configured for multiple sample inlets external alarm output remote access, using telephone, mobile network or satellite phone direct access using serial communications port large data log capacity automatic calibration of ammonia/ammonium, nitrate and phosphate sensors temperature compensation for dissolved oxygen, electrical conductivity and pH

ION SPECIFIC MEASUREMENTS Ammonia or Ammonium Nitrate

PHOTO-COLORIMETRIC MEASUREMENTS Phosphate

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The Mini-Analyser can be thought of as an automated chemical laboratory. It consists of pumps, valves, tubing, chemical storage and sensors interconnected so that a wide range of tasks can be performed. Controlled by a microprocessor it provides for excellent accuracy, precision and flexibility. Figure 1 shows a simplified block diagram.

Figure 1: Mini-Analyser block diagram 1.1 Applications The Mini-Analyser has been designed as a stand-alone analyser for installation in a diverse range of applications, some of these include: River Monitoring: Greenspan Analysers are used extensively to monitor river water quality prior to extraction for treatment and distribution by the water supply network Wastewater: The on-line monitoring of nutrient levels in wastewater treatment plants Wetlands: Unattended operation in remote areas monitoring the impact of human and agricultural nutrient levels on wetlands Harbour Monitoring: Used in conjunction with external sensors linked to the system, to monitor physical and nutrient levels and alert to the possible pollution of the waters Aquaculture: The Mini-Analyser can assist farm operators to maintain the best possible levels of nutrients to maximise returns on their investments

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2 SAFETY
2.1 Guidelines For Working With Chemicals 1. Always follow approved procedures when handling, storing, packaging or using chemicals and chemical waste. 2. Personnel who handle chemicals and waste must be trained in these procedures and informed of the potential hazards associated with them. 3. Always read the material safety data sheets before using a chemical. In particular read the first aid information. The material safety data sheet should also provide information on the correct storage and transport of that material. 4. Wear protective clothing when handling chemicals. This includes eye protection, rubber gloves and protective coat or apron. 5. Do not consolidate untreated Mini-Analyser waste with any other waste. 6. Keep a record of chemical inventory. This does not apply to chemicals installed in the Mini-Analyser cabinet. Approximately every six months check that all chemicals are stored correctly, in particular check for damaged labels, outdated chemicals and damaged containers. 7. Chemicals when stored should be segregated according to hazard class and compatibility. The ammonia ionic strength adjuster (ISA) reagent is classed as corrosive. 8. The waste container should not be allowed to fill more than 90% full. The headspace is needed for ease of dispensing. 2.2 Other Safety Guidelines Do not attempt to perform maintenance or repairs not covered in this manual. All repairs are to be carried out by Greenspan or Greenspan trained personnel.

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3 OVERVIEW OF MINI-ANALYSER
3.1 The Greenspan Mini-Analyser The Greenspan Mini-Analyser can provide a tailored solution to your specific monitoring needs. Designed specifically to suit certain monitoring situations such as environmental, industrial discharge or single point of source. The Mini-Analyser can be configured to suit a wide range of applications in a variety of locations.

Figure 3.1: Mini-Analyser

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3.2 Communications Interface

The connections to and from the Mini-Analyser terminate at the communications interface as shown in Figure 3.2 The communications interface has the following features: Modem interface. Modem power and data connections are made here. External sensor inputs. Up to 8 external 4 20 mA sensors may be connected. Rain gauge input. External alarm output. An external output pulse can be generated from an alarm occurring within the Mini-Analyser. This can be used to trigger a warning bell or light. Pump control output. This controls the pump that draws sample water from the source (river, lake etc) into the sample pot. Sampler trigger output. This can control an external water sampler. 4 20 mA parameter outputs. Normally 4 but expandable to 8. External output control signals. The analyser can be configured with up to 20 additional 12Vdc outputs for controlling external devices.

3.3 Serial Communication Port To make a direct connection from a PC to the Mini-Analyser, use the serial port located on the lower right-hand side panel. The connector is labelled User. Figure 3.2 shows the location of this connector. The connector is a standard 9-pin female Dconnector. Figure 3.2: Communications interface

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3.4 Battery Back-Up The Mini-Analyser electronics are powered from a 12V DC lead-acid gel battery. The battery is kept charged from the AC mains power. In case of loss of AC mains power supply the battery can keep the Mini-Analyser running for many hours. The output of the battery charger is set to 14.7VDC on charge and 13.8VDC on float. Do not adjust the power supply to any other voltage. 3.5 Configuration File The configuration file is stored in the Mini-Analysers memory and is a very important file. The information it contains includes: The serial number Calibration data Machine control code - for the control of pumps and valves User configurable settings - site information, phone numbers, alarm settings and schedule details. Chemical store information - reagent levels, constituents etc.

A default configuration file is loaded into the Mini-Analyser at the factory. The Analyser32 software updates this file when user configurable settings are changed.

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3.6 Sample Delivery

Fig 3.6: Sample deliver system When the Mini-Analyser requires sample for testing, the sample delivery system is initiated. Upon initiation of the sample delivery system the Mini-Analyser starts the sample delivery pump and pumps water through the sample pot for several minutes ensuring that the pot has been flushed and filled with fresh sample. During the sample pumping a small valve on top of the sample pot is closed. At the end of the sample-pumping period the pump stops and the valve is opened venting the top of the pot to atmosphere. The Mini-Analyser then primes the sample from the pot to the analysis area for several minutes. The system is now ready to begin testing.

3.7 Optional 4-20mA Output The Mini-Analyser can be configured to transmit sensor results to other control and data capture / display systems such as those used in water treatment plants. This data can be transmitted using an optional 4 - 20 mA current loop printed circuit assembly. Each assembly is capable of four data outputs. Voltage and current specifications: Supply voltage range 8 to 30VDC with 100R load. Reverse polarity protected to 30VDC Maximum load of 340R with 12V supply.

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4 WATER QUALITY PARAMETERS


This section details the various parameters measured by the Mini-Analyser providing background information on: What the parameters are. How the Mini-Analyser measures these parameters.

4.1 Dissolved Oxygen Dissolved oxygen refers to the amount of oxygen dissolved in the water. DO can be significantly influenced by factors such as temperature, presence of dissolved salts and the biological and chemical demand of the water. To measure DO, the Mini-Analyser uses a galvanic cell type oxygen sensor. The sensor is a lead-oxygen battery, which has a lead anode and gold cathode. Oxygen molecules enter the cell through a semi-permeable membrane. They then diffuse in the acid electrolyte and are reduced at the gold electrode. A temperature compensated voltage output is proportional to the partial pressure of oxygen concentration. The Mini-Analyser measures DO in % saturation. 4.2 Electrical Conductivity Electrical conductivity is a measure of how well a solution conducts electrical current. It can be used to detect changes in the water system, ie new pollutants or rising salinity. To measure EC the Mini-Analyser uses a flow cell with two electrodes. The Mini-Analyser makes a resistance/conductivity measurement using alternating current. Alternating current is used in EC measurements to prevent polarisation occurring. The spacing and size of the electrodes determines the cell constant. The Mini-Analyser EC sensor has a cell constant of 1 cm-1. 4.3 ORP ORP, oxidation-reduction potential or redox measures the ability of a fluid to be oxidised or reduced (give or take electrons) and is dependent on the types and concentrations of ions present. Oxidation and reduction happen simultaneously; while one substance is being oxidised the other is being reduced. Oxidation and reduction reactions occur until equilibrium is reached. Unreacted agents give the water the ability or potential to oxidise or reduce. This potential is what is measured. The Mini-Analyser measures ORP using a noble metal electrode. When a metal electrode is exposed to varying concentrations of chemicals, an electric potential is developed. The MiniAnalyser uses a platinum electrode for this purpose. The potential of the platinum electrode is measured against that of a reference electrode made from Ag/AgCl. This reference electrode does not vary its potential when chemicals in solution change. ORP is an aggregate measure incorporating all ions that are oxidising or reducing agents. The result is given in mV.

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4.4 pH The pH of a solution is a measure of hydrogen ion activity in a solution. It defines how acidic or alkaline the solution is. Measured on a scale from 0 to 14, a value of 7 is said to be pH neutral, less than 7, acidic and above 7, basic or alkaline. The Mini-Analyser uses a flat, glass electrode pH sensor with a combined double junction reference electrode. The glass has a special composition so that a potential is formed across it in the presence of hydrogen ions. Inside the glass is an electrolyte of constant pH and concentration and a reference electrode which gives a stable voltage as a comparison. Between measurements the pH electrode is stored in moist air to prolong electrode life. 4.5 Turbidity Turbidity is a measure of the amount of suspended solids in a solution. In natural water, turbidity can be caused by clay, silt, small organic matter and microscopic organisms. Turbidity is measured by passing light through a transparent cell containing the sample and measuring the amount of scattered light with a detector. The Mini-Analyser uses a nephelometer in which the detector is orientated at 90 to the emitter. This result is expressed in NTU calibrated against Formazin Standards. 4.6 Ammonia and Ammonium When ammonia is dissolved in water it reacts to form ammonium. Both species are normally present in a solution but the relative amounts of each are influenced by the pH and, to a lesser extent, the ionic strength of the solution. When the Mini-Analyser performs a measurement of ammonia or ammonium all of the species are converted to one type by pH adjustment.
4.6.1 Ammonia

Ammonia has the symbol NH3, and is a pungent colourless gas that is highly soluble in water. A saturated water solution of ammonia contains about 30% ammonia at room temperature. Its main uses are as a fertiliser, a refrigerant (or freezing agent) and for manufacturing nitric acid. The Mini-Analyser uses an ammonia electrode that has a membrane separating the sample from an internal solution. The membrane is permeable to gas and impermeable to water. Dissolved ammonia in the sample solution diffuses through the membrane until the partial pressure of ammonia is the same on both sides of the membrane. The diffused ammonia gas dissolves and its concentration in the form of ammonia is related to the internal concentration of hydroxide ions. The measurement is then similar to a pH probe. The Mini-Analyser uses pH 4 buffer to reset the response of the electrode. Between measurements the Mini-Analyser keeps the electrode stored in a solution appropriate to the sample range being measured. The check results are given in machine counts and the test results are given in ppm.

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4.6.2

Ammonium

Ammonium has the symbol NH4. Formed during the breakdown of protein molecules from organic matter by bacteria, NH4 occurs naturally in water systems. Ammonium is measured with an ion specific electrode (ISE) and a separate half-cell reference. The electrode has an ammonium ion selective membrane. When ammonium is present in the sample a voltage develops across the membrane and is measured with respect to the reference electrode. The sample result is calculated by applying a 2-point calibration each time the Mini-Analyser is used. The check results are given in machine counts and the test results are given in ppm. 4.7 Nitrate The chemical symbol for the nitrate ion is NO3. Nitrate is a very soluble ion and an oxidising agent. It is often found with salts such as potassium (KNO3) or sodium (NaNO3). It is a common ingredient in agricultural fertilisers. The Mini-Analyser measures nitrate using an ion specific electrode (ISE) and a separate reference half-cell. The electrode has a nitrate ion selective membrane. When nitrate is present in the sample a voltage develops across the membrane and is measured with respect to the reference electrode. The sample result is calculated by applying a 2-point calibration each time the Mini-Analyser is used. The check results are given in machine counts and the test results are given in ppm. 4.8 Phosphate Almost all phosphorous found in natural waters is in the form of phosphates. Phosphates are compounds, which include the molecule PO4. They are normally produced from phosphoric acid H3PO4 by removing a number of hydrogen atoms and replacing them with a metal. Commercially phosphates are used in water softeners and fertilisers. The Mini-Analyser uses a colorimetric method to measure phosphate. Reagents added to the sample react with the dissolved phosphate present to produce a blue colour, the strength of which is relative to the amount of phosphate in the sample. A spectrophotometer is used to measure this colour development. The turbidity of the sample is compensated for by measuring an unreacted sample. As there is no filtering of the sample the phosphorus measured by this process is termed total reactive phosphorus. The check results are given in machine counts and the test results are given in ppb or ppm.

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GETTING STARTED CHECKLIST

The following is a checklist to follow when installing and using the Mini-Analyser for the first time. Sections 6-11 will guide you through these steps. 1. Verify that the selected installation site and infrastructure is ready for the installation. 2. Ensure that the chemicals have been mixed according to the supplied Greenspan recipes, placed in the bottles supplied with the analyser and are ready for the installation. 3. Check that the computer to be used at the site has HyperTerminal installed. Refer to section 13.1.9 for detail on setting up HyperTerminal. 4. Install the user interface (Analyser32) on a PC or notebook computer for use at the site. 5. Carry out the installation of the Mini-Analyser and system components. See section 6 6. Set up communications. Set up modems, cables, initialisation strings and telephone numbers. See section 7. 7. Set password access. See Analyser32 Manual, Section 4. 8. Start and stop the analyser. See section 8. 9. Enter schedule details. See section 8. 10. Set alarms and dialout phone numbers. See section 9. 11. Download from the data store. See section 10. 12. Check the chemical store. See section 11. 13. Check measurements and sensors. See section 12.

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6 INSTALLATION
The instructions detailed here are for a typical mains powered installation with a landline telephone connection and one sample inlet. For the installation of optional components consult Greenspan Technology or your local Greenspan representative. 6.1 Choosing the site In most cases, by the time the installation stage has been reached, the sites will have been chosen for the Analyser and the pump. To cover the possibility that your site has not been chosen and prepared prior to the installation we will recap on the preferred criteria.
6.1.1 Positioning the Analyser

The Analyser cabinet should be positioned in a location that offers some protection from the extremes of the weather. An air-conditioned room is ideal but a location on a wall or bench with shelter from the sun and rain is equally acceptable. Extremes of temperature should be avoided ie below 5 Deg C and above 40 Deg C The location should also be away from large electrical or magnetic fields and not be subjected to vibration. High humidity with condensing vapour as you would find at a turbulent outflow is another area to be avoided.
6.1.2 Positioning the pump

The installation of the pump, control module, cable and piping is usually the biggest part of the total installation and will require many hours. The time required will depend on the specific site and may vary considerably with each site but at least one full day may be required for even a relatively simple site. The purpose of the sample delivery pump is to supply a representative sample of the water body being monitored to the analyser location at a flow rate between 20 to 60 litres per minute. The position of the pump in the water source requires careful consideration. Take care to avoid areas where weed, turbulence or silt may foul the pump or have an undesirable influence on the parameters that are to be monitored. The availability of mains power to the pump location is another factor that may influence the siting of the pump. The practical limit for standard cable to supply power to the pump may be as little as 25 metres. This distance depends on the start and run current demands of the pump being used. For longer distances the cable size may need to be upgraded appropriate to the distance involved and this can become quite expensive for long distances. In a typical installation the pump should ideally be installed in a stilling well that is fixed firmly to a pile or solid structure in the water source. The pump should be installed at a depth that is not too close to the bottom to suck up silt or too near the top such that it may run dry should the water level drop appreciably. Security of the pump once installed also has to be taken into account.

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6.2 Setting up the Mini-Analyser The Mini-Analyser has been designed to be able to be fixed to a wall using the optional Wall Mounting Kit available from Greenspan. The unit is also fitted with rubber feet for sitting directly onto a bench or tabletop. The primary requirement is that it be a level, stable surface.
6.2.1 Mounting the cabinets

To fix the cabinet to a wall the wall structure and fixing points must be able to support a weight of 30 Kg. Use the optional wall mounting kit referring to the enclosed engineering note for details on fitting the kit. If the analyser configuration includes the larger chemical storage module then the complete unit may be freestanding. The top and bottom modules are fixed together with four small bolts. The requirement when freestanding is that it be a firm, level, stable surface and located where the combined cabinets cannot be knocked over. The chosen location should also have mains power and telephone services available unless alternative options have been purchased.
6.2.2 Unpacking the battery and sensors

Once the cabinet is in place, unpack and install the lead-acid gel battery. If you have purchased the accessories cabinet fit the battery in that cabinet. If you do not have the accessories cabinet do not install the battery in the electronics compartment as corrosion may be a concern should the battery vent gas. Place the battery on the bench top or close to the analyser cabinet. Connect the supplied power plug-pack to the mains power outlet (100-240VAC 50-60Hz) and the analyser 12V Batt input on the right-hand side of the analyser cabinet. Connect the cable marked Battery to the battery terminals with black to the negative and red to the positive +. If a digital multimeter is available, set it to read 12VDC and connect to the 12V battery terminals. Note the voltage reading, it should be approximately 12.6V. Turn on the main power switch for the plug pack and note the voltage again. It should now read 13.8V indicating that the battery charger is on and operating correctly. Some of the sensors will have been removed from the flow cells and packed for storage and shipping. These will require unpacking and replacing in the flow cells in the analyser. The pH and ORP electrodes will have protective cover caps that have to be removed carefully. Wipe any excess liquid from the electrode. Check that it is undamaged and fit to the relevant marked flow cell. The ammonia electrode NH3 requires careful unpacking and preparation before use. Refer to section 13.2.7 Ammonia for details. Ammonium NH4 and nitrate NO3 are small replaceable tip electrodes that are fitted to an electrode holder. These tips are packed dry in small glass vials during shipping. Remove the tip from the vial and fit to the appropriate electrode holder. Both the glass vial and the electrode holder will be marked with the parameter name. Once fitted to the holder the complete electrode can be fitted to the parameter flow cell. For full details on dealing with the sensors refer to section 13.2 Sensor Maintenance.

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The next step is to position the chemicals in the cabinet and connect the supply tubes. The chemicals should have been mixed by a local certified laboratory and placed in the bottles supplied with the analyser prior to the installation day. Place the solution bottles in the cabinet and connect the colour coded pick-up tubes to the bottles. Refer to section 11 for full details on the chemical store. 6.3 Configuring the communications Communications with the Mini-Analyser can be done using the following options: A serial link using a standard 9 way serial cable. A landline modem or cellphone modem and the public telephone network.

The first option requires that the PC be directly connected to the analyser with a 9-way serial cable. A notebook computer is a convenient choice of computer for this purpose. The second option can use standard telephone networks, cellular networks and radio or satellite phone systems as the communications link. When on-site for the installation the direct connection method is essential for the setup and testing that is required. The Greenspan supplied software, Analyser32 will need to be installed on the computer for the installation. The computer should also have HyperTerminal installed. HyperTerminal is a communications program included with Microsoft Windows but is not always installed by default. Check that it is installed on the computer prior to installation day.
6.3.1 Connecting the modem

The analyser will be supplied with a modem for connection to a telephone landline as standard. The modem is positioned external to the analyser cabinet in a location of your choice and connected to the analyser Modem connector on the right-hand side of the cabinet. Two cables are supplied with the modem for connection to the power and data connectors on the right-hand side of the analyser. These connectors are marked Phone/Modem Power and Modem. The telephone landline will also need to be connected to the modem using a modular connector. Direct connection to the analyser is done from the computer to the analyser using the supplied 9-way serial cable. The connection to the analyser is on the lower right-hand side of the cabinet and is marked User. 6.4 Installing the sample delivery module
6.4.1 Selecting a position for the module

The sample delivery module (sample pot) should be situated close to the analyser cabinet (within 2 metres) and at a height slightly lower than the cabinet. If it is positioned higher than the cabinet the possibility exists that sample may be able to syphon into the cabinet should there be a tubing failure within the cabinet. The sample pot should also be positioned higher than the water source so that the waste side can drain away once the pump is stopped. If the installation location does not allow these criteria to be met, contact Greenspan Technology or your local Greenspan representative.

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If the analyser is mounted to a wall, then the wall is also a good mounting point for the sample pot. When the analyser is bench mounted the sample pot may be attached to the edge of the bench top. When choosing the mounting point be aware that two 25mm pipes will connect to the sample pot from outside the building. One is the sample from the pump and the other is the sample waste outflow back to the water source. The position should also allow for the removal of the white cylindrical portion of the pot assembly for cleaning. Refer to section 13.1.7 Sample Delivery Pot for details on maintenance.
6.4.2 Mounting the sample delivery module

The sample pot has a stainless steel mounting bracket attached to it and this bracket has four holes for fixing to a vertical surface. Use the screws provided for fixing to a wooden surface or the expanding bolts for a masonry surface. If your fixing needs differ from these two choices appropriate fixings will have to be obtained from your local hardware supplier.
6.4.3 Connecting The sample delivery and Analyser

Once mounted in position several connections need to be made to the sample delivery module. There are two connectors on the top of the pot assembly. These two connectors are of different types and cannot be interchanged. One connector Fig 6.4: Sample delivery module is for the sample temperature sensor and is a small multi-pin connector on a short cable. The second connector is part of a small air valve on the top of the assembly. Connect the cable exiting from the analyser on the right-hand side marked Sample Temp to the temperature sensor on the top of the pot assembly. The second cable marked Air Valve should be connected on the top of the pot but left free at the other end. This will connect to the pump control module to be installed later. There are two small polyethylene tubes that also attach to the top of the pot assembly. One is the sample pick-up that connects to the analyser and this tube will have the number 71 (violet and brown) and is connected to the mating luer fitting directly in the middle of the top of the pot. The second tube is an air vent that can also vent a small amount of sample at times. This 2.5mm internal diameter tube will be supplied as a separate item (not connected to anything) and will not have any fittings attached. Connect one end of the tubing to the 2.5mm barb fitting on the top of the sample pot and run the free end of the tubing to a location where it can vent liquid without harm. Do not place the free end in liquid or an enclosed place as it does need to be open to clean air. Once these cables and tubes have been connected to the pot assembly and analyser support them by fixing to the wall or bench using appropriate clamps.
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6.4.4

Connecting the pump to the sample delivery

Once the pump has been installed the pipe has to be run to the analyser position for connection to the sample delivery pot and another pipe of the same diameter or slightly larger run from the sample pot back to the water source or some suitable drain. It may be convenient to run both pipes and the power cable along the same route. If this is done ensure that the discharge point for the sample pot outflow does not influence the intake to the pump. Greenspan personnel have found that it is easier to connect from the sample delivery pot assembly to the sample supply and discharge pipes close to the analyser location with 25mm flexible hose. The use of flexible hose close to the analyser reduces stress on the connections and makes the task of routing the pipes to the sample delivery module easier. Usually this is done from the entry point to the room where the analyser has been installed. Connect the sample supply from the pump to the side of the sample pot marked inlet and the discharge hose to the side marked outlet. Ensure all fittings that are threaded have been assembled using teflon thread tape and have been tightened firmly. Refer to section 3.6 and look at the diagram for the sample delivery system to verify that the system installed conforms with this diagram. 6.5 Installing the sample delivery pump control module In most cases the pump used will be powered from the mains power at the site. The analyser outputs a low voltage signal to control this pump so some form of interface and control module is required to do that task The Greenspan external pump control module provides this with a switched 12Vdc 3A output. The control module can be fixed to the wall or bench next to the sample delivery module or fitted in the optional accessories cabinet. The control module comes fitted with a Din rail clip so all that is required for mounting is that a 50mm long piece of Din rail be fixed at the preferred mounting point and the module clipped to that rail. Connect the cable from the sample delivery module to the connector marked Air Valve. The connector marked Analyser on the control module and the connector marked I/P 4&5 / Pump on the analyser communications interface are connected using the cable marked in the same way. Connect the cable from the power supply/charger marked Sample control 12V In to the mating connector on the control module. There is one connector left and this is the switched 12Vdc out of the control module. This output is normally at 0V and goes to 12Vdc when the analyser enables the sample pump control signal. A cable is supplied to connect to this output and interface with a suitable mains power switching circuit (user installed) to enable the pump. Greenspan suggests a relay appropriate to the voltage and current demands of the pump with a 12Vdc solenoid coil. This method has proven to be simple and reliable. A qualified electrician may be required to install the mains power relay and pump wiring.

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6.5.1

Checking the operation of the sample delivery

On completion of the installation of the pump, sample delivery and control module the full sample delivery system can be tested using the computer and diagnostic routines in the analyser. Refer to section 13.1.9 Running Diagnostics for details on setting up the computer and connection. Warning: If the pump is turned on manually (not using analyser control) without the tubing fitted to the air vent port sample will be vented strongly from the port as the air vent is normally open. When connected to the analyser and at the diagnostic menu, select G Set/Clear External output. This will give a selection of four external outputs to switch. Number 3 - Ext1 power is the control output for the sample delivery. Ensure that the sample delivery is ready to operate and press 3. This will toggle the output on and enable the pump at the water source. Pressing 3 again will toggle the output off. Enable the pump and verify that sample flow is happening and that the flow rate is as expected with no leaks. When satisfied with the sample delivery disable the pump. Should problems be encountered requiring assistance contact Greenspan Technology or your local Greenspan representative. 6.6 Connecting or adding external devices The analyser has considerable capability for external sensors to be fitted and can capture the data from those sensors for inclusion in the on-board data logging and transmission. Because of the large range of devices and connector types available it is not possible here to detail fitting any of these devices to the analyser. Should you wish to connect any external sensors to the analyser inputs contact Greenspan Technology or your local Greenspan representative. 6.7 Getting the Analyser commissioned Now that the analyser, communications and sample delivery are in place, it is time to commission and check that the analyser is functioning correctly. Refer to the Analyser32 manual section 18 and 18.1 for detail on commissioning the system. While the analyser is running the commission regime look around inside the wet chemistry side of the analyser to check that nothing has become disconnected during shipping to cause any leaks. If a problem is noted and the correction of the problem is not obvious contact Greenspan Technology or your local Greenspan representative.
6.7.1 Running some test schedules

After the analyser has been commissioned and checked for leaks it is time to run a test of the full system. Refer to section 8 Schedules for details on setting up and running a schedule. Complete details on working with the User Interface are in the Analyser32 software user manual.

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Setup a schedule to run all tests and the sample delivery pump using periodic timing with a period start of 0 hours and a trigger period of 1 minute. This will have the effect of retriggering the schedule at the next 1 minute interval after the schedule stops effectively causing the analyser to run continuously. This is a good method to use when testing the analyser. Be aware that this timing is not recommended to be used under normal circumstances as it increases the chemical usage considerably. Allow this schedule to run several times before stopping the analyser as it will assist in the stabilising of the sensors after shipping. Refer to section 12 Checking Measurements and Sensors for details on how to check the sensors and analyse the results.
6.7.2 Testing a known sample

Now that everything is working and stabilised a schedule could be run using a sample with known parameter values. This will verify the correct function of the analyser and sensors and give confidence that the installation has been completed effectively. To setup this schedule refer to sections 8.1.14 and 8.1.15 to disable the sample delivery pump control for the period of this testing. Disconnect the sample pick-up tube number 71 from the top of the sample delivery pot and place it in the known sample. Edit the schedule to contain the tests for the parameters you wish to verify ensuring that the fill/clean operations are unchecked and run the schedule. Allow the schedule to run for several passes if possible and then download the data. Check the data using Aquagraph and compare the results to those expected. Refer to section 12 Checking Measurements and Sensors for assistance with evaluating the results. When you have completed the verification testing reconnect the sample inlet tube 71 to the port on the top of the sample delivery pot. If this is not done water will be vented strongly from the open port on the sample delivery the next time the sample pump is operated. Should there be problems that you cannot resolve, contact Greenspan Technology or your local Greenspan representative.

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7 COMMUNICATIONS
Communications with the Mini-Analyser can be done using the following options: Modem and communications network. Serial link using standard serial cable.

The first option can use standard telephone networks, cellular networks and radio or satellite phone systems as the communications link. The second option requires a site visit. A notebook computer is a convenient choice of computer for this purpose. 7.1 Getting Started with the User Interface Analyser32 is a fully featured program that allows the user to do tasks like setting up schedules and calibrating sensors. Sections 8 through 10 of this manual give a brief overview of the basic use of the interface. For more in depth information please refer to the Analyser32 user manual You may also find it useful to have a terminal emulator program such as HyperTerminal or Telix. These programs are useful for specific tasks such as upgrading firmware (see Section 14), incorporating new sensors or functions and when setting the modem initialisation string (see below). The terminal emulator program can also be used for diagnostic testing of the Mini-Analyser. See section 13.1.9. 7.2 Installing a Modem Some recommended modems for use with the Mini-Analyser: Zoom Fax/Modem 56Kx. US Robotics Courier V Everything 56k. Banksia mymodem 56v Diamond SupraExpress 336e and 56e.

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7.2.1

Setting the modem initialisation string

The modem initialisation string needs to be set should you change the type of modem used with your Mini-Analyser. This can only be done at the site by a direct connection. Contact Greenspan or your service agent before undertaking this task to obtain the correct initialisation string for your modem. Procedure: 1. Connect a PC to the Mini-Analyser serial communications port using a standard serial cable. 2. Run a terminal emulator program such as HyperTerminal or Telix. For more information on setting up these two applications refer to section 13.1.9. Running diagnostics. 3. Set the communication parameters to 19200 baud, 8 data bits, 1 stop bit and no parity. 4. When the terminal program is setup and a connection made with the Mini-Analyser a return string will be displayed on the screen similar to 002.A034Y49NY10491520;. This sequence may vary with different versions of firmware but will be similar. 5. Refer to the return string example in step 4 and note the characters that are underlined. Look at the return string that has appeared on your PC screen after connection to the MiniAnalyser and note these three characters. These refer to the version of firmware installed in the Mini-Analyser. 6. Press the keyboard sequence *& by pressing SHIFT-8 and SHIFT-7 on the PC keyboard. The factory menu will appear. 7. Turn caps lock on. Press M for Set Modem init string. The current init string will be displayed and you will be prompted to change it or not. Press Y to change. 8. You can choose from the two default strings provided, one for normal, and one for cellular phones or you can press E to edit. Choose a string or edit the current string. To type in a completely new string use the edit option. 9. Press Y when asked to save the init string. Press any key and then exit the interface.

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8 SCHEDULES
Schedules control the operation of the Mini-Analyser chemical laboratory and external sensors. They describe what tests are performed and when they are performed. By using the Mini-Analyser user interface software, an operator can choose the tests to be performed by a schedule. To set up a schedule, the operator of the Mini-Analyser performs the following steps: 1. Create a new schedule. 2. Selects the tests to be performed and their order. 3. Chooses the activation mechanism for the schedule. 4. Sets the timer if required. 5. Enables the Schedule. 8.1
8.1.1

Working With Schedules Using Analyser32


Setting up a schedule

From the Main Menu press the Setup button. From the Setup Menu select Scheduling. The Schedule Setup window shown in Figure 8.1.1 will appear.

Figure 8.1.1 The Schedule Setup window To create a new schedule, press the New button. If a schedule name already exists and you want to modify it, select that schedule, then press the Edit button. It is possible to create more than one schedule.

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8.1.2

Creating or editing schedules

To access the schedule editor, press New or Edit in the Schedule Setup window.
8.1.3 Entering a name

Enter a name for your schedule in the box located at top left of the window. If no name is entered then the Mini-Analyser will create one. The name can be up to 24 characters in length.
8.1.4 Viewing and editing tests in the schedule

The Tests in Schedule list describes all of the tests to be performed in the schedule as well as the fill and clean operations. The maximum number of tests permitted in one schedule is 20. Fill operations bring the sample from the sample source to the Mini-Analyser chemical laboratory ready for testing. Clean operations send leftover sample back to the sample source and clean the line. If fill and clean operations are included in the schedule they are always run at the beginning and end of the schedule respectively. To edit what tests are performed press the Edit Tests button. For more information on this see section 8.1.14.
8.1.5 The schedule duration

The time it takes for the schedule to execute is displayed in the top right corner of the window. This time is calculated by the software, based on which tests are selected. This information is useful to help plan the timing of multiple schedules.
8.1.6 Timing a schedule

To set the times when the schedule will execute there are five options: Periodic - A periodic schedule will execute at fixed time intervals. Timetable - A timetable schedule will execute at specified times on a daily basis. Event The schedule will start in response to a variation detected in another parameter. External Trigger A signal from an external line will start the schedule. Initial Schedule The Initial schedule will run immediately the Analyser is started and run once only. Note. The Initial schedule will run once every time the Analyser is started.
Enabling the schedule

8.1.7

To enable a schedule, tick the Schedule Enabled box. A schedule will not run without this box being ticked.
8.1.8 The scheduler priority ANY SCHEDULE, WHICH IS DUE TO COMMENCE WHILE ANOTHER IS IN PROGRESS, WILL NOT RUN.

Note:

If two or more schedules are due to execute at the same time, the schedule earliest in the list will run. The other schedule(s) will not run.

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8.1.9

Using periodic triggering

Periodic timing is set by selecting Periodic from the Scheduled Times box in the schedule edit window. See Figure 8.1.9.

Figure 8.1.9: Setting triggering to periodic The schedule will run first at the start time. It will run again depending on what time is used for a Trigger Period. If the Trigger Period is larger than the schedule duration then the schedule will run at the next trigger time. If the Trigger Period is less than the schedule duration it will run again at the next trigger time when the scheduler is not already running, ie this schedule will run continuously. If more than one schedule is required to run, avoid conflict by making sure this is not the case.

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8.1.10 Using timetable triggering

Timetable Triggering allows the user to set schedules to run at specific times rather than after specified periods. In the Schedule Editor, choose the timetable option under the heading, Scheduled Times. Next, press the Edit Timetable button. This brings up the timetable editor. See Figure 8.1.10 below.

Figure 8.1.10: The Timetable window Add times to the timetable by entering them in the Enter Time box and then pressing the Add>> button. The new time will be added to the list in chronological order. To remove a time, highlight it in the list and press the Delete button. The Clear All button removes all of the times listed.
8.1.11 Using event triggering

Event triggering is used when you wish to have a schedule run in response to a change of a certain magnitude in another parameter, for example temperature. You can select from a list of parameters to use as a trigger by pressing the down arrow in the Trigger box. The magnitude of change that is required to cause a trigger is entered into the box labelled Data Variation Value. When the sample data for the triggering parameter changes by more than the Data Variation Value, either up or down, it will trigger an Event and start the second Event triggered schedule. The data value at this time becomes the new reference point for the Data Variation Value. For this option to work a schedule that tests the trigger parameter must be enabled and started. This provides the sample testing that can cause the event that will trigger the second schedule.
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8.1.12 Using the external trigger

The external trigger option allows a signal from an external source to start the schedule. This trigger can be a negative going pulse or relay contact closure. The pulse should be a minimum 100S in duration, and pull the Mini-Analyser trigger input from 5VDC to ground. The relay contact should provide a short duration ground (less than the period of the schedule) on the Mini-Analyser trigger input. This trigger could be from a SCADA system in response to a pump being activated or some other event where you may wish to synchronise the sampling and testing by the MiniAnalyser.
8.1.13 Using initial triggering

The Initial triggering is used to ensure that any regime that has to be run every time the Analyser is restarted can be set to run automatically at start up. The Initial schedule will run immediately after the Analyser is started and will run once only after that start sequence until the Analyser is stopped. When the Analyser is stopped and started again the Initial schedule will again run once for that start / stop sequence. Any schedule setup to use the Initial trigger function should be created as the first schedule in the list. This will ensure that the Initial schedule always runs first, irrespective of the timing or triggering methods used for other schedules as the Analyser processes the schedules starting from the first schedule in the list. Refer to Figure 8.1.13.

Figure 8.1.13: Setting the schedule to Initial

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8.1.14 Editing the tests for a schedule

This allows the schedules to be setup with a variety of tests. The Edit Tests window is shown in Figure 8.1.14.

Figure 8.1.14: The Edit Tests window The tests available are shown in a list on the left hand side of the window. To add a test to the current list of tests shown on the right, highlight the test to add and press the Add Test >> button. The same test can be added more than once to the schedule. When the test is added to the list it is also given a channel number. The channel number is the code used for the test in the data log. A schedule can be rearranged to execute in any order by using the following buttons: Push Test Up Push Test Down Delete Test Clear All Tests Move the position of a highlighted test up the list. Move the position of a highlighted test down the list. Remove a highlighted test. Remove all tests from the list.

8.1.15 Adding fill and clean operations

These procedures bring the sample to the internal inlets of the Mini-Analyser and then clean out the lines afterwards. The fill operations occur at the beginning of a schedule and clean operations at the end of a schedule. If the automatic box is ticked fills and cleans will be automatically added according to which internal inlets are used.

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The fills and cleans can be manually deselected by unticking the Automatic box. There are a few cases where this is desirable. For example testing procedures where a known solution is used in place of a sample. 8.2 Starting a Schedule Using Analyser32 The Start Mini-Analyser window, shown in Figure 8.2, appears after pressing the Start button in the main menu to turn the scheduler on.

Figure 8.2: The Start Mini-Analyser


8.2.1 The current date/time display

This display shows the settings on both the Mini-Analyser and computer. If the computer settings are incorrect they should be reset. Use the Windows control panel to reset the time and date information. The Analyser32 software will update the Mini-Analyser time and date information with that of the PCs when the scheduler is started. It is important when using External Triggering that the Mini-Analyser time be synchronised with the SCADA system time.
8.2.2 Inserting comments

Type text into the Comment field to insert a comment in the data log. The length can be up to 128 characters. Comments are very helpful when trying to locate events in the data log or troubleshooting problems with the Mini-Analyser. Aquagraph can display this comment information.
8.2.3 Operator identification

You can type text in the Operator 1 and Operator 2 fields to record who started the scheduler. These fields will accept 3 characters.
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8.2.4

Clear memory

Clears all the logger memory. A warning will be displayed before the memory can be cleared. Note: Once the memory is cleared all data that was in the logger is erased. Ensure that all important data is retrieved before clearing the logger memory.

8.3 Stopping a Schedule

Figure 8.3: The Stop Mini-Analyser window To stop the Mini-Analyser press the Stop button in the main menu. The Stop Mini-Analyser window will appear as shown in Figure 8.3.
8.3.1 The last started display

A display at the top of this window gives the date and time the Mini-Analyser was last started.
8.3.2 Current date/time

This shows the settings on both the Mini-Analyser and computer. If the computer settings are incorrect they should be reset via the Windows control panel.
8.3.3 Inserting a comment

Type text in the Comment field to put a comment in the data log. The comment might be why the Mini-Analyser was stopped. The length can be up to 128 characters. Again, comments are very helpful when trying to locate events in the data log.

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8.3.4

Operator identification

You can put text in the Operator 1 and Operator 2 fields to identify who stopped the scheduler. This information is recorded in the data log. The field will accept up to 3 characters.
8.3.5 Confirming the end of scheduling

Once your Stop Mini-Analyser window details are correct press the Stop button. If the scheduler is currently performing operations the stop command will take affect as soon as the Mini-Analyser is finished the current schedule.

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9 ALARMS
Alarms bring important events to the attention of the user and are normally used to notify the user that action is required. An Mini-Analyser can be set to phone a remote location in response to an alarm. Alarms can be used to trigger an external output. 9.1 Setting Alarms With Analyser32 To go to the Alarms window: 1. From the main menu choose Setup. 2. From the Setup menu choose Alarms. The Alarms window is shown in Figure 9.1.

Figure 9.1: The Alarms window There are 2 categories of alarm: Sample alarms a result from a sensor test is outside preset limits. System alarms part of the Mini-Analyser system requires attention. The 4 main system alarms are triggered by: Liquid volumes from the chemical store. Memory level of the data log. Battery level. Water ingress - leakage of liquid inside the Mini-Analyser.

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9.1.1

Setting the sample alarms

Sample alarms are triggered when an alarm threshold is reached. The channel alarm set window allows for a high and low threshold to be set. Once triggered an alarm cannot be activated again until the measured value crosses a re-enable threshold. This is to prevent the unwanted activation of alarms due to small fluctuations. To set a sample alarm, highlight the parameter of interest in the Channels box and press Set. A Channel Alarm window will appear as shown in Figure 9.1.1.

Figure 9.1.1: The Channel Alarm window To set an alarm, type in values for the Trigger Value and the Re-enable Value then tick the corresponding Enabled box. Press the OK button to confirm the change. As a guide: The low alarm re-enable value should be higher than the low alarm trigger value. The high alarm re-enable value should be lower than the higher alarm trigger value.
Memory alarm

9.1.2

The memory alarm area is located in the top right corner of the Alarms window. A memory alarm will be activated if: The Memory alarm is enabled, and, The amount of stored data in the memory goes above the trigger level.
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When the memory reaches full capacity the Mini-Analyser will stop. The data log should be downloaded and then the memory cleared prior to restarting the Mini-Analyser. The memory alarm can also be used to trigger the external output by ticking the Memory External Output box.
9.1.3 The battery alarm

The battery alarm is located in the Channels box. The battery alarm does not have a re-enable value and can only be triggered from a low alarm.
9.1.4 The solutions alarms

The solution alarms are located in the middle of the alarms window and can be set by highlighting the relevant solution and pressing the Set button, a window like the one shown in Figure 9.1.4 will appear.

Figure 9.1.4: The Solution Alarm window The default value for the trigger is set to 10% at the factory. The Mini-Analyser will cease to operate when the volume remaining reaches 5% of the bottle value. The Solution alarms have a common external output enable box located in the Alarms window. If this box is ticked any solution alarm will trigger an external output. See section 9.1.6.

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9.1.5

Water or liquid ingress

This alarm detects water ingress into the internal sensor compartment of the Mini-Analyser. This alarm is triggered by a sensor that has two moisture-sensing electrodes and is located in the drip tray at the bottom of the chemistry module. Note: A water ingress alarm will cause the Mini-Analyser to cease operation. Fingers or metal objects that come into contact with the sensor can trigger this alarm.
9.1.6 Enabling an external output

The Mini-Analyser has an external output that is enabled in the software. This external output is in the form of a 500ms active low pulse. Other software or hardware can use this as a trigger for a program or event. This could be in the form of making a bell ring or a light shine. The steps to enable an external output are: 1. From the Main Menu choose Setup. 2. From the Setup Menu choose Alarms. 3. Choose a source for the alarm ie pH, phosphate, Battery. 4. Highlight the source by clicking it and press the Set button. 5. Tick the Enable External Output on Alarm box. The output (a 500 ms pulse active low) will occur if:
9.1.7

An alarm occurs, and, The source of the alarm has its Enable External Output on Alarm box ticked.
Alarms and the data log

When any alarm is triggered details of the alarm are written to the data log. The details logged are:
9.1.8

The source of the alarm. For example, Nitrate, pH etc. The value which caused the alarm to trigger. The date and time of the alarm.
Enabling the alarm system

For any of the individual alarms to activate the Global Alarms Enabled box needs to be ticked in the bottom right corner of the Alarms window.

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9.1.9

Dialout on alarm

The alarm dialout function allows the user to receive notification of alarms from remote sites. This feature is accessed by pressing the Dialout Phone Numbers button in the alarms window. The window is shown in Figure 9.1.9.

Figure 9.1.9: The DialOut Phone Numbers window The user can specify up to 4 phone numbers for the Mini-Analyser to dial in response to an alarm. If an alarm is present the Mini-Analyser will look to see if the current time falls within any of the time windows. If one is found the Mini-Analyser will dial the corresponding phone number. For a dialout to happen a time window must be set. To specify the amount of time the Mini-Analyser modem is powered up after an alarm dialout: 1. From the main menu choose Setup. 2. From the Setup menu choose Communication Times. 3. Enter the duration of power-up in minutes and seconds into the box labelled Duration of Power up following an Alarm Dialout. 4. Press OK. This time is set to give the user a period in which to dial up the Mini-Analyser and check the cause of the alarm dialout.

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An alarm dialout will occur if: There is no direct connection with the Mini-Analyser. A valid telephone number and time window are set. The current time is inside a dialout window. An unacknowledged alarm exists.

The Mini-Analyser will attempt to call the corresponding phone number a maximum of 3 times.
9.1.10 Receiving dialout alarms

To receive a dialout alarm at a remote computer several conditions have to be met. The telephone number that the Mini-Analyser dials must be for a modem connected to the remote computer. This computer must also be powered on, running Windows and have the appropriate program (SmartStandby) running in the background. For further details on using SmartStandby contact Greenspan Technology or your local Greenspan representative. 9.2 Clearing Alarms With Analyser32 The Acknowledge Alarm window, shown in Figure 9.2, is accessed by pressing the Acknowledge button in the alarm display area of the Main Menu.

Figure 9.2: The Acknowledge Alarm window

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9.2.1

Clearing the alarm

Pressing the Clear Alarm button will bring up a message asking the user to confirm that the alarm is to be deleted. If the answer is yes the alarm is cleared and deactivated. A no answer will return the user to the main menu. After checking the Mini-Analyser to determine and rectify the cause of the alarm you will need to re-enable the alarm. Refer to section 9.1.
9.2.2 Cancelling a dialout

Press the Dialout Cancel button to stop the Mini-Analyser from continuing a modem dialout sequence.

10 DOWNLOADING DATA
The data log is a record kept by the Mini-Analyser detailing the results of scheduled tests, alarms and reagent levels. This data can be downloaded for graphical analysis using Aquagraph or archived for future reference. 10.1 Downloading Data using Analyser32 To download data from the Mini-Analyser press the Data button from the Main Menu. The Download Data window is shown in Figure 10.1.

Figure 10.1: The Download Data window The data files that will be stored on the computer are in a Greenspan data format. These can be converted into a comma separated format for use with many common spreadsheets using the Aquagraph utility supplied with the Mini-Analyser.

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Note: The Scheduler does not need to be stopped to download the data file.
10.1.1 Downloading the entire data log

The first option labelled All Stored Data will download the whole data log. This option is useful for archive and backup prior to clearing the data memory.
10.1.2 Downloading new data

Selecting Data Since Last Download will gather only the data recorded since the last download. File markers are inserted where the data was last downloaded. These markers are set at the end of the file once data has been downloaded.
10.1.3 Downloading data between dates

When the Data between Following Dates option is selected the edit boxes for Data From and Data To are made available. The default From and To dates are the log start and end dates. Data can be downloaded from between any dates. The file markers for the data since last download are not adjusted when using the data between dates option.

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11 CHEMICAL STORE
The Mini-Analyser chemical store contains a variety of chemicals that can change from one installation to another depending on the water parameters being measured. Some of these chemicals are very corrosive, others can be hazardous to your health, which means that all of them need to be handled with care and attention all of the time so that you normally have safe work practices. Rubber gloves and eye protection should be worn at all times when handling the chemicals to reduce the risk of contact and most importantly, work carefully. The Mini-Analyser is supplied with two complete bottle sets. This is done so that chemicals do not have to be poured into bottles at the site. With two sets, one can be in use at the MiniAnalyser and the other at the laboratory being refilled. The empty bottles should be washed at the laboratory before being refilled. When a chemical needs replenishing, the empty bottle is taken out and a new bottle installed using the procedure below. The empty or near empty bottles are then taken to the laboratory for refilling. This puts the hazardous handling of the chemicals into the laboratory and reduces the risk of accident at the Mini-Analyser site. The chemicals are connected to the Mini-Analyser by polyethylene tubing and Luer fittings. This type of fitting is used widely and is very reliable and chemical resistant. A numbering system is used to identify chemicals and tubes. When replacing reagents always check that the labelled tube has the same colour code and numbering as the bottle it connects to. 11.1 Changing Solution Bottles All of the chemicals have a number and colour allocated to them and this numbering follows the colour code shown in table 11.1a. Table 11.1a: Chemical colour code Number Colour 0
Black

1
Brown

2
Red

5
Green

6
Blue

7
Violet

8
Grey

9
White

Orange Yellow

Table 11.1b: Chemicals and their allocated numbers Chemical pH/EC Standard Standard 1 Standard 2 Cleansing solution 1 Air Nitrate Ammonia 1 Ammonia 2 Ammonium Number 12 15 16 50 51 55 23 49 24 Combined Waste Non-Modified Waste 87 90 Chemical Phosphate 1 Phosphate 2 Phosphate 3 Phosphate 4 Sample 1 Number 21 20 53 54 71

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Procedure: 14. Stop the scheduler if it is running, and wait for any remaining steps to finish. 15. Put on safety equipment - a protective coat, gloves and eye protection. 16. Connect a PC to the Mini-Analyser. Run Analyser32 and check which reagent requires replacement. 17. Locate the bottle that requires replacement. Disconnect the tubing luer fitting. 18. Remove the bottle with dropper cap from the Mini-Analyser. 19. Unscrew the cap from the new bottle. Unscrew the dropper cap from the bottle being replaced. 20. Check that the colour code on the bottle matches the colour code on the inlet tube. 21. Swap the caps on each bottle. DO NOT TOP BOTTLES UP, ALWAYS REPLACE WITH
FRESH BOTTLES.

22. Place the new bottle back into position. Connect the tubing to the bottle and tighten the luer fitting to be finger tight. Do not over tighten this fitting. Firm pressure is all that is required. 23. Reset the volume level for the replaced solution in the chemical store, using the PC. Refer to Section 11.2 in this manual to do this using Analyser32. 24. Do a visual check that the bottle volumes match the recorded bottle volumes displayed on the PC and if necessary, edit the volume level in the chemical store. 25. Visually check the level of the waste bottle to see if it requires replacement. 26. You may now restart the scheduler or start logging if desired. 27. Exit the user interface, disconnect the serial cable from the Mini-Analyser.

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11.2 Updating Reagents Using Analyser32 The Mini-Analyser keeps record of the levels of solutions available in the chemical store. This is done to notify you when they are close to empty and also to prevent the Mini-Analyser from running when they are completely empty. Note: The chemical store can only be edited or updated with the scheduler OFF To access the chemical store database: 1. 2. From the Main Menu choose Setup. From the Setup Menu choose Chemical Store.

The Setup Chemical Store window shown in Figure 11.2a will appear.

Figure 11.2a: The Setup Chemical Store window If a complete refill of all bottles has been done you can quickly reset all volumes to full by pressing the Set All Solutions as Full button. A message will appear asking you to confirm this. To change the level of an individual solution highlight that row by clicking it with the mouse and press the Edit button, the Edit Reagent window shown in Figure 11.2b will appear.

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Figure 11.2b: The Edit Reagent window If the bottle has been completely refilled tick the Full Solution Bottle Installed box. To set the level to something else click on the Current Level box and edit the data. In this window you can also edit the alarm volume level in the Trigger Volume box and the Active Constituent Concentration if applicable. The concentration value is used in calibration procedures and analysis calculations. These values would not normally be changed unless the concentration of the standard is changed. Press the OK button to confirm your changes. NOTE: Changing the active constituent values will change the data results. DO NOT change these values unless you have been instructed to do so. 11.3 Waste Disposal
11.3.1 Unmodified waste

Unmodified waste has the same composition as the source. Therefore for disposal it can be pumped back to the water source, to a drain or combined with modified waste depending on the installation setup.
11.3.2 Modified waste

28.Modified waste is collected in a 20L plastic container. This waste must be treated by pH neutralisation before disposal as the pH of the combined waste may be from 1.5 to 12 depending on the sensor installation in the Mini-Analyser.

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12 CHECKING MEASUREMENTS AND SENSORS


It is important to be able to verify the accuracy of measured results. This is normally done with the help of standards. Verification also tells you whether the sensor is operating properly or if it may need maintenance or replacing. View the sensor check values using Analyser32 or by viewing the data file using Aquagraph. Using Aquagraph to view a downloaded data file is best as it allows you to see many data point and trends that cannot be seen with Analyser32. When analysing data and encountering problems, refer to section 15 Troubleshooting for assistance in locating the problem. For further assistance contact Greenspan Technology or your local Greenspan representative. 12.1 Dissolved Oxygen Each time the Mini-Analyser does a test on the DO a correction to the sample result is made by applying a single point calibration. This is done to compensate for changes in the response of the electrode. The DO check result does not have this correction applied to it and can be used as an indicator of the sensor condition. Under normal operation the Mini-Analyser check will give a result for the dissolved oxygen of the air bubbled deionised water. This value is 105%. The Mini-Analyser check value can drift over time. This drift is usually a result of a change in sensor characteristics. Once this result has drifted out of an acceptable range (20 %), then the sensor may have to be cleaned, re-calibrated or replaced. Re-calibration may be achieved by following the sensor calibration procedure (see section 12.3). If results for the sample vary significantly from expected and the check results are acceptable then other causes may need to be investigated. Contact your Greenspan Technology Service agent.
12.1.1 Analysing the DO data

The easiest way to check if the analyser is functioning properly is to use Aquagraph to graph each process individually and check for unusual values. What to graph Graph both DO data series, DO 1 and DO check, on the same graph. Checking results When analysing the results, you should look for a steady check value around 105% and the data returns expected results. What should the graph look like if the Analyser is working correctly? The check values in the graph you obtain should look something like this.

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What if the graph does not look like this? The check value should remain steady. If this is not the case, ie drift, sudden variation or unusual values, this may indicate that there is a problem. Data results will vary between sites and over time but extreme variation, ie sudden peaks, indicates a possible problem. In either case further action should be taken to discover the cause of unusual data. What to do if the graph is abnormal If there is an obvious problem that does not seem to have a cause that you can determine, contact your Greenspan Service Agent. Note that data from a period of time with an obvious problem may not be valid and including it in a data summary may lead to incorrect inferences. Some typical graphs Both the check value and the data value are very similar in value in graph 1. As the check should normally be 105% the analyser has applied compensation to the data result giving a value to the data that may be incorrectly high. The DO should be re-calibrated when the check value is this incorrect. Note that this has been done near the end of the graph and the data is now valid.

Graph 1

In graph 2 the DO check value has gone very low and the automatic compensation has caused the result to go very high. The most likely reason is that the analyser has run out of de-ionised water and is still running (incorrect volume levels in the chemical store). When the DI water is refilled the check value returns near normal and the data is once again valid.

Graph 2

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12.2 Electrical Conductivity Each time the Mini-Analyser does a test on the EC a correction to the sample result is made by applying a 2-point calibration. This is done to compensate for changes in the response of the electrode. The EC check result is a raw data value and does not have the 2-point correction applied to it so it can be used as an indicator of the sensor condition. Under normal operation the Mini-Analyser check value will give a value for the conductivity of the pH/EC Standard 3 solution. This information can be found on the solution bottle and in the chemical store under pH standard. It typically has a value of 2045 S/cm. When the prepared standard arrives it should come with a known test value. This value should be input to the user interface in the Chemical Store section under Active Constituent Concentration Elec Cond. The Mini-Analyser check value can drift over time. This drift is usually a result of a change in sensor characteristics. Once this result has drifted out of an acceptable range (20 %), then the sensor may have to be cleaned, adjusted, re-calibrated or replaced. Re-calibration may be achieved by following the calibration procedure in section 13.3. If results of the sample vary significantly from expected and the check results are acceptable then other causes may need to be investigated. Contact your Greenspan Technology Service agent.
12.2.1 Analysing the EC data

The easiest way to check if the analyser is functioning properly is to use Aquagraph to graph each process individually and check for unusual values. What to graph Graph all four EC data series, EC 1, EC 1 not norm, EC Base and EC check, on the same graph. Checking results When analysing the results, you should check that the standard and check values are steady and give expected results. The EC Base is testing the cell when empty and should give a value of around zero. The EC check is usually around 2045S and is derived from the pH/EC Standard.

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What should the graph look like if the Analyser is working correctly? The check values in the graph you obtain should look something like this: Note: Both the EC Base and EC check are fairly steady at 0 and 2000S respectively. What if the graph does not look like this? Base and check values should remain steady. If this is not the case, ie drift, sudden variation or unusual values, this may indicate that there is a problem. Data results will vary between sites and over time but extreme variation, ie sudden peaks, indicates a possible problem. In either case further action should be taken to discover the cause of unusual data. What to do if the graph is abnormal If there is an obvious problem that does not seem to have a cause that you can determine, contact your Greenspan Service Agent. Note that data from a period of time with an obvious problem may not be valid and including it in a data summary may lead to incorrect inferences. Some typical graphs Note the big drop in data on 9 Jan in graph 1. As the check and base values continue to be accurate here, this indicates a sampling problem. As the result approaches the EC Base (air) value it is probable that there was no sample taken at this time. Graph 1 Note the change of the sensor response to the standard over time in graph 2. This shows that the sensor may need cleaning and calibrating but also shows that the data stayed consistent over this time due to compensation for this sensor drift. Note also the zigzag effect in the results due to tidal influence in the river.
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Graph 2
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12.3 Oxidation-Reduction Potential Contact your Greenspan Technology Service agent. 12.4 pH All pH sensors age in use. While the sensor gives a stable reading and is responsive, cleaning and recalibration is all that is required to maintain an acceptable measurement. Under normal operation, the Mini-Analyser check will give a result of pH 4.01 for the pH/EC standard solution. The Mini-Analyser check value can drift over time. This drift is usually a result of a change in electrode characteristics. Once this result has drifted out of an acceptable range (10 %), then the electrode may have to be cleaned and re-calibrated or replaced. Re-calibration may be achieved by following the calibration procedure in section 13.3. If results of the sample vary significantly from expected and the check results are acceptable then other causes may need to be investigated. Biological build-up in the sample tubes is a contributing factor for incorrect pH results. Contact your Greenspan Technology Service agent.
12.4.1 Analysing the pH data

The easiest way to check if the analyser is functioning properly is to use Aquagraph to graph each process individually and check for unusual values. What to graph Graph all pH data series, usually pH 1 and pH check, on the same graph. Checking results When analysing these results, you should verify that the check value is steady and gives expected results. The pH check tests a pH/EC Standard solution and should give a value very close to 4. What should the graph look like if the Analyser is working correctly? The check values in the graph you obtain should look something like this: Note: The pH check value is fairly steady around pH 4.0. What if the graph does not look like this?

The check value should remain steady around 4. If this is not the case, ie drift, variation or unusual values, this may indicate that there is a problem. Data results will vary between sites and over time but extreme variation, ie sudden peaks, indicates a possible problem. In either case further action should be taken to discover the cause of unusual data.
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What to do if the graph is abnormal If there is an obvious problem that does not seem to have a cause that you can determine, contact your Greenspan Service Agent. Note that data from a period of time with an obvious problem may not be valid and including it in a data summary may lead to incorrect inferences. Some typical graphs Note the big drop in data on 9 Jan in Graph 1. As the check value continues to be accurate here, this indicates a sampling problem. At this time, if you look at the corresponding EC graph showing the same data period that graph shows the EC value approaching the EC Base value at that point, so it is probable that there was no sample taken at this time. Graph 1 The above graph 2 shows good pH check and data values until there was a loss of sample on the 20th. Both values have then dropped to the check value and remained there as the pH/EC std was still being pumped through the cell during the running of the schedules. On the 22nd the analyser was stopped, probably awaiting a maintenance visit to resolve the loss of sample pumping. On the 26th the system was again operating normally with good check values and valid data.

Graph 2

Graph 3 shows a slowly rising check value which could indicate a sensor problem (ie needs cleaning or replacing). The downward spike in the pH 1 data is probably a loss of sample at that time.

Graph 3

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12.5 Turbidity Each time the Mini-Analyser is used a correction to the sample result is made by applying a single point calibration. The turbidity check result does not have this correction applied to it and can be used as an indication of the sensor condition. Under normal operation the Mini-Analyser check will give a result of around 0 NTU for the Wash 1 solution. The turbidity check value can drift over time. This drift is usually a result of cell fouling. Once this result has drifted out of an acceptable range (10 %), then the sensor may have to be cleaned or calibrated. Typically, cell cleaning is all that is required. Calibration may be achieved by following the calibration procedure in section 13.3. If results of the sample vary significantly from expected values and the check results are acceptable then other causes may need to be investigated. Contact your Greenspan Technology Service agent.
12.5.1 Analysing the turbidity data

The easiest way to check if the analyser is functioning properly is to use Aquagraph to graph each process individually and check for unusual values. What to graph Graph the Turbidity data series, Turbidity 1 and Turbidity chk, on the same graph. Checking results When analysing the results, you should verify that the check values are steady and give expected results. The turbidity chk is testing de-ionised water and should give a value of around zero. What should the graph look like if the Analyser is working correctly? The check values in the graph you obtain should look something like this:

Graph 1

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In graph 2 the turbidity chk values is steady at 0. Note the sudden peaks in the result data while the chk value remains steady. These peaks indicate that two storms may have occurred on this afternoon, this is valid data. What if the graph does not look like this? The check value should always remain Graph 2 steady. If this is not the case, ie drift, variation or unusual values, this may indicate that there is a problem. Data results will vary between sites and over time but extreme variation, ie sudden peaks, indicates a possible problem. In either case further action should be taken to discover the cause of unusual data. What to do if the graph is abnormal If there is an obvious problem that does not seem to have a cause that you can determine, contact your Greenspan Service Agent. Note that data from a period of time with an obvious problem may not be valid and including it in a data summary may lead to incorrect inferences. Some typical graphs In graph 3 the check value starts way above zero at 35 and continues to drift upwards. This is an indication of a dirty cell. After the large peak on the 9 Jan. it drops back to zero showing that maintenance had been carried out to clean the cell. Graph 4 shows that although the cell was dirty, compensation from the check value was used and therefore the data result remains valid.

Graph 3

Note the high value of the check value. It should be around zero but is about 12. This could indicate some dirt in the cell or a drift requiring calibration. A maintenance visit to clean the cell would most probably correct this.

Graph 4

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12.6 Ammonia The ammonia analysis uses Dynamic Calibration instead of stored calibration data to calculate a result for the sample being tested. Dynamic calibration is the process where the Mini-Analyser uses values derived from onboard standards each time an analysis on ammonia is performed. This ensures that any changes in the sensor due to temperature or drift are effectively compensated for each time the sensor is used. These standard values are in the form of raw machine counts. Under normal operation the difference in counts between standard 1 and 2 on a new electrode is 2500500 counts. This is known as the slope of the electrode. It is the most important information in determining the performance of the electrode. The absolute value of the counts may change due to temperature and system variability and can range from 10,000 to 50,000 counts. If the count falls outside this range the electrode tip or the reference electrode may need to be replaced. If the slope decreases, the sensitivity of the electrode decreases. This is noted by a decrease in the difference between the count value of standard 1 and 2. If the difference is below 1000 counts over a period of 6-10 tests then the membrane and internal filling solution should be replaced. Refer to section 13.2.7 for details on replacing the membrane. If after membrane and internal filling solution replacement, the counts are still outside that range contact your Greenspan Technology Service agent.
12.6.1 Analysing the ammonia data

The easiest way to check if the analyser is functioning properly is to use Aquagraph to graph each process individually and check for unusual values. What to graph Graph the two check data series, Ammonia ck s1 and Ammonia ck s2, on the same graph. Checking results When analysing the results, you should check that these standard values are steady and give expected results. The values will vary as they are affected by temperature, however both standard graphs should only vary at the same points. What should the graph look like if the Analyser is working correctly? The check values in the graph you obtain should look something like this: Note: Both the Ammonia ck s1 and Ammonia ck s2 are fairly steady and vary only at the same points.

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What if the graph does not look like this? The check values should remain steady relative to each other. If this is not the case, ie drift, variation or unusual values, this may indicate that there is a problem. Data results will vary between sites and over time but extreme variation, ie sudden peaks, indicates a possible problem. In either case further action should be taken to discover the cause of unusual data. What to do if the graph is abnormal If there is an obvious problem that does not seem to have a cause that you can determine, contact your Greenspan Service Agent. Note that data from a period of time with an obvious problem may not be valid and including it in a data summary may lead to incorrect inferences. Some typical graphs

Referring to graph 1 no results have been recorded between 25 July and 1 August. This indicates that either the Analyser was not running schedules or this parameter test was not being carried out during this time. Graph 1 Note in graph 2 the large downward spikes. Note also that these spikes occur in both standards, this probably indicates a standard or sensor problem and should be investigated further.

Graph 2 Graph 3 shows that although the two lines follow each other (only varying at the same time), there appears to be a significant upward drift in sensor readings over time. The data result will probably be valid but this should be investigated further to discover the cause of the drift. Possibly the sensor needs servicing or replacing or has just been serviced or replaced and is still stabilising.
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Graph 3
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12.7 Ammonium The ammonium analysis uses Dynamic Calibration instead of stored calibration data to calculate a result for the sample being tested. Dynamic calibration is the process where the Mini-Analyser uses values derived from onboard standards each time an analysis on ammonium is performed. This ensures that any changes in the sensor due to temperature or drift are effectively compensated for each time the sensor is used. These standard values are in the form of raw machine counts. Under normal operation the difference in counts between standards 1 and 2 (typically 1.4 ppm and 2.8 ppm NH4) on a new sensing tip is 2500500 counts. This is known as the slope of the electrode. It is the most important information in determining the performance of the electrode. The absolute value of the counts may change due to temperature and system variability and can range from 10,000 to 50,000 counts. If the count falls outside this range the electrode tip or the reference electrode may need to be replaced. If the slope decreases, the sensitivity of the electrode decreases. This is noted by a decrease in the difference between the count value of standard 1 and 2. If the difference is below 1000 counts over a period of 6-10 tests then the electrode tip may need cleaning or replacing. If the electrode passes these requirements then it is okay for use. Otherwise check that the electrode and the half-cell reference are clean. If cleaning does not restore working order then replace the electrode. If after electrode tip replacement and/or reference electrode replacement, the counts are still outside that range, contact your Greenspan Technology Service agent.
12.7.1 Analysing the ammonium data

The easiest way to check if the analyser is functioning properly is to use Aquagraph to graph each process individually and check for unusual values. What to graph Graph the three Ammonia ck s1, ck s2 and ck sa data series on the same graph. Checking results When analysing the results, you should check that these standard values are steady and give expected results. The values will vary as they are affected by temperature, however both standard graphs should only vary at the same points. What should the graph look like if the Analyser is working correctly? The check values in the graph you obtain should look something like this: Note: The three check graphs remain fairly steady and only have large variations at the same points.

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What if the graph does not look like this? The check values should remain steady with each other. If this is not the case, ie drift, variation or unusual values, this may indicate that there is a problem. Data results will vary between sites and over time but extreme variation, ie sudden peaks, indicates a possible problem. In either case further action should be taken to discover the cause of unusual data. What to do if the graph is abnormal If there is an obvious problem that does not seem to have a cause that you can determine, contact your Greenspan Service Agent for advice. Note that data from a period of time with an obvious problem may not be valid and including it in a data summary may lead to incorrect inferences. Some typical graphs Note here that the values have a definite drift. Although this requires investigation, this will still give valid data as these standard values are remaining consistent in relation to each other. This could be an indication of cell fouling or a deteriorating electrode.

Graph 1 Note: The graph 2 shows quite good results except for the sudden large downwards spike in the results graph. This warrants further investigation to ensure that this does not indicate some larger problem but most probably indicates a loss of sample at this time.

Graph 2

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12.8 Nitrate The nitrate analysis uses Dynamic Calibration instead of stored calibration data to calculate a result for the sample being tested. Dynamic calibration is the process where the MiniAnalyser uses values derived from onboard standards each time an analysis on nitrate is performed. This ensures that any changes in the sensor due to temperature or drift are effectively compensated for each time the sensor is used. These standard values are in the form of raw machine counts. Under normal operation the difference in counts between standards 1 and 2 on a new sensing tip is 2500500 counts. This is known as the slope of the electrode. It is the most important information in determining the performance of the electrode. The absolute value of the counts may change due to temperature and system variability and can range from 10,000 to 50,000 counts. If the count falls outside this range the electrode tip or the reference electrode may need to be replaced. If the slope decreases, the sensitivity of the electrode decreases. This is noted by a decrease in the difference between the count value of standard 1 and 2. If the difference is below 1000 counts over a period of 6-10 tests then the electrode tip may need cleaning or replacing. If the electrode passes these requirements then it is okay for use. Otherwise check that the electrode and the half-cell reference are clean. If cleaning does not restore working order then replace the electrode. If after electrode tip replacement and/or reference electrode replacement, the counts are still outside that range, contact your Greenspan Technology Service agent.
12.8.1 Analysing the nitrate data

The easiest way to check if the analyser is functioning properly is to use Aquagraph to graph each process individually and check for unusual values. What to graph Graph the two check data series, Nitrate chk s1 and Nitrate chk s2- on the same graph. Checking results When analysing the results, you should check that these standard values are steady and give expected results. The values will vary as they are affected by temperature, however both standard graphs should only vary at the same points. What should the graph look like if the Analyser is working correctly? The check values in the graph you obtain should look something like this: Note: Both the Nitrate chk s1 and Nitrate chk s2 are fairly steady and vary only at the same points. The sample data has no more variation than is expected in a sample graph.

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What if the graph does not look like this? The check values should remain steady with each other. If this is not the case, ie drift, variation or unusual values, this may indicate that there is a problem. Data results will vary between sites and over time but extreme variation, ie sudden peaks, indicates a possible problem. In either case further action should be taken to discover the cause of unusual data. What to do if the graph is abnormal If there is an obvious problem that does not seem to have a cause that you can determine, contact your Greenspan Service Agent for advice. Note that data from a period of time with an obvious problem may not be valid and including it in a data summary may lead to incorrect inferences. Some typical graphs Graph 1 shows a large variation in standard 2. This variation does not occur in the standard 1 results, so could indicate a problem with the standard 2 solution. This should be investigated further.

Graph 1

Graph 2 has a sudden large drop in the result value and lack of data points between 8th and 10th. This data shows that the parameter was not being tested for those days. Notice that the sample data has started prior to the standards and is now of a lower value than the standards. Graph 2 The cause of this should be investigated. There may have been a replenishment of chemicals with an error in the mixing of those chemicals.

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12.9 Phosphate The phosphate analysis uses Dynamic Calibration instead of stored calibration data to calculate a result for the sample being tested. Dynamic calibration is the process where the Mini-Analyser uses values derived from onboard standards each time an analysis on phosphate is performed. This ensures that any changes in the sensor due to temperature or drift are effectively compensated for each time the sensor is used. These standard values are in the form of raw machine counts. The sample result is calculated by applying a 3-point calibration and a correction for sample turbidity each time the phosphate analysis is used. The check results are all in the form of machine counts. Under normal operation the difference in counts between phos zero, standards 1 and 2 (typically 0ppb, 64 ppb and 124 ppb PO4) is about 10,000 counts between each combination (0 and std1, std1 and std2). This information is used in determining the performance of the sensor. When functioning correctly the difference in counts between zero and standard 1 should be very similar to the difference between standard 1 and standard 2. If these two difference values become substantially unequal then the cause will need investigation. If the lower or upper check result falls below 5000 or above 60 000 counts for 6-10 tests the cause will need investigation. Common causes for these parameters going outside the normal range are mostly chemical. Incorrect mixing and storage of the standards and phosphate 4 solutions being the most common. Other causes can be loose luer fittings or an empty chemical container. The phosphate Mini-Analyser cell does not normally require cleaning but could do so if the Mini-Analyser has not been operating for several months. If after replacing chemicals, checking and cleaning, the counts are still outside that range, contact your Greenspan Technology Service agent.
12.9.1 Analysing the phosphate data

The easiest way to check if the analyser is functioning properly is to use Aquagraph to graph each process individually and check for unusual values. What to graph Graph all five check data series, Phos chk sa, Phos chk s1, Phos chk s2, Phos chk Turb and Phos chk Zero on the same graph. Checking results When analysing the results, you should check that these standard values are steady and give expected results. The values will vary as they are affected by temperature however the standard graphs should only vary at the same points. The Phos chk Turb and Phos chk sa (sample) are also affected by dirty water, but again these two should only vary at the same points.

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What should the graph look like if the Analyser is working correctly? The check values in the graph you obtain should look something like this: Note: The Phosphate chk zero, chk s1 and chk s2 are fairly steady. Also note that on the 6th there is a small peak in the phos turb and sample graphs, this can be interpreted as an inlet of dirtier water as the peak occurs in both these graphs. What if the graph does not look like this?

The check values should remain steady with each other. If this is not the case, ie drift, variation or unusual values, this may indicate that there is a problem. Data results will vary between sites and over time but extreme variation, ie sudden peaks, indicates a possible problem. In either case further action should be taken to discover the cause of unusual data. What to do if the graph is abnormal If there is an obvious problem that does not seem to have a cause that you can determine, contact your Greenspan Service Agent for advice. Note that data from a period of time with an obvious problem may not be valid and including it in a data summary may lead to incorrect inferences. Some typical graphs Note here in graph 1 that all data points have trended down. This is still good data as the relationship between Check base, std1 and std2 have remained the same. The effect of turbidity in the sample is also clearly visible in the values for the turbidity check and the sample.

Graph 1 Graph 2 shows good data until all data points suddenly drop to the base line. This is an indication that there may have been a problem with a chemical during replacement such that no colour development was happening.. After the problem was resolved all data points have returned to normal. Incorrect making of the phosphate 1 and 4 reagents can cause problems of this nature. Graph 2
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13 MAINTENANCE
13.1 General Mini-Analyser Maintenance
13.1.1 Stopping or aborting the schedule

Before commencing any maintenance you should stop the analyser. There are two ways to stop the analyser when it is running a schedule. The first is to connect with the analyser32 software, stop the scheduler and wait for any running schedules to finish. This method may involve quite a wait if the analyser has just started a long duration schedule. This second method may be quicker in that situation. Connect to the analyser with HyperTerminal and go to the Factory Menu. Refer to section 13.1.9 and Figure 13.1.9a. Select A for abort and the abort command will pop-up as in figure 13.1.1. Issuing this command will stop the current schedule that is running and run a clean-up Figure 13.1.1: The abort command regime to ensure that the analyser is stopped in a safe condition. At the end of this regime exit HyperTerminal and continue with the maintenance procedures. Do not stop the scheduler by turning the power off as this may leave hazardous chemicals in the area in which you are going to work.
13.1.2 Cabinet

A regular check-up and clean of the cabinet itself is necessary every 3 months or on each site visit. This should include a general check of door catches, hinges and panels for signs of wear, rust and any maintenance that may be necessary. The cabinet should be given a quick wipe-over with a damp cloth and the chemical store checked for spills and cleaned if spills are present. The pumps, tubing, sample delivery pot and battery connections should also be checked and serviced if necessary.

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13.1.3 Pump tubing

The Mini-Analyser will have one or two peristaltic pumps depending on the sensor configuration. Each pump uses two pump-tube assemblies. This pump tubing should be replaced after 1500 hours of actual pumping to prevent ruptures occurring. Procedure: 1. Make a note of the flow paths to and from the pump and disconnect the inlet and outlet tubing from the pump. 2. Release the pump tensioning screws on the side of the pump by pushing the adjuster and ball sideways Refer to Figs. 13.1.3a and b (Do not loosen the screw.) 3. Swing the pressure block back and remove the two tube sets from the rollers by unsnapping the fittings from the front of the pump. Use a small flat-blade screwdriver for this. Refer to Fig. 13.1.3b and c. 4. Replace the tube sets with new ones by pushing the plastic fitting into the tube mounts. 5. Reposition the pressure block and tension screw and repeat the process should there be a second pump

Figure 13.1.3a

Figure 13.1.3b

Figure 13.1.3c

Figure 13.1.3a: Complete pump assembly closed. Figure 13.1.3b: Tensioning screw and pressure block released. Figure 13.1.3c: Unsnapping the tubes from the retaining clips.
13.1.4 Setting the pump pressure

Once the pump tubes have been replaced the pumping pressures need to be set. This is necessary to ensure that the pumps operate in a consistent manner. The method of adjustment is the same for both pumps. You will need: Two pieces of 1.5mm internal diameter PVC tubing 400mm long.

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A small pressure gauge able to read 300 to 400kPa full scale fitted with a 1.5mm hose barb to suit the tubing. Suitable gauges are available from Greenspan Technology. A small container of clean water. Procedure: 1. Make a note of the flow paths to and from the pump and disconnect the inlet and outlet tubing from the pump. 2. Fit one piece of the 400mm long PVC tubing to one inlet of the pump and insert the loose end into the container of water. 3. Fit the second piece of 400mm long PVC tubing to the outlet side of the same channel on the pump. 4. Refer to section 13.1.9, Running Diagnostics and set the pump to run at 30 RPM. The upper pump is pump 0 and the lower pump, pump 1. 5. Hold the tubing from the outlet over the water container until all air has been purged from the tubing and then, stop the pump. 6. Connect the free end of the outlet tube to the pressure gauge. 7. Set the pump running again at 30 RPM and watch the pressure on the gauge. The required pressure is an average around 200 kPa and is achieved by adjusting the tensioning screw shown in figure 13.1.3a. Adjust the screw in to increase pressure and out to decrease pressure. 8. Repeat this procedure with the second channel on the pump. When the pressures have been set, reconnect the chemical flow tubing to the pump referring to the note made earlier on the flow paths and return the system to normal operation.
13.1.5 Sample/chemical tubing

The polyethylene tubing used for the chemicals and plumbing in the Mini-Analyser will, after some time, start to discolour depending on the solution that it is carrying. Some discolouration is acceptable but if it appears to have a deposit on the inside, such as algae, then it should be replaced. The frequency with which this needs to be done depends very much on conditions at the MiniAnalyser site. Temperature, humidity, nutrients in the sample and natural light all play a part in the development of this growth. Usually it is from three to six months between replacements. The tubes involved are mostly, sample, standard 1, standard 2 and the pH/EC standard. Fouling will also occur in the waste line but this does not usually cause any problems.

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13.1.6 Valve tubing

The Mini-Analyser uses Santoprene tubing in the pinch valves. This tubing should only need replacing every twelve months. At that time it is advisable to replace the tubing in all valves. When replacing old tubing, use new tubing of the same material unless specifically directed to do otherwise. Tubing replacement kits are available from your Greenspan Technology service agent. Procedure: Remove the old tubing by grabbing it on both sides of the pinch valve and pulling it so that it will slide out of the slot on the side of the valve. Install the new tubing by stretching it slightly and sliding it into the slot in the pinch valve. It may be necessary to saw the tubing back and forth slightly to help ease it into the valve pinch mechanism. Once the tubing is positioned correctly, grab the tubing on both sides of the pinch valve stretching it slightly and release it. This relieves any binding on the pinch valve mechanism.
13.1.7 Sample delivery pot

The sample delivery pot requires periodic maintenance to ensure the integrity of the pumped sample. Under normal conditions, 3 monthly servicing is all that is required. If the installation is in a high nutrient or particulate situation then the servicing may have to be more frequent. Your Greenspan Technology service agent will advise you on this. Before commencing, ensure that the sample delivery pump or flow is off and will not turn on during servicing. If the Mini-Analyser is operating in a hazardous environment put on rubber gloves. Place a 10 litre plastic bucket under the sample delivery module and unscrew the pot from the module. Remove the large O-Ring from the top of the pot to prevent it from being lost during cleaning. Empty and rinse with clean water. If necessary wipe clean with a soft cloth. Do not use abrasive materials to clean the sample pot as this will scratch the inside surface and promote algae growth. Wipe the O-Ring clean with the cloth. When the pot is clean, refit the O-Ring and screw the pot back onto the sample delivery module. Tighten firmly by hand. Using diagnostics (section 13.1.9) turn on the sample flow and check the pot for leaks.

Figure 13.1.7: Sample delivery module

When all testing has been completed return the system to normal.
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13.1.8 The water ingress detector

The water detector is located on the bottom tray of the Wet Chemistry Module. To access the detector, open the left-hand door of the cabinet. It is then visible in the rear of the tray behind the chemical bottles. The water detector consists of two stainless steel bars held slightly above the bottom of the module by adhesive feet. Under normal conditions, the detector is dry and has a high resistance. When water rises to the level of the bars, this causes a low resistance triggering the water alarm. This area must be kept clean of dissolved salts and as moisture free as possible to prevent the water alarm triggering falsely. If the detector has been contaminated and is causing false alarms, it will need to be cleaned. This is best accomplished by rinsing it with clean water. Unplug the cable. Gently lift the detector, unsticking the adhesive feet. Remove the assembly from the cabinet, rinse thoroughly and dry off. Ensure that the detector is fully dry before replacing and if necessary place it in a sunny spot or heat with a hot air blower. Check that the rubber feet are still adhesive, if not, apply some thin double-sided adhesive tape, reposition the assembly in the bottom tray and reconnect the cable. The function of the detector and alarm can be tested by starting a schedule and when an internal peristaltic pump is running, apply a wet finger to bridge the stainless steel rods. The internal pump should stop and the Mini-Analyser raise a water ingress alarm on the user interface software. Acknowledge and clear the alarm and return the system to normal.
13.1.9 Running diagnostics

Embedded in the Mini-Analyser firmware is a set of diagnostic routines that may be accessed using a terminal emulation program such as HyperTerminal or Telix. HyperTerminal is included with Windows 98 but is not always installed by default. Check that it has been installed on the PC. Telix is a shareware program that should be registered and paid for by the user. These routines can be used to test the pumps, valves, external ports, etc. To setup the terminal program, connect to the analyser user port with a PC and carry out the following steps. 1. Setup HyperTerminal by going to Programs/Accessories/Communications/HyperTerminal and running Hypertrm.exe, follow the setup windows and select a name and icon, connect direct to com 1 (or the appropriate com port), 19200 baud, 8 data bits, 1 stop bit and no parity. This will setup the connection parameters and connect to the Mini-Analyser. At the end of the session you will be prompted to save the setup when you close the window. Select yes. This setup can then be run easily in the future from the HyperTerminal window. 2. If you are using Telix, run the program and set the communication options to 19200 baud, 8 data bits, 1 stop bit and no parity. Also check that the COM port setting is correct. This can be done by pressing Alt-P, then typing F, J, R, S and the number of the COM port.

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3. When the terminal program is setup and a connection made with the Mini-Analyser a return string will be displayed on the screen similar to 002.A034Y49NY10491520;. This sequence may vary with different versions of firmware but will be similar. 4. Press the keyboard sequence *& by pressing SHIFT-8 and SHIFT-7. 5. A menu screen will appear as in Figure 13.1.9a. Since the commands use upper case characters turn caps lock on.

Figure 13.1.9a: The Factory Menu 6. Select K to enter the Diagnostics menu. 7. Figure 13.1.9b shows the diagnostic menu. Selecting from these options allows the user to do such things as, test the operation of the valves, set a pump running at a chosen RPM, turn the external sample pump on and off, etc by following the on-screen prompts.

Figure 13.1.9b: The Diagnostic Menu 8. The use of these diagnostic routines would, in most cases, be done with the supervision or guidance of Greenspan personnel.

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13.1.10

The clean regime

Included in the standard regimes available for scheduling is one called Clean. This regime has been developed as a method of counteracting the slow growth of algae and other deposits within the flow path inside the analyser by flushing the flow path with an acid solution. Greenspan recommends that this regime be run initially at least monthly as a preventative maintenance measure. The frequency at which the regime is run in the long term will depend very much on the site and sample conditions and will largely be arrived at by experience with your installation. Refer to section 8, Schedules for detail on setting up and running a schedule.

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13.2 Sensor Maintenance Before cleaning, replacing and maintaining any sensor you must stop the analyser. There are two ways to stop the analyser when it is running a schedule. The first is to connect with the analyser32 software, stop the scheduler and wait for any running schedules to finish. This method may involve quite a wait if the analyser has just started a long duration schedule. This second method may be quicker in that situation. Connect to the analyser with HyperTerminal and go to the Factory Menu. Refer to section 13.1.9 and Figure 13.1.9a. Select A for abort and the abort command will pop-up as in figure 13.2. Issuing this command will stop the current schedule that is running and run a clean-up Figure 13.2: The abort command regime to ensure that the analyser is stopped in a safe condition. At the end of this regime exit HyperTerminal and continue with the maintenance procedures. Do not stop the scheduler by turning the power off as this may leave hazardous chemicals in the area in which you are going to work.
13.2.1 Replacing sensor bodies and electrodes

When replacing sensor bodies (phosphate and turbidity) or electrodes, access to the electronics compartment may be required. If the electronics compartment needs to be accessed, then the power to the Mini-Analyser should be turned off and an anti-static wrist strap must be worn. The wrist strap should be connected to a good earth point on the cabinet or analyser chassis. You will need: Anti-static wrist strap. Small cutters - Ensure these are clean so that foreign objects do not fall on to the circuit boards. Small cable ties.

Procedure: 1. Turn off the power switch at the lower right-hand side of the cabinet. 2. Open the left-hand side of the analyser cabinet. 3. Locate the sensor body to be replaced and remove the retaining screws or remove the electrode from the flow cell. Cut the any cable ties holding the electrode cables together. If replacing the phosphate or turbidity body the cable may not need replacing unless it has failed or is being updated to a newer version. 4. Open the right-hand side of the analyser cabinet. Connect the antistatic wrist strap to your wrist and to the metallic frame of the Mini-Analyser.
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5. Continue to cut the cable ties along the length of the cables to the sensor printed circuit assemblies (PCA). 6. Disconnect the cable of the sensor to be replaced from that sensors PCA. 7. Remove the electrode or body. Fit the new electrode or body and place the end of the cable through the hole to the electronics compartment. 8. Connect the cable to the sensor PCA. Loom the cables together again using cable ties at about 100mm intervals. Remove the wrist strap and close the electronics compartment. 9. Complete the looming of the cables in the left-hand side of the cabinet and close the cabinet. Turn on the power, return the system to normal and run some test schedules to verify that the sensor is serviceable.
13.2.2 DO

The frequency of cleaning necessary for these sensors will depend on nutrient levels in the water being sampled. Some small level of algae growth is normal and will not cause problems but regular cleaning is best to ensure continued good performance. The life of the sensor may vary depending on conditions but should be around 1-2 years. The sensor will normally have to be recalibrated a few times throughout its life as its output range decreases with use. The sensor can be stored in the temperature range 5 to 35C. Removal and replacement procedure: 1. Stop the scheduler and wait for any remaining tests to complete. 2. Open the left-hand side of the analyser cabinet. 3. Locate the DO sensor assembly. The DO sensor assembly is the cylindrical sensor located low down on the outer edge of the left side panel. 4. Carefully unplug the cable connector from the rear of the sensor. 5. Remove the sensor from the flow cell by grasping the smaller section at the upper rear of the assembly, unscrew it counterclockwise and withdraw it from the rear of the flow cell. 6. The silicone O-Ring should also be inspected and if necessary, cleaned or replaced. To remove the O-Ring, remove the two flow-cell mounting screws and tilt the cell so that the O-Ring falls out. 7. If the sensor is to be replaced, omit step 8 and proceed to step 9. 8. Carry out the cleaning procedure detailed below. Figure 13.2.2: DO Sensor

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9. Make sure that the O-Ring is seated in the recess inside the clear front window. Screw the new or cleaned sensor into the back of the flow cell until it just contacts the O-Ring. Tighten a further turn to compress the O-Ring. Reconnect the cable to the rear of the sensor. 10. Close the left-hand side of the analyser cabinet and restore the system to normal operation. Recalibration should be done after cleaning or replacing the DO cell. Cleaning procedure: Note Care must be taken when handling the DO sensor. Do not touch the membrane with any sharp object. If the membrane is damaged the sensor must be replaced.

To clean, carefully remove the electrode from the housing and using a good quality, clean, soft tissue, gently wipe any build up from the sensor tip. Rinse in a small container of de-ionised water. Care must be taken not to rub the electrode against the container as this could damage the membrane. Check the tip for any residual alga or silt and if necessary, repeat the process. Replace the electrode in the housing.

13.2.3 EC

Periodically it will be necessary to clean the EC cell. There are two levels of cleaning depending on the degree of fouling that has occurred: Class 1 Cleaning with Decon detergent and Class 2 Cleaning with hydrochloric acid. Class 2 is used for removing stubborn organic matter from the cell. The EC sensor has a life expectancy of up to 2 years. When replacing it, access to the electronics cabinet is required. Cleaning procedure: 29. Stop the scheduler and wait for any remaining tests to complete. 30. Open the left-hand side of the analyser cabinet. 31. Locate the EC sensor on the left-hand side panel. The sensor is shown here in Figure 13.2.3. 32. Disconnect the tubing from the sensor. Go to Class 1 or Class 2 cleaning instructions.

Figure 13.2.3: EC sensor

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Class 1 cleaning: 1. Connect a 50mL syringe filled with 10:1 water and Decon mixture to the bottom of the sensor. 2. Connect tubing and a waste container to the discharge side of the sensor. 3. Pump the mixture back and forth through the sensor by moving the plunger in and out of the syringe to dislodge any particulate. Remove the syringe with Decon and replace with a syringe filled with DI water and flush the cell thoroughly with the DI water. 4. Reconnect tubing and close the left-hand side panel. Class 2 cleaning: 1. Fill a syringe with 1 Molar Hydrochloric acid and connect to the bottom of the EC cell. Take care not to spill any acid solution while doing this procedure. 2. Fill the EC cell with acid and leave for several hours or overnight if possible. 3. Remove the syringe with acid and replace with a syringe filled with DI water. 4. Flush the cell at least three times using a back and forward motion with the DI water to completely remove any residues. 5. Reconnect tubing and close the left-hand side panel. Replacement procedure: 1. Follow steps 1-3 as for cleaning procedure. Disconnect the tubing from the sensor. 2. Using a spanner or socket driver and screwdriver unscrew the M3 nuts that hold the EC sensor in place. Remove the saddle clamps and black sponge rubber mountings. 3. Follow the procedure 13.2.1 Replacing sensor bodies and electrodes. 4. Fit the black sponge rubber mountings and saddle clamps to the glass sensor body, refit the M3 fasteners and reconnect the tubing to the sensor. 5. Close the left-hand side panel and turn on the power switch. The Mini-Analyser is ready for operation. If recalibration is considered necessary it should be done at this time.

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13.2.4 ORP

The frequency of cleaning necessary for these sensors will depend on nutrient levels in the water being sampled. Some small level of algae growth is normal and will not cause problems but regular cleaning is best to ensure continued good performance. The ORP sensor has an expected life of 1-2 years. Cleaning procedure: 1. 2. 3. Stop the scheduler and wait for any remaining tests to complete. Open the left-hand side of the analyser cabinet and locate the ISE sensor block on the lefthand side panel. The location is shown here in Figure 13.2.4. Loosen the holder capturing the electrode in the flow cell and remove the ORP sensor from the flow through cell. It is usually the bottom sensor in the flow path. Refer to Figure 13.2.4. Gently clean build-up from the sensor tip with a soft tissue. Rinse with DI water. After cleaning, place the electrode back in the flow cell. When refitting the electrode it is necessary to feel that the tip has penetrated the O-Ring seal at the bottom of the holder. Insert the electrode until it has bottomed in the holder and then withdraw it about 1 mm. Tighten the holder with firm finger pressure.

4. 5.

Figure 13.2.4: ISE flowcells

6.

Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable.

Replacement procedure: Follow the procedure 13.2.1 Replacing sensor bodies and electrodes.

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13.2.5 pH

The pH sensor will require cleaning with a frequency dependent on the nature of the water being sampled. Generally this will be about 3 monthly. See the previous section 12.4 to determine if the sensor requires cleaning. The lifespan of the sensor may vary from 6 to 12 months. Cleaning procedure: 1. Stop the scheduler and wait for any remaining tests to complete. 7. 8. Open the left-hand side of the analyser cabinet and locate the ISE sensor block on the lefthand side panel. The location is shown in Figure 13.2.4. Loosen the holder capturing the electrode in the flow cell and remove the pH sensor from the flow through cell. It is usually the upper sensor in the flow path. Refer to Figure 13.2.4.

2. Loosen the holder capturing the electrode in the flow cell and remove the pH sensor from the flow through cell. 3. First clean the electrode by wiping it gently with a soft tissue. Make sure you also clean the electrode flow cell by removing the holder and O-Ring and wiping the cell hole with tissue. Check that there are no pieces of tissue left in the cell. Clean the O-Ring and refit it and the holder to the cell. 4. The pH glass electrode is susceptible to coating by many substances and the speed of response can be dramatically changed. Usually a rinse with methyl alcohol will remove any films and improve the speed of response. Rinse thoroughly with DI water after cleaning with the methyl alcohol. 5. After cleaning, place the electrode back in the flow cell. When refitting the electrode it is necessary to feel that the tip has penetrated the O-Ring seal at the bottom of the holder. Tighten the holder with firm finger pressure. 6. Calibrate the electrode before resuming schedules. Refer to section 13.3.4. 7. Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable. Replacement procedure: Follow the procedure 13.2.1 Replacing sensor bodies and electrodes.

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13.2.6 Turbidity

The turbidity cell has a potentially unlimited lifespan provided it is regularly cleaned and maintained. Care should be taken not to spill any liquids on the sensor body or circuit board when working around the sensor. Liquid spillage on the sensor body could cause corrosion and failure of the electronics. Cleaning procedure: 1. 2. 3. Stop the scheduler and wait for any remaining tests to complete. Open the left-hand side of the analyser cabinet. Locate the turbidity sensor assembly. The turbidity sensor assembly is located on the upper inside corner of the left side panel. Unscrew the small screw on top of the PVC body and lift the flow-cell until it is clear of the body. Invert the cell and remove the tube from the bottom of the cell. Move the cell to the side away from the body and place a container under the cell to capture any liquid and remove the top tube. The cell can now be removed from the MiniAnalyser for cleaning Figure 13.2.6: Turbidity sensor

4.

5.

6. 7. 8. 9.

Gently pull out the O-Ring sealed end caps. Caution is needed here as any sideways pressure on the glass cylinder can cause it to break. Clean the inside and outside of the glass cylinder with a soft tissue. If the cylinder is badly marked or cracked it can be replaced at this time. Clean the end caps and O-Rings. If there is a lot of fouling it may be necessary to remove the O-Rings from the end caps to enable thorough cleaning.

10. Replace the O-Rings on the end caps and refit the end caps to the glass cylinder taking care not to use too much pressure or the glass cell may be broken. 11. Wipe the outside of the glass cell to remove any finger marks. 12. Refit the tubing to the cell and reposition the cell in the PVC body. Replace the screw. 13. Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable. Sensor body replacement procedure: Follow the procedure 13.2.1 Replacing sensor bodies and electrodes.
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13.2.7 Ammonia

The ammonia electrode is located inside the left-hand side of the analyser on the lower outer section of the panel and can be accessed by opening the left-hand side of the analyser cabinet. In general, maintenance on the ammonia sensor takes the form of replacing the membrane and the internal filling solution. This should be done about every 3 months or when the membrane fails. Drift in check values and decreasing sensitivity are signs of membrane failure. Dark spots or discolouration of the membrane are also signs of failure. Note that the entire sensor does not require replacement, unless after a membrane is replaced the sensor does not return to good working order. When changing membranes, avoid excessive handling of the new membrane as this may affect its hydrophobic properties and shorten its life. If the electrode has been stored dry or is new then the inner body should be soaked in the internal filling solution for at least two hours before use. You will need: Replacement membrane Internal filling solution Tweezers Soft tissues

Procedure: 1. Remove the electrode from the flowcell by loosening the retaining clamp on top of the flowcell and withdrawing the electrode. Refer to figure 13.2.7. 2. Unscrew the top cap of the electrode and remove the glass electrode inner body from the electrode outer body. The top cap is located at the end of the electrode where the cable connects. Tip out the internal filling solution. Set cap with inner body aside being very careful with the placement of the glass electrode with the encapsulated outer reference electrode. 3. Unscrew the bottom cap from the electrode outer body, retaining the cap, remove and discard the membrane. 4. Using tweezers, carefully grasp a new white teflon membrane figure 13.2.7: from between the paper separators. Hold the membrane at one Ammonia flowcell narrow end with the tweezers. Care should be taken not to touch or damage the middle part of the membrane during this procedure. 5. Hold the electrode outer body in your free hand with threads between thumb and forefinger.

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6. Place the membrane end against the threads so that the longer side of the membrane is in the same direction as the body. Capture the end of the membrane against the threads with the tip of your thumb. Loosely stretch the membrane lengthwise across the open end of the body using the tweezers. Do not pull tightly as this will change the properties of the membrane. The membrane should now be smoothly stretched across the opening with the ends laying on the threaded section of the body. 7. Gently fold the sides of the membrane over the end of the body and screw the cap on until finger-tight. The membrane should be smooth with no wrinkles. Hold the body with the membrane down and slowly fill with electrode filling solution. If the body is filled too quickly bubbles can be trapped inside. 8. Place the inner body into the outer body containing internal filling solution and screw on the upper cap. Some excess solution will run out of the vent hole. This is normal. 9. Hold the electrode with the membrane down and pull lightly on the cable several times (Sensor is spring loaded.) This helps to ensure that there are no bubbles between the end of the electrode and the membrane. 10. The assembled electrode is now ready to refit to the flow cell. When refitting the electrode it is necessary to feel that the tip has penetrated the O-Ring seal at the bottom of the holder. Tighten the holder with firm finger pressure. 11. Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable. Replacing the electrode: Refer to section 13.2.1 Replacing sensor bodies and electrodes.

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13.2.8 Ammonium

Typically, the ammonium electrode tip requires replacement about 6 monthly. Sensor performance is the biggest factor in determining the replacement period. Signs that the electrode may need replacing include decreasing slope (sensitivity) and drift in check counts. The reference electrode may require replacement about every 12 months. The sensor should be checked to see if cleaning will restore it to good working order before replacing. Cleaning procedure: 1. Locate the ammonium sensor by opening the left-hand side of the analyser cabinet. Refer to figure 13.2.8. The ammonium electrode and associated reference electrode are mounted in a common flow cell pair at the lower outer edge of the panel. The ammonium electrode is the smaller of the 2 electrodes in this position. The other electrode is the reference electrode. The ammonium electrode must always be positioned upstream of the reference electrode. 2. Loosen the holder capturing the electrode in the flow cell and remove the sensor from the flow cell. 3. Clean the electrode by gently wiping the tip with a soft tissue. If necessary, rinse with clean water and wipe clean again. Avoid rough handling as this will damage the membrane. 4. After cleaning, place the electrode back in the flow cell. When refitting the electrode it is necessary to feel that the tip has penetrated the O-Ring seal at the bottom of the holder. Tighten the holder with firm finger pressure. 5. Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable. Replacing the electrode: 1 2 3 4 Follow steps 1-2 as for cleaning procedure. Unscrew the electrode tip and sealing washer from the body. Remove the new tip and washer from the shipping container. Take care not to touch or damage the membrane. Screw the new tip and washer into the body and refit the electrode to the flow cell. When refitting the electrode it is necessary to feel that the tip has penetrated the O-Ring seal at the bottom of the holder. Tighten the holder with firm finger pressure.
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Figure 13.2.8: Ammonium Nitrate and Phosphate sensors

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Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable.

13.2.9 Nitrate

The nitrate electrode life is variable but it should last about 6 months. Sensor performance is the biggest factor in determining the replacement period. Signs that the electrode may need replacing include decreasing slope (sensitivity) and drift in check counts. The reference electrode may require replacement about every 12 months. The sensor should be checked to see if cleaning will restore it to good working order before replacing. Cleaning procedure: 1. Locate the nitrate sensor by opening the left-hand side of the analyser cabinet. Refer to figure 13.2.8. The nitrate electrode and associated reference electrode are mounted in a common flow cell pair in the middle of the panel. The nitrate electrode is the smaller of the 2 electrodes in this position. The other electrode is the reference electrode. The nitrate electrode must always be positioned upstream of the reference electrode. 2. Loosen the holder capturing the electrode in the flow cell and remove the sensor from the flow cell. 3. Clean the electrode by gently wiping the tip with a soft tissue. If necessary, rinse with clean water and wipe clean again. Avoid rough handling as this will damage the membrane. 4. After cleaning, place the electrode back in the flow cell. When refitting the electrode it is necessary to feel that the tip has penetrated the O-Ring seal at the bottom of the holder. Tighten the holder with firm finger pressure. 5. Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable. Replacing the electrode: 1. Follow steps 1-2 as for cleaning procedure. 2. Unscrew the electrode tip and sealing washer from the body. 3. Remove the new tip and washer from the shipping container. Take care not to touch or damage the membrane. 4. Screw the new tip and washer into the body and refit the electrode to the flow cell. When refitting the electrode it is necessary to feel that the tip has penetrated the O-Ring seal at the bottom of the holder. Tighten the holder with firm finger pressure. 5. Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable.

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13.2.10

Reference electrodes.

Reference electrodes are used with both the ammonium and nitrate sensors. Both reference electrodes are of the same type and generally, require little attention. A check and clean on the same frequency as the associated sensor electrode is all that is required. Cleaning procedure: 1. Locate the reference electrode by opening the left-hand side of the analyser cabinet. Refer to figure 13.2.8. The reference electrodes are mounted in the upper position in the flow cells, downstream of their associated ammonium and nitrate sensor electrodes. 2. Loosen the holder capturing the electrode in the flow cell and remove the sensor from the flow cell. 3. Clean the electrode by gently wiping the tip with a soft tissue. Avoid rough handling. 4. After cleaning, place the electrode back in the flow cell. When refitting the electrode it is necessary to feel that the tip has penetrated the O-Ring seal at the bottom of the holder. Tighten the holder with firm finger pressure. 5. Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable. Replacing the electrode: Refer to section 13.2.1 Replacing sensor bodies and electrodes.

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13.2.11

Phosphate

Like the turbidity cell, the phosphate cell has an unlimited life expectancy unless damaged. This assumes regular maintenance is provided.
Warning: Any fluid in the phosphate analyser cell may contain acid. Be prepared to drain contents into a suitable container. Have some disposable tissues available.

Cleaning procedure: 1. Stop the scheduler and wait for any remaining tests to complete. 2. Open the left-hand side of the analyser cabinet. 3. Locate the phosphate sensor assembly. The phosphate sensor assembly is located on the upper inside corner of the left side panel. Refer to figure 13.2.8 4. The glass flow through cell is captured in the PVC detector assembly by a small retaining plate. Remove the screws holding this plate and remove the cell from the PVC body. 5. Note the orientation of the cell and the tubes connected to it. Make a drawing if you need to and mark the cell back. 6. The cell can now be inspected. The middle section of the cell has a clear optical glass window and this should be clean and easy to see through. 7. If the cell appears to be obscured in any way or cloudy to look through it will need to be cleaned. 8. Place a container in the Mini-Analyser to catch any liquid and disconnect the top tube. 9. Invert the cell and remove what is now the top tube. Any liquid will now run into the container and the cell can be removed for cleaning 10. Clean the cell by first injecting it with a Decon detergent solution. Connect a 50mL syringe filled with 10:1 water and detergent mixture to one end of the cell and flush the solution through the cell leaving it filled with the detergent mix. 11. Allow the cell to soak with the detergent for 2 to 12 hours. 12. Rinse the cell with distilled water until there is no detergent residue. 13. If the cell is not clean repeat the process with strong sulfuric acid (5M). The Phosphate reagent 2 may be used for this purpose.
Warning: Phosphate reagent 2 is a strong acid. Caution is required when handling the fluid. Wear rubber gloves, safety glasses and protective clothing. See safety instructions on the fluid container.

14. Rinse thoroughly with distilled water again. 15. Make sure the outside window of the cell is wiped dry and clean with a lint free nonabrasive material.
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16. Reconnect the tubing to the cell and replace the cell in the detector assembly. Refer to the drawing you made earlier if you have doubts about the connections. Make sure that the clear optical glass window is oriented from side to side in the detector body. 17. Replace the retaining plate, ensuring that the cell is seated firmly in the bottom of the housing before tightening the screws and the task is complete. Check that the wires to the assembly were not dislodged during the work. 18. Close the left-hand side of the analyser cabinet, return the system to normal and run some test schedules to verify that the sensor is serviceable. Sensor body replacement procedure: Follow the procedure 13.2.1 Replacing sensor bodies and electrodes.

13.3 Sensor Calibration Before commencing any calibration procedures you must stop the analyser. There are two ways to stop the analyser when it is running a schedule. The first is to connect with the analyser32 software, stop the scheduler and wait for any running schedules to finish. This method may involve quite a wait if the analyser has just started a long duration schedule.

This second method may be quicker in that situation. Connect to the analyser with HyperTerminal and go to the Factory Menu. Refer to section 13.1.9 and Figure 13.1.9a. Select A for abort and the abort command will pop-up as in figure 13.3a.

Issuing this command will stop the current Figure 13.3a: The abort command schedule that is running and run a clean-up regime to ensure that the analyser is stopped in a safe condition. At the end of this regime exit HyperTerminal and continue with the calibration procedures.

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To be able to access the Calibrate screen in the system setup menu a /x switch must be added to the end of the file path in the Target field in the program shortcut. Refer to Figure 13.3b below. At the end of the calibration you should remove the /x if you wish to limit access by your operators. This switch is set in the PC and not the Mini-Analyser so if you are using your own notebook or PC to do this calibration you can leave it set. All calibration standard solutions to be used during the calibration should preferably be at the same temperature as the Mini-Analyser. If possible place them in the same location as the MiniAnalyser cabinet the day before. The internal sensors in the MiniAnalyser are mounted inside the wet chemistry module. The types of sensors can be divided into several groups. The Physical sensors are: Dissolved oxygen (DO). Electrical conductivity (EC). Oxidation-reduction potential (ORP). pH. Temperature. Turbidity. Figure 13.3b: The Analyser32 shortcut

DO, EC and pH measurements are temperature compensated. Other types, classed as ion specific, are: Ammonia / Ammonium. Nitrate.

Phosphate, being colourphotometric, is in a category of its own. The ion specific and phosphate sensors do not need to be calibrated. These sensors are automatically calibrated at the time of measurement using standards in the chemical store. The standards used are standard 1, standard 2 and wash 1. This ensures that any changes in the sensor characteristics are compensated for during each test to produce very repeatable results.
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13.3.1 Dissolved oxygen

You will need: Safety equipment - gloves, lab coat and eye protection. A 250mL HDPE bottle filled with de-ionised water with cap. A teaspoon measure of sodium sulphite. A PC loaded with the Analyser32 user interface software with the /x switch set. Refer to section 13.3. A sample pick-up tube. Tissues.

Procedure: 1. Put on safety equipment - gloves, coat and eye protection. 2. Connect a PC to the Analyser with a serial cable. Start the Analyser32 user interface. 3. Upon successful connection to the Analyser, click the Setup button. 4. Click System Setup, then Calibrate. 5. Select DO Cal from the list of sensors to calibrate. 6. Follow the instructions provided on the screen. You will not be required to do anything for the first part of the calibration as the Mini-Analyser will use the on-board de-ionised water for this step. It will clean tubes then bubble air through de-ionised water in the DO cell. 7. The second part of the calibration requires you to connect a fresh sodium sulphite solution to the calibration inlet port in the wet chemistry area. 8. Open the wet chemistry side panel of the Mini-Analyser. Facing the front of the MiniAnalyser this will be the left-hand side. Remove the cover cap from the calibration inlet port and fit a sample pick-up tube to the port. 9. Place approximately one teaspoon of sodium sulphite powder into a HDPE bottle with 250mL of DI water, cap and shake to dissolve the powder. This will strip the oxygen from the water and create the 0% DO standard. The dosing of the DI with sodium sulphite should be done just before resuming the calibration process as the solution will start absorbing oxygen from the atmosphere immediately. A long delay could affect the calibration result. Place the sample pick-up tube into the bottom of the Sodium Sulphite solution. 10. Click Resume on the user interface.

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11. When the zero DO step is complete remove the sample pick-up tube from the calibration inlet port and click Resume. Refit the cover cap to the port and close the cabinet side. Note - If you are doing more than one calibration leave the cabinet open until all calibrations are completed. Thoroughly rinse the sample pick-up tubing with clean water. Cap and rinse the standard bottles and clean up any spills. 12. At the end of the calibration steps you will be presented with a screen similar to figure 13.3.1. You will need to click Calculate and then Send to Analyser. For the MiniAnalyser to recognise and use this new calibration data in the calculations the MiniAnalyser needs to be reset. To do this, exit the user interface and turn off power to the Mini-Analyser, wait five seconds and turn on power to the Mini-Analyser.

Figure 13.3.1: DO Calibration 13. If you have completed all the calibrations that you are going to do at this time return the system to normal and run some test schedules to verify that the sensor is serviceable.

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13.3.2 Electrical conductivity

You will need: Safety equipment - gloves, lab coat and eye protection. You will require EC calibration standards with conductivities of 500, 1000, 1500 and 2000 S/cm, 100mL of each. The values do not need to be exactly on the mark, 10% variation is ok as long as you do have the laboratory measured normalised value of each standard. To determine the raw or un-normalised EC value of each standard, measure the temperature of the standards and apply the following formula. The raw EC value is the value that is entered into the EC calibrate screen. The temperature of the standards should be measured at the time of calibration and the calculations done at that time. Refer to step 2 in the procedure below. The temperature coefficient of 0.0191 is used when calibrating with KCl standards so if using other conductivity standards then the temperature coefficient for those standards will have to be substituted. Raw EC = normalised EC in S/cm (1+0.0191(temp measured-25)). Example: normalised EC is 2045 temp measured is 20 Raw EC=2045x(1+0.0191x(20-25)) =2045x(1+0.0191x-5) =2045x(1-0.0955) =2045x0.9045 =1849 =Raw EC A PC loaded with the Analyser32 user interface software with the /x switch set. Refer to section 13.3. A sample pick-up tube and tissues.

Procedure: 33. Put on safety equipment - gloves, coat and eye protection. 34. The standards should be placed in the vicinity of the Mini-Analyser cabinet for several hours before the calibration is done so that Mini-Analyser and standards are at the same temperature. 35. Connect a PC to the Analyser with a serial cable. Start the Analyser32 user interface. 36. Upon successful connection to the Mini-Analyser, click the Setup button. 37. Click System Setup, then Calibrate. 38. Select EC from the list of sensors to calibrate. 39. For the first step of the calibration you will not be required to do anything as the MiniAnalyser will use the on-board de-ionised water for this step.

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40. Steps 2-5 of the calibration require you to connect calibration solutions to the calibration inlet port in the wet chemistry area. Open the wet chemistry side panel of the MiniAnalyser. Facing the front of the Mini-Analyser this will be the left-hand side. Remove the cover cap from the calibration inlet port and fit a sample pick-up tube to the port. Connect the standards to this port when instructed to do so by the calibration routine. 41. When the fifth step has finished remove the sample pick-up tube from the calibration inlet port and click Resume. Refit the cover cap to the port and close the cabinet side. Note - If you are doing more than one calibration leave the cabinet open until all calibrations are completed. Thoroughly rinse the sample pick-up tubing with clean water. Cap and rinse the standard bottles and clean up any spills. 42. At the end of the calibration steps you will be presented with a screen similar to figure 13.2.2a. You will need to check that the Poly Order is set to 4 and click Calculate. 43. You may check the curve fit of the polynomial by clicking Graph. Refer to figure 13.2.2b. If the curve is too excessive trying to fit the points then select a Poly Order of 3 and Calculate again. Recheck the Graph. When you have the best fit click Send to Analyser. 44. For the Mini-Analyser to recognise and use this new calibration data in the calculations the MiniAnalyser needs to be reset. To do this, exit the user interface and turn off power to the Mini-Analyser, wait five seconds and turn on power to the Mini-Analyser. 45. If you have completed all the calibrations that you are going to do at this time return the system to normal and run some test schedules to verify that the sensor is serviceable.

Figure 13.2.2a: EC Cal data

Figure 13.2.2b: EC Graph

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13.3.3 Oxidation-reduction potential

You will need: A PC loaded with the Analyser32 user interface software with the /x switch set. Refer to section 13.3. A stable DC voltage source capable of outputting 0 and 800 millivolts. An accurate DC digital voltmeter. A cable from the voltage source terminating with a BNC connector.

The polarity of the voltage from the DC source through the BNC connector is important. It should be positive on the centre pin of the BNC connector. Procedure: 1. Connect to the Mini-Analyser with the PC and the user interface and select Setup, System Setup and Calibrate. This will bring up a selection of sensors to calibrate, select ORP and Calibrate. 2. Open the right-hand side of the Mini-Analyser cabinet. 3. The ORP PCA (printed circuit assembly) is fitted in the lower section of the large motherboard mounted on the cabinet door and is clearly marked ORP on the white surround for the cable BNC connector. 4. Disconnect the ORP sensor from the PCA at the BNC connector. 5. Ensure that the output from the DC source is at 0 volts and connect the BNC connector from the DC source to the PCA. 6. Refer to fig 13.3.3b and note the two boxes under Data Points. Enter 0 in the Current value box and click the Read button below. Figure 13.3.3a: Sensor PCA 7. After a short delay there will be a number appear in motherboard the ADC counts box. This number should be around 31,460. Click Accept and the data will be transferred to the middle column. 8. Adjust the DC source to read 800 mV on the voltmeter and repeat steps 6 and 7 for the 800 mv point. The returned counts should be around 48,200. 9. Remove the DC source cable from the ORP PCA and reconnect the sensor to the PCA. Close the door of the cabinet.

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Select the Precision required, for ORP this will be 0 decimal places. Click on Calculate and a group of coefficients will appear in the coefficients field. Click the Send button to send this calibration to the Mini-Analyser to be stored in the configuration file.

Figure 12.3.3b: ORP Calibration 10. For the Mini-Analyser to recognise and use this new calibration data in the calculations for ORP the Mini-Analyser needs to be reset. To do this, exit the user interface and turn off power to the Mini-Analyser, wait five seconds and turn on power to the Mini-Analyser. 11. The ORP sensor calibration has now been completed and any future tests on the physical parameters will use this new data to calculate the result for ORP.

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13.3.4 pH

You will need: Safety equipment - gloves, lab coat and eye protection. Three calibration standards at values of 4, 7 and 10 pH. Ensure that you have fresh calibration standards. Old or time expired standards can cause incorrect calibration points. A PC loaded with the Analyser32 user interface software with the /x switch set . Refer to section 13.3. A sample pick-up tube. Tissues.

Procedure 1. Put on safety equipment - gloves, overalls or coat and eye protection. 2. The standards should be placed in the vicinity of the Mini-Analyser cabinet for several hours before the calibration is done so that the Mini-Analyser and standards are at the same temperature. 3. Connect a PC to the Analyser with a serial cable. Start the Analyser32 user interface. 4. Upon successful connection to the Mini-Analyser, click the Setup button. 5. Click System Setup, then Calibrate. 6. Select pH Cal from the list of sensors to calibrate. 7. Open the wet chemistry side panel of the Mini-Analyser. Facing the front of the MiniAnalyser this will be the left-hand side. Remove the cover cap from the calibration inlet port and fit a sample pick-up tube to the port. 8. Follow the instructions provided on the screen to complete the calibration. 9. When the pH calibration is complete remove the sample pick-up tube from the calibration inlet port and click Resume. Refit the cover cap to the port and close the cabinet side. Note - If you are doing more than one calibration leave the cabinet open until all calibrations are completed. Thoroughly rinse the sample pick-up tubing with clean water. Cap and rinse the standard bottles and clean up any spills.

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10. At the end of the calibration steps you will be presented with a screen similar to figure 13.3.4. You will need to click Calculate and then Send to Analyser. For the MiniAnalyser to recognise and use this new calibration data in the calculations the MiniAnalyser needs to be reset. To do this, exit the user interface and turn off power to the Mini-Analyser, wait five seconds and turn on power to the Mini-Analyser.

Figure 13.3.4: pH Calibration


13.3.5 Turbidity

You will need: Safety equipment - gloves, lab coat and eye protection. The Mini-Analyser is calibrated using formazin turbidity standards. Three cal points are used for the low range 0 to 100NTU and five points for higher ranges. The MiniAnalyser provides the DI water for Standard 1, 0 NTU. Try to select standards that are equally spaced over the range of the sensor. You will need 100mL of each standard. The values do not need to be exactly on the mark, 10% variation is ok as long as you do have the laboratory measured value of each standard. 0 to 100 NTU fullscale. Standards at 50 and 100 NTU. 0 to 500 NTU fullscale. Standards at 125, 250, 375 and 500 NTU. A PC loaded with the Analyser32 user interface software with the /x switch set. Refer to section 13.3. A sample pick-up tube. Tissues.
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Procedure: Warning: This procedure uses Formazin which is a suspected carcinogen (cancer causing agent) and should be handled with care. Rubber gloves, eye protection and a lab coat should be worn when handling these standards as well as observing safe work practices. 1. Put on safety equipment - gloves, lab coat and eye protection. 2. Connect a PC to the Analyser with a serial cable. Start the Analyser32 user interface. 3. Upon successful connection to the Mini-Analyser, click the Setup button. 4. Click System Setup, then Calibrate. 5. Select turbidity from the list of sensors to calibrate. 6. For the first step of the calibration you will not be required to do anything as the MiniAnalyser will use the on-board de-ionised water for this step. 7. Steps 2-5 of the calibration require you to connect calibration solutions to the calibration inlet port in the wet chemistry area. Open the wet chemistry side panel of the MiniAnalyser. Facing the front of the Mini-Analyser this will be the left-hand side. Remove the cover cap from the calibration inlet port and fit a sample pick-up tube to the port. Connect the standards to this port when instructed to do so by the calibration routine. 8. When the fifth step has finished remove the sample pick-up tube from the calibration inlet port and click Resume. Refit the cover cap to the port and close the cabinet side. Note - If you are doing more than one calibration leave the cabinet open until all calibrations are completed. Thoroughly rinse the sample pick-up tubing with clean water. Cap and rinse the standard bottles and clean up any spills. 9. At the end of the calibration steps you will be presented with a screen similar to figure 13.2.5a. You will need to check that the Poly Order is set to 4 and click Calculate.

Figure 13.2.5a: Turbidity Cal data


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10. You may check the curve fit of the polynomial by clicking Graph. Refer to figure 13.2.5b. If the curve is too excessive trying to fit the points then select a Poly Order of 3 and Calculate again. Recheck the Graph. When you have the best fit click Send to Analyser. 11. For the Mini-Analyser to recognise and use this new calibration data in the calculations for turbidity the Mini-Analyser needs to be reset. To do this, exit the user interface and turn off power to the Mini-Analyser, wait five seconds and turn on power to the Mini-Analyser. 12. If you have completed all the calibrations that you are going to do at this time return the system to normal and run some test schedules to verify that the sensor is serviceable.

Figure 13.2.5b: Turbidity Graph

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13.4 Maintenance Schedule Table 13.4: Mini-Analyser maintenance schedule For the purposes of this table, Inspect is taken to mean either check (as in check and download data) or physically inspect (ie ammonium electrode). Service means to take necessary action (ie clean or repair). Replace means replace or replenish damaged or missing parts. Legend I-inspect S-service R-replace Alarms Ammonia electrode Ammonium electrode Analyser tubing and chemical tubing Batteryleaks and corrosion Cabinet--spills and cleanliness Chemical solution levels DO cell Download and check data EC cell Inlet tubing Memory usage Nitrate electrode PH electrode Pump tubing Run clean regime Sample delivery pipe Sample presentation pot Sample pump intake Turbidity cell Waste container level I I I S I S S S I I I I I S R S R I Time Period Weekly I S I I I S I S I/R Monthly 3 Monthly 6 Monthly

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14 UPGRADING FIRMWARE
There are two methods that can be used to upgrade the firmware in the Mini-Analyser. Both methods are very similar once connected to the Mini-Analyser. The big difference is in the methods of connection and these are: 1. Direct connection, you are on-site and connect to the Mini-Analyser with a serial cable. 2. A dial-up connection, where you connect to the remote Mini-Analyser using a modem. Method 1, direct connect is the recommended procedure to use for upgrading the firmware. While it is possible to upgrade the firmware using a modem connection, this method may not be able to be used in many situations, for example, poor quality or very noisy telephone lines. For this method to be used there are several requirements that need to be met or set up before commencing. These steps will be detailed in section 14.2 Modem connection. 14.1 Direct connection You will need: A PC with a terminal emulation program such as HyperTerminal or Telix. A serial cable. Physical access to the Mini-Analyser. A hex file. This file will contain the new firmware program to be uploaded and will have the file extension .hex.

Procedure: 1. Connect the PC to the Mini-Analyser using the Analyser32 software and stop the scheduler if it is running. Wait for all processes to stop. Step number 2 can be done while you are waiting for this. 2. Retrieve any data not already retrieved from the Mini-Analyser. Reloading firmware will delete the data log. For how to do this see section 10, Downloading Data. 3. Download the configuration file and save it on the PC. See section titled Uploading and Downloading the Configuration in the Analyser32 user manual. The scheduler must be OFF for you to be able to access the Configure firmware menu and do this. 4. Disconnect from the Mini-Analyser with the Analyser32 software but leave the serial cable connected to the Comm port on the Mini-Analyser. 5. Setup and run your terminal emulator program. To setup your terminal program refer to section 13.1.9 steps 1 and 2.

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6. When the terminal program is setup and a connection made with the Mini-Analyser a return string will be displayed on the screen similar to 002.A034Y49NY10491520;. If the string is not displayed type the ctrl-B key sequence this should cause it to appear. This return string may vary with different versions of firmware but will be similar. 7. Refer to section 14.3 Uploading the Firmware and follow the steps detailed there. 14.2 Modem connection. You will need: A PC with a terminal emulation program such as HyperTerminal or Telix. A modem connected to the PC. The remote Mini-Analyser setup with a Zoom 56Kx modem. The Mini-Analyser configuration must be setup to communicate with the modem at 19200 baud and have the correct modem string installed to communicate with the Zoom modem. A reliable telephone line connection to the Mini-Analyser site. Note. If this telephone connection breaks while the file upload is in progress you will have to go to the Mini-Analyser site to recover from the disconnection and complete the uploading of the firmware. A hex file. This file will contain the new firmware program to be uploaded and will have the file extension .hex. You may find it advisable to consult with your Greenspan Technology service agent before you commence this procedure.

Procedure: 1. Connect the PC to the Mini-Analyser by modem using the Analyser32 software and stop the scheduler if it is running. Wait for all processes to stop. Step number 2 can be done while you are waiting for this. 2. Retrieve any data not already retrieved from the Mini-Analyser. Reloading firmware will delete the data log. For how to do this see section 10, Downloading Data. 3. Download the configuration file and save it on the PC. See section titled Uploading and Downloading the Configuration in the Analyser32 user manual. The scheduler must be OFF for you to be able to access the Configure firmware menu and do this. 4. Disconnect from the Mini-Analyser with the Analyser32 software. 5. Setup and run your terminal emulator program. To setup your terminal program refer to section 13.1.9 steps 1 and 2.

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6. When the terminal program is setup and a connection made with the modem, type AT and enter. The modem should return with OK. This indicates that the terminal program and the modem are communicating. Next type ATDTnumber where number is the telephone number of the Mini-Analyser you are dialing and enter. This should then dial the MiniAnalyser. 7. You should hear the modem dial the Mini-Analyser and the modems communicating. In a short while (20 to 30 seconds) the word Connect will appear on the screen. Type the ctrlB key sequence and a return string should be displayed on the screen similar to 002.A034Y49NY10491520;. This return string may vary with different versions of firmware but will be similar. 8. Refer to section 14.3 Uploading the Firmware and follow the steps detailed there. 14.3 Uploading the firmware 1. Press the key sequence *& by pressing SHIFT-8 and SHIFT-7. 2. A menu screen will appear as in Figure 14.3a. Since the commands use upper case characters turn caps lock on.

Figure 14.3a: The Factory Menu. 3. Press L for Program Loader 4. The screen will give a warning message and ask you to type the word LOAD to continue. Type this word to continue. If you do not the program will go back to the main menu. 5. You will then be asked if you wish to erase the configuration. Type Y to erase the configuration. You will then be presented with the program loader screen as in Figure 14.3b.

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Figure 14.3b: The Loader 6. Press 1 to load program. A prompt will appear asking if you want to continue. Press Y to continue. The screen will then ask you to type the word ERASE as in Figure 14.3c. You have a limited time to begin typing (3 sec.) or the program will go back to the previous menu.

Figure 14.3c: Erase Memory 7. The program will prompt you with the question Erase All Blocks ? (Y/N). Type Y. The next screen will ask if you wish to continue. Type Y. You will be presented with the screen in Figure 14.3d prompting for the file upload. Use the send file feature of your terminal emulation program to send the hex file to the Mini-Analyser.

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8. For HyperTerminal, goto the Transfer menu and select Send text file. Select the file path to the location where you have the Hex file stored. You will have to change the type of files you are viewing to All Files to be able to see the Hex file. Select the file and click Open. The file transfer will commence. There will not be any visible signs that the file is uploading unless you are uploading by modem then there will be activity on the Tx data light on the modem.

Figure 14.3d: Upload File 9. For Telix this can be done by pressing Alt-S or the Page Up key. 10. Select ASCII as the file transfer protocol, and enter the name of the file to send. While the file is uploading with Telix you will see a line counter scrolling at the bottom of the Telix window. 11. After a minimum time of about 7 minutes (longer if your modem line may be noisy and have slow data transfer) you will see a comment telling you that the load is complete and to press any key to continue.

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12. The factory boot screen will appear and you need to select 4 as in Figure 14.3e.

Figure 14.3e: The Factory Boot 13. At the prompt type Y to continue. There will be a small delay period and when the process is complete a string of characters similar to 002.A034Y49NY10491520;. will appear. 14. If you have been uploading by modem then the connection will have broken at this point. Reconnect to the Mini-Analyser by typing ATDTnumber where number is the telephone number of the Mini-Analyser and enter. When the modems have completed their handshaking you will see the connect comment. Type the ctrl-B key sequence and the return string should appear. This verifies that the upload was successful and that you can communicate with the Mini-Analyser normally. 15. Exit the terminal emulator program. In Telix, hang up the modem by typing the Alt-H key sequence and then exit by pressing Alt-X key sequence and selecting Yes. 16. Run the Analyser32 program and upload the configuration file. Refer to the Analyser32 user manual, section 22 titled Uploading and Downloading the Configuration. 17. The firmware upgrade is now complete.

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15 TROUBLESHOOTING
15.1 Common Mini-Analyser problems.

Problem Mini-Analyser is started but no tests are performed.

Possible cause One or more reagent levels in the chemical store have dropped to less than 5%. The water ingress alarm has been triggered. The data memory is full

Remedy Replenish reagents and update the chemical store with the user interface software. Verify that the solution levels match the chemical store levels See below. Download all data and clear the memory. Refer to section 9. Identify the cause of the leak. Note: Prior to performing any maintenance on the Mini-Analyser plumbing system, the Mini-Analyser must be chemically decommissioned. Replace tubing. Replace fittings. Replace pump tubes. See Section 13.1.3 Determine if the sensor is damaged or loose in the flow cell and replace or repair as necessary. Check the sample pump and the sample flow path. Test the sample pumping using diagnostics and the assistance of your Greenspan service agent. Clean or check the sensor. Refer to section 11, Checking measurements and sensors. Run the clean regime. Replace the chemicals with fresh solutions. Replace the chemicals with fresh solutions ensuring that they have been mixed correctly. The solution levels in the chemical store do not accurately reflect the bottle levels. Check the solution levels and update the chemical store. Replenish the chemicals Check that the mains power supply / battery charger for the Mini-Analyser is connected and turned ON. Restore power or replace the charger. Refer to section 15.3

Water alarm is triggered.

Typically this is triggered by leakage of fluid within the Mini-Analyser or by ingress of water from outside the MiniAnalyser housing. Tubing leak Fittings leak Pump tube leak Sensor leak

One or more test results are bad.

Loss of sample flow.

Dirty or defective sensor Old or deteriorated chemicals Chemicals not mixed correctly Empty chemical standard or reagent bottle.

The Mini-Analyser stops and no communications are possible Cannot connect to the MiniAnalyser with remote communications

Discharged battery

COMMUNICATIONS PROBLEMS

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15.2 Analyser Problems within the Mini-Analyser

Problem Pump tubing failure Pump failure

Possible cause Santoprene tubing inside the peristaltic pump has fatigued and split. The control cable to the pump has been dislodged during work in the electronics compartment. Pump motor seizes due to failure of the bearings caused by ageing or entry of liquid. Not enough pressure on the pump tubing to pump liquid properly. Blockage in the tubing. Ageing or fatigue of transmission tubing. Santoprene tubing inside a valve has fatigued and split or has crimped permanently closed. Pinch valve seizes due to entry of liquid or dust or failure of solenoid. Plastic fittings joining tubes break. Failure of the seal between a fitting and tube results in ingress of air in intake lines, affecting test results. Reagents or standards have been in service for too long or have reached their expiry date. ISE sensor clamp loose ISE sensor not inserted correctly Split or damaged O-Ring

Remedy Replace the pump tube. Check and refit the cable. Replace entire pump. Set the pump pressures, refer to section 13.1.4, Setting the pump pressure. Identify the area of blockage and replace or flush the tubing with a syringe filled with water. Replace tubing using appropriate tubing type and size. Replace tubing. Replace entire valve and pinch valve tube. Replace the fitting. Determine source of leak. Disassemble and replace fitting and tube. Replace the reagent or standard. Tighten clamp Loosen clamp, push sensor down ensuring that it has seated into the ORing seal and re-tighten the clamp. Loosen clamp and remove the ISE sensor. Remove the clamp and O-Ring, replace the O-Ring, re-fit the clamp and sensor.

The pump is rotating but not pumping liquid. Sample or chemicals are not being pumped even though the pump is working. Liquid transmission tubing failure Pinch valve tubing failure Pinch valve failure Tube fitting failure Air leaks Ageing of reagents and standards Liquid leaking from ISE sensor block

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15.3 Communications Problems


Problem Cannot direct connect. Possible cause Incorrect comm port set in the PC software. Incorrect baud rate set in the PC software. Serial cable not connected. Defective serial cable. Modem power switch set to OFF. DC Voltage cable not plugged into the modem. Analyser remote communications not enabled or no communications time window set up. User interface still direct connected to front panel. Analyser to modem data cable not connected. Modem is not the same type as originally installed. Incompatible initialisation string set in the Analyser. Direct connection has been reconnected. Modem is ON but will not answer the call. Modem powered from the main power and has not had a handshake with the Analyser. Telephone line not connected to the modem. Analyser to modem data cable disconnected since power on. The modem has been powered off and back on again without handshaking with the Analyser. Defective modem. Remedy Check the software connection setup. Refer to the Analyser32 user manual, section 3, Changing the communication and access setup. Connect the serial cable. Replace the serial cable. Check the modem Power switch is ON. Check that the power cable is connected to the modem. Connect with the User Interface and check that the communications system is enabled and a time window is set. Normally 00:00 to 23:59 Exit the User Interface software and remove the direct connect cable Check that the cable is connected. Replace the modem with the correct type or update the Initialisation string to be compatible. Check that the initialisation string is correct and update if necessary. Exit the User Interface software and remove the direct connect cable. Direct connect with the User Interface and then Exit to trigger the modem initialisation. Remove the serial cable. Connect the telephone line to the modem. Reconnect the modem data cable. Direct connect with the User Interface and then Exit to trigger the modem initialisation. Remove the serial cable. Replace the modem with a modem of the same type and model. If the same type is not available contact Greenspan for advice on the selection of a replacement modem. Check that the battery charger is working. The battery is charged, connected to the Mini-Analyser and the Mini-Analyser is turned ON. Check fuses in Mini-Analyser communication interface are not blown. Connect the serial cable. Switch the power to the Mini-Analyser off, wait 5 seconds and turn ON. If software is still not operating, call your Greenspan service agent.

Analyser modem will not power on.

Modem powers ON but then powers OFF.

Modem is ON, answers the call but does not connect with the Analyser. Modem is on, data cable is connected, correct procedures carried out to initialise the modem but it still does not work. Error window Communications timeout is displayed on attempt to direct connect to Mini-Analyser.

Power Supply to Mini-Analyser has failed or is not connected. The Mini-Analyser is not turned on. The serial communications cable is not connected. Software inside Mini-Analyser is not operating.

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Problem Error window Communications timeout. is displayed during a modem connection to the MiniAnalyser. Error window Unable to find modem Error window Unable to dial modem Error window Unable to initialise modem

Possible cause Modem connection failed No phone window is set for MiniAnalyser. Mini-Analyser will not respond to incoming calls. Modem is not powered or connected to computer. Modem is not connected to phone line. Modem setup string is incorrectly set in user interface software.

Remedy Redial the Mini-Analyser. Wait till a preset phone window time and re-attempt connection. If none are set, a site visit is required to set up phone windows. Check modem power supply and connections. Check connection between modem and computer. Check connection between modem and phone line. Check the initialisation string. Refer to section 7.2.1. Setup the correct modem string. If you dont know this, contact your Greenspan Technology service agent Check that the battery is charged, connected to the Mini-Analyser and the Mini-Analyser is turned ON. Check battery charger or solar panel is charging battery. Check fuses in Mini-Analyser communication interface are not blown. Disconnect from the Mini-Analyser and remove the direct connect serial cable. Check the initialisation string. Refer to section 7.2.1. Setup the correct modem string. If you dont know this, contact your Greenspan Technology service agent Check power cable from Mini-Analyser to cell phone is connected. Check continuity of cable using a multimeter. Check cell phone fuse in Mini-Analyser is not blown Set a phone window for desired time using the user interface software. Enable cell phone system in user interface. Switch the power to the Mini-Analyser off, wait 5 seconds and turn ON. If software is still not operating, call your Greenspan service agent. Call your Greenspan service agent.

Cell phone/modem does not operate on site.

Power supply to the Mini-Analyser has failed or is not connected.

A PC on site is direct connected to the Mini-Analyser The initialisation string is not compatible with the modem.

Power supply to cell phone has failed or is not connected.

There is not a cell phone window for the current time. Cell phone has been disabled. Software inside Mini-Analyser is not operating. Electronics failure in Mini-Analyser cabinet. Any possible cause listed in the previous section. Aerial is not connected or is faulty. Aerial is not suitable for cellular area coverage.

Cell phone does not dial out.

Check that aerial is serviceable and is properly connected to the cell phone. Use a suitable aerial.

Remember, if all else fails and you still cannot connect to the Analyser, call your Greenspan Technology service agent or Greenspan direct.

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16 SPECIFICATIONS
16.1 Mechanical Cabinet Dimensions analyser cabinet. WIDTH 365 HEIGHT 425 DEPTH 425

Cabinet Dimensions chemical store. WIDTH 365 16.2 Power Supply Supply voltage: Supply frequency: Power: Charge voltage: Float voltage: Operating temperature range: Lead-Acid gel battery: 16.3 Communications Baud Rate 19,200 bps (downgradeable to 9600). 8 data bits. 1 stop bit. No parity. 16.4 Telephone Modem V.90, V.34 protocols. Error correction. Lightning protection. 16.5 GSM Modem Wavecom GSM.
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HEIGHT 570

DEPTH 425

100-240 VAC. 50 Hz, 60Hz. maximum 40 watts 14.7VDC 13.8VDC -10 to +40 deg C. 12 VDC, 6 AH.

16.6 Operating Environment IP54 protection from dust and water. PARAMETER EXTERNAL TEMPERATURE EXTERNAL RELATIVE HUMIDITY 16.7 Housing Requirements The mini analyser has been designed with as small a footprint as possible. This makes it suitable for mounting on existing desks or bench tops. The analyser can also be wall mounted with an optional wall mounting kit. The larger chemical storage module has been designed to have the analyser installed directly on top. When combined the complete unit may be free standing. It is recommended that it be anchored to some structure to prevent being accidentally knocked over. The location should be protected from direct sun, rain and temperatures below 5 degrees Centigrade. 16.8 Measurement Range PARAMETER TEMPERATURE
PH

RANGE 5 - 40 0 - 90

UNITS C % RH

STANDARD RANGE 0-50 C 2 - 12 0 - 2000 S/cm 0 - 100 NTU 0 - 200 % SATURATION +/- 1000 mV 0.1 14 ppm 0.1 14 ppm 0.1 - 3 ppm 3 - 310 ppb

EXTENDED RANGE

N/A 0 - 5000 S/cm 0 - 500 NTU N/A N/A 0.3 - 30 ppm N/A 0.1 - 15 ppm 0.1 - 2 ppm

EC TURBIDITY DO ORP (REDOX) NITRATE AMMONIUM AMMONIA PHOSPHATE 16.9 Measurement Accuracy

5% of full scale for all measurements.


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16.10 Measurement Times PARAMETER TEST DURATION MINUTES PHYSICALS NITRATE AMMONIUM PHOSPHATE 26 5 8 32 SECONDS 53 24 00 41 INCLUDING CLEAN AND FILL MINUTES 33 11 14 39 SECONDS 27 58 34 15

*Physicals includes EC, DO, pH, ORP & Turbidity. These parameters cannot be tested alone. Physicals test will test all installed sensors in this group. 16.11 Sensor Life SENSOR LIFE (MONTHS) EC 12-24 DO 12-24
PH

ORP 6-12

TURBIDITY
INDEFINITE

6-12

SENSOR LIFE (MONTHS)

NITRATE 6

REFERENCE 12 6

NO3

AMMONIUM

REFERENCE 12
INDEFINITE

NH4+

PHOSPHATE

16.12 External inputs The Mini-Analyser can have up to 8 external 4-20mA sensors connected with full data logging to the Mini-Analyser data store. 16.13 External Outputs Several external outputs are available as standard on the Mini-Analyser to trigger external pumping, a sampler or other devices. Additional external outputs can be configured dependant upon the customer or site requirements. 4 20 mA parameter outputs. Normally 4 but expandable to 8. External output control signals. The analyser can be configured with up to 20 additional 12Vdc outputs for controlling external devices. 16.14 Storage Conditions Must be stored upright, under shelter. If the Mini-Analyser is to be stored unused for any period longer than several weeks contact Greenspan Technology for advice on preparing the analyser and sensors for storage.

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17 SPARE PARTS LIST.

This spare parts list does not detail all parts used in the Greenspan Analysers. Only those that are most likely to be required once a system is installed. For parts that are not detailed here contact your Greenspan Technology service agent.

17.1 Sensors

Sensor ISE Ammonia Gas sensing electrode Sensor ISE Ammonium tip electrode Sensor ISE Nitrate tip electrode Sensor ISE ORP combination electrode Sensor ISE pH combination electrode Sensor ISE Reference assembly Sensor EC flow cell assembly Sensor DO electrode Sensor Phosphate flow cell Sensor Turbidity cell flow through cylinder(pyrex tube) Sensor Analyser temperature flow cell assembly Sensor Water detect assembly Sub assembly EC sensor tubing adapter Sub assembly ISE electrode holder

070-0013 070-0014 070-0002 070-0006 070-0001 570-0003 570-0007 070-0004 070-0009 070-0012 570-0292A 593-0005 571-9105 590-0876

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17.2 Electronics

Hardware electronics Motor 12V DC geared OEM 40W power supply 100-240VAC input 13.8VDC output OEM 15 pin HD to 9 pin D type adapter OEM 3dB Antenna with 4M cable with adapter OEM Battery Valve regulated 12V 6AH OEM Wavecom modem GSM data PCA Analyser sample select interconnect Sub assembly 80C188 Logger board assembly Sub assembly Mini-Analyser connector interface Sub assembly AQ motor controller board Sub assembly EC sensor PCA Sub assembly GLIB motherboard Sub assembly ISE sensor PCA Ammonia Sub assembly ISE sensor PCA Ammonium Sub assembly ISE sensor PCA Chloride Sub assembly ISE sensor PCA Dissolved oxygen Sub assembly ISE sensor PCA Nitrate Sub assembly ISE sensor PCA ORP Sub assembly ISE sensor PCA pH Sub assembly Phosphate sensor PCA Sub assembly Pulse valve controller board assembly Sub assembly Temperature sensor PCA Sub assembly Turbidity sensor PCA

069-0026 087-0111 087-0102 087-0080 069-0237 087-0096 585-0862 585-0800 585-0865 585-0801 585-0805 585-0811 585-0807 585-0807 585-0807 585-0807 585-0807 585-0807 585-0807 085-0806A 585-0820 585-0808 085-0806B

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17.3 Cables

Cable assembly 10way modem connect Cable assembly 40way comms connect Cable assembly 40way sensor connect Cable assembly Analyser/Modem interconnect cable Cable assembly Connector interface input #2 to T1 Cable assembly Debug port assembly Cable assembly DO cable Cable assembly Front user comms Cable assembly IIC data buss Cable assembly Motor control 0 Cable assembly Motor control 1 Cable assembly Phone/Modem power cable Cable assembly Phosphate cable Cable assembly Power A Cable assembly Turbidity cable Cable assembly Valve bank 0 Cable assembly Valve bank 1 Cable assembly Valve bank 2 Cable assembly Valve bank 3

5CB-0021M 5CB-0020M 5CB-0019M 5CC-101-100 5CB-0071 5CB-0037M 5CB-0031 5CB-0017M 5CB-0018M 5CB-0026M 5CB-0027M 5CI-605 5CB-0030 5CB-0028M 5CB-0029 5CB-0022M 5CB-0023M 5CB-0024M 5CB-0025M

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17.4 Plastic parts

BSP elbow BSP to barb Fitting #10-32 to 1.5mm barb Fitting Female luer bulkhead to 1.5mm barb Fitting Female luer bulkhead to 2.5mm barb Fitting Female luer to 1.5mm barb Fitting Kynar lock nut Fitting Kynar lock ring Fitting L connector for 1.5mm tubing Fitting Male luer to -28 UNF thread Fitting Male luer to 1.5mm barb Fitting Male luer to 2.5mm barb Fitting T connector for 1.5mm tubing Fitting Tube to tube connector 1.5 to 1.5mm Fitting Tube to tube connector 1.5 to 2.5mm Fitting Tube to tube connector 1.5 to 4.8mm Fitting Y connector for 1.5mm tubing Machined plastic Ammonia flow cell nut Machined plastic ISE sensor clamp Plastic parts Micro stir bar Tubing 1.5mm ID LDPE natural Tubing High strength silicone 4.8mm ID x 1.6mm wall Tubing PVC 10mm Tubing Santoprene / Pharmed 65 tubing 1.52 ID x 0.84 wall

071-0028 071-0029 071-9097 071-0001 071-0002 071-9079 071-9077 071-9078 071-9095 071-0005 071-9084 071-9085 071-9086 071-9101 071-9104 071-9106 071-9100 090-0866 090-0858 091-0021 071-9082 071-0077 071-9096 071-9092

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17.5 Miscellaneous

Analyser bottle set Cap set for 1 / 2 ltr bottle Cap set for 10 ltr bottle Cap set for 20 ltr bottle Cap set for 5 ltr bottle Electro-mechanical 2 way valve BSP NO 12VDC Gauge 0-60 PSI / 0-400 kPa stainless steel pressure gauge Plastic parts 38mm wedge cap Red Sub assembly Air/water trap assembly (50mm) Sub assembly Water trap assembly (80mm) Sub assembly pump tubing assembly Sub assembly sample/reagent pump 15:1 Sub assembly sample/reagent pump 75:1 Hardware O-Ring BMS5251 Sponge rubber strip 3mm x 27mm

5AQ-BS1 591-0032 591-0034 591-0035 591-0033 097-0007 070-9000 091-0032 590-0877 590-0878 597-9091A 597-1006 597-1004 011-BMS5251 014-0104

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